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    • 3. 发明授权
    • Method of making a liquid crystal device
    • 制造液晶装置的方法
    • US06331884B1
    • 2001-12-18
    • US09115495
    • 1998-07-14
    • Naoki MasazumiNobuyuki KobayashiMasakazu OkadaKiyofumi HashimotoTakuji Hatano
    • Naoki MasazumiNobuyuki KobayashiMasakazu OkadaKiyofumi HashimotoTakuji Hatano
    • G02F11339
    • G02F1/133377G02F1/13718
    • A method of making a liquid crystal device having a plurality of cells of liquid crystal material, includes the steps of: (a) preparing a first base having a first surface; (b) providing a first phase of a material and a plurality of second phases of at least one liquid crystal material on the first surface, said second phases being spatially dispersed in a first prescribed pattern; (c providing a second base having a second surface, the second surface being substantially in contact with the first and second phases; and (d) solidifying the material of the first phase. The liquid crystal cells are formed of the dispersed liquid crystal materials. The plurality of second phases may include at least a group of liquid crystal materials which exhibits a cholesteric characteristic having a selective reflection wavelength in the visible range and a group of liquid crystal materials which exhibits a cholesteric characteristic having a different selective reflection wavelength in the visible range.
    • 制造具有多个液晶材料单元的液晶装置的方法包括以下步骤:(a)制备具有第一表面的第一基底; (b)在第一表面上提供至少一种液晶材料的材料和多个第二相的第一相,所述第二相以第一规定图案空间分散; (c)提供具有第二表面的第二基底,所述第二表面基本上与所述第一和第二相接触;以及(d)固化所述第一相的材料,所述液晶单元由分散的液晶材料形成。 多个第二相可以包括至少一组液晶材料,其表现出在可见光范围内具有选择性反射波长的胆甾醇特征,以及一组在可见光下具有不同选择反射波长的胆甾醇特性的液晶材料 范围。
    • 7. 发明授权
    • Liquid crystal device having a resin wall using different resins with
different surface interactions structure and manufacturing method for
same
    • 具有使用具有不同表面相互作用结构的不同树脂的树脂壁的液晶装置及其制造方法
    • US6130738A
    • 2000-10-10
    • US71114
    • 1998-05-01
    • Takuji HatanoMasakazu Okada
    • Takuji HatanoMasakazu Okada
    • G02F1/13G02F1/1333G02F1/1337G02F1/1339
    • G02F1/133377
    • A liquid crystal device that includes a pair of substrates and a composite layer disposed between the substrates. The composite layer has a liquid crystal phase of a liquid crystal material and a resin phase of a resin. The liquid crystal device is made such that the resin phase comprises a resin wall structure which does not contain a substantial amount of the liquid crystal material. To enhance contrast and viewing angle, the resin phase has a rough surface which is sufficient to disarrange an orientation of molecules of the liquid crystal material. The invention is further directed to a method of manufacturing a liquid crystal device, which includes the steps of defining a mixing ratio of two kinds of resin raw materials that have different contact angles, mixing these kinds of resin raw materials, mixing the mixed raw material with a liquid crystal material, and separating the mixed material from the liquid crystal material. In a preferred embodiment the resulting resin phase would have a contact angle with respect to the liquid crystal material in the range of 11.degree. to 15.degree..
