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1. 发明授权

US4185023A Catalytic oxidative process for the manufacture of anthraquinone from o-benzyl toluene 失效
标题翻译：用于由邻 - 苄基甲苯制备蒽醌的催化氧化方法
公开(公告)号：US4185023A
公开(公告)日：1980-01-22
申请号：US8387
申请日：1979-02-01
申请人： Kurt Handrick , Georg Kolling , Clemens Linden , Gunter Droll, Jr.
发明人： Kurt Handrick , Georg Kolling , Clemens Linden , Gunter Droll, Jr.
IPC分类号： B01J31/00 , C07B61/00 , C07C45/00 , C07C46/02 , C07C50/18 , C07C51/265 , C07C67/00 , C07C49/68 , C09B1/00
CPC分类号： C07C46/02 , C07C51/265
摘要： A process for the manufacture of anthraquinone, in which o-benzyl-toluene is oxidized with air or an oxygen-containing gas in an acetic acid solution in the presence of cobalt, manganese and bromine salts as catalysts, to which solution sufficient acetic anhydride is added to bind the reaction water, thereby keeping the acid concentration constant. The crude o-benzoyl-benzoic acid is then esterified with methanol, the methyl ester distilled from the reaction mixture and heated with concentrated sulfuric acid to yield anthraquinone in good yield and of a high degree of purity.
摘要翻译：在钴，锰和溴盐作为催化剂的存在下，用邻苯二甲酸甲酯在乙酸溶液中用空气或含氧气体氧化的蒽醌的方法，足够的乙酸酐为加入以结合反应水，从而保持酸浓度恒定。然后将粗的邻苯甲酰基 - 苯甲酸用甲醇酯化，将甲酯从反应混合物中蒸馏出并用浓硫酸加热，得到高产率和高纯度的蒽醌。

2. 发明授权

US4185024A Nitric acid process for the manufacture of anthraquinone from o-benzyl-toluene 失效
标题翻译：用于从邻 - 甲苯甲苯制备蒽醌的硝酸方法
公开(公告)号：US4185024A
公开(公告)日：1980-01-22
申请号：US8388
申请日：1979-02-01
申请人： Kurt Handrick , Georg Kolling , Clemens Linden
发明人： Kurt Handrick , Georg Kolling , Clemens Linden
IPC分类号： B01J31/00 , C07B61/00 , C07C45/00 , C07C46/02 , C07C50/18 , C07C51/265 , C07C67/00 , C07C49/68 , C09B1/00
CPC分类号： C07C46/02 , C07C51/265
摘要： A process for the manufacture of anthraquinones in which o-benzyl-toluene is first oxidized with 25 to 50 weight-% nitric acid at atmospheric pressure and moderate temperatures, and then further oxidized with a more dilute nitric acid at elevated temperatures and pressures to yield crude o-benzoyl-benzoic acid. The crude product is then esterified with methanol, the methyl ester distilled and, when necessary, recrystallized, and heated with concentrated sulfuric acid to yield anthraquinone in high yield and of a high degree of purity.
摘要翻译：一种制备蒽醌的方法，其中邻甲苯甲苯首先在大气压和中等温度下用25至50重量％的硝酸氧化，然后在较高的温度和压力下用更稀硝酸进一步氧化，得到粗苯甲酰苯甲酸。然后将粗产物用甲醇酯化，蒸馏甲酯，必要时重结晶，并用浓硫酸加热，以高产率和高纯度得到蒽醌。

3. 发明授权

US4243590A Process for making indole 失效
标题翻译：制造吲哚的方法
公开(公告)号：US4243590A
公开(公告)日：1981-01-06
申请号：US41516
申请日：1979-05-22
申请人： Kurt Handrick , Georg Kolling
发明人： Kurt Handrick , Georg Kolling
IPC分类号： C07D209/08
CPC分类号： C07D209/08
摘要： Process for making indole by subjecting 1,2,3,4-tetrahydroquinoline to a thermal decomposition at a reaction temperature of about 650.degree. to 750.degree. C. in a reactor filled with a substantially inert material and in the presence of steam. The starting product for this process is easily available and can easily be obtained by chemical reaction and the process itself has a high yield.
摘要翻译：在约650℃至750℃的反应温度下，在充满基本上惰性的物质的反应器中并在蒸汽存在下，使1,2,3,4-四氢喹啉进行热分解，制备吲哚的方法。该方法的起始产物易于获得，并且可以通过化学反应容易地获得，并且该方法本身具有高产率。

