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1. 发明授权

US07943789B2 Alkenylsuccinic anhydride composition and method of using the same 失效
标题翻译：烯基琥珀酸酐组合物及其使用方法
公开(公告)号：US07943789B2
公开(公告)日：2011-05-17
申请号：US10533702
申请日：2003-12-17
申请人： Harold A. Goldsberry, III , Kimberly C. Dilts , Charles R. Hunter , Michael P. O'Toole , Robert J. Proverb , Lucyna Pawlowska , Glenn E. Baikow , Katarzyna Komarowska , David L. Dauplaise , Michael J. Scanlon
发明人： Harold A. Goldsberry, III , Kimberly C. Dilts , Charles R. Hunter , Michael P. O'Toole , Robert J. Proverb , Lucyna Pawlowska , Glenn E. Baikow , Katarzyna Komarowska , David L. Dauplaise , Michael J. Scanlon
IPC分类号： C07D307/60
CPC分类号： D21H21/16 , D06M13/192 , D06M15/11 , D21H17/16 , D21H17/28
摘要： The invention relates to an aqueous sizing composition comprising (a) an emulsion comprising an alkenylsuccinic anhydride component containing alkenylsuccinic anhydride particles suspended in a first starch component containing emulsifying starch selected from the group consisting of non-ionic starches, ionic starches, and mixtures thereof, and (b) a second starch component selected from the group consisting of non-ionic starches, ionic starches and mixtures thereof, such that the alkenylsuccinic anhydride and the starch in the emulsion and the second starch component are present at a starch: alkenylsuccinic anhydride weight ratio that is sufficiently high to enable the sizing composition to impart useful sizing properties to a fibrous substrate when the sizing composition contacts the fibrous substrate. The invention also relates to fibrous substrates treated with the sizing composition, processes for making the composition and processes for using such a composition, and other compositions. In one embodiment, alkylene ketene dimer is used instead of alkenylsuccinic anhydride.
摘要翻译：本发明涉及水性施胶组合物，其包含（a）乳液，其包含含有链烯基琥珀酸酐组分的链烯基琥珀酸酐组分，所述烯基琥珀酸酐组分悬浮于含有非离子淀粉，离子淀粉及其混合物的含乳化淀粉的第一淀粉组分中，和（b）选自非离子淀粉，离子淀粉及其混合物的第二淀粉组分，使得乳液中的烯基琥珀酸酐和淀粉和第二淀粉组分存在于淀粉：链烯基琥珀酸酐重量比率足够高以使上胶料组合物在施胶组合物接触纤维基材时能赋予纤维基质有用的施胶性能。本发明还涉及用施胶组合物处理的纤维基质，制备组合物的方法和使用这种组合物的方法以及其它组合物。在一个实施方案中，使用亚烷基烯酮二聚体代替烯基琥珀酸酐。

2. 发明申请

US20090277355A1 ALKENYLSUCCINIC ANHYDRIDE SURFACE-APPLIED SYSTEM AND USES THEREOF 审中-公开
标题翻译：烷基磺酸盐表面应用体系及其用途
公开(公告)号：US20090277355A1
公开(公告)日：2009-11-12
申请号：US12505578
申请日：2009-07-20
申请人： Lucyna Pawlowska , Kimberly C. Dilts , Charles R. Hunter , Michael P. O'Toole , Robert J. Proverb , Thomas T. Long , Gina Garro , David L. Dauplaise , Katarzyna Komarowska , Harold A. Goldsberry, III , Glenn E. Baikow
发明人： Lucyna Pawlowska , Kimberly C. Dilts , Charles R. Hunter , Michael P. O'Toole , Robert J. Proverb , Thomas T. Long , Gina Garro , David L. Dauplaise , Katarzyna Komarowska , Harold A. Goldsberry, III , Glenn E. Baikow
IPC分类号： C09D103/02
CPC分类号： D06M13/192 , D06M2200/40 , D21H17/16 , D21H17/28 , D21H17/29 , D21H21/16 , D21H21/24 , D21H21/52
摘要： The invention relates to an aqueous sizing composition including: (a) a first component comprising an emulsion having an alkenylsuccinic anhydride component containing alkenylsuccinic anhydride particles and a surfactant component; suspended in water; and (b) a second component selected from the group consisting of cationic starches, non-ionic starches, anionic starches, water, water-soluble polymers, and mixtures thereof; such that the alkenylsuccinic anhydride component and the second component are sufficiently diluted to enable the sizing composition to impart useful sizing properties to a fibrous substrate when the sizing composition contacts the fibrous substrate. The invention also relates to fibrous substrates treated with such a composition as well as processes for making and using the composition. In one embodiment, alkyl ketene dimer is used instead of alkenylsuccinic anhydride.
摘要翻译：本发明涉及水性施胶组合物，其包括：（a）第一组分，其包含具有含有烯基琥珀酸酐颗粒和表面活性剂组分的烯基琥珀酸酐组分的乳液; 悬浮在水中和（b）选自阳离子淀粉，非离子淀粉，阴离子淀粉，水，水溶性聚合物及其混合物的第二组分; 使得烯基琥珀酸酐组分和第二组分被充分稀释，使得上浆组合物能够在施胶组合物接触纤维基材时赋予纤维基质有用的施胶性能。本发明还涉及用这种组合物处理的纤维基材以及制备和使用该组合物的方法。在一个实施方案中，使用烷基烯酮二聚体代替烯基琥珀酸酐。

