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1. 发明授权

US06934067B2 Electrochromic mirror with two thin glass elements and a gelled electrochromic medium 失效
标题翻译：具有两个薄玻璃元件和凝胶电致变色介质的电致变色镜
公开(公告)号：US06934067B2
公开(公告)日：2005-08-23
申请号：US10115433
申请日：2002-04-03
申请人： Kevin L. Ash , William L. Tonar , Frederick T. Bauer , Kathy E. Roberts
发明人： Kevin L. Ash , William L. Tonar , Frederick T. Bauer , Kathy E. Roberts
IPC分类号： B60R1/04 , B60R1/06 , B60R1/08 , C09K9/02 , G02F1/15 , G02F1/161 , G02F1/153
CPC分类号： C09K9/02 , B60R1/088 , G02F1/1521 , G02F1/161 , G02F2001/1502 , G02F2001/1512 , G02F2001/1515
摘要： An improved electrochromic rearview mirror for motor vehicles, the mirror incorporating thin front and rear spaced glass elements having a thickness ranging from about 0.5 to about 1.5. A layer of transparent conductive material is placed onto the mirror's second surface, and either another layer of transparent conductive material or a combined reflector/electrode is placed onto the mirror's third surface. A chamber, defined by the layers on the interior surfaces of the front and rear glass elements and a peripheral sealing member, contains a free-standing gel comprising a solvent and a crosslinked polymer matrix. The chamber further contains at least one electrochromic material in solution with the solvent and interspersed in the crosslinked polymer matrix. The gel cooperatively interacts with the thin glass elements to form a thick, strong unitary member which is resistant to flexing, warping, bowing and/or shattering and further allows the mirror to exhibit reduced vibrational distortion and double imaging.
摘要翻译：一种用于机动车辆的改进的电致变色后视镜，该镜具有薄的前后间隔玻璃元件，其厚度范围为约0.5至约1.5。将透明导电材料层放置在反射镜的第二表面上，将另一层透明导电材料或组合的反射器/电极放置在反射镜的第三表面上。由前玻璃元件和后玻璃元件的内表面上的层限定的室和外围密封元件包含含有溶剂和交联聚合物基质的独立凝胶。该室还含有至少一种溶剂中的电致变色材料，并且散布在交联的聚合物基质中。凝胶与薄玻璃元件协作地相互作用以形成厚而坚固的整体构件，其抗弯曲，翘曲，弯曲和/或破碎，并且还允许反射镜显示减小的振动失真和双重成像。

2. 发明授权

US06246507B1 Non-planar interior electrochromic rearview mirror for a vehicle 有权
标题翻译：非平面内部电致变色车后视镜
公开(公告)号：US06246507B1
公开(公告)日：2001-06-12
申请号：US09454551
申请日：1999-12-07
申请人： Frederick T. Bauer , William L. Tonar , Kevin L. Ash , Kathy E. Roberts , Timothy A. Bonardi
发明人： Frederick T. Bauer , William L. Tonar , Kevin L. Ash , Kathy E. Roberts , Timothy A. Bonardi
IPC分类号： G02F1153
CPC分类号： B60R1/088 , C09K9/02
摘要： An inside non-planar electrochromic mirror includes front and rear non-planar elements, a layer of transparent conductive material, a reflector and a perimeter sealing member which bonds the front and rear non-planar elements in a spaced apart relationship. The front and rear non-planar elements each include front and rear surfaces. A layer of transparent conductive material is disposed on the rear surface of the front non-planar element. The reflector can be disposed on either side of the rear non-planar element. When the reflector is on the rear surface of the rear non-planar element then the front surface of the rear non-planar element contains a layer of transparent conductive material. When the reflector is on the front surface of the rear element it must be constructed of conductive material. The perimeter sealing member bonds the front and rear non-planar elements and defines a chamber therebetween. The chamber contains at least one electrochromic material. The reflector is effective to reflect light through the chamber and the front non-planar element when light reaches the reflector after passing through the front non-planar element and the chamber.
摘要翻译：内部非平面电致变色镜包括前和后非平面元件，透明导电材料层，反射器和周边密封构件，其以间隔开的关系结合前和后非平面元件。前后非平面元件各自包括前表面和后表面。透明导电材料层设置在前非平面元件的后表面上。反射器可以设置在后面的非平面元件的两侧。当反射器在后非平面元件的后表面上时，后非平面元件的前表面包含一层透明导电材料。当反射器在后部元件的前表面上时，它必须由导电材料构成。周边密封构件结合前和后非平面元件并且在它们之间限定一个室。该室含有至少一种电致变色材料。当光通过前面的非平面元件和腔室时，当反射器到达反射器时，反射器有效地反射光通过腔室和前部非平面元件。

