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1. 发明授权

US06248474B1 Composite electrode for secondary battery and production method thereof 失效
标题翻译：二次电池用复合电极及其制造方法
公开(公告)号：US06248474B1
公开(公告)日：2001-06-19
申请号：US09185589
申请日：1998-11-04
申请人： Toshihiko Nishiyama , Junko Kurihara , Gaku Harada , Koji Sakata , Shinako Okada
发明人： Toshihiko Nishiyama , Junko Kurihara , Gaku Harada , Koji Sakata , Shinako Okada
IPC分类号： H01M460
CPC分类号： H01M4/137 , H01M4/04 , H01M4/60
摘要： An electrode for a secondary or rechargeable battery using a conducting polymer as an active material is provided, which realizes a large capacity, a good cycling property, and a high power density. This electrode is comprised of an active material layer having an active material made of a mixture of a nitrogen-containing compound polymer and a quinone-system compound. The molar ratio of the nitrogen-containing compound polymer and the quinone-system compound is preferably in the range of 0.25:0.75˜0.75:0.25 and is more preferably in the range of 0.33:0.66˜0.66:0.33. The active material of the electrode is produced by using a mixture of powders of the nitrogen-containing compound polymer and the quinone-system compound.
摘要翻译：提供了一种使用导电聚合物作为活性材料的二次电池或可再充电电池的电极，其实现了大容量，良好的循环性能和高功率密度。该电极由具有由含氮化合物聚合物和醌系化合物的混合物制成的活性物质的活性物质层构成。含氮化合物聚合物和醌系化合物的摩尔比优选在0.25:0.75〜0.75:0.25的范围内，更优选在0.33:0.66〜0.66:033的范围内。通过使用含氮化合物聚合物和醌系化合物的粉末的混合物来制造电极的活性材料。

2. 发明授权

US6099989A Polymer secondary batteries 失效
标题翻译：聚合物二次电池
公开(公告)号：US6099989A
公开(公告)日：2000-08-08
申请号：US174312
申请日：1998-10-19
申请人： Gaku Harada , Koji Sakata , Junko Kurihara , Shinako Okada
发明人： Gaku Harada , Koji Sakata , Junko Kurihara , Shinako Okada
IPC分类号： C08L79/00 , H01M4/13 , H01M4/137 , H01M4/60 , H01M10/05 , H01M10/0565
CPC分类号： H01M4/606 , H01M4/60 , H01M4/602 , H01M4/608
摘要： The present invention provides a polymer secondary battery comprising a pair of current collectors and electrodes arranged in opposed relationship with an electrolyte solution-containing separator or a solid electrolyte interposed therebetween, the polymer secondary battery having a structure in which a first polymer active material layer adjacent to the current collector of the negative electrode has laminated thereto at least one layer of a polymer material having an oxidation-reduction potential higher than that of the first polymer active material layer. This polymer secondary battery has a high rate of appearance of capacity, is capable of quick charging and discharging, and exhibits excellent cycle characteristics.
摘要翻译：本发明提供了一种聚合物二次电池，其包括一对集电体和电极，其与含有电解质溶液的隔膜或固体电解质相对地设置，所述聚合物二次电池具有这样的结构，其中第一聚合物活性材料层相邻负极的集电体层叠有至少一层具有比第一聚合物活性物质层的氧化还原电位高的氧化还原电位的聚合物材料。该聚合物二次电池具有高容量的外观，能够快速充放电，并具有优异的循环特性。

3. 发明授权

US06343003B1 Capacitor element and battery cell 失效
标题翻译：电容元件和电池单元
公开(公告)号：US06343003B1
公开(公告)日：2002-01-29
申请号：US09187757
申请日：1998-11-09
申请人： Koji Sakata , Shinako Okada , Junko Kurihara , Gaku Harada
发明人： Koji Sakata , Shinako Okada , Junko Kurihara , Gaku Harada
IPC分类号： H01G900
CPC分类号： H01G11/72 , H01G11/20 , H01G11/52 , H01G11/58 , H01M4/62 , H01M6/22 , H01M10/0525 , H01M2300/0085 , Y02E60/13
摘要： A capacitor element and a battery cell which a dry-up phenomenon is restricted and an internal resistance is small are provided. The capacitor element provides a porous separator which has ion permeability and the ability of insulation, a pair of carbon electrode layers having many successive through holes separated by the porous separator, a non-conductive gasket holding the surrounding ends of the carbon electrode layers, a pair of conductive separators holding the carbon electrode layers and the non-conductive gasket from the outside, electrolyte solution in the successive through holes of the carbon electrode layers, and minute particles which are more than 0.1 weight % and less than 5.0 weight % of the electrolyte solution. A battery cell provides electrolyte solution and positive/negative electrode active material layers containing minute particles which are more than 0.1 weight % and less than 5.0 weight % of the electrolyte solution in the successive through holes.
摘要翻译：提供了电容器元件和干燥现象被限制并且内部电阻小的电池单元。电容器元件提供了具有离子渗透性和绝缘能力的多孔分离器，一对具有由多孔分离器隔开的连续通孔的碳电极层，保持碳电极层的周围端部的非导电垫圈，从外部保持碳电极层和非导电垫圈的一对导电隔板，碳电极层的连续通孔中的电解质溶液和大于0.1重量％且小于5.0重量％的微小颗粒电解液。电池单体提供电解质溶液和含有比连续通孔中的电解质溶液的0.1重量％以上5.0重量％以下的微小粒子的正/负极活性物质层。

