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    • 6. 发明授权
    • Preparation of aqueous polymer dispersions having a polymer content of
up to 75% by weight
    • 制备聚合物含量高达75%(重量)的聚合物水分散体
    • US4371659A
    • 1983-02-01
    • US246058
    • 1981-03-20
    • Wolfgang DruschkeAlbrecht KerckowBernd Stanger
    • Wolfgang DruschkeAlbrecht KerckowBernd Stanger
    • C08F2/00C08F2/22C08F2/24C08F2/26C08L35/06
    • C08F2/24
    • Aqueous polymer dispersions containing up to 75% by weight of polymer are prepared advantageously by emulsion copolymerization in the presence of conventional anionic emulsifiers, polymerization initiators and small amounts of polymerization inhibitors, at conventional polymerization temperatures, by copolymerizing at least two monomers A, which per se are not copolymerizable with one another, mixed with from 60 to 95% by weight of at least one monomer B, which is copolymerizable with both monomers A, in the presence of a polymerization inhibitor, by the emulsion feed process, wherein (a) the initial aqueous phase at the start of the monomer emulsion feed contains from 0.01 to 0.5% by weight of anionic emulsifier and from 1 to 7% by weight of water-soluble salts, (b) the monomer emulsion contains from 50 to 500 ppm of polymerization inhibitor, (c) from 1 to 10% by weight of the monomer emulsion is added, within the first 1/2 hour from the start of the feed, at an increasing rate per unit time, to the initial charge and thereafter (d) the remaining monomer emulsion is added in a conventional manner in accordance with the rate of polymerization of the monomers.
    • 含有高达75%(重量)聚合物的聚合物水分散体有利地通过在常规聚合温度下常规阴离子乳化剂,聚合引发剂和少量聚合抑制剂的存在下,通过共聚至少两种单体A 在聚合抑制剂存在下,通过乳液进料方法与60至95重量%的至少一种可与两种单体A共聚的单体B混合,其中(a) 单体乳液进料开始时的初始水相含有0.01至0.5重量%的阴离子乳化剂和1至7重量%的水溶性盐,(b)单体乳液含有50至500ppm的 聚合抑制剂,(c)1至10重量%的单体乳液在从进料开始起的前1/2小时内以每un增加的速率加入 (d)按照常规方式,按照单体的聚合速率加入剩余的单体乳液。