3. 发明授权

US06545794B2 Electrochromic device with two thin glass elements and a gelled electrochromic medium 有权
标题翻译：具有两个薄玻璃元件和凝胶电致变色介质的电致变色器件
公开(公告)号：US06545794B2
公开(公告)日：2003-04-08
申请号：US09745639
申请日：2000-12-23
申请人： Kevin L. Ash , William L. Tonar , Frederick T. Bauer , Kathy E. Roberts , David A. Theiste
发明人： Kevin L. Ash , William L. Tonar , Frederick T. Bauer , Kathy E. Roberts , David A. Theiste
IPC分类号： G02F1153
CPC分类号： B60R1/088 , C09K9/02 , G02F1/1521 , G02F1/161 , G02F2001/1502 , G02F2001/1512
摘要： An electrochromic device comprising: a first glass element having an electrically conductive material associated therewith, wherein said first element comprises a height (h1), a width (w1), a thickness (t1), an inner surface, and an outer surface; a second element having an electrically conductive material associated therewith, wherein said second element comprises a height (h2), a width (w2) , and a thickness (t2), an inner surface, and an outer surface; a cell spacing (c) which comprises a distance between said inner surface of said first element and said inner surface of said second element; a gelled electrochromic medium contained within a chamber positioned between said first and second elements; wherein (h1), (w1), (t1), (h2), (w2), (t2), and (c) are numerical values in millimeters; and wherein (h1), (w1), and (t1) of said first element, and (h2), (w2), and (t2) of said second element and (c) comprise numerical values such that the following inequality is satisfied: 2 ⁢ h 1 5 ⁢ ( 1 - ⅇ - 2 ( h 1 / w 1 ) 2 ) t 1 3 ⁢ ( 7.57 × 10 12 ) + 2 ⁢ h 2 5 ⁢ ( 1 - ⅇ - 2 ( h 2 / w 2 ) 2 ) t 2 3 ⁢ ( 7.57 × 10 12 ) ≥ .1 ⁢ ( c ) .
摘要翻译：一种电致变色装置，包括：具有与其相关联的导电材料的第一玻璃元件，其中所述第一元件包括高度（h1），宽度（w1），厚度（t1），内表面和外表面; 具有与其相关联的导电材料的第二元件，其中所述第二元件包括高度（h2），宽度（w2）和厚度（t2），内表面和外表面; 包括所述第一元件的所述内表面和所述第二元件的所述内表面之间的距离的单元间隔（c）包含在位于所述第一和第二元件之间的腔室内的凝胶状电致变色介质; 其中（h1），（w1），（t1），（h2），（w2），（t2）和（c）并且其中所述第一元素的（h1），（w1）和（t1）和所述第二元素的（h2），（w2）和（t2）和（c）包括数值，使得满足以下不等式：

4. 发明授权

US06268950B1 Electrochromic mirror with two thin glass elements and a gelled electrochromic medium 有权
标题翻译：具有两个薄玻璃元件和凝胶电致变色介质的电致变色镜
公开(公告)号：US06268950B1
公开(公告)日：2001-07-31
申请号：US09560849
申请日：2000-04-28
申请人： Kevin L. Ash , William L. Tonar , Frederick T. Bauer , Kathy E. Roberts
发明人： Kevin L. Ash , William L. Tonar , Frederick T. Bauer , Kathy E. Roberts
IPC分类号： G02F115
CPC分类号： C09K9/02 , B60R1/088 , G02F1/1521 , G02F1/161 , G02F2001/1502 , G02F2001/1512 , G02F2001/1515
摘要： An improved electrochromic rearview mirror for motor vehicles, the mirror incorporating thin front and rear spaced glass elements having a thickness ranging from about 0.5 to about 1.5. A layer of transparent conductive material is placed onto the mirror's second surface, and either another layer of transparent conductive material or a combined reflector/electrode is placed onto the mirror's third surface. A chamber, defined by the layers on the interior surfaces of the front and rear glass elements and a peripheral sealing member, contains a free-standing gel comprising a solvent and a crosslinked polymer matrix. The chamber further contains at least one electrochromic material in solution with the solvent and interspersed in the crosslinked polymer matrix. The gel cooperatively interacts with the thin glass elements to form a thick, strong unitary member which is resistant to flexing, warping, bowing and/or shattering and further allows the mirror to exhibit reduced vibrational distortion and double imaging.
摘要翻译：一种用于机动车辆的改进的电致变色后视镜，该镜具有薄的前后间隔玻璃元件，其厚度范围为约0.5至约1.5。将透明导电材料层放置在反射镜的第二表面上，将另一层透明导电材料或组合的反射器/电极放置在反射镜的第三表面上。由前玻璃元件和后玻璃元件的内表面上的层限定的室和外围密封元件包含含有溶剂和交联聚合物基质的独立凝胶。该室还含有至少一种溶剂中的电致变色材料，并且散布在交联的聚合物基质中。凝胶与薄玻璃元件协作地相互作用以形成厚而坚固的整体构件，其抗弯曲，翘曲，弯曲和/或破碎，并且还允许反射镜显示减小的振动失真和双重成像。

