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    • 6. 发明授权
    • Method of chemically decontaminating components of radioactive material handling facility and system for carrying out the same
    • 化学去除放射性物质处理设备的组成部分的方法及其执行方法
    • US06635232B1
    • 2003-10-21
    • US09468906
    • 1999-12-22
    • Yumi YaitaMasami EndaHitoshi Sakai
    • Yumi YaitaMasami EndaHitoshi Sakai
    • G21C1900
    • C25B1/13C25B9/10G21F9/002G21F9/004
    • Ozone gas having a high ozone concentration is generated by a solid electrolyte electrolytic process. An ozone solution is prepared by injecting the ozone gas into an acidic solution of pH 6 or below. The ozone solution heated at a temperature in the range of 50° to 90° C. is supplied to a contaminated object to oxidize and dissolve a chromium oxide film by an oxidizing dissolving process. The ozone solution used in the oxidizing dissolving process is irradiated with ultraviolet rays to decompose ozone contained in the ozone solution, the ozone solution is passed through an ion-exchange resin to remove ions contained in the ozone solution. An oxalic acid solution is supplied to the contaminated object to dissolve an iron oxide film by a reductive dissolving process. Oxalic acid remaining in the oxalic acid solution after the reduction dissolving process is decomposed by injecting ozone into the oxalic acid solution and irradiating the oxalic acid solution with ultraviolet rays, and ions contained in the oxalic acid solution is removed by an ion-exchange resin.
    • 通过固体电解质电解法生成臭氧浓度高的臭氧气体。 通过将臭氧气体注入pH6以下的酸性溶液中制备臭氧溶液。 在50〜90℃的温度范围内加热的臭氧溶液被供给到污染物,通过氧化溶解法氧化和溶解氧化铬膜。 在氧化溶解过程中使用的臭氧溶液用紫外线照射以分解臭氧溶液中所含的臭氧,臭氧溶液通过离子交换树脂以除去臭氧溶液中所含的离子。 向被污染物质供给草酸溶液,通过还原溶解法溶解氧化铁膜。 在还原溶解工序后残留在草酸溶液中的草酸通过将臭氧注入草酸溶液中并用紫外线照射草酸溶液而分解,并且通过离子交换树脂除去草酸溶液中所含的离子。