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1. 发明申请

US20180044541A1 NON-FLUORINATED WATER-BASED SUPERHYDROPHOBIC COMPOSITIONS 审中-公开
公开(公告)号：US20180044541A1
公开(公告)日：2018-02-15
申请号：US15551634
申请日：2016-02-25
申请人： Kimberly-Clark Worldwide, Inc. , The Board of Truestees of the University of Illinois
发明人： Jian Qin , Donald Eugene Waldroup , Deborah Joy Calewarts , Constantine Michael Megaridis , Joseph Edward Mates
IPC分类号： C09D5/16 , C09D123/08 , C08K3/00 , C08L23/06 , C08L23/14 , C08K3/22 , C09D7/12 , C09D123/14
CPC分类号： C09D5/1681 , C08K3/013 , C08K3/22 , C08K2003/2241 , C08L23/06 , C08L23/14 , C08L2201/54 , C09D7/67 , C09D123/08 , C09D123/14
摘要： A superhydrophobic non-fluorinated composition includes a hydrophobic matrix component free of fluorine, a hydrophilic filler particles, wherein the filler particles are metal oxide nanoparticles, and water, wherein the hydrophobic component is in an aqueous dispersion. Also, a superhydrophobic non-fluorinated composition includes a hydrophobic polymer free of fluorine, a titanium dioxide nanoparticle filler particle, and water. In addition, a superhydrophobic non-fluorinated composition includes a hydrophobic polymer free of fluorine, wherein the hydrophobic polymer includes a polyolefin, titanium dioxide nanoparticles as filler, wherein the titanium dioxide nanoparticles are rutile titanium dioxide, anatase titanium dioxide, or a mixture of rutile and anatase titanium dioxide, and water.

2. 发明授权

US10533096B2 Non-fluorinated water-based superhydrophobic compositions 有权
公开(公告)号：US10533096B2
公开(公告)日：2020-01-14
申请号：US15551634
申请日：2016-02-25
申请人： KIMBERLY-CLARK WORLDWIDE, INC. , THE BOARD OF TRUSTEES OF THE UNIVERSITY OF ILLINOIS
发明人： Jian Qin , Donald Eugene Waldroup , Deborah Joy Calewarts , Constantine Michael Megaridis , Joseph Edward Mates
IPC分类号： C09D5/16 , C08K3/013 , C08K3/22 , C09D7/40 , C08L23/06 , C08L23/14 , C09D123/08 , C09D123/14
摘要： A superhydrophobic non-fluorinated composition includes a hydrophobic matrix component free of fluorine, a hydrophilic filler particles, wherein the filler particles are metal oxide nanoparticles, and water, wherein the hydrophobic component is in an aqueous dispersion. Also, a superhydrophobic non-fluorinated composition includes a hydrophobic polymer free of fluorine, a titanium dioxide nanoparticle filler particle, and water. In addition, a superhydrophobic non-fluorinated composition includes a hydrophobic polymer free of fluorine, wherein the hydrophobic polymer includes a polyolefin, titanium dioxide nanoparticles as filler, wherein the titanium dioxide nanoparticles are rutile titanium dioxide, anatase titanium dioxide, or a mixture of rutile and anatase titanium dioxide, and water.

3. 发明授权

US10233296B2 Method of forming creped thin film-like structures from frothed chemistry 有权
公开(公告)号：US10233296B2
公开(公告)日：2019-03-19
申请号：US13905429
申请日：2013-05-30
申请人： Kimberly-Clark Worldwide, Inc.
发明人： Keyur Desai , Jian Qin , Jeffrey Frank Jurena , Frank Paul Abuto , Susan Elaine Shawver , Donald Eugene Waldroup , Deborah Joy Calewarts
IPC分类号： C08J5/18 , B29C41/08
摘要： A method is presented for forming a collapsed foam film-like structure, the method including positioning a composition applicator adjacent to a hot non-permeable dryer surface, producing a first frothed dispersion or frothed solution from a first dispersion or solution, applying the first frothed dispersion or frothed solution to the dryer surface, allowing the first frothed dispersion or frothed solution to convert to a collapsed foam film-like structure, and scraping the collapsed foam film-like structure from the dryer surface. The method can further include producing a second dispersion or solution, blending the first dispersion or solution and the second dispersion or solution, frothing the blended dispersion or solution, applying the blended frothed dispersion or frothed solution to the dryer surface, and allowing the frothed dispersion or frothed solution to convert to a collapsed foam film-like structure.