5. 发明授权

US6057956A Electrochromic mirror with two thin glass elements and a gelled electrochromic medium 有权
公开(公告)号：US6057956A
公开(公告)日：2000-05-02
申请号：US375136
申请日：1999-08-16
申请人： Kevin L. Ash , William L. Tonar , Frederick T. Bauer
发明人： Kevin L. Ash , William L. Tonar , Frederick T. Bauer
IPC分类号： B60R1/04 , B60R1/06 , B60R1/08 , C09K9/02 , G02F1/15 , G02F1/161 , G02F1/153 , G02B11/04
CPC分类号： C09K9/02 , B60R1/088 , G02F1/1521 , G02F1/161 , G02F2001/1502 , G02F2001/1512 , G02F2001/1515
摘要： An improved electrochromic rearview mirror for motor vehicles, the mirror incorporating thin front and rear spaced glass elements having a thickness ranging from about 0.5 to about 1.5. A layer of transparent conductive material is placed onto the mirror's second surface, and either another layer of transparent conductive material or a combined reflector/electrode is placed onto the mirror's third surface. A chamber, defined by the layers on the interior surfaces of the front and rear glass elements and a peripheral sealing member, contains a free-standing gel comprising a solvent and a crosslinked polymer matrix. The chamber further contains at least one electrochromic material in solution with the solvent and interspersed in the crosslinked polymer matrix. The gel cooperatively interacts with the thin glass elements to form a thick, strong unitary member which is resistant to flexing, warping, bowing and/or shattering and further allows the mirror to exhibit reduced vibrational distortion and double imaging.

6. 发明授权

US5940201A Electrochromic mirror with two thin glass elements and a gelled electrochromic medium 失效
公开(公告)号：US5940201A
公开(公告)日：1999-08-17
申请号：US834783
申请日：1997-04-02
申请人： Kevin L. Ash , William L. Tonar , Frederick T. Bauer
发明人： Kevin L. Ash , William L. Tonar , Frederick T. Bauer
IPC分类号： B60R1/04 , B60R1/06 , B60R1/08 , C09K9/02 , G02F1/15 , G02F1/161 , G02F1/153
CPC分类号： C09K9/02 , B60R1/088 , G02F1/1521 , G02F1/161 , G02F2001/1502 , G02F2001/1512 , G02F2001/1515
摘要： An improved electrochromic rearview mirror for motor vehicles, the mirror incorporating thin front and rear spaced glass elements having a thickness ranging from about 0.5 to about 1.5. A layer of transparent conductive material is placed onto the mirror's second surface, and either another layer of transparent conductive material or a combined reflector/electrode is placed onto the mirror's third surface. A chamber, defined by the layers on the interior surfaces of the front and rear glass elements and a peripheral sealing member, contains a free-standing gel comprising a solvent and a crosslinked polymer matrix. The chamber further contains at least one electrochromic material in solution with the solvent and interspersed in the crosslinked polymer matrix. The gel cooperatively interacts with the thin glass elements to form a thick, strong unitary member which is resistant to flexing, warping, bowing and/or shattering and further allows the mirror to exhibit reduced vibrational distortion and double imaging.

