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1. 发明授权

US07291185B2 Method of manufacturing both-side metallized film with reduced blocking of metallized film and metallized film capacitor using the same 有权
标题翻译：制造具有减少的金属化膜阻挡的双面金属化膜和使用其的金属化膜电容器的方法
公开(公告)号：US07291185B2
公开(公告)日：2007-11-06
申请号：US10479594
申请日：2002-06-06
申请人： Kohei Shiota , Toshiharu Saito , Kazumi Osamura , Hiroki Takeoka , Kazuhiro Nakatsubo , Toshiyuki Nishimori , Masatoshi Shibuya , Toshihiro Sasaki , Shigeo Okabe
发明人： Kohei Shiota , Toshiharu Saito , Kazumi Osamura , Hiroki Takeoka , Kazuhiro Nakatsubo , Toshiyuki Nishimori , Masatoshi Shibuya , Toshihiro Sasaki , Shigeo Okabe
IPC分类号： H01G9/00
CPC分类号： H01G13/006 , C23C14/08 , C23C14/562 , C23C14/5853 , H01G4/32 , Y10T29/417 , Y10T29/435 , Y10T29/49117
摘要： A method of manufacturing a both-side metallized insulation film comprises steps of: depositing zinc or a blend of zinc and aluminum onto both sides of an insulation film; and winding this metallized film into a product roll. The method is characterized in spraying an oxidizing gas onto a deposited layer on an inner side of the insulation film to be wound, during the winding step. During a vacuum deposition step, an oil layer is formed on at least one side of the metallized film. In addition, an oxide layer is formed by exposing a deposited layer on at least one side to oxygen, or by spraying an oxygen-containing gas onto the deposited layer on at least one side during the winding of the metallized film into the product roll.
摘要翻译：制造双面金属化绝缘膜的方法包括以下步骤：在绝缘膜的两侧上沉积锌或锌和铝的共混物; 并将该金属化膜卷绕成产品卷。该方法的特征在于，在卷绕步骤期间，将氧化气体喷射到待缠绕的绝缘膜的内侧上的沉积层上。在真空沉积步骤期间，在金属化膜的至少一侧上形成油层。此外，通过将至少一侧的沉积层暴露于氧，或者在将金属化膜卷入产品辊期间，在至少一侧上将含氧气体喷射到沉积层上形成氧化物层。

2. 发明授权

US08669367B2 Method for producing 2-azaadamantane 有权
标题翻译： 2-氮杂金刚烷的制备方法
公开(公告)号：US08669367B2
公开(公告)日：2014-03-11
申请号：US13585592
申请日：2012-08-14
申请人： Toshimasa Hamada , Noriaki Nagahama , Masami Kozawa , Yoshiharu Iwabuchi , Masatoshi Shibuya , Masaki Tomizawa , Yusuke Sasano
发明人： Toshimasa Hamada , Noriaki Nagahama , Masami Kozawa , Yoshiharu Iwabuchi , Masatoshi Shibuya , Masaki Tomizawa , Yusuke Sasano
IPC分类号： C07D451/14 , C07C61/29 , C07C211/41 , C07C247/00 , C07C271/24
CPC分类号： C07D451/14
摘要： To provide a method whereby a 2-azaadamantane can easily be obtained in good yield.A method for producing a 2-azaadamantane represented by the formula (1), which comprises cyclizing a compound represented by the following formula (2) in the presence of an acid.
摘要翻译：提供可以容易地以良好的产率获得2-氮杂金刚烷的方法。一种制备由式（1）表示的2-氮杂金刚烷的方法，其包括在酸存在下环化下式（2）表示的化合物。

3. 发明申请

US20080221331A1 ALCOHOL OXIDATION CATALYST AND ITS PREPARATION PROCESS 失效
标题翻译：酒精氧化催化剂及其制备方法
公开(公告)号：US20080221331A1
公开(公告)日：2008-09-11
申请号：US11943836
申请日：2007-11-21
申请人： Yoshiharu IWABUCHI , Masatoshi Shibuya , Masaki Tomizawa
发明人： Yoshiharu IWABUCHI , Masatoshi Shibuya , Masaki Tomizawa
IPC分类号： C07D453/06
CPC分类号： C07D453/06 , C07C45/30 , C07C2601/14 , C07D487/04 , C07D493/20 , C07C47/228 , C07C49/657 , C07C49/603 , C07C49/76 , C07C49/04
摘要： An alcohol oxidation catalyst which is an organic oxidation catalyst to oxidize an alcohol, which contains azabicyclo [3.3.1]nonane N-oxyl represented by the following formula (1) having an N-oxyl group incorporated in a bicycle[3.3.1]nonane skeleton: wherein X is H2, O or NOH.
摘要翻译：作为氧化醇的有机氧化催化剂的醇氧化催化剂，其含有结合在自行车中的具有N-氧基的由下式（1）表示的氮杂双环[3.3.1]壬烷N-氧基[3.3.1] 壬烷骨架：其中X是H 2，O或NOH。

