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1. 发明授权

US5436314A Process for making a polyetherester by insertion of a carboxylic acid into a polyether 失效
标题翻译：通过将羧酸插入聚醚制造聚醚酯的方法
公开(公告)号：US5436314A
公开(公告)日：1995-07-25
申请号：US228845
申请日：1994-04-18
申请人： Lau S. Yang , Jeffrey A. Klang
发明人： Lau S. Yang , Jeffrey A. Klang
IPC分类号： C08G18/42 , C08G63/668 , C08G63/82
CPC分类号： C08G63/668 , C08G18/4252 , C08G63/82
摘要： A process for making polyetheresters is disclosed. A polyether is reacted with a carboxylic acid in the presence of a strong protic acid or a metal salt of a strong protic acid to promote insertion of the carboxylic acid into polyether carbon-oxygen bonds to produce a polyetherester. The polyetheresters are useful for various applications in the polyurethane and unsaturated polyester industries.
摘要翻译：公开了制造聚醚酯的方法。在强质子酸或强质子酸金属盐存在下，使聚醚与羧酸反应，以促进羧酸插入聚醚碳 - 氧键中以产生聚醚酯。聚醚酯可用于聚氨酯和不饱和聚酯工业中的各种应用。

2. 发明授权

US06323281B1 Miscible blends of epoxy-extended polyetherester resins and commercial polymer resins 失效
标题翻译：环氧树脂延伸聚醚酯树脂与商业聚合物树脂的混溶混合物
公开(公告)号：US06323281B1
公开(公告)日：2001-11-27
申请号：US08685365
申请日：1996-07-23
申请人： Lau S. Yang , Gangfeng Cai , Jeffrey M. McFarland , Jeffrey A. Klang
发明人： Lau S. Yang , Gangfeng Cai , Jeffrey M. McFarland , Jeffrey A. Klang
IPC分类号： C08L6702
CPC分类号： C08L67/025 , C08L2666/02
摘要： Miscible blends of epoxy-extended polyetherester resins and commercial polymer resins are disclosed. Thermosets from the resin blends offer high-performance physical properties at a reduced cost compared with that of commercial high-performance resins. The thermosets have improved physical properties, including excellent water resistance, compared with many commercial systems. Resin blends of the invention are readily thickened, and are thus useful for SMC applications.
摘要翻译：公开了环氧树脂延伸的聚醚酯树脂和商业聚合物树脂的混溶混合物。与商业高性能树脂相比，来自树脂混合物的热固性材料以更低的成本提供高性能的物理性能。与许多商业系统相比，热固性材料具有改善的物理性能，包括优异的耐水性。本发明的树脂共混物容易增稠，因此可用于SMC应用。

3. 发明授权

US5952436A Process for making water-resistant polyetherester resins and thermosets 失效
标题翻译：制造防水聚醚酯树脂和热固性材料的方法
公开(公告)号：US5952436A
公开(公告)日：1999-09-14
申请号：US6912
申请日：1998-01-13
申请人： Gangfeng Cai , Jeffrey A. Klang , Lau S. Yang
发明人： Gangfeng Cai , Jeffrey A. Klang , Lau S. Yang
IPC分类号： C08F283/00 , C08F283/01 , C08G18/42 , C08G18/68 , C08G18/79 , C08G63/676 , C08F20/00
CPC分类号： C08G18/4252 , C08F283/006 , C08F283/01 , C08G18/68 , C08G18/797 , C08G63/676
摘要： A general approach to making water-resistant polyetherester resins and thermosets is disclosed. In one aspect, an unsaturated polyetherester resin prepared by inserting a carboxylic acid derivative into a polyether is co-cured with a vinyl monomer and a di- or polyisocyanate to give a water-resistant, thermoset that has excellent dimensional stability, flexibility, and strength properties. Processes for making low-viscosity resins that give thermosets with good water resistance are also described. In one process, an unsaturated polyetherester resin intermediate reacts with a mono-functional isocyanate or fatty alcohol to produce an easy-to-formulate, low-viscosity, low-molecular-weight capped resin.
摘要翻译：公开了制备防水聚醚酯树脂和热固性材料的一般方法。在一个方面，通过将羧酸衍生物插入聚醚制备的不饱和聚醚酯树脂与乙烯基单体和二异氰酸酯或多异氰酸酯共固化，得到具有优异尺寸稳定性，柔韧性和强度的耐水热固性属性。还描述了制备具有良好耐水性的热固性材料的低粘度树脂的方法。在一个方法中，不饱和聚醚酯树脂中间体与单官能异氰酸酯或脂肪醇反应以产生易于配制，低粘度，低分子量的封端树脂。

4. 发明授权

US5569737A Process for making a polyetherester by insertion of a carboxylic acid into a polyether 失效
公开(公告)号：US5569737A
公开(公告)日：1996-10-29
申请号：US419323
申请日：1995-04-10
申请人： Lau S. Yang , Jeffrey A. Klang
发明人： Lau S. Yang , Jeffrey A. Klang
IPC分类号： C08G18/42 , C08G63/668 , C08G63/82
CPC分类号： C08G63/668 , C08G18/4252 , C08G63/82
摘要： A process for making polyetheresters is disclosed. A polyether is reacted with a carboxylic acid in the presence of a strong protic acid or a metal salt of a strong protic acid to promote insertion of the carboxylic acid into polyether carbon-oxygen bonds to produce a polyetherester. The polyetheresters are useful for various applications in the polyurethane and unsaturated polyester industries.