4. 发明授权

US09410292B2 Multilayered tissue having reduced hydrogen bonding 有权
标题翻译：具有降低氢键的多层组织
公开(公告)号：US09410292B2
公开(公告)日：2016-08-09
申请号：US14416504
申请日：2013-12-20
申请人： Kimberly-Clark Worldwide, Inc.
发明人： Stephen Michael Lindsay , Michael Andrew Zawadzki , Jian Qin , Mike Thomas Goulet , Cathleen Mae Uttecht , Donald Eugene Waldroup , Deborah Joy Calewarts , Kenneth John Zwick
IPC分类号： D21H27/40 , D21H27/00 , D21H21/22 , D21H27/38 , D21C9/00 , D21H11/16
CPC分类号： D21H27/40 , D21C9/005 , D21H11/16 , D21H21/22 , D21H27/002 , D21H27/005 , D21H27/38
摘要： The disclosure provides a multilayered tissue web comprising treated cellulosic fibers selectively disposed in one or more layers, wherein the tissue layer comprising treated fibers is adjacent to a layer comprising untreated fiber and which is substantially free from untreated fiber. Generally the treated fibers have a rate of substitution of about 0.02 to 0.07. In this manner, the disclosure provides a multi-layered tissue web having treated fiber selectively incorporated therein, where the tissue web has basis weight greater than about 10 grams per square meter (gsm), such as from about 10 to about 50 gsm, a sheet bulk greater than about 8 cc/g, such as from about 8 to about 15 cc/g and Stiffness Index less than about 15, such as from about 8 to about 12.
摘要翻译：本公开提供了包含选择性地设置在一个或多个层中的经处理的纤维素纤维的多层织物网，其中包含经处理的纤维的组织层与包含未处理的纤维的层相邻，并且基本上不含未处理的纤维。通常处理的纤维具有约0.02至0.07的取代率。以这种方式，本公开提供了一种具有选择性地结合在其中的经处理纤维的多层纸巾纸，其中纸巾纸的基重大于约10克/平方米（gsm），例如约10至约50gsm，片状体积大于约8cc / g，例如约8至约15cc / g，刚度指数小于约15，例如约8至约12。

5. 发明授权

US08834679B2 Soft tissue having reduced hydrogen bonding 有权
标题翻译：软组织具有降低的氢键
公开(公告)号：US08834679B2
公开(公告)日：2014-09-16
申请号：US13726904
申请日：2012-12-26
申请人： Kimberly-Clark Worldwide, Inc.
发明人： JeongKyung Kim , SeungRim Yang , Jian Qin , Deborah Joy Calewarts
IPC分类号： D21H21/22 , D21H17/07 , D21H17/11 , D21H23/04 , D21H23/76 , D21C1/06
CPC分类号： D21H23/76 , D06M13/364 , D06M23/10 , D06M2101/06 , D21C9/005 , D21H11/16 , D21H17/07 , D21H17/11 , D21H21/22 , D21H23/04 , D21H27/002 , Y10T442/689
摘要： The present invention provides a modified cellulosic fiber having reduced hydrogen bonding capabilities. The modified fiber formed in accordance with the present invention may be useful in the production of tissue products having improved bulk and softness. More importantly, the modified fiber is adaptable to current tissue making processes and may be incorporated into a tissue product to improve bulk and softness without an unsatisfactory reduction in tensile.
摘要翻译：本发明提供具有降低的氢键能力的改性纤维素纤维。根据本发明形成的改性纤维可用于生产具有改善体积和柔软度的纸巾制品。更重要的是，改性纤维适用于当前的组织制备方法，并且可以并入组织产品中以改善体积和柔软度，而不会令人不满意的拉伸减小。

