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1. 发明申请

US20090292039A1 OXIME ESTER COMPOUND AND PHOTOPOLYMERIZATION INITIATOR CONTAINING THE SAME 审中-公开
标题翻译：含有酯化合物和含有它的光聚合引发剂
公开(公告)号：US20090292039A1
公开(公告)日：2009-11-26
申请号：US12447139
申请日：2007-12-21
申请人： Daisuke Sawamoto , Koichi Kimijima , Kiyoshi Murata , Yasunori Kozaki , Takeo Oishi
发明人： Daisuke Sawamoto , Koichi Kimijima , Kiyoshi Murata , Yasunori Kozaki , Takeo Oishi
IPC分类号： C08F2/50 , C07D209/82
CPC分类号： C08F2/50 , C07D209/88 , G03F7/0045 , G03F7/031
摘要： Disclosed is an oxime ester compound represented by the following general formula (I). (In the formula, R1, R2 and R3 independently represent R11, OR11, COR11, SR11, CONR12R13 or CN; R11, R12 and R13 Independently represent a hydrogen atom, an alkyl group having 1-20 carbon atoms, an aryl group having 6-30 carbon atoms, an arylalkyl group having 7-30 carbon atoms or a heterocyclic group having 2-20 carbon atoms; R4 and R5 independently represent R11, OR11, SR11, COR11, CONR12R13, NR12COR11, OCOR11, COOR11, SCOR11, OCSR11, COSR11, CSOR11, CN, a halogen atom or a hydroxy group; and a and b independently represent a number of 0-3.)
摘要翻译：公开了由以下通式（I）表示的肟酯化合物。（式中，R 1，R 2，R 3独立地表示R 11，OR 11，COR 11，SR 11，CONR 12 R 13或CN; R 11，R 12和R 13独立地表示氢原子，碳原子数为1〜20的烷基， -30个碳原子的芳基烷基或具有2-20个碳原子的杂环基; R4和R5独立地表示R11，OR11，SR11，COR11，CONR12R13，NR12COR11，OCOR11，COOR11，SCOR11，OCSR11， COSR11，CSOR11，CN，卤原子或羟基; a和b独立地表示0-3的数）。

2. 发明授权

US08148045B2 Oxime ester compound and photopolymerization initiator containing the same 有权
标题翻译：肟酯化合物和含有它的光聚合引发剂
公开(公告)号：US08148045B2
公开(公告)日：2012-04-03
申请号：US12950275
申请日：2010-11-19
申请人： Kiyoshi Murata , Takeo Oishi , Koichi Kimijima
发明人： Kiyoshi Murata , Takeo Oishi , Koichi Kimijima
IPC分类号： G03F7/00 , G03F7/004 , G03F7/028 , C07C69/16 , C07C321/30
CPC分类号： C08F2/50 , B33Y70/00 , C07C251/66 , C07C323/47 , C07C323/65 , C07C391/02 , C07C2601/14 , C07F9/5022 , G03F7/0042 , G03F7/0045 , G03F7/031 , G03F7/033 , G03F7/105 , Y10S430/114
摘要： A novel compound is a highly-sensitive photopolymerization initiator with excellent stability, low sublimability, excellent developability, and high transmittance in the visible region. It efficiently absorbs, and is activated by, near-ultraviolet rays such as at 365 nm. Also provided are a photopolymerization initiator and a photosensitive composition using such compound. An oxime ester compound is represented by the following general formula (I), a photopolymerization initiator containing the same, and a photosensitive composition containing the photopolymerization initiator and a polymerizable compound having an ethylenically unsaturated bond: R1 and R2 each represent R11, COR11, CONR12R13, CN, etc.; R11, R12, and R13 each represent a C1-20 alkyl group, etc.; R3 and R4 each represent R11, OR11, COR11, CONR12R13, OCOR11, CN, a halogen atom, etc.; a and b each represent an integer 0-4; X represents an oxygen atom, a sulfur atom, etc.; and R5 represents OH, COOH, or a group represented by general formula (II).
摘要翻译：新型化合物是可见光区域中具有优异的稳定性，低升华性，优异的显影性和高透射率的高灵敏度光聚合引发剂。它有效地吸收并被诸如365nm的近紫外线激发。还提供了光聚合引发剂和使用这种化合物的光敏组合物。肟酯化合物由以下通式（I）表示，含有该肟酯化合物的光聚合引发剂和含有光聚合引发剂的光敏组合物和具有烯键式不饱和键的可聚合化合物：R1和R2各自表示R11，COR11，CONR12R13 ，CN等; R11，R12和R13各自表示C1-20烷基等; R 3和R 4各自表示R 11，OR 11，COR 11，CONR 12 R 13，OCOR 11，CN，卤素原子等; a和b各自表示0-4的整数; X表示氧原子，硫原子等; 并且R 5表示OH，COOH或由通式（II）表示的基团。

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