5. 发明授权

US5780558A Process for making dicyclopentadiene polyetherester resins 失效
标题翻译：制备二环戊二烯聚醚酯树脂的方法
公开(公告)号：US5780558A
公开(公告)日：1998-07-14
申请号：US937778
申请日：1997-09-25
申请人： Jeffrey A. Klang , Lau S. Yang
发明人： Jeffrey A. Klang , Lau S. Yang
IPC分类号： C08G63/553 , C08G63/676 , C08G63/78 , C08L67/06 , C08F20/00 , C08G63/42
CPC分类号： C08G63/676 , C08G63/553 , C08L67/06
摘要： A low-cost way to modulate the reactivity and acid number of polyetherester thermoset resins is disclosed. "Beginning" and "end" methods for making dicyclopentadiene (DCPD)-modified polyetherester resins are described. The "beginning" method comprises first heating a polyether, DCPD, a diol, an insertion catalyst, and a carboxylic acid derivative to produce a mixture that contains the polyether and a DCPD-diol diester adduct. Increasing the temperature causes insertion of the DCPD-diol diester into the polyether to give a DCPD polyetherester resin. The "end" method reacts a polyetherester resin made by insertion with DCPD to give a DCPD polyetherester resin. Compared with DCPD polyester resins, those of the invention give more flexible thermosets. Compared with unmodified polyetherester resins, the DCPD polyetherester resins offer formulators more control over curing, which eliminates mold distortion and shrinking or cracking of thermoset parts. Thermosets from blends of the subject resins and DCPD polyester resins show synergistic property improvements compared with thermosets from either resin alone.
摘要翻译：公开了一种低成本调节聚醚酯热固性树脂的反应性和酸值的方法。描述了制备二环戊二烯（DCPD）改性的聚醚酯树脂的“开始”和“结束”方法。 “起始”方法包括首先加热聚醚，DCPD，二醇，插入催化剂和羧酸衍生物，以产生含有聚醚和DCPD-二醇二酯加合物的混合物。增加温度导致将DCPD-二醇二酯插入聚醚中，得到DCPD聚醚酯树脂。 “末端”方法使通过DCPD插入制备的聚醚酯树脂反应得到DCPD聚醚酯树脂。与DCPD聚酯树脂相比，本发明的聚酯树脂具有更多的柔性热固性材料。与未改性的聚醚酯树脂相比，DCPD聚醚酯树脂可使配方设计师更好地控制固化，从而消除热固性部件的模具变形和收缩或开裂。与单独的树脂的热固性材料相比，主题树脂和DCPD聚酯树脂的共混物的热固性显示出协同的性能改进。

6. 发明授权

US5696225A Process for making high-performance polyetherester resins and thermosets 失效
标题翻译：制造高性能聚醚酯树脂和热固性材料的工艺
公开(公告)号：US5696225A
公开(公告)日：1997-12-09
申请号：US608379
申请日：1996-02-28
申请人： Gangfeng Cai , Jeffrey A. Klang , Lau S. Yang
发明人： Gangfeng Cai , Jeffrey A. Klang , Lau S. Yang
IPC分类号： C08G63/668 , C08F283/06 , C08G59/42 , C08G63/676 , C08G63/42
CPC分类号： C08F283/06 , C08G63/676
摘要： A process for making high-performance polyetherester resins and thermosets is disclosed. A polyether polyol reacts with a dicarboxylic acid or anhydride in the presence of an insertion catalyst to produce an acid-terminated polyetherester resin. Reaction of this resin reacts with a primary diol or a diepoxy compound gives a chain-extended polyetherester resin that can be cured with a vinyl monomer to produce a high-performance polyetherester thermoset. Properties of the thermosets rival or exceed those of more expensive high-performance iso and vinyl ester resins.
摘要翻译：公开了制备高性能聚醚酯树脂和热固性材料的方法。在插入催化剂的存在下，聚醚多元醇与二羧酸或酸酐反应，生成酸封端的聚醚酯树脂。该树脂与一次二醇或二环氧化合物的反应得到可用乙烯基单体固化的扩链聚醚酯树脂，以制备高性能聚醚酯热固性树脂。热固性材料的性能与或高于更昂贵的高性能异氰酸酯和乙烯基酯树脂相比。

