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    • 1. 发明授权
    • Ceramic capacitor and method for making the same
    • 陶瓷电容器及其制作方法
    • US06301092B1
    • 2001-10-09
    • US09591298
    • 2000-06-09
    • Kotaro HataToshihiro OkamatsuTomoyuki NakamuraKenji HoriHarunobu Sano
    • Kotaro HataToshihiro OkamatsuTomoyuki NakamuraKenji HoriHarunobu Sano
    • H01G406
    • H01G4/1245H01G4/1218H01G4/1236
    • A ceramic capacitor has a dielectric ceramic layer and at least one pair of electrodes. The dielectric ceramic layer has a primary phase and secondary phases, and the size of the secondary phases in the thickness direction of the dielectric ceramic layer is not more than about one-third of the thickness of the dielectric ceramic layer. A method for making the ceramic capacitor includes the steps of mixing compounds constituting secondary phases in a primary phase of a dielectric ceramic, annealing and then pulverizing the mixture to prepare a raw material for the secondary phases, mixing the raw material for the secondary phases with other materials for the dielectric ceramic shaping and sintering the mixture to form a dielectric ceramic, and forming electrodes on the dielectric ceramic. The ceramic capacitor has high insulation resistance, superior load characteristics at high temperatures or high humidity and high weather resistance, even when sintered in a reducing atmosphere.
    • 陶瓷电容器具有介电陶瓷层和至少一对电极。 电介质陶瓷层具有主相和次相,并且介电陶瓷层的厚度方向上的次相的尺寸不超过介电陶瓷层的厚度的约三分之一。 制造陶瓷电容器的方法包括以下步骤:将构成第二相的化合物混合在电介质陶瓷的初生相中,退火然后粉碎混合物以制备二次相的原料,将第二相的原料与 电介质陶瓷的其他材料成型并烧结混合物以形成电介质陶瓷,并在电介质陶瓷上形成电极。 陶瓷电容器具有高绝缘电阻,在高温或高湿度下具有优异的负载特性和高耐候性,即使在还原气氛中烧结也是如此。
    • 3. 发明授权
    • Dielectric ceramic composition and monolithic ceramic capacitor
    • 介电陶瓷组合物和单片陶瓷电容器
    • US06310761B1
    • 2001-10-30
    • US09655071
    • 2000-09-05
    • Kenji HoriKotaro HataToshihiro IkamatsuTomoyuki NakamuraHarunobu Sano
    • Kenji HoriKotaro HataToshihiro IkamatsuTomoyuki NakamuraHarunobu Sano
    • H01G406
    • C04B35/4682C01G23/002C01P2004/61C01P2006/40H01G4/1227
    • A dielectric ceramic composition is composed of barium titanate (BamTiO3), a rare-earth oxide (RO3/2), where the rare-earth element is at least one of Y, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm and Yb, calcium oxide and a silicon oxide. When the dielectric ceramic composition is represented by the formula 100BamTiO3+aRO3/2+bCaO+cSiO2, where coefficients 100, a, b, and c indicate moles, the relationships 0.990≦m≦1.030, 0.5≦a≦30, 0.5≦b≦30, and 0.5≦c≦30 are satisfied. A monolithic ceramic capacitor includes a plurality of dielectric ceramic layers, internal electrodes formed between the dielectric ceramic layers and external electrodes electrically connected to the internal electrodes. The dielectric ceramic layers are composed of the dielectric ceramic composition described above, and the internal electrodes are composed of a base metal as a principal constituent.
    • 介电陶瓷组合物由稀土元素为Y,Sm,Eu,Gd,Tb,Dy,Ho,Er中的至少一种的钛酸钡(BamTiO 3),稀土类氧化物(RO3 / 2) ,Tm和Yb,氧化钙和氧化硅。 当电介质陶瓷组合物由式100BamTiO3 + aRO3 / 2 + bCaO + cSiO2表示时,其中系数100,a,b和c表示摩尔数,关系0.990 <= m <= 1.030,0.5 <= a <= 30 ,0.5 <= b <= 30,满足0.5 <= c <30。 单片陶瓷电容器包括多个电介质陶瓷层,形成在电介质陶瓷层和电连接到内部电极的外部电极之间的内部电极。 电介质陶瓷层由上述介电陶瓷组合物构成,内部电极以贱金属为主要成分。
    • 5. 发明授权
    • Monolithic ceramic capacitor
    • 单片陶瓷电容器
    • US5995360A
    • 1999-11-30
    • US18156
    • 1998-02-03
    • Kotaro HataHarunobu Sano
    • Kotaro HataHarunobu Sano
    • H01G4/12H01G4/30H01G4/06H01G4/20H01G4/228
    • H01G4/1227
    • A monolithic ceramic capacitor composed of laminated plural dielectric ceramic layers, internal electrodes disposed between the dielectric ceramic layers and external electrodes formed at both the edge surfaces of the dielectric ceramic layers such that they are alternately connected to the internal electrodes, wherein the dielectric ceramic layers are composed of a material comprising principal components shown by the formula: (1-.alpha.-.beta.){BaO}.sub.m .cndot.TiO.sub.2 +.alpha.{(1-x)M.sub.2 O.sub.3 +xRe.sub.2 O.sub.3 }+.beta.(Mn.sub.1-y-z Ni.sub.y Co.sub.z)O (wherein M.sub.2 O.sub.3 is at least one of Sc.sub.2 O.sub.3 and Y.sub.2 O.sub.3 ; Re.sub.2 O.sub.3 is at least one of Gd.sub.2 O.sub.3, Tb.sub.2 O.sub.3 and DY.sub.2 O.sub.3 ; 0.0025.ltoreq..alpha..ltoreq.0.025, 0.0025.ltoreq..beta..ltoreq.0.05, .beta./.alpha..ltoreq.4, 0
    • 由叠层的多个介电陶瓷层构成的单片陶瓷电容器,设置在电介质陶瓷层之间的内部电极和形成在电介质陶瓷层的两个边缘表面的外部电极,使得它们交替地连接到内部电极,其中介电陶瓷层 由包含主要成分的材料组成,所述主要组分由下式表示:(1-α-β){BaO} m.TiO 2 +α{(1-x)M 2 O 3 + xRe 2 O 3} +β(Mn 1-y-z Ni y Co z)O 是Sc 2 O 3和Y 2 O 3中的至少一种; Re 2 O 3是G​​d 2 O 3,Tb 2 O 3和D 2 O 3中的至少一种; 0.0025 和1.000