4. 发明授权

US4357450A Method for the production of hydrocarbon resins 失效
标题翻译：生产烃树脂的方法
公开(公告)号：US4357450A
公开(公告)日：1982-11-02
申请号：US254383
申请日：1981-04-15
申请人： Kurt Handrick , Georg Kolling
发明人： Kurt Handrick , Georg Kolling
IPC分类号： C08F4/00 , C08F2/00 , C08F4/06 , C08F240/00 , C08F110/00
CPC分类号： C08F240/00
摘要： In a method for the production of hydrocarbon resins based upon pyrolysates through cationic polymerization of the pyrolyzate in the presence of Friedel-Crafts catalysts and solvents at temperatures between -40.degree. and +60.degree. C., tetralin and/or tetralin derivatives are pyrolysed at 660.degree.-710.degree. C., preferably at 675.degree.-690.degree. C., in the presence of 1-10 mol, preferably 3-7 mol, vaporous water per mole tetralin or tetralin derivative with a dwell time of 1-2 seconds; the pyrolyzate is distilled to free it of high boiling (tarry) portions; and the unsaturated compounds contained in the distillate are polymerized in known manner. Styrene formed during the pyrolysis is preferably removed through distillation before the polymerization. The hydrocarbon mixture regenerated with the separation of the resins formed through polymerization are hydrogenated to tetralin and/or tetralin derivatives and again pyrolyzed.
摘要翻译：在-40〜+ 60℃的温度下，在Friedel-Crafts催化剂和溶剂存在下通过热解物的阳离子聚合制备基于热解物的烃类树脂的方法，四氢化萘和/或四氢化萘衍生物在 660℃-710℃，优选675℃-690℃，在1-10摩尔，优选3-7摩尔蒸气水/摩尔四氢化萘或四氢化萘衍生物存在下，停留时间为1-2秒 ; 将热解物蒸馏以使其沸腾（焦油）部分释放; 馏出物中所含的不饱和化合物以已知的方式聚合。在热解过程中形成的苯乙烯优选在聚合之前通过蒸馏除去。通过聚合形成的树脂分离再生的烃混合物被氢化成四氢化萘和/或四氢化萘衍生物，并再次热解。

5. 发明授权

US4440957A Preparation of .beta.-isopropylnaphthalene 失效
标题翻译：制备β-异丙基萘
公开(公告)号：US4440957A
公开(公告)日：1984-04-03
申请号：US289525
申请日：1981-08-03
申请人： Kurt Handrick , Georg Kolling , Paul Kiedel
发明人： Kurt Handrick , Georg Kolling , Paul Kiedel
IPC分类号： C07C2/66 , C07C1/00 , C07C2/70 , C07C5/22 , C07C5/27 , C07C15/24 , C07C67/00 , C07C2/68
CPC分类号： C07C15/24 , C07C2/70 , C07C5/2745 , C07C2521/08 , C07C2527/173
摘要： Process of preparing .beta.-isopropylnaphthalene substantially free of corresponding .alpha.-isomer, in yields amounting to 90% and more by a continuous two-stage process comprising (1) alkylating naphthalene with propylene at a temperature of about 150.degree.-280.degree. C. under a pressure of 5 to 30 atm in the presence of a phosphoric acid catalyst supported on a SiO.sub.2 carrier and using a mol ratio of 1/5 to 1/20 mol propylene to 1 mol naphthalene to isopropylate 45 to 65% of the naphthalene and form a mixture of .alpha.- and .beta.-isopropylnaphthalene and then without separating off the unreacted naphthalene, (2) heating the isomeric mixture from stage (1) in the presence of a phosphoric acid catalyst supported on SiO.sub.2, to a temperature of 180.degree.-280.degree. C. under an inert gas pressure of 5 to 30 atm until no further .beta.-isopropylnaphthalene is formed and recovering said .beta.-isopropylnaphthalene from the isomerization mixture.
摘要翻译：通过连续两步法制备基本上不含相应α-异构体的β-异丙基萘的方法，其收率为90％以上，其包括（1）在约150℃-280℃的温度下将萘与丙烯烷基化，在负载在SiO 2载体上的磷酸催化剂存在下，使用5〜30atm的压力，使用1/5〜1/20摩尔丙烯与1摩尔萘的摩尔比，将45〜65％的萘异丙酯化，形成 α和β-异丙基萘的混合物，然后不分离出未反应的萘，（2）在负载在SiO 2上的磷酸催化剂存在下，将阶段（1）的异构体混合物加热至180-280℃ 在5至30atm的惰性气体压力下进行，直至不再形成β-异丙基萘，并从异构化混合物回收所述β-异丙基萘。