7. 发明授权

US5612444A Process for making polyetheresters with high aromatic ester content 失效
标题翻译：制备具有高芳香族酯含量的聚醚酯的方法
公开(公告)号：US5612444A
公开(公告)日：1997-03-18
申请号：US412176
申请日：1995-03-28
申请人： Gangfeng Cai , Lau S. Yang , Jeffrey A. Klang
发明人： Gangfeng Cai , Lau S. Yang , Jeffrey A. Klang
IPC分类号： C08G63/66 , C08G63/672 , C08G63/676 , C08G63/78
CPC分类号： C08G63/672 , C08G63/676
摘要： A two-step process for making polyetherester resins is disclosed. A low molecular weight polyol reacts with an aromatic dicarboxylic acid in step one to produce a polyester intermediate. In step two, the polyester intermediate reacts with an anhydride or an aliphatic dicarboxylic acid in the presence of an insertion catalyst to produce a polyetherester resin that contains greater than about 10 wt. % of recurring units derived from the aromatic dicarboxylic acid. The polyetheresters are useful for making thermoset resins with excellent mechanical properties and chemical resistance.
摘要翻译：公开了制造聚醚酯树脂的两步法。在步骤1中，低分子量多元醇与芳族二羧酸反应，生成聚酯中间体。在步骤二中，聚酯中间体在插入催化剂的存在下与酸酐或脂肪族二羧酸反应生成含有大于约10重量％的聚醚酯树脂。衍生自芳族二羧酸的重复单元的百分比。聚醚酯可用于制备具有优异机械性能和耐化学性的热固性树脂。

8. 发明授权

US5610205A Process for making a polyetherester by insertion of a carboxylic acid into a polyether 失效
标题翻译：通过将羧酸插入聚醚制造聚醚酯的方法
公开(公告)号：US5610205A
公开(公告)日：1997-03-11
申请号：US644997
申请日：1996-05-14
申请人： Lau S. Yang , Jeffrey A. Klang
发明人： Lau S. Yang , Jeffrey A. Klang
IPC分类号： C08G18/42 , C08G63/668 , C08G63/82 , C08F2/46 , C08J3/28
CPC分类号： C08G63/668 , C08G18/4252 , C08G63/82
摘要： A process for making polyetheresters is disclosed. A polyether is reacted with a carboxylic acid in the presence of a strong protic acid or a metal salt of a strong protic acid to promote insertion of the carboxylic acid into polyether carbon-oxygen bonds to produce a polyetherester. The polyetheresters are useful for various applications in the polyurethane and unsaturated polyester industries.
摘要翻译：公开了制造聚醚酯的方法。在强质子酸或强质子酸金属盐存在下，使聚醚与羧酸反应，以促进羧酸插入聚醚碳 - 氧键中以产生聚醚酯。聚醚酯可用于聚氨酯和不饱和聚酯工业中的各种应用。

9. 发明授权

US5436313A Process for making a polyetherester 失效
标题翻译：制造聚醚酯的方法
公开(公告)号：US5436313A
公开(公告)日：1995-07-25
申请号：US220149
申请日：1994-03-30
申请人： Jeffrey A. Klang , Lau S. Yang
发明人： Jeffrey A. Klang , Lau S. Yang
IPC分类号： C08G18/42 , C08G63/668 , C08G63/82
CPC分类号： C08G63/82 , C08G18/4252 , C08G63/668
摘要： An improved process for making polyetheresters is disclosed. A polyether is reacted with an anhydride in the presence of a strong protic acid or a metal salt of a strong protic acid in an amount effective to promote insertion of the anhydride into carbon-oxygen bonds of the polyether to produce the polyetherester. Polyetheresters made by the process of the invention are useful in a wide variety of applications, particularly in the polyurethane and unsaturated polyester industries.
摘要翻译：公开了一种制备聚醚酯的改进方法。在强质子酸或强质子酸金属盐存在下，聚醚与酸酐反应，其量有效促进酸酐插入聚醚的碳 - 氧键以产生聚醚酯。通过本发明的方法制备的聚醚酯可用于各种应用，特别是在聚氨酯和不饱和聚酯工业中。

10. 发明授权

US06696521B2 High performance ortho UPR 失效
标题翻译：高性能原位UPR
公开(公告)号：US06696521B2
公开(公告)日：2004-02-24
申请号：US10207256
申请日：2002-07-29
申请人： Lau S. Yang , Paul Malcolm Puckett
发明人： Lau S. Yang , Paul Malcolm Puckett
IPC分类号： C08L6706
CPC分类号： C08G63/54 , C08F283/01
摘要： A high performance UPR (unsaturated polyester resin) is disclosed. The UPR comprises recurring units of phthalic anhydride, 2-methyl-1,3-propanediol, and maleic anhydride. It has a fumarate/maleate ratio 85/15 or greater. It has a bi- or multi-modal molecular weight distribution. A high molecular weight portion of the UPR has a peak molecular weight (Mp) 50,000 or greater. It has a weight average molecular weight (Mw) 15,000 or greater. An ortho UPR of the invention performs as well as or better than traditional iso UPR.
摘要翻译：公开了一种高性能UPR（不饱和聚酯树脂）。 UPR包括邻苯二甲酸酐，2-甲基-1,3-丙二醇和马来酸酐的重复单元。富马酸盐/马来酸盐比率为85/15或更高。它具有双分子或多峰分子量分布。 UPR的高分子量部分的峰值分子量（Mp）为50,000或更大。其重均分子量（Mw）为15,000以上。本发明的邻位UPR与传统的等级UPR相同或更好。

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