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    • 1. 发明申请
    • COMBINATIONS OF FLUORINATED SOLVENTS WITH IMIDE SALTS OR METHIDE SALTS FOR ELECTROLYTES
    • 氟化溶剂与电解质的二氧化硅沉淀物的组合
    • US20130337340A1
    • 2013-12-19
    • US13910105
    • 2013-06-04
    • Leyden Energy, Inc.
    • Konstantin TikhonovKa Ki YipTzu-Yuan LinNorman LeiGuillermo Guerrero-ZavalaKristie W. Kwong
    • H01M10/0569H01M10/0568H01M10/0567
    • H01M10/0569H01M10/052H01M10/0525H01M10/0567H01M10/0568H01M2300/0034H01M2300/0037Y02E60/122
    • Provided are electrochemical cells and electrolytes used to build such cells. The electrolytes include imide salts and/or methide salts as well as fluorinated solvents capable of maintaining single phase solutions at between about −30° C. to about 80° C. The fluorinated solvents, such as fluorinated carbonates, fluorinated esters, and fluorinated esters, are less flammable than their non-fluorinated counterparts and improve safety characteristics of cells containing these solvents. The amount of fluorinated solvents in electrolytes may be between about 30% and 80% by weight not accounting weight of the salts. Linear and cyclic imide salts, such as LiN(SO2CF2CF3)2, and LiN(SO2CF3)2, as well as methide salts, such as LiC(SO2CF3)3 and LiC(SO2CF2CF3)3, may be used in these electrolytes. Fluorinated alkyl groups enhance solubility of these salts in the fluorinated solvents. In some embodiments, the electrolyte may also include a flame retardant, such as a phosphazene, and/or one or more ionic liquids.
    • 提供用于构建这种电池的电化学电池和电解质。 电解质包括酰亚胺盐和/或甲基化物盐以及能够将单相溶液保持在约-30℃至约80℃之间的氟化溶剂。氟化溶剂如氟化碳酸酯,氟化酯和氟化酯 ,比其非氟化对应物更易燃,并提高含有这些溶剂的电池的安全性。 电解质中氟化溶剂的量可以在约30%至80%(重量)之间,不占盐重量。 线性和环状酰亚胺盐如LiN(SO2CF2CF3)2和LiN(SO2CF3)2以及甲基化物盐如LiC(SO2CF3)3和LiC(SO2CF2CF3)3可用于这些电解质中。 氟化烷基增强这些盐在氟化溶剂中的溶解度。 在一些实施方案中,电解质还可以包括阻燃剂,例如磷腈,和/或一种或多种离子液体。
    • 3. 发明申请
    • CELL ASSEMBLIES WITH NEUTRAL CASES
    • 电池组件与中性病例
    • US20130236757A1
    • 2013-09-12
    • US13787704
    • 2013-03-06
    • LEYDEN ENERGY
    • Konstantin TikhonovHashmatullah HaidariNorman Lei
    • H01M2/02
    • H01M2/0257H01M2/0287H01M2/0413H01M2/046H01M2/0491H01M4/485H01M10/0445H01M10/052H01M10/0587Y10T29/4911
    • Provided are electrochemical cell assemblies and methods of fabricating thereof. A cell assembly includes an anode containing lithium titanium oxide and a cathode forming a jellyroll together with the anode. Each of the electrodes is connected to a separate cap and electrically insulated from the case. As such, the case is electrochemically neutral and may be made from a larger selection of materials. For example, a case may be made from steel that would otherwise dissolve if exposed to the anode potential during cycling of the battery. Some of these case materials simplify processing and sealing characteristics. In certain embodiments, a case may be crimped around each of the caps and corresponding gaskets to provide sealing interfaces. The caps or at least their surfaces exposed to the electrolyte are made from materials that are electrochemically stable at corresponding potentials of the electrodes.
    • 提供电化学电池组件及其制造方法。 电池组件包括含有锂二氧化钛的阳极和与阳极一起形成果冻胶的阴极。 每个电极连接到单独的盖并与壳体电绝缘。 因此,这种情况是电化学中性的,并且可以由更多的材料选择制成。 例如,可以由钢制成,否则如果在电池循环期间暴露于阳极电位,则可以溶解。 这些壳体材料中的一些简化了加工和密封特性。 在某些实施例中,壳体可以卷绕在每个盖和相应的垫圈周围以提供密封界面。 盖或其至少暴露于电解质的表面由在电极的相应电位下电化学稳定的材料制成。