6. 发明授权

US4384152A Anthracene production from phenanthrene 失效
标题翻译：蒽从菲生产
公开(公告)号：US4384152A
公开(公告)日：1983-05-17
申请号：US218000
申请日：1980-12-18
申请人： Kurt Handrick , Georg Kolling , Fritz Mensch
发明人： Kurt Handrick , Georg Kolling , Fritz Mensch
IPC分类号： C07C1/00 , C07C5/11 , C07C5/27 , C07C5/32 , C07C5/367 , C07C13/58 , C07C15/28 , C07C67/00 , C07C2/00 , C07C4/00
CPC分类号： C07C15/28 , C07C5/11 , C07C5/2721 , C07C5/367 , C07C2103/24 , C07C2103/26 , C07C2521/04 , C07C2523/26 , C07C2523/755 , C07C2527/126 , Y10S194/906
摘要： A method for production of anthracene from phenanthrene is disclosed. Phenanthrene is hydrogenated at a nickel on a carrier catalyst at temperatures from about 140.degree. C. to 170.degree. C. under a pressure of from about 10 to 30 bar by gradual addition of hydrogen. The hydrogenation product is separated by distillation into sym.-octahydrophenanthrene and asym.-octahydrophenanthrene. The sym.-octahydrophenanthrene is isomerized in the presence of methylene chloride as a solvent and of aluminum chloride as a catalyst at a temperature from about -30.degree. to +5.degree. C. to sym.-octahydroanthracene. The sym.-octahydroanthracene is dehydrogenated at a chromium oxide-aluminum oxide catalyst at temperatures from about 450.degree. to 550.degree. C. to anthracene.The resulting anthracene is obtained with high yield and is very pure after a single recrystallization step.
摘要翻译：公开了一种从菲生产蒽的方法。在约140〜170℃的温度下，在约10〜30巴的压力下，通过逐渐加入氢将菲在载体催化剂上的镍氢化。通过蒸馏将氢化产物分离成对 - 八氢菲和非 - 八氢菲。在二氯甲烷作为溶剂和氯化铝作为催化剂的存在下，在约-30℃至+5℃的温度下将对 - 八氢菲异构化为对映 - 八氢蒽。在约450-550℃的温度下，氧化铬 - 氧化铝催化剂将蒽 - 八氢蒽脱氢。得到的蒽以高产率获得，并且在单次再结晶步骤后是非常纯的。

7. 发明授权

US4113817A Coal-containing shaped bodies and process for making the same 失效
标题翻译：含煤成形体及其制造方法
公开(公告)号：US4113817A
公开(公告)日：1978-09-12
申请号：US649920
申请日：1976-01-16
申请人： Carl Kroger , Ingo Romey , Georg Kolling
发明人： Carl Kroger , Ingo Romey , Georg Kolling
IPC分类号： C08K3/04 , C08L21/00 , C10L5/10 , C10L5/14 , C08L7/00
CPC分类号： C08L9/02 , C08K3/04 , C08L11/00 , C08L9/06 , C10L5/10 , C10L5/14 , C08K7/02 , C08K7/12 , C08L23/06 , C08L27/06 , C08L97/002 , Y10S524/925
摘要： Coal-containing shaped bodies are made by intimately mixing particulate coal with 10 to 30 percent by weight of a polymer. The mixture is shaped by subjecting it to a pressure between about 295 and 3430 newtons per square centimeter. Shaping takes place within a temperature range of 100.degree. to 250.degree. C. The shaped bodies have high compressive and bending strengths and can be precisely dimensioned.
摘要翻译：含煤成形体通过将颗粒状煤与10〜30重量％的聚合物紧密混合而制成。混合物通过使其在约295至3430牛顿/平方厘米之间的压力下成形。成型在100〜250℃的温度范围内进行。成形体具有高的压缩和弯曲强度，并且可以精确地定尺寸。