    • 一种液晶装置,包括一对基板和设置在基板之间的复合层。 复合层具有液晶材料的液晶相和树脂的树脂相。 液晶装置被制成使得树脂相包括不含有大量液晶材料的树脂壁结构。 为了增强对比度和视角,树脂相具有足以使液晶材料分子的取向歧化的粗糙表面。 本发明还涉及一种液晶装置的制造方法,其特征在于,包括以下步骤:确定两种具有不同接触角的树脂原料的混合比例,混合这些树脂原料,混合混合原料 与液晶材料一起分离混合材料。 在优选的实施方式中,所得到的树脂相相对于液晶材料的接触角在11°至15°的范围内。
    • 8. 发明授权
    • Liquid crystal device with composite layer of cured resin pillars and liquid crystal phase and method of producing the same
    • 具有固化树脂柱和液晶相复合层的液晶装置及其制造方法
    • US06331881B1
    • 2001-12-18
    • US09072402
    • 1998-05-04
    • Takuji HatanoMasakazu Okada
    • Takuji HatanoMasakazu Okada
    • G02F11333
    • G02F1/133377G02F1/13394G02F1/13718G02F2203/30
    • A liquid crystal device comprises a pair of substrates; and a composite layer disposed between the pair of substrates, the composite layer including a resin phase and a liquid crystal phase of a liquid crystal material exhibiting cholesteric characteristic, the composite layer having an area defining one pixel, and the area including a plurality of regions being different from each other in condition of the resin phase. A method of producing a liquid crystal device comprises the steps of defining an area corresponding to one pixel; and forming a plurality of regions of composite layer in the area, the composite layer including a resin phase and a liquid crystal phase of a liquid crystal material exhibiting cholesteric characteristic, and each of the regions being different from the others in condition of the resin phase. The step of forming the regions may include the steps of supplying a composition of the liquid crystal material and the resin material into a space between the paired substrates; and separating the liquid crystal material in a region corresponding to each of the regions from the resin under a condition different from the others. If the resin material is a photo-curing resin material, the separating step may include the steps of masking the composition with a mask having a plurality of regions, each of which has a plurality of openings and is different from the others in condition of the openings; and exposing the composition to light through the mask.
    • 液晶装置包括一对基板; 以及配置在所述一对基板之间的复合层,所述复合层包括树脂相和显示胆甾醇特性的液晶材料的液晶相,所述复合层具有限定一个像素的区域,所述区域包括多个区域 在树脂相的条件下彼此不同。 制造液晶装置的方法包括以下步骤:定义对应于一个像素的区域; 并且在该区域中形成复合层的多个区域,复合层包括树脂相和显示胆甾醇特性的液晶材料的液晶相,并且每个区域在树脂相的条件下不同于其他区域 。 形成区域的步骤可以包括以下步骤:将液晶材料和树脂材料的组合物供给到成对的基板之间的空间中; 并且在与其他区域不同的条件下,将与每个区域相对应的区域中的液晶材料与树脂分离。 如果树脂材料是光固化树脂材料,则分离步骤可以包括以下步骤:用具有多个区域的掩模掩蔽该组合物,每个区域具有多个开口,并且在 开口 并通过掩模将组合物曝光。
    • 9. 发明授权
    • Liquid crystal element
    • 液晶元件
    • US6124908A
    • 2000-09-26
    • US872202
    • 1997-06-10
    • Nobuyuki KobayashiTakuji HatanoMasakazu OkadaNaoki Masazumi
    • Nobuyuki KobayashiTakuji HatanoMasakazu OkadaNaoki Masazumi
    • C09K19/54G02F1/1334G02F1/137G02F1/1335
    • C09K19/542G02F1/1334G02F1/13718
    • A liquid crystal element has a pair of substrates at least one of which is transparent, and a composite layer, which is retained between said pair of substrates, comprising a transparent resin matrix and a liquid crystal material having cholesteric characteristics.(1) In the liquid crystal element, a contact angle between the liquid crystal material and the resin used in the transparent resin matrix is 30.degree. or less.(2) In the liquid crystal element, said liquid crystal material reflects a light component having a wavelength in a range from 1.0 .mu.m to 1.5 .mu.m in a planar state.(3) In the liquid crystal element, said transparent resin matrix is formed by polymerizing of a mixture of compound having the following formula (1) and multi-functional acrylate derivative, ##STR1## wherein n is a natural number from 1 to 2.
    • 液晶元件具有至少一个透明的一对基板,并且保持在所述一对基板之间的复合层包括透明树脂基体和具有胆甾醇特性的液晶材料。 (1)在液晶元件中,透明树脂基体中使用的液晶材料与树脂的接触角为30°以下。 (2)在液晶元件中,所述液晶材料在平面状态下反射波长在1.0μm至1.5μm范围内的光成分。 (3)在液晶元件中,所述透明树脂基体是通过使具有下式(1)的化合物和多官能丙烯酸酯衍生物的混合物聚合形成的,其中n为1〜2的自然数。