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1. 发明授权

US5549843A Annealed alkaline earth metal fluorohalide storage phosphor, preparation method, and radiation image storage panel 失效
标题翻译：退火碱土金属氟卤化物储存荧光粉，制备方法和放射图像存储面板
公开(公告)号：US5549843A
公开(公告)日：1996-08-27
申请号：US342975
申请日：1991-11-21
申请人： Kyle E. Smith , Joseph F. Bringley , Patrick M. Lambert , David P. Trauernicht , Philip S. Bryan , Paul M. Hoderlein , Andrea M. Hyde
发明人： Kyle E. Smith , Joseph F. Bringley , Patrick M. Lambert , David P. Trauernicht , Philip S. Bryan , Paul M. Hoderlein , Andrea M. Hyde
IPC分类号： C09K11/77 , G21K4/00 , C09K11/61
CPC分类号： C09K11/7768 , C09K11/7717 , C09K11/7718 , C09K11/772 , C09K11/7721 , C09K11/773 , C09K11/7731 , C09K11/7733 , C09K11/7734 , C09K11/7745 , C09K11/7746 , C09K11/7748 , C09K11/7749 , C09K11/776 , C09K11/7761 , C09K11/7763 , C09K11/7764 , C09K11/7767 , C09K11/7773 , C09K11/7774 , C09K11/7785 , C09K11/7786 , C09K11/7791 , C09K11/7792 , G21K4/00 , G21K2004/06
摘要： A method, a storage phosphor prepared by the method, and a storage panel. In the method, a precursor mixture is fired, at a temperature between 700.degree. C. and the melting point of the phosphor, to produce an intermediate product. The precursor mixture comprises a combination of species characterized by the relationship:MFX.sub.1-x I.sub.z.uM.sup.a X.sup.a :yA:eQwherein M is selected from Mg, Ca, Sr and Ba; X is selected from Cl and Br; M.sup.a is selected from Na, K, Rb and Cs; X.sup.a is selected from F, Cl, Br and I; A is selected from Eu, Ce, Sm, and Tb; Q is metal oxide; and 0
摘要翻译：一种方法，通过该方法制备的存储荧光体和存储面板。在该方法中，将前体混合物在700℃至荧光体的熔点之间的温度下焙烧以产生中间产物。前体混合物包括以下关系特征的物质的组合：MFX1-xIz.uMaXa：yA：eQ其中M选自Mg，Ca，Sr和Ba; X选自Cl和Br; Ma选自Na，K，Rb和Cs; Xa选自F，Cl，Br和I; A选自Eu，Ce，Sm和Tb; Q是金属氧化物; 和0

2. 发明授权

US5464568A Alkaline earth metal fluorobromoiodide storage phosphor, and radiation image storage panel, and method 失效
标题翻译：碱土金属氟溴碘化物储存荧光体和辐射图像存储面板及方法
公开(公告)号：US5464568A
公开(公告)日：1995-11-07
申请号：US300116
申请日：1994-09-02
申请人： Joseph F. Bringley , Philip S. Bryan , Andrea M. Hyde
发明人： Joseph F. Bringley , Philip S. Bryan , Andrea M. Hyde
IPC分类号： C09K11/02 , C09K11/77 , G21K4/00 , C09K11/61
CPC分类号： G21K4/00 , C09K11/025 , C09K11/772 , C09K11/7733 , C09K11/7748 , C09K11/7763 , G21K2004/06
摘要： A radiation image storage phosphor; a composition of matter including the storage phosphor and a stabilizer for iodine; and a radiation image storage panel including the inventive phosphor. The storage phosphor has a combination of species characterized by the relationship:(Ba.sub.1-a-b-c Mg.sub.a Ca.sub.b Sr.sub.c)FBr.sub.1-z I.sub.z.rKX:yA:eQ:tDwhere X is selected from the group consisting of F, Cl, Br, and I; A is selected from the group consisting of Eu, Ce, Sm, and Tb; Q is selected from the group consisting of BeO, MgO, CaO, SrO, BaO, ZnO, Al.sub.2 O.sub.3, La.sub.2 O.sub.3, In.sub.2 O.sub.3, SiO.sub.2, TiO.sub.2, ZrO.sub.2, GeO.sub.2, SnO.sub.2, Nb.sub.2 O.sub.5, Ta.sub.2 O.sub.5, and ThO.sub.2 ; D is selected from the group consisting of V, Cr, Mn, Fe, Co, and Ni; a+b+c is from 0 to 0.4; z is from 1.times.10.sup.-4 to 1; r is from 10.sup.-6 to 0.1; y is from 1.times.10.sup.-4 to 0.1; e is from 10.sup.-5 to 0.1; and t is from 0 to 10.sup.-2.
摘要翻译：放射线图像存储荧光体; 包括存储磷光体和碘稳定剂的物质组成; 以及包括本发明的荧光体的辐射图像存储面板。存储荧光体具有以下关系的特征的组合：（Ba1-a-b-cMgaCabSrc）FBr1-zIz.rKX：yA：eQ：tD其中X选自F，Cl，Br和I; A选自Eu，Ce，Sm和Tb; Q选自BeO，MgO，CaO，SrO，BaO，ZnO，Al2O3，La2O3，In2O3，SiO2，TiO2，ZrO2，GeO2，SnO2，Nb2O5，Ta2O5和ThO2; D选自V，Cr，Mn，Fe，Co和Ni; a + b + c为0〜0.4; z为1×10 -4〜1; r为10-6至0.1; y为1×10 -4〜0.1; e为10-5至0.1; t为0〜10-2。

