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    • 4. 发明授权
    • Continuous manufacture of silicone copolymers via multi-stage blade-mixed plug flow tubular reactor
    • 通过多级叶片混合塞流式管式反应器连续制造硅氧烷共聚物
    • US06897280B2
    • 2005-05-24
    • US10253263
    • 2002-09-23
    • Ladislau HeislerDavid D. FarrisDavid B. DavisPaul E. Austin
    • Ladislau HeislerDavid D. FarrisDavid B. DavisPaul E. Austin
    • C10J3/50C08G77/08
    • C08G77/06C08G77/46C10J3/50C10J2200/09C10J2200/152
    • A process is disclosed for producing silicone copolymers, wherein the process comprises the steps of: (a) providing at least one multi-stage blade-mixed plug flow reactor having an entry and an exit; (b) continuously feeding (i) hydrogen siloxane, (ii) olefinically substituted polyether or olefin capable of reacting with said hydrogen siloxane, and (iii) catalyst for the reaction to the entry of the multi-stage blade-mixed plug flow reactor, and (c) continuously withdrawing from the exit of the multi-stage blade-mixed plug flow reactor a stream that comprises silicone copolymer and is substantially free of unreacted hydrogen siloxane, provided that said hydrogen siloxane and said polyether or olefin have a residence time at reaction temperature in the multi-stage blade-mixed plug flow reactor sufficient to effect substantially complete hydrosilation.
    • 公开了一种用于生产硅氧烷共聚物的方法,其中该方法包括以下步骤:(a)提供具有入口和出口的至少一个多级叶片混合活塞式流动反应器; (b)连续进料(i)氢硅氧烷,(ii)能够与所述氢硅氧烷反应的烯属取代的聚醚或烯烃,和(iii)用于与多级叶片混合活塞式流动反应器进入的反应的催化剂, 并且(c)从多级叶片混合活塞式流动反应器的出口连续地抽出包含硅氧烷共聚物并且基本上不含未反应的氢硅氧烷的流,条件是所述氢硅氧烷和所述聚醚或烯烃在 多级叶片混合活塞式流动反应器中的反应温度足以实现基本上完全的硅氢化。