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1. 发明申请

US20050244712A1 Sealed nickel-zinc primary cell 失效
标题翻译：密封镍锌原电池
公开(公告)号：US20050244712A1
公开(公告)日：2005-11-03
申请号：US10514556
申请日：2003-05-28
申请人： Kunihiko Miyamoto , Shuichiro Irie , Eiki Kashiwazaki , Teiji Okayama
发明人： Kunihiko Miyamoto , Shuichiro Irie , Eiki Kashiwazaki , Teiji Okayama
IPC分类号： H01M6/08 , H01M4/06 , H01M4/24 , H01M4/32 , H01M4/52 , H01M4/62 , H01M10/30 , H01M10/42 , H01M4/50
CPC分类号： H01M4/62 , H01M4/06 , H01M4/364 , H01M4/52 , H01M6/08 , H01M2010/4292
摘要： The object of the invention is to provide an alkali primary battery being excellent in high rate discharge characteristics with less increase of the inner pressure by generating hydrogen in the overdischarge process. The invention provides a sealed nickel zinc primary battery comprising at least a positive electrode having a higher oxide of nickel as a positive electrode active substance, a negative electrode having zinc or an alloy thereof as a negative electrode active substance, a separator and an electrolyte solution housed in a vessel, wherein manganese dioxide is added in a proportion of 3 to 7% by mass relative to the higher oxide of nickel in the positive electrode, and the ratio between the theoretical capacity of the negative electrode to the theoretical capacity of the positive electrode (the theoretical capacity of the negative electrode/theoretical capacity of the positive electrode) is in the range of 1.2 to 1.0.
摘要翻译：本发明的目的是提供一种具有优异的高倍率放电特性的碱性一次电池，其中在过放电过程中产生氢气，内部压力增加较少。本发明提供一种密封的镍锌一次电池，其至少包括具有较高镍的氧化物作为正极活性物质的正极，具有锌的负极或其合金作为负极活性物质，隔膜和电解质溶液容纳在容器中，相对于正极中的较高的镍的氧化物，以相对于正极的镍的较高的氧化物为3〜7质量％的比例添加二氧化锰，负极的理论容量与正极的理论容量之比电极（负极的理论容量/正极的理论容量）在1.2〜1.0的范围内。

2. 发明授权

US07763383B2 Sealed nickel-zinc primary cell 失效
标题翻译：密封镍锌原电池
公开(公告)号：US07763383B2
公开(公告)日：2010-07-27
申请号：US10514556
申请日：2003-05-28
申请人： Kunihiko Miyamoto , Shuichiro Irie , Eiki Kashiwazaki , Teiji Okayama
发明人： Kunihiko Miyamoto , Shuichiro Irie , Eiki Kashiwazaki , Teiji Okayama
IPC分类号： H01M4/50
CPC分类号： H01M4/62 , H01M4/06 , H01M4/364 , H01M4/52 , H01M6/08 , H01M2010/4292
摘要： The object of the invention is to provide an alkali primary battery being excellent in high rate discharge characteristics with less increase of the inner pressure by generating hydrogen in the overdischarge process. The invention provides a sealed nickel zinc primary battery comprising at least a positive electrode having a higher oxide of nickel as a positive electrode active substance, a negative electrode having zinc or an alloy thereof as a negative electrode active substance, a separator and an electrolyte solution housed in a vessel, wherein manganese dioxide is added in a proportion of 3 to 7% by mass relative to the higher oxide of nickel in the positive electrode, and the ratio between the theoretical capacity of the negative electrode to the theoretical capacity of the positive electrode (the theoretical capacity of the negative electrode/theoretical capacity of the positive electrode) is in the range of 1.2 to 1.0.
摘要翻译：本发明的目的是提供一种具有优异的高倍率放电特性的碱性一次电池，其中在过放电过程中产生氢气，内部压力增加较少。本发明提供一种密封的镍锌一次电池，其至少包括具有较高镍的氧化物作为正极活性物质的正极，具有锌的负极或其合金作为负极活性物质，隔膜和电解质溶液容纳在容器中，相对于正极中的较高的镍的氧化物，以相对于正极的镍的较高的氧化物为3〜7质量％的比例添加二氧化锰，负极的理论容量与正极的理论容量之比电极（负极的理论容量/正极的理论容量）在1.2〜1.0的范围内。

