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    • 1. 发明授权
    • Process for preparing pyridylmethyl isothiocyanates
    • 制备吡啶基甲基异硫氰酸酯的方法
    • US6166214A
    • 2000-12-26
    • US298593
    • 1999-04-23
    • Klaus WagnerReinhard Lantzsch
    • Klaus WagnerReinhard Lantzsch
    • C07D213/36C07D213/40C07D213/61C07D249/53
    • C07D213/40C07D213/61
    • The present invention relates to a novel process for preparing pyridylmethyl isothiocyanates of the formula (I) ##STR1## in which R.sup.1 represents halogen or C.sub.1 -C.sub.4 -alkyl, characterized in that in a first step, amines of the formula (II) ##STR2## in which R.sup.1 is as defined above, are reacted with xanthogenates of the formula (III)R.sup.2 O--CS--S.sup..crclbar. M.sup..sym. (III)in whichR.sup.2 represents C.sub.1 -C.sub.4 -alkyl, preferably methyl or ethyl andM represents an alkali metal, preferably sodium and potassium or represents ammonium,if appropriate in the presence of a diluent, and in a second step, the resulting novel dithiocarbamates of the formula (IV) ##STR3## in which R.sup.1 and M are each as defined above, are oxidized, if appropriate in the presence of a diluent, to give the isothiocyanates of the formula (I).
    • 本发明涉及一种制备式(I)的吡啶基甲基异硫氰酸酯的新方法,其中R 1表示卤素或C 1 -C 4 - 烷基,其特征在于在第一步中,式(II)的胺其中R1为 与式(III)R2O-CS-S( - )M(+)(III)的黄原酸酯反应,其中R 2表示C 1 -C 4烷基,优选甲基或乙基,M表示碱金属,优选 钠和钾,或代表铵,如果合适,在稀释剂存在下,并且在第二步中,得到的式(Ⅳ)的新型二硫代氨基甲酸酯,其中R 1和M如上所定义,如果适用,则在 存在稀释剂,得到式(I)的异硫氰酸酯。
    • 5. 发明授权
    • Process for the production of a silver halide emulsion
    • 制备卤化银乳剂的方法
    • US5472838A
    • 1995-12-05
    • US272669
    • 1994-07-11
    • Gunter HellingKlaus Wagner
    • Gunter HellingKlaus Wagner
    • G03C7/392G03C7/396G03C1/005
    • G03C7/396G03C7/39236
    • Silver halide emulsions with tabular grains showing increased aspect ratio are produced by adding to the precipitiation vessel a compound of the formula I: ##STR1## in which R.sub.1 means H or optionally substituted alkyl, aralkyl or cycloalkylR.sub.2 means H or optionally substituted alkyl, aryl or aralkyl or a polymer chainR.sub.3 means H, OH, alkyl, aryl, aralkyl, halogen, NHR.sub.4, O--CO--R.sub.4, O--CO--NHR.sub.4 or an optionally substituted oxazoline ringR.sub.4 means optionally substituted or alkyl, aralkyl or arylm means 2 or 3,n means 2 to 10,000,or a compound of the formula II ##STR2## in which R.sub.1, R.sub.3, n and m have the meaning stated above and may be identical or different andR.sub.5 means optionally substituted alkene, arylene, aralkene or a polyaddition, polycondensation or polymerisation chain.
    • 通过向沉淀容器中加入式I化合物(其中R 1表示H或任选取代的烷基,芳烷基或环烷基R 2表示H或任选取代的),产生具有增加的纵横比的片状颗粒的卤化银乳剂 烷基,芳基或芳烷基或聚合物链R3表示H,OH,烷基,芳基,芳烷基,卤素,NHR4,O-CO-R4,O-CO-NHR4或任选取代的恶唑啉环R4表示任选取代的或烷基, 或芳基m表示2或3,n表示2至10,000,或式II(II)化合物,其中R 1,R 3,n和m具有上述含义并且可以相同或不同,R 5表示 任选取代的烯烃,亚芳基,芳烯或加聚,缩聚或聚合链。