4. 发明授权

US08273889B2 Method for producing 2-azaadamantane 有权
标题翻译： 2-氮杂金刚烷的制备方法
公开(公告)号：US08273889B2
公开(公告)日：2012-09-25
申请号：US12744015
申请日：2008-11-20
申请人： Toshimasa Hamada , Noriaki Nagahama , Masami Kozawa , Yoshiharu Iwabuchi , Masatoshi Shibuya , Masaki Tomizawa , Yusuke Sasano
发明人： Toshimasa Hamada , Noriaki Nagahama , Masami Kozawa , Yoshiharu Iwabuchi , Masatoshi Shibuya , Masaki Tomizawa , Yusuke Sasano
IPC分类号： C07D451/14 , C07C61/29 , C07C211/41 , C07C247/00 , C07C271/24
CPC分类号： C07D451/14
摘要： The invention provides a method for producing 2-azaadamantanes represented by formula (1) in good yields. The method includes cyclizing a compound represented by formula (2) in the presence of an acid.
摘要翻译：本发明提供以良好的产率制备由式（1）表示的2-氮杂金刚烷的方法。该方法包括在酸存在下环化由式（2）表示的化合物。

5. 发明授权

US07705152B2 Alcohol oxidation catalyst and its preparation process 失效
标题翻译：醇氧化催化剂及其制备方法
公开(公告)号：US07705152B2
公开(公告)日：2010-04-27
申请号：US11943836
申请日：2007-11-21
申请人： Yoshiharu Iwabuchi , Masatoshi Shibuya , Masaki Tomizawa
发明人： Yoshiharu Iwabuchi , Masatoshi Shibuya , Masaki Tomizawa
IPC分类号： C07D453/06
CPC分类号： C07D453/06 , C07C45/30 , C07C2601/14 , C07D487/04 , C07D493/20 , C07C47/228 , C07C49/657 , C07C49/603 , C07C49/76 , C07C49/04
摘要： An alcohol oxidation catalyst which is an organic oxidation catalyst to oxidize an alcohol, which contains azabicyclo[3.3.1]nonane N-oxyl represented by the following formula (1) having an N-oxyl group incorporated in a bicycle[3.3.1]nonane skeleton: wherein X is H2, O or NOH.
摘要翻译：作为氧化醇的有机氧化催化剂的醇氧化催化剂，其含有结合在自行车中的具有N-氧基的由下式（1）表示的氮杂双环[3.3.1]壬烷N-氧基[3.3.1] 壬烷骨架：其中X是H 2，O或NOH。

6. 发明申请

US20110287106A1 COGNITIVE IMPAIRMENT AMELIORANT 审中-公开
标题翻译：认真的不利因素
公开(公告)号：US20110287106A1
公开(公告)日：2011-11-24
申请号：US12672768
申请日：2009-06-16
申请人： Kikuji Yamaguchi , Yasushi Ohizumi , Tohru Yamakuni , Akira Nakajima , Yoshiharu Iwabuchi , Masatoshi Shibuya
发明人： Kikuji Yamaguchi , Yasushi Ohizumi , Tohru Yamakuni , Akira Nakajima , Yoshiharu Iwabuchi , Masatoshi Shibuya
IPC分类号： A61K35/64 , C07D311/30 , A61P25/00 , A61K36/41
CPC分类号： A61K35/644 , A61K31/352 , A61K31/353 , A61K36/16 , A61K36/41 , A61K2300/00
摘要： A cognitive impairment ameliorant is provided that is useful for the prevention or treatment of cognitive impairment, and particularly Alzheimer's disease. The cognitive impairment ameliorant contains royal jelly as an active ingredient thereof.
摘要翻译：提供了一种认知障碍改善剂，其用于预防或治疗认知障碍，特别是阿尔茨海默氏病。认知障碍改善剂含有蜂王浆作为其活性成分。