3. 发明授权

US07594938B2 Enclosed nickel-zinc primary battery, its anode and production methods for them 失效
标题翻译：封闭的镍锌一次电池，其阳极及其制作方法
公开(公告)号：US07594938B2
公开(公告)日：2009-09-29
申请号：US11754034
申请日：2007-05-25
申请人： Kunihiko Miyamoto , Shuichiro Irie , Shinichi Miyamoto , Naomi Hadano , Teiji Okayama
发明人： Kunihiko Miyamoto , Shuichiro Irie , Shinichi Miyamoto , Naomi Hadano , Teiji Okayama
IPC分类号： H01M4/08 , H01M4/06 , H01M4/52 , H01M6/06
CPC分类号： H01M6/04 , H01M2/0235 , H01M4/02 , H01M4/06 , H01M4/08 , H01M4/244 , H01M4/42 , H01M4/52 , H01M6/08 , H01M2004/021 , H01M2004/023 , H01M2004/027 , H01M2300/0014 , Y10T29/4911
摘要： A high-capacity enclosed nickel-zinc primary battery excellent in characteristics such as capacity maintenance factor, energy density, and high-efficient discharge characteristics, an anode using it, and a production method for them. An enclosed nickel-zinc primary battery which uses as an anode an anode active material of nickel hydroxide compound, such as nickel oxyhydroxide, particles and uses zinc alloy gel as a cathode material, wherein a ratio of anode theoretical capacity to cathode theoretical capacity is 1.0-1.6, and a ratio of alkali electrolyte to anode theoretical capacity is 1.0-1.6 ml/Ah.
摘要翻译：使用容量维护率，能量密度，高效放电特性等特性优异的高容量封闭镍锌一次电池，使用它们的阳极及其制造方法。使用氢氧化镍化合物的正极活性物质如氢氧化镍，颗粒并使用锌合金凝胶作为阴极材料的封装的镍 - 锌一次电池，其中阳极理论容量与阴极理论容量的比率为1.0 -1.6，碱电解液与阳极理论容量的比为1.0〜1.6ml / Ah。

4. 发明授权

US07851087B2 Enclosed nickel-zinc primary battery, its anode and production methods for them 失效
标题翻译：封闭的镍锌一次电池，其阳极及其制作方法
公开(公告)号：US07851087B2
公开(公告)日：2010-12-14
申请号：US12435963
申请日：2009-05-05
申请人： Kunihiko Miyamoto , Shuichiro Irie , Shinichi Miyamoto , Naomi Hadano , Teiji Okayama
发明人： Kunihiko Miyamoto , Shuichiro Irie , Shinichi Miyamoto , Naomi Hadano , Teiji Okayama
IPC分类号： H01M4/52 , H01M6/06
CPC分类号： H01M6/04 , H01M2/0235 , H01M4/02 , H01M4/06 , H01M4/08 , H01M4/244 , H01M4/42 , H01M4/52 , H01M6/08 , H01M2004/021 , H01M2004/023 , H01M2004/027 , H01M2300/0014 , Y10T29/4911
摘要： A high-capacity enclosed nickel-zinc primary battery excellent in characteristics such as capacity maintenance factor, energy density, and high-efficient discharge characteristics, an anode using it, and a production method for them. An enclosed nickel-zinc primary battery which uses as an anode an anode active material of nickel hydroxide compound, such as nickel oxyhydroxide, particles and uses zinc alloy gel as a cathode material, wherein a ratio of anode theoretical capacity to cathode theoretical capacity is 1.0-1.6, and a ratio of alkali electrolyte to anode theoretical capacity is 1.0-1.6 ml/Ah.
摘要翻译：使用容量维护率，能量密度，高效放电特性等特性优异的高容量封闭镍锌一次电池，使用它们的阳极及其制造方法。使用氢氧化镍化合物的正极活性物质如氢氧化镍，颗粒并使用锌合金凝胶作为阴极材料的封闭的镍 - 锌一次电池，其中阳极理论容量与阴极理论容量的比率为1.0 -1.6，碱电解液与阳极理论容量的比为1.0〜1.6ml / Ah。