7. 发明授权

US06195193B1 Seal for electrochromic devices 有权
标题翻译：电致变色装置的密封
公开(公告)号：US06195193B1
公开(公告)日：2001-02-27
申请号：US09540219
申请日：2000-03-31
申请人： John S. Anderson , William L. Tonar , Kevin L. Ash , Thomas F. Guarr
发明人： John S. Anderson , William L. Tonar , Kevin L. Ash , Thomas F. Guarr
IPC分类号： G02F115
CPC分类号： G02F1/161
摘要： An improved seal member is provided as a part of an electrochromic device to bond two glass elements together in a spaced-apart relationship. In one embodiment the seal member provides improved adhesion to a reflector/electrode on the third surface of an electrochromic mirror, or to a layer of metal on the second or third surface for an electrochromic light filter. This seal member comprises a mixture of an organic resin scaling system and an adhesion promoter, where the adhesion promotor comprises a first and a second region, where the first region interacts with the reflector/electrode or the metal layer, and a second region that interacts with the organic resin sealing system, and may even chemically react with the organic resin sealing system. In another embodiment the seal member is provided with a coefficient of thermal expansion that is closer to glass than a standard epoxy sealing system.
摘要翻译：提供改进的密封构件作为电致变色装置的一部分，以将间隔开的关系将两个玻璃元件结合在一起。在一个实施例中，密封构件对电致变色镜的第三表面上的反射器/电极或用于电致变色光过滤器的第二或第三表面上的金属层提供改进的粘附。该密封构件包括有机树脂缩放系统和粘合促进剂的混合物，其中粘合促进剂包括第一和第二区域，其中第一区域与反射器/电极或金属层相互作用，第二区域与与有机树脂密封系统，甚至可能与有机树脂密封系统发生化学反应。在另一个实施例中，密封构件具有比标准环氧树脂密封系统更接近玻璃的热膨胀系数。

8. 发明授权

US6157480A Seal for electrochromic devices 有权
标题翻译：电致变色装置的密封
公开(公告)号：US6157480A
公开(公告)日：2000-12-05
申请号：US158423
申请日：1998-09-21
申请人： John S. Anderson , William L. Tonar , Kevin L. Ash , Thomas F. Guarr
发明人： John S. Anderson , William L. Tonar , Kevin L. Ash , Thomas F. Guarr
IPC分类号： G02F1/15 , G02F1/161 , G02F1/153
CPC分类号： G02F1/161
摘要： An improved seal member is provided as a part of an electrochromic device to bond two glass elements together in a spaced-apart relationship. In one embodiment the seal member provides improved adhesion to a reflector/electrode on the third surface of an electrochromic mirror, or to a layer of metal on the second or third surface for an electrochromic light filter. This seal member comprises a mixture of an organic resin sealing system and an adhesion promoter, where the adhesion promotor comprises a first and a second region, where the first region interacts with the reflector/electrode or the metal layer, and a second region that interacts with the organic resin sealing system, and may even chemically react with the organic resin sealing system. In another embodiment the seal member is provided with a coefficient of thermal expansion that is closer to glass than a standard epoxy sealing system.
摘要翻译：提供改进的密封构件作为电致变色装置的一部分，以将间隔开的关系将两个玻璃元件结合在一起。在一个实施例中，密封构件对电致变色镜的第三表面上的反射器/电极或用于电致变色光过滤器的第二或第三表面上的金属层提供改进的粘附。该密封构件包括有机树脂密封系统和粘合促进剂的混合物，其中粘合促进剂包括第一和第二区域，其中第一区域与反射器/电极或金属层相互作用，第二区域与第二区域相互作用与有机树脂密封系统，甚至可能与有机树脂密封系统发生化学反应。在另一个实施例中，密封构件具有比标准环氧树脂密封系统更接近玻璃的热膨胀系数。

9. 发明授权

US5888431A Electrochromic layer and devices comprising same 失效
公开(公告)号：US5888431A
公开(公告)日：1999-03-30
申请号：US616275
申请日：1996-03-15
申请人： William L. Tonar , Harlan J. Byker , Kathy E. Siegrist , John S. Anderson , Kevin L. Ash
发明人： William L. Tonar , Harlan J. Byker , Kathy E. Siegrist , John S. Anderson , Kevin L. Ash
IPC分类号： C09K9/02 , G02F1/15 , G02F1/00 , G02F1/153
CPC分类号： C09K9/02 , G02F1/1521 , C09K2211/1029 , G02F2001/1502 , G02F2001/1512 , G02F2202/022
摘要： The present invention provides improved electrochromic layers, which comprise polymeric matrices with electrochromic solutions interspersed therein. Varying an electrical potential difference across a layer of the invention results in reversible variation in the transmittance of light across the layer because of electrochemical processes in the electrochromic solution of the layer. The invention further provides electrochromic devices, in which the electrochromic layers of the invention provide reversibly variable transmittance to light, and various apparatus in which the devices of the invention provide light-filtering or light-color modulation. Such apparatus include windows, including those for use inside and on the outside walls of buildings and in sunroofs for automobiles, and variable reflectance mirrors, especially rearview mirrors for automobiles.

10. 发明授权

US08345345B2 Electrochromic device having an improved fill port plug 有权
公开(公告)号：US08345345B2
公开(公告)日：2013-01-01
申请号：US13022912
申请日：2011-02-08
申请人： Steven J. Veenman , William L. Tonar , Joel A. Stray , Leroy J. Kloeppner , David L Poll , Gary J. Dozeman