6. 发明申请

US20140357743A1 Method Of Forming Creped Thin Film-Like Structures From Frothed Chemistry 审中-公开
标题翻译：从起泡化学形成起皱薄膜状结构的方法
公开(公告)号：US20140357743A1
公开(公告)日：2014-12-04
申请号：US13905429
申请日：2013-05-30
申请人： Kimberly-Clark Worldwide, Inc.
发明人： Keyur Desai , Jian Qin , Jeffrey Frank Jurena , Frank Paul Abuto , Susan Elaine Shawver , Donald Eugene Waldroup , Deborah Joy Calewarts
IPC分类号： C08J5/18
CPC分类号： C08J5/18 , B29C41/085 , C08J2323/08
摘要： A method is presented for forming a collapsed foam film-like structure, the method including positioning a composition applicator adjacent to a hot non-permeable dryer surface, producing a first frothed dispersion or frothed solution from a first dispersion or solution, applying the first frothed dispersion or frothed solution to the dryer surface, allowing the first frothed dispersion or frothed solution to convert to a collapsed foam film-like structure, and scraping the collapsed foam film-like structure from the dryer surface. The method can further include producing a second dispersion or solution, blending the first dispersion or solution and the second dispersion or solution, frothing the blended dispersion or solution, applying the blended frothed dispersion or frothed solution to the dryer surface, and allowing the frothed dispersion or frothed solution to convert to a collapsed foam film-like structure.
摘要翻译：提出了一种用于形成塌陷的泡沫膜状结构的方法，该方法包括将组合物施用器定位成与热不可渗透干燥器表面相邻，从第一分散体或溶液产生第一发泡分散体或起泡溶液，施加第一发泡分散或发泡的溶液到干燥器表面，允许第一发泡的分散体或发泡的溶液转化成塌陷的泡沫膜状结构，并且从干燥器表面刮下塌陷的泡沫膜状结构。该方法还可以包括制备第二分散体或溶液，将第一分散体或溶液与第二分散体或溶液混合，使共混的分散体或溶液起泡，将混合的发泡分散体或发泡的溶液施加到干燥器表面，或发泡的溶液转化成塌陷的泡沫膜状结构。

7. 发明申请

US20140178660A1 SOFT TISSUE HAVING REDUCED HYDROGEN BONDING 有权
公开(公告)号：US20140178660A1
公开(公告)日：2014-06-26
申请号：US13726904
申请日：2012-12-26
申请人： KIMBERLY-CLARK WORLDWIDE, INC.
发明人： JeongKyung Kim , SeungRim Yang , Jian Qin , Deborah Joy Calewarts
IPC分类号： D21C1/06
CPC分类号： D21H23/76 , D06M13/364 , D06M23/10 , D06M2101/06 , D21C9/005 , D21H11/16 , D21H17/07 , D21H17/11 , D21H21/22 , D21H23/04 , D21H27/002 , Y10T442/689
摘要： The present invention provides a modified cellulosic fiber having reduced hydrogen bonding capabilities. The modified fiber formed in accordance with the present invention may be useful in the production of tissue products having improved bulk and softness. More importantly, the modified fiber is adaptable to current tissue making processes and may be incorporated into a tissue product to improve bulk and softness without an unsatisfactory reduction in tensile.

8. 发明申请

US20150176222A1 MULTILAYERED TISSUE HAVING REDUCED HYDROGEN BONDING 有权
标题翻译：具有减少氢键的多层组织
公开(公告)号：US20150176222A1
公开(公告)日：2015-06-25
申请号：US14416504
申请日：2013-12-20
申请人： Kimberly-Clark Worldwide, Inc.
发明人： Stephen Michael Lindsay , Michael Andrew Zawadzki , Jian Qin , Mike Thomas Goulet , Cathleen Mae Uttecht , Donald Eugene Waldroup , Deborah Joy Calewarts , Kenneth John Zwick
IPC分类号： D21H27/40 , D21H27/00 , D21H21/22 , D21H27/38
CPC分类号： D21H27/40 , D21C9/005 , D21H11/16 , D21H21/22 , D21H27/002 , D21H27/005 , D21H27/38
摘要： The disclosure provides a multilayered tissue web comprising treated cellulosic fibers selectively disposed in one or more layers, wherein the tissue layer comprising treated fibers is adjacent to a layer comprising untreated fiber and which is substantially free from untreated fiber. Generally the treated fibers have a rate of substitution of about 0.02 to 0.07. In this manner, the disclosure provides a multi-layered tissue web having treated fiber selectively incorporated therein, where the tissue web has basis weight greater than about 10 grams per square meter (gsm), such as from about 10 to about 50 gsm, a sheet bulk greater than about 8 cc/g, such as from about 8 to about 15 cc/g and Stiffness Index less than about 15, such as from about 8 to about 12.
摘要翻译：本公开提供了包含选择性地设置在一个或多个层中的经处理的纤维素纤维的多层织物网，其中包含经处理的纤维的组织层与包含未处理的纤维的层相邻，并且基本上不含未处理的纤维。通常处理的纤维具有约0.02至0.07的取代率。以这种方式，本公开提供了一种具有选择性地结合在其中的经处理纤维的多层纸巾纸，其中纸巾纸的基重大于约10克/平方米（gsm），例如约10至约50gsm，片状体积大于约8cc / g，例如约8至约15cc / g，刚度指数小于约15，例如约8至约12。