5. 发明申请

US20090274959A1 ENCLOSED NICKEL-ZINC PRIMARY BATTERY, ITS ANODE AND PRODUCTION METHODS FOR THEM 失效
标题翻译：镀镍镍原子电池及其阳极及其生产方法
公开(公告)号：US20090274959A1
公开(公告)日：2009-11-05
申请号：US12435963
申请日：2009-05-05
申请人： Kunihiko Miyamoto , Shuichiro Irie , Shinichi Miyamoto , Naomi Hadano , Teiji Okayama
发明人： Kunihiko Miyamoto , Shuichiro Irie , Shinichi Miyamoto , Naomi Hadano , Teiji Okayama
IPC分类号： H01M4/00
CPC分类号： H01M6/04 , H01M2/0235 , H01M4/02 , H01M4/06 , H01M4/08 , H01M4/244 , H01M4/42 , H01M4/52 , H01M6/08 , H01M2004/021 , H01M2004/023 , H01M2004/027 , H01M2300/0014 , Y10T29/4911
摘要： A high-capacity enclosed nickel-zinc primary battery excellent in characteristics such as capacity maintenance factor, energy density, and high-efficient discharge characteristics, an anode using it, and a production method for them. An enclosed nickel-zinc primary battery which uses as an anode an anode active material of nickel hydroxide compound, such as nickel oxyhydroxide, particles and uses zinc alloy gel as a cathode material, wherein a ratio of anode theoretical capacity to cathode theoretical capacity is 1.0-1.6, and a ratio of alkali electrolyte to anode theoretical capacity is 1.0-1.6 ml/Ah.
摘要翻译：使用容量维护率，能量密度，高效放电特性等特性优异的高容量封闭镍锌一次电池，使用它们的阳极及其制造方法。使用氢氧化镍化合物的正极活性物质如氢氧化镍，颗粒并使用锌合金凝胶作为阴极材料的封装的镍 - 锌一次电池，其中阳极理论容量与阴极理论容量的比率为1.0 -1.6，碱电解液与阳极理论容量的比为1.0〜1.6ml / Ah。

6. 发明申请

US20080096106A1 ENCLOSED NICKEL-ZINC PRIMARY BATTERY, ITS ANODE AND PRODUCTION METHODS FOR THEM 审中-公开
标题翻译：镀镍镍原子电池及其阳极及其生产方法
公开(公告)号：US20080096106A1
公开(公告)日：2008-04-24
申请号：US11754080
申请日：2007-05-25
申请人： Kunihiko Miyamoto , Shuichiro Irie , Shinichi Miyamoto , Naomi Hadano , Teiji Okayama
发明人： Kunihiko Miyamoto , Shuichiro Irie , Shinichi Miyamoto , Naomi Hadano , Teiji Okayama
IPC分类号： H01M2/02
CPC分类号： H01M6/04 , H01M2/0235 , H01M4/02 , H01M4/06 , H01M4/08 , H01M4/244 , H01M4/42 , H01M4/52 , H01M6/08 , H01M2004/021 , H01M2004/023 , H01M2004/027 , H01M2300/0014 , Y10T29/4911
摘要： A high-capacity enclosed nickel-zinc primary battery excellent in characteristics such as capacity maintenance factor, energy density, and high-efficient discharge characteristics, an anode using it, and a production method for them. An enclosed nickel-zinc primary battery which uses as an anode an anode active material of nickel hydroxide compound, such as nickel oxyhydroxide, particles and uses zinc alloy gel as a cathode material, wherein a ratio of anode theoretical capacity to cathode theoretical capacity is 1.0-1.6, and a ratio of alkali electrolyte to anode theoretical capacity is 1.0-1.6 ml/Ah.
摘要翻译：使用容量维护率，能量密度，高效放电特性等特性优异的高容量封闭镍锌一次电池，使用它们的阳极及其制造方法。使用氢氧化镍化合物的正极活性物质如氢氧化镍，颗粒并使用锌合金凝胶作为阴极材料的封装的镍 - 锌一次电池，其中阳极理论容量与阴极理论容量的比率为1.0 -1.6，碱电解液与阳极理论容量的比为1.0〜1.6ml / Ah。