4. 发明授权

US06277518B1 Electrode materials for use in batteries, and electrodes and batteries using same 有权
标题翻译：用于电池的电极材料，以及使用其的电极和电池
公开(公告)号：US06277518B1
公开(公告)日：2001-08-21
申请号：US09210999
申请日：1998-12-15
申请人： Katsuhiko Naoi , Shunzou Suematsu , Ari Manago , Junko Kurihara , Toshihiko Nishiyama , Gaku Harada , Shinako Okada , Koji Sakata
发明人： Katsuhiko Naoi , Shunzou Suematsu , Ari Manago , Junko Kurihara , Toshihiko Nishiyama , Gaku Harada , Shinako Okada , Koji Sakata
IPC分类号： H01M460
CPC分类号： H01M4/137 , H01M4/60 , H01M10/05
摘要： A polymer composed of structural units having a fused ring structure derived from a nitrogen-containing cyclic compound and a quinone compound as represented by the following formula is used as an electrode material for use in batteries. This makes it possible to provide batteries having excellent cycle characteristics and a high power density.
摘要翻译：作为用于电池的电极材料，使用由具有来自含氮环状化合物的稠环结构的结构单元和由下式表示的醌化合物构成的聚合物。这使得可以提供具有优异的循环特性和高功率密度的电池。

5. 发明授权

US06300015B1 Proton conductive polymer battery and method of forming the same 有权
标题翻译：质子导电聚合物电池及其形成方法
公开(公告)号：US06300015B1
公开(公告)日：2001-10-09
申请号：US09285795
申请日：1999-04-05
申请人： Toshihiko Nishiyama , Gaku Harada , Shinako Okada , Masaki Fuziwara
发明人： Toshihiko Nishiyama , Gaku Harada , Shinako Okada , Masaki Fuziwara
IPC分类号： H01M614
CPC分类号： H01M4/604 , H01M4/60 , H01M4/606 , H01M4/608 , H01M4/62 , H01M4/624 , H01M4/625
摘要： The present invention provides a positive electrode active material doped with a dopant comprising an anion having the same or similar molecular structure to a polymer matrix of at least one of a solid electrolyte and a gel solid electrolyte.
摘要翻译：本发明提供一种掺杂有掺杂剂的正极活性材料，该掺杂剂包含与固体电解质和凝胶固体电解质中的至少一种的聚合物基质具有相同或相似分子结构的阴离子。

6. 发明授权

US06254761B1 Method of preparing a conductive polymer for electrode and method of forming an electrode 有权
标题翻译：电极用导电性聚合物的制造方法及电极形成方法
公开(公告)号：US06254761B1
公开(公告)日：2001-07-03
申请号：US09528712
申请日：2000-03-20
申请人： Shinako Okada , Toshihiko Nishiyama , Masaki Fujiwara , Gaku Harada , Masato Kurosaki
发明人： Shinako Okada , Toshihiko Nishiyama , Masaki Fujiwara , Gaku Harada , Masato Kurosaki
IPC分类号： C25B500
CPC分类号： H01G9/0036 , H01B1/128 , H01G9/04 , H01M4/0438 , H01M4/0466
摘要： A method of producing a conductive polymer comprises the following steps of depositing a solid-state organic compound and contacting a collector with an electrolytic solution thereby to cause an electrolytic polymerization of said organic compound.
摘要翻译：制备导电聚合物的方法包括以下步骤：沉积固态有机化合物并使集电体与电解液接触，从而引起所述有机化合物的电解聚合。

7. 发明授权

US06686089B1 Battery electrode, secondary battery, and method of manufacturing same 失效
标题翻译：电池电极，二次电池及其制造方法
公开(公告)号：US06686089B1
公开(公告)日：2004-02-03
申请号：US09384594
申请日：1999-08-27
申请人： Masaki Fujiwara , Gaku Harada , Shinako Okada , Toshihiko Nishiyama
发明人： Masaki Fujiwara , Gaku Harada , Shinako Okada , Toshihiko Nishiyama
IPC分类号： H01M460
CPC分类号： H01M10/36 , H01M4/13 , H01M4/137 , H01M4/139 , H01M4/602 , H01M4/606 , H01M4/608
摘要： A battery electrode is obtained by coating an electrically conductive film serving as a collector with an aqueous solution of formic acid containing polypyridine, which is an active material, in dissolved form as well as carbon powder serving as a conduction aid, and drying the solution on the film. A secondary battery is manufactured using such electrodes.
摘要翻译：通过用溶解形式的作为活性物质的聚吡啶的甲酸水溶液以及作为导电助剂的碳粉末涂布作为集电体的导电膜，并将溶液干燥，得到电池电极这个电影。使用这样的电极制造二次电池。

