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1. 发明授权

US5527751A Polymerization catalyst and method for producing polyolefin or olefin block copolymer using the same 失效
标题翻译：聚合催化剂及使用其制备聚烯烃或烯烃嵌段共聚物的方法
公开(公告)号：US5527751A
公开(公告)日：1996-06-18
申请号：US266390
申请日：1994-06-27
申请人： Kunihiro Inamatsu , Tsuyoshi Matsumoto , Kazuo Soga
发明人： Kunihiro Inamatsu , Tsuyoshi Matsumoto , Kazuo Soga
IPC分类号： C08F10/00 , C08F297/06 , C08F4/52
CPC分类号： C08F297/06 , C08F10/00
摘要： A polymerization catalyst comprising a reaction product of an organic rare earth metal compound of the formula (I),Cp.sub.a Lx.sub.b M.sub.c D.sub.d (I)(wherein in the formula (I), Cp is a substituted or unsubstituted cyclopentadienyl group, indenyl group, fluorenyl group or their derivatives, or a multidentate coordination compound residue obtained by bonding these groups by way of hydrocarbon or silicon,L is a metal selected from the group consisting of elements having an atomic number of 39 and 57-71,X is a halogen atom,M is an alkaline metal or alkaline earth metal,D is an electron donor,a is 1-2,b is 1-2,c is 0-1, andd is 0-3) with a Grignard reagent of the formula (II),RMgX (II)wherein in the formula (II), R is a hydrocarbon group, and X is a halogen atom); a method for producing a polyolefin or an olefin block copolymer by using the above-mentioned catalyst; and an olefin block copolymer produced by the above-mentioned method.
摘要翻译：包含式（I）的有机稀土金属化合物，CpaLxbMcDd（I）的反应产物的聚合催化剂，其中在式（I）中，Cp为取代或未取代的环戊二烯基，茚基，芴基或它们的衍生物或通过烃或硅键合这些基团而获得的多齿配位化合物残基，L是选自原子序数为39和57-71的元素的金属，X为卤素原子，M为碱金属或碱土金属，D为电子给体，a为1-2，b为1-2，c为0-1，d为0-3）与式（II）的格利雅试剂反应， RMgX（II）其中在式（II）中，R是烃基，X是卤素原子）; 使用上述催化剂制造聚烯烃或烯烃嵌段共聚物的方法; 和通过上述方法制备的烯烃嵌段共聚物。

2. 发明授权

US5422400A Method for producing an ethylenic polymer composition 失效
标题翻译：烯属聚合物组合物的制造方法
公开(公告)号：US5422400A
公开(公告)日：1995-06-06
申请号：US285762
申请日：1994-08-03
申请人： Sakae Kamiyama , Masao Kawahara , Kunihiro Inamatsu , Keizo Kase , Kouji Mizokami , Tsuyoshi Matsumoto
发明人： Sakae Kamiyama , Masao Kawahara , Kunihiro Inamatsu , Keizo Kase , Kouji Mizokami , Tsuyoshi Matsumoto
IPC分类号： C08F4/638 , C08F4/60 , C08F4/685 , C08F10/00 , C08F10/02 , C08F110/02 , C08F210/16 , C08L23/04 , C08L23/06 , C08L23/08
CPC分类号： C08F10/00 , C08F10/02 , C08L23/04 , C08F110/02 , C08F210/16
摘要： The invention relates to a method for producing an ethylenic polymer composition, suitable for molding, at high catalytic efficiency. The ethylenic polymer composition produced has as a high melt tension when melted, and a high melt modulus (die swell ratio). The process comprises a three step polymerization of an olefin employing a transition metal catalyst, the catalyst being produced in a specific manner.
摘要翻译：本发明涉及一种适用于以高催化效率成型的乙烯聚合物组合物的制备方法。所生成的乙烯类聚合物组合物在熔融时具有高熔体张力，并具有高熔体模量（模头膨胀比）。该方法包括使用过渡金属催化剂的烯烃三步聚合，催化剂以特定的方式制备。

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