7. 发明申请

US20070298323A1 ENCLOSED NICKEL-ZINC PRIMARY BATTERY, ITS ANODE AND PRODUCTION METHODS FOR THEM 失效
公开(公告)号：US20070298323A1
公开(公告)日：2007-12-27
申请号：US11754034
申请日：2007-05-25
申请人： Kunihiko Miyamoto , Shuichiro Irie , Shinichi Miyamoto , Naomi Hadano , Teiji Okayama
发明人： Kunihiko Miyamoto , Shuichiro Irie , Shinichi Miyamoto , Naomi Hadano , Teiji Okayama
IPC分类号： H01M6/42
CPC分类号： H01M6/04 , H01M2/0235 , H01M4/02 , H01M4/06 , H01M4/08 , H01M4/244 , H01M4/42 , H01M4/52 , H01M6/08 , H01M2004/021 , H01M2004/023 , H01M2004/027 , H01M2300/0014 , Y10T29/4911
摘要： A high-capacity enclosed nickel-zinc primary battery excellent in characteristics such as capacity maintenance factor, energy density, and high-efficient discharge characteristics, an anode using it, and a production method for them. An enclosed nickel-zinc primary battery which uses as an anode an anode active material of nickel hydroxide compound, such as nickel oxyhydroxide, particles and uses zinc alloy gel as a cathode material, wherein a ratio of anode theoretical capacity to cathode theoretical capacity is 1.0-1.6, and a ratio of alkali electrolyte to anode theoretical capacity is 1.0-1.6 ml/Ah.

8. 发明授权

US07238447B2 Enclosed nickel-zinc primary battery its anode and production methods for them 失效
标题翻译：封闭镍锌一次电池的阳极及其制作方法
公开(公告)号：US07238447B2
公开(公告)日：2007-07-03
申请号：US10416787
申请日：2001-11-16
申请人： Kunihiko Miyamoto , Shuichiro Irie , Shinichi Miyamoto , Naomi Hadano , Teiji Okayama
发明人： Kunihiko Miyamoto , Shuichiro Irie , Shinichi Miyamoto , Naomi Hadano , Teiji Okayama
IPC分类号： H01M4/52
CPC分类号： H01M6/04 , H01M2/0235 , H01M4/02 , H01M4/06 , H01M4/08 , H01M4/244 , H01M4/42 , H01M4/52 , H01M6/08 , H01M2004/021 , H01M2004/023 , H01M2004/027 , H01M2300/0014 , Y10T29/4911
摘要： A high-capacity enclosed nickel-zinc primary battery excellent in characteristics such as capacity maintenance factor, energy density, and high-efficient discharge characteristics, an anode using it, and a production method for them. An enclosed nickel-zinc primary battery which uses as an anode an anode active material of nickel hydroxide compound, such as nickel oxyhydroxide, particles and uses zinc alloy gel as a cathode material, wherein a ratio of anode theoretical capacity to cathode theoretical capacity is 1.0-1.6, and a ratio of alkali electrolyte to anode theoretical capacity is 1.0-1.6 ml/Ah.
摘要翻译：使用容量维护率，能量密度，高效放电特性等特性优异的高容量封闭镍锌一次电池，使用它们的阳极及其制造方法。使用氢氧化镍化合物的正极活性物质如氢氧化镍，颗粒并使用锌合金凝胶作为阴极材料的封装的镍 - 锌一次电池，其中阳极理论容量与阴极理论容量的比率为1.0 -1.6，碱电解液与阳极理论容量的比为1.0〜1.6ml / Ah。