3. 发明授权

US06576049B1 Paper sizing compositions and methods 失效
标题翻译：纸张施胶组合物和方法
公开(公告)号：US06576049B1
公开(公告)日：2003-06-10
申请号：US09573373
申请日：2000-05-18
申请人： Kimberly C. Dilts , Robert J. Proverb , David L. Dauplaise
发明人： Kimberly C. Dilts , Robert J. Proverb , David L. Dauplaise
IPC分类号： C09D712
CPC分类号： D21H21/16 , D21H17/16 , D21H17/17 , D21H17/62
摘要： This invention relates to paper sizing compositions comprised of at least one sizing agent selected from ASA, AKD and rosin where the at least one sizing agent is emulsified in water, at least one emulsion stabilizer, and from about 0.01% to about 15% by weight of at least one hydrophobic substance, based on the total weight of sizing agent present, provided that the hydrophobic substance is not highly alkoxylated. The sizing promotion efficiency of the paper sizing compositions, as determined by at least one method selected from the Cytec size testing method, the Hercules size testing method, and the Cobb size testing method, is greater than or equal to about 4. Exemplary hydrophobic substances include fatty acid esters, triglycerides, hydrocarbons, esters and/or amides derived from ASA, silicone oils, alcohols, and stearic anhydride. The invention also relates to methods for sizing paper products with these paper sizing compositions and paper or paperboard treated with these sizing compositions.
摘要翻译：本发明涉及由至少一种选自ASA，AKD和松香的上浆剂组成的纸浆施胶组合物，其中至少一种施胶剂在水中乳化，至少一种乳化稳定剂和约0.01重量％至约15重量％的至少一种疏水性物质，基于存在的施胶剂的总重量，条件是疏水性物质不是高度烷氧基化的。通过选自Cytec尺寸测试方法，Hercules尺寸测试方法和Cobb尺寸测试方法中的至少一种方法确定的纸浆施胶组合物的施胶效率大于或等于约4.示例性疏水物质包括衍生自ASA，脂肪酸酯，甘油三酸酯，烃，酯和/或酰胺衍生自ASA，硅油，醇和硬脂酸酐。本发明还涉及用这些上胶组合物和用这些施胶组合物处理的纸或纸板来调整纸制品的方法。

4. 发明授权

US06666952B2 Paper sizing compositions and methods 失效
公开(公告)号：US06666952B2
公开(公告)日：2003-12-23
申请号：US10431741
申请日：2003-05-06
申请人： Kimberly C. Dilts , Robert J. Proverb , David L. Dauplaise
发明人： Kimberly C. Dilts , Robert J. Proverb , David L. Dauplaise
IPC分类号： C09D712
CPC分类号： D21H21/16 , D21H17/16 , D21H17/17 , D21H17/62
摘要： This invention relates to paper sizing compositions comprised of at least one sizing agent selected from ASA, AKD and rosin where the at least one sizing agent is emulsified in water, at least one emulsion stabilizer, and from about 0.01% to about 15% by weight of at least one hydrophobic substance, based on the total weight of sizing agent present, provided that the hydrophobic substance is not highly alkoxylated. The sizing promotion efficiency of the paper sizing compositions, as determined by at least one method selected from the Cytec size testing method, the Hercules size testing method, and the Cobb size testing method, is greater than or equal to about 4. Exemplary hydrophobic substances include fatty acid esters, triglycerides, hydrocarbons, esters and/or amides derived from ASA, silicone oils, alcohols, and stearic anhydride. The invention also relates to methods for sizing paper products with these paper sizing compositions and paper or paperboard treated with these sizing compositions.