7. 发明申请

US20100311977A1 METHOD FOR PRODUCING 2-AZAADAMANTANE 有权
标题翻译：生产2-氮杂AD啶的方法
公开(公告)号：US20100311977A1
公开(公告)日：2010-12-09
申请号：US12744015
申请日：2008-11-20
申请人： Toshimasa Hamada , Noriaki Nagahama , Masami Kozawa , Yoshiharu Iwabuchi , Masatoshi Shibuya , Masaki Tomizawa , Yusuke Sasano
发明人： Toshimasa Hamada , Noriaki Nagahama , Masami Kozawa , Yoshiharu Iwabuchi , Masatoshi Shibuya , Masaki Tomizawa , Yusuke Sasano
IPC分类号： C07D451/14 , C07C271/24 , C07C211/41 , C07C61/29 , C07C247/00
CPC分类号： C07D451/14
摘要： To provide a method whereby a 2-azaadamantane can easily be obtained in good yield.A method for producing a 2-azaadamantane represented by the formula (1), which comprises cyclizing a compound represented by the following formula (2) in the presence of an acid.
摘要翻译：提供可以容易地以良好的产率获得2-氮杂金刚烷的方法。一种制备由式（1）表示的2-氮杂金刚烷的方法，其包括在酸存在下环化下式（2）表示的化合物。

8. 发明申请

US20090124806A1 PROCESS FOR PRODUCING CARBOXYLIC ACID FROM PRIMARY ALCOHOL 审中-公开
标题翻译：从一级酒精生产羧酸的方法
公开(公告)号：US20090124806A1
公开(公告)日：2009-05-14
申请号：US12115847
申请日：2008-05-06
申请人： Yoshiharu IWABUCHI , Masatoshi Shibuya , Masaki Tomizawa , Takahisa Sato , Susumu Sato
发明人： Yoshiharu IWABUCHI , Masatoshi Shibuya , Masaki Tomizawa , Takahisa Sato , Susumu Sato
IPC分类号： C07D471/08 , C07D211/94
CPC分类号： C07D471/08 , C07D207/08 , C07D211/94
摘要： To provide an industrially-useful and environmentally-friendly novel oxidation reaction.A process for producing a carboxylic acid from a primary alcohol, which comprises using an alkali metal chlorite as a co-oxidizing agent and using, as a catalyst, an oxoammonium salt of the formula (1):
摘要翻译：提供工业上有用和环保的新型氧化反应。一种由伯醇生产羧酸的方法，其包括使用碱金属亚氯酸盐作为助氧化剂并使用式（1）的氧代铵盐作为催化剂：

9. 发明申请

US20070232838A1 Alcohol Oxidation Catalyst and Method of Synthesizing the Same 审中-公开
标题翻译：醇氧化催化剂及其合成方法
公开(公告)号：US20070232838A1
公开(公告)日：2007-10-04
申请号：US11570756
申请日：2005-06-24
申请人： Yoshiharu Iwabuchi , Masatoshi Shibuya , Masaki Tomizawa
发明人： Yoshiharu Iwabuchi , Masatoshi Shibuya , Masaki Tomizawa
IPC分类号： C07D487/00 , B01J31/02 , C07C29/00
CPC分类号： C07D471/08 , B01J31/006 , B01J31/0235 , B01J31/0237 , B01J2231/70 , C07C45/29
摘要： An organic oxidation catalyst for alcohols which is environmentally less harmful and with which efficient oxidation can be conducted. The oxidation catalyst for alcohols is a 1-alkyl-2-azadamantan-N-oxyl which has a nitroxyl group incorporated in the adamantane skeleton and was synthesized from as a base material a bicyclic compound obtained by the Grob-type ring-opening reaction of 1,3-adamantanediol. Due to the nitroxyl group on the adamantane skeleton, the α-position hydrogen is stabilized based on Bredt's rule and the stability of the oxoammonium group generated by the oxidation thereof is ensured. Compared to TEMPO, which is a conventional oxidation catalyst, this catalyst is reduced in steric hindrance and is usable in a wide range of reaction fields. Because of this, not only a primary alcohol but a secondary alcohol having a sterically complicated structure, which has been difficult to oxidize with TEMPO, can be oxidized at a high efficiency.
摘要翻译：用于醇的有机氧化催化剂，其对环境无害且能够进行有效的氧化。醇的氧化催化剂是在金刚烷骨架中具有硝酰基的1-烷基-2-氮杂金刚烷-N-氧基，其作为基材通过由Grob型开环反应获得的双环化合物合成， 1,3-金刚烷二醇由于金刚烷骨架上的硝酰基，基于Bredt规则使α位氢稳定，并且确保了通过其氧化产生的氧代铵基团的稳定性。与作为常规氧化催化剂的TEMPO相比，该催化剂的空间位阻减小，可用于广泛的反应领域。因此，不仅可以高效地氧化难以用TEMPO氧化的伯醇和具有空间复杂结构的仲醇。

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