9. 发明申请

US20140102650A1 Stretchable Nonwoven Materials 审中-公开
标题翻译：可拉伸无纺布材料
公开(公告)号：US20140102650A1
公开(公告)日：2014-04-17
申请号：US14109632
申请日：2013-12-17
申请人： Kimberly-Clark Worldwide, Inc.
发明人： Jian Qin , Donald Eugene Waldroup , Deborah Joy Calewarts , Keyur Desai
IPC分类号： D21F11/00
CPC分类号： D21F11/002 , A61F13/51 , A61K8/0208 , A61K8/39 , A61K8/8111 , A61K8/96 , A61Q19/00 , A61Q19/10 , B32B5/022 , B32B5/20 , B32B5/245 , B32B37/12 , B32B38/145 , B32B2262/0253 , B32B2262/067 , B32B2305/20 , B32B2307/51 , B32B2307/726 , B32B2307/75 , B32B2555/00 , B32B2555/02 , D04H1/552 , D06M13/17 , D06M15/227 , D06M15/263 , D06M23/04 , D06N3/0045 , D06N3/0047 , D21H27/002 , D21H27/005
摘要： The present invention provides a nonwoven substrate comprising a fibrous web defining a surface; and a layer of a benefit agent wherein said benefit agent is selected from an additive composition, an enhancement component and combinations thereof; wherein said benefit agent is frothed and bonded to the fibrous web surface through a creping process and wherein said nonwoven substrate demonstrates improvements selected from enhanced tactile feel, enhanced printing, a decrease in hysteresis, an increase in bulk, an increase in elasticity/extensibility, an increase in retractability, a reduction in rugosities and combinations thereof when compared to an untreated substrate.
摘要翻译：本发明提供一种非织造基底，其包括限定表面的纤维网; 和有益试剂层，其中所述有益试剂选自添加剂组合物，增强组分及其组合; 其中所述有益剂通过起皱过程被发泡并结合到纤维幅材表面，并且其中所述无纺衬底表现出从增强的触感，增强印刷，滞后减小，增加体积，增加弹性/伸长性，与未处理的基材相比，收缩性的增加，皱纹的减少和组合的减少。

10. 发明申请

US20140099469A1 Polymer Webs Having Enhanced Softness 审中-公开
标题翻译：具有增强柔软度的聚合物网
公开(公告)号：US20140099469A1
公开(公告)日：2014-04-10
申请号：US14106101
申请日：2013-12-13
申请人： Kimberly-Clark Worldwide, Inc.
发明人： Frank Paul Abuto , Virginia Lee Day , Ray A. Sterling , Michael J. Faulks , Donald Eugene Waldroup , David G. Biggs , Jian Qin , Deborah Joy Calewarts
IPC分类号： D04H3/16 , D04H3/08 , D04H11/00
CPC分类号： D04H3/16 , A61F13/51121 , A61F13/513 , A61K8/0208 , A61K8/8111 , A61K9/70 , A61Q19/00 , A61Q19/10 , B32B5/022 , B32B5/20 , B32B5/245 , B32B27/12 , B32B37/12 , B32B38/145 , B32B2305/20 , B32B2307/51 , B32B2307/75 , B32B2555/00 , B32B2555/02 , D04H1/4291 , D04H1/4326 , D04H1/488 , D04H1/552 , D04H3/08 , D04H11/00 , Y10T428/23929 , Y10T428/24446
摘要： The present invention provides a nonwoven substrate comprising a fibrous web defining a surface; and a layer of a benefit agent wherein said benefit agent is selected from an additive composition, an enhancement component and combinations thereof; wherein said benefit agent is frothed and bonded to the fibrous web surface through a creping process and wherein said nonwoven substrate demonstrates improvements selected from enhanced tactile feel, enhanced printing, a decrease in hysteresis, an increase in bulk, an increase in elasticity/extensibility, an increase in retractability, a reduction in rugosities and combinations thereof when compared to an untreated substrate.
摘要翻译：本发明提供一种非织造基底，其包括限定表面的纤维网; 和有益试剂层，其中所述有益试剂选自添加剂组合物，增强组分及其组合; 其中所述有益剂通过起皱过程被发泡并结合到纤维幅材表面，并且其中所述无纺衬底表现出从增强的触感，增强印刷，滞后减小，增加体积，增加弹性/伸长性，与未处理的基材相比，收缩性的增加，皱纹的减少和组合的减少。

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