8. 发明授权

US06413675B1 Multi layer electrolyte and cell using the same 失效
标题翻译：多层电解质和电池使用相同
公开(公告)号：US06413675B1
公开(公告)日：2002-07-02
申请号：US09353384
申请日：1999-07-15
申请人： Gaku Harada , Toshihiko Nishiyama , Masaki Fujiwara , Shinako Okada
发明人： Gaku Harada , Toshihiko Nishiyama , Masaki Fujiwara , Shinako Okada
IPC分类号： H01M1040
CPC分类号： H01M10/052 , H01M4/04 , H01M4/13 , H01M4/137 , H01M4/139 , H01M4/1399 , H01M4/602 , H01M4/622 , H01M4/623 , H01M6/187 , H01M6/188 , H01M10/0565 , H01M10/058 , H01M2300/0085 , H01M2300/0094 , Y10T29/49112
摘要： A multi layer electrolyte and a secondary cell using the multi layer electrolyte. The multi layer electrolyte comprises a solid electrolyte and other electrolyte such as gel electrolyte and/or electrolytic solution layer laminated on the solid electrolyte. The secondary cell using the multi layer electrolyte includes at least a positive electrode, a negative electrode and the multi layer electrolyte which comprises: a solid electrolyte layer; and at least one electrolyte layers selected from a gel electrolyte layer and an electrolytic solution layer and laminated on the solid electrolyte layer. By this structure, it is possible to use active material dissoluble in electrolytic solution as electrode active material and to realize a cell which can be quickly charged and discharged and which has superior capacity appearance rate and superior charge-discharge cycle characteristics.
摘要翻译：多层电解质和使用多层电解质的二次电池。多层电解质包含固体电解质和层压在固体电解质上的诸如凝胶电解质和/或电解溶液层的其它电解质。使用多层电解质的二次电池至少包括正极，负极和多层电解质，其包括：固体电解质层; 以及选自凝胶电解质层和电解液层中的至少一层电解质层，并层叠在固体电解质层上。通过这种结构，可以使用溶解于电解液中的活性物质作为电极活性物质，实现能快速充放电的电池，具有优异的容量出现率和优异的充放电循环特性。

9. 发明授权

US06428928B1 Battery and capacitor using quinoxaline resin 失效
标题翻译：电池和电容器使用喹喔啉树脂
公开(公告)号：US06428928B1
公开(公告)日：2002-08-06
申请号：US09520797
申请日：2000-03-08
申请人： Gaku Harada , Toshihiko Nishiyama , Masaki Fujiwara , Shinako Okada , Masato Kurosaki
发明人： Gaku Harada , Toshihiko Nishiyama , Masaki Fujiwara , Shinako Okada , Masato Kurosaki
IPC分类号： H01M460
CPC分类号： C08G61/122
摘要： The present invention provides an electrode containing a quinoxaline resin and an electrolyte which includes at least one of sulfuric acid ions and sulfonic acid ions, or the electrolyte which includes cations having ion radius of not more than 3 angstroms.
摘要翻译：本发明提供了含有喹喔啉树脂和包含硫酸离子和磺酸离子中的至少一种的电解质的电极，或者包含离子半径不大于3埃的阳离子的电解质。

10. 发明授权

US06274268B1 Polymer secondary battery and method of making same 失效
标题翻译：聚合物二次电池及其制造方法
公开(公告)号：US06274268B1
公开(公告)日：2001-08-14
申请号：US09346047
申请日：1999-07-07
申请人： Masaki Fujiwara , Gaku Harada , Shinako Okada , Toshihiko Nishiyama
发明人： Masaki Fujiwara , Gaku Harada , Shinako Okada , Toshihiko Nishiyama
IPC分类号： H01M460
CPC分类号： H01M4/137 , H01M4/1399 , H01M4/366 , H01M4/60 , H01M4/602 , H01M4/625 , H01M10/36
摘要： A polymer secondary battery uses, for at least one of the active material of positive electrode and the active material of negative electrode, a polymer-carbon composite material including powdered carbon having its surfaces coated with an organic compound polymer capable of adsorbing and desorbing protons electrochemically. The polymer secondary battery has a high rate of appearance of capacity and excellent cycle characteristics.
摘要翻译：聚合物二次电池用于正极活性物质和负极活性物质中的至少一种，包括其表面涂覆有能够电化学吸附和解吸质子的有机化合物聚合物的粉末状碳的聚合物 - 碳复合材料。聚合物二次电池的容量高，循环特性优异。

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