9. 发明授权

US06528209B2 ACTIVE MATERIAL FOR POSITIVE ELECTRODE FOR ALKALINE SECONDARY CELL AND METHOD FOR PRODUCING THE SAME, AND ALKALINE SECONDARY CELL USING THE ACTIVE MATERIAL FOR POSITIVE ELECTRODE AND METHOD FOR PRODUCING THE SAME 失效
标题翻译：用于碱性二次电池的正电极的活性材料及其制造方法以及使用活性物质的碱性电极的碱性二次电池及其制造方法
公开(公告)号：US06528209B2
公开(公告)日：2003-03-04
申请号：US09749789
申请日：2000-12-28
申请人： Kunihiko Miyamoto , Naomi Bando
发明人： Kunihiko Miyamoto , Naomi Bando
IPC分类号： H01M432
CPC分类号： H01M4/52 , H01M10/28 , H01M10/342
摘要： Provided is a active material for positive electrode for an alkaline secondary cell, which advantageously exhibits improved overdischarge characteristics, improved utilization of the active material and an improved effect of suppressing the rise in cell internal pressure, a method for producing the same, and an alkaline secondary cell using the above active material for positive electrode, especially a nickel-hydrogen secondary cell. The above active material comprises nickel hydroxide particles each having a surface to which a cobalt oxide sticks, wherein the cobalt oxide contains 20 to 40% by mole of cobalt(II) oxide, wherein the nickel hydroxide particles form an eutectic together with Co and Zn or/and Y, and the Co content of the eutectic is 2% by mass or less, and the nickel hydroxide particles have a value of a half width of the peak ascribed to the (101) crystal face diffraction of 0.8°/2&thgr;(Cu—K&agr;) or more as measured by powder X-ray diffractometry.
摘要翻译：本发明提供一种碱性二次电池用正极活性物质，其有利地具有改善的过放电特性，改善了活性物质的利用率和改善了抑制电池内部压力上升的效果，其制备方法和碱使用上述正极活性物质，特别是镍 - 氢二次电池的二次电池。上述活性物质包含氢氧化钴颗粒，每个氧化钴具有钴氧化物粘附的表面，其中氧化钴含有20〜40摩尔％氧化钴（II），其中氢氧化镍颗粒与Co和Zn或/和Y一起形成共晶，共晶的Co含量为2质量％以下，氢氧化镍颗粒的值为一半归属于（101）晶面衍射的峰值的宽度，通过粉末X射线衍射法测量为0.8°/2θ（Cu-Kalpha）或更大。

10. 发明授权

US5432031A Paste-type electrode for alkali secondary cell 失效
公开(公告)号：US5432031A
公开(公告)日：1995-07-11
申请号：US321867
申请日：1994-10-14
申请人： Hirohito Teraoka , Katuyuki Hata , Kunihiko Miyamoto , Kouji Ishiwa
发明人： Hirohito Teraoka , Katuyuki Hata , Kunihiko Miyamoto , Kouji Ishiwa
IPC分类号： H01M4/24 , H01M4/02 , H01M4/32 , H01M4/36 , H01M4/38 , H01M4/52 , H01M4/62 , H01M4/66 , H01M4/74 , H01M4/80 , H01M6/10 , H01M10/04
CPC分类号： H01M4/366 , H01M10/0431 , H01M4/32 , H01M4/383 , H01M4/52 , H01M4/80 , H01M4/808 , H01M2004/021 , H01M2300/0014 , H01M4/621 , H01M6/10
摘要： There is provided a paste-type electrode for an alkali secondary cell which can suppress occurrence of internal short-circuiting, which is likely to happen when an electrode is rolled along with another electrode having the opposite polarity and a separator interposed therebetween. The paste-type electrode for an alkali secondary cell comprises a three-dimensional substrate including a felt-like metal porous member in which a plurality of hollow metal fibers are arranged three-dimensionally, diameters of those of the metal fibers arranged near the surface portion of the porous member being greater than those arranged in the inner portion, an average diameter of those of the metal fibers near the surface portion being in a range of 20 to 150 .mu.m, and an average diameter of those of the metal fibers in the inner portion being in a range of 10 to 100 .mu.m, and paste containing an activation substance filled in the three-dimensional substrate.

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