5. 发明申请

US20090281212A1 ALKENYLSUCCINIC ANHYDRIDE SURFACE-APPLIED SYSTEM AND USES THEREOF 审中-公开
标题翻译：烷基磺酸盐表面应用体系及其用途
公开(公告)号：US20090281212A1
公开(公告)日：2009-11-12
申请号：US12505753
申请日：2009-07-20
申请人： Lucyna Pawlowska , Kimberly C. Dilts , Charles R. Hunter , Michael P. O'Toole , Robert J. Proverb , Thomas T. Long
发明人： Lucyna Pawlowska , Kimberly C. Dilts , Charles R. Hunter , Michael P. O'Toole , Robert J. Proverb , Thomas T. Long
IPC分类号： C08L3/02 , C08K5/1539
CPC分类号： D21H21/16 , D21H17/16 , D21H17/28 , D21H17/29 , D21H21/24 , D21H21/52
摘要： The invention relates to an aqueous sizing composition including (a) an emulsion comprising alkenylsuccinic anhydride component containing alkenylsuccinic anhydride particles suspended in an aqueous polymer, and (b) a second component selected from the group consisting of cationic starches, non-ionic starches, anionic starches, water-soluble polymer, water and mixtures thereof, such that the alkenylsuccinic anhydride component is sufficiently dilute to enable the sizing composition to impart useful sizing properties to a fibrous substrate when the sizing composition contacts the fibrous substrate. The invention also relates to fibrous substrates treated with such a composition as well as processes for making and using the composition. In one embodiment, alkylene ketene dimer can be used instead of alkenylsuccinic anhydride.
摘要翻译：本发明涉及水性施胶组合物，其包含（a）包含含有悬浮在含水聚合物中的链烯基琥珀酸酐颗粒的烯基琥珀酸酐组分的乳液，和（b）选自阳离子淀粉，非离子淀粉，阴离子淀粉，水溶性聚合物，水和它们的混合物，使得链烯基琥珀酸酐组分充分稀释，以使施胶组合物能够在施胶组合物接触纤维基质时赋予纤维基质有用的施胶性能。本发明还涉及用这种组合物处理的纤维基材以及制备和使用该组合物的方法。在一个实施方案中，可以使用亚烷基烯酮二聚体代替烯基琥珀酸酐。

6. 发明申请

US20100307706A1 REDUCED SHEAR CELLULOSE REACTIVE SIZING AGENT FOR WET END APPLICATIONS 审中-公开
标题翻译：减少剪切纤维素反应性尺寸代谢的湿度应用
公开(公告)号：US20100307706A1
公开(公告)日：2010-12-09
申请号：US11817722
申请日：2005-10-27
申请人： Lucyna Pawlowska , Kimberly C. Dilts , Thomas Long , Charles R. Hunter , Robert Proverb
发明人： Lucyna Pawlowska , Kimberly C. Dilts , Thomas Long , Charles R. Hunter , Robert Proverb
IPC分类号： D21H21/16
CPC分类号： D21H17/16 , D21H17/28 , D21H17/44 , D21H21/16 , D21H21/24 , D21H23/04
摘要： The invention relates to a method for sizing a paper product that involves the steps of (a) providing a paper stock system; (b) forming, in the absence of high shearing forces, an aqueous sizing emulsion comprising an alkenylsuccinic anhydride component; (c) submitting the emulsion formed from step b to a post-dilution step in the presence of a cationic component under conditions, in the absence of high shearing forces, that produce a post-diluted emulsion having improved sizing efficacy; (d) adding the post-diluted emulsion to the paper stock; and (e) forming a paper web.
摘要翻译：本发明涉及一种纸张尺寸调整方法，该方法涉及以下步骤：（a）提供纸料系统; （b）在没有高剪切力的情况下，形成包含烯基琥珀酸酐组分的水性施胶乳液; （c）在没有高剪切力的条件下，在阳离子组分存在下，将由步骤b形成的乳液提交到后稀释步骤，产生具有改善的施胶效力的后稀释乳液; （d）将该稀释后的乳液加入到纸料中; 和（e）形成纸幅。

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