8. 发明授权

US4124529A Carbonaceous adsorbents and process for making same 失效
标题翻译：碳质吸附剂及其制备方法
公开(公告)号：US4124529A
公开(公告)日：1978-11-07
申请号：US801384
申请日：1977-05-27
申请人： Harald Juntgen , Horst Schumacher , Jurgen Klein , Karl Knoblauch , Hans-Jurgen Schroter , Georg Kolling , Ingo Romey
发明人： Harald Juntgen , Horst Schumacher , Jurgen Klein , Karl Knoblauch , Hans-Jurgen Schroter , Georg Kolling , Ingo Romey
IPC分类号： C01B31/08 , B01D53/02 , B01J20/20 , C01B31/10 , C01B31/14 , B01J21/18 , C01B31/02
CPC分类号： C01B31/14 , B01D53/02
摘要： A carbonaceous adsorbent in the form of a shaped body which has been heated to about 400 to 1400.degree. C in an inert atmosphere is composed essentially of a mixture of finely divided carbonaceous material of a grain size below 50 and up to below 100 microns with a binder composed of about 1 to 20% by weight of a natural or synthetic elastomer and about 1 to 15% by weight of a thermoplastic material. The adsorbent is made by subjecting the mixture to a shaping step followed by heating to a temperature of about 400.degree. to 1400.degree. C in an inert atmosphere which step may be followed by an activation of the carbonaceous material.
摘要翻译：在惰性气氛中加热至约400至1400℃的成型体形式的含碳吸附剂主要由粒度低于50至高达100微米的细碎碳质材料的混合物组成，粘合剂由约1至20重量％的天然或合成弹性体和约1至15重量％的热塑性材料组成。吸附剂是通过使混合物进行成型步骤，然后在惰性气氛中加热至约400至1400℃的温度制备的，该步骤之后可以活化碳质材料。

9. 发明授权

US4104150A Process for the production of coke from pitch 失效
标题翻译：从沥青生产焦炭的工艺
公开(公告)号：US4104150A
公开(公告)日：1978-08-01
申请号：US765892
申请日：1977-02-07
申请人： Ingo Romey , Georg Kolling , Hellmut Kokot
发明人： Ingo Romey , Georg Kolling , Hellmut Kokot
IPC分类号： C10B55/00 , C10L9/00 , C10G9/14
CPC分类号： C10L9/00 , C10B55/00
摘要： Coal-tar pitch is heated to a temperature which is at least 100.degree. C above its softening point but below its decomposition temperature and is mixed with a filter aid, such as kieselghur or activated carbon prior to filtering the pitch at at least the preheat temperature so as to remove ashes, soot and heavy metals therefrom. The thus-purified pitch is then coked. In this manner, it is possible to obtain high-quality, anisotropic acicular coke which is readily convertible into graphite.
摘要翻译：将煤焦油沥青加热至高于其软化点至少100℃但低于其分解温度的温度，并在至少预热温度下过滤沥青之前与助滤剂例如kieselghur或活性炭混合从而从其中除去灰分，烟灰和重金属。然后将如此纯化的沥青焦化。以这种方式，可以获得易于转化为石墨的高质量的各向异性针状焦炭。

10. 发明授权

US4289604A Method of producing an isotropic coke 失效
标题翻译：生产各向同性焦炭的方法
公开(公告)号：US4289604A
公开(公告)日：1981-09-15
申请号：US783030
申请日：1977-03-31
申请人： Georg Kolling , Gerhard Pietzka , Ingo Romey , Harald Tillmanns
发明人： Georg Kolling , Gerhard Pietzka , Ingo Romey , Harald Tillmanns
IPC分类号： C10B57/04 , C01B31/00 , C10B55/00
CPC分类号： C10B55/00
摘要： Manufacture of isotropic coke by first selecting as feed material tar from low temperature carbonization with a hydrogen content above 5.5%, a carbon content less than 88% and a softening point above 60.degree. C., filtering the tar to remove solid particles, and heating the filtrate to a temperature between about 900.degree. C. and 1300.degree. C. to form an isotropic coke.
摘要翻译：通过首先从低温碳酸化中选择氢含量高于5.5％，碳含量低于88％，软化点高于60℃的原料焦油制备各向同性焦炭，过滤焦油以除去固体颗粒，加热滤液在约900℃至1300℃之间的温度下形成各向同性的焦炭。

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