3. 发明授权

US5507976A Stabilized phosphor intermediates, storage phosphors, radiation image storage panels, and preparation methods 失效
标题翻译：稳定磷光体中间体，储存荧光体，辐射图像存储面板及其制备方法
公开(公告)号：US5507976A
公开(公告)日：1996-04-16
申请号：US300113
申请日：1994-09-02
申请人： Joseph F. Bringley , Philip S. Bryan , Andrea M. Hyde
发明人： Joseph F. Bringley , Philip S. Bryan , Andrea M. Hyde
IPC分类号： C09K11/77 , G21K4/00 , C09K11/61
CPC分类号： G21K4/00 , C09K11/772 , C09K11/7722 , C09K11/7733 , C09K11/7736 , C09K11/7748 , C09K11/7751 , C09K11/7763 , C09K11/7765 , G21K2004/06
摘要： A radiographic image storage phosphor, stabilized intermediate, and methods for preparing storage phosphor, and stabilized intermediate. The storage phosphor is the product of firing a combination of species characterized by the relationship:MFX.sub.1-z I.sub.z.uM.sup.a X.sup.a :yA:eQ:tDwherein M is selected from Mg, Ca, Sr, and Ba; X is selected from Cl and Br; M.sup.a is selected from Na, K, Rb, and Cs; X.sup.a is selected from F, Cl, Br, and I; A is selected from Eu, Ce, Sm, and Tb; Q is selected from BeO, MgO, CaO, SrO, BaO, ZnO, Al.sub.2 O.sub.3, La.sub.2 O.sub.3, In.sub.2 O.sub.3, SiO.sub.2, TiO.sub.2, ZrO.sub.2, GeO.sub.2, SnO.sub.2, Nb.sub.2 O.sub.5, Ta.sub.2 O.sub.5, and ThO.sub.2 ; D is selected from V, Cr, Mn, Fe, Co, and Ni; z is from 1 .times.10.sup.-4 to 1; u is from 0 to 1; y is from 1.times.10.sup.-4 to 0.1; e is from 0 to 1; and t is from 0 to 10.sup.-2 ; and oxosulfur reducing agent for iodine, which is present in an amount sufficient to increase relative photostimulated luminescence intensities relative to the phosphor defined above absent the reducing agent for iodine.
摘要翻译：放射线照相图像存储磷光体，稳定化中间体，以及制备储存磷光体的方法和稳定的中间体。存储磷光体是以下述关系进行燃烧的物质的组合的产物：MFX1-zIz.uMaXa：yA：eQ：tD其中M选自Mg，Ca，Sr和Ba; X选自Cl和Br; Ma选自Na，K，Rb和Cs; Xa选自F，Cl，Br和I; A选自Eu，Ce，Sm和Tb; Q选自BeO，MgO，CaO，SrO，BaO，ZnO，Al2O3，La2O3，In2O3，SiO2，TiO2，ZrO2，GeO2，SnO2，Nb2O5，Ta2O5和ThO2; D选自V，Cr，Mn，Fe，Co和Ni; z为1×10 -4〜1; 你是从0到1; y为1×10 -4〜0.1; e为0〜1; t为0〜10-2; 和碘的氧化硫还原剂，其存在的量足以相对于不存在碘的还原剂而相对于上述荧光体增加相对光刺激的发光强度。

4. 发明授权

US5427868A Radiographic phosphor panel having binder compatible oxosulfur stabilizer and method for preparing phosphor panel 失效
标题翻译：具有粘合剂相容的氧硫稳定剂的射线荧光体面板和制备荧光体面板的方法
公开(公告)号：US5427868A
公开(公告)日：1995-06-27
申请号：US157796
申请日：1993-11-24
申请人： Joseph F. Bringley , Barbara J. Fisher , Andrea M. Hyde , Philip S. Bryan , Luther C. Roberts
发明人： Joseph F. Bringley , Barbara J. Fisher , Andrea M. Hyde , Philip S. Bryan , Luther C. Roberts
IPC分类号： G01N21/62 , C09K11/02 , C09K11/61 , C09K11/77 , G01T1/29 , G03B42/02 , G21K4/00
CPC分类号： G21K4/00 , C09K11/025 , C09K11/772 , C09K11/7733 , C09K11/7748 , C09K11/7763 , C09K11/7773 , C09K11/7791 , G21K2004/06 , G21K2004/08 , G21K2004/10 , G21K2004/12
摘要： A radiographic phosphor panel having binder compatible oxosulfur stabilizer and a preparation method. The phosphor panel has a support and a luminescent layer overlaying the support. The luminescent layer includes phosphor crystals, binder and an oxosulfur reducing agent. The oxosulfur reducing agent is dispersed within the luminescent layer on a substantially molecular basis. The oxosulfur reducing agent is a reducing agent for iodine. The oxosulfur reducing agent has a concentration sufficient to substantially increase the photostimulated luminescence of the panel.
摘要翻译：一种具有粘合剂相容性硫氧化物稳定剂的射线荧光体面板及其制备方法。荧光体面板具有覆盖支撑体的支撑体和发光层。发光层包括磷光体晶体，粘合剂和氧化硫还原剂。氧化硫还原剂基本上分子量分散在发光层内。氧化硫还原剂是碘的还原剂。氧化硫还原剂具有足以显着增加面板的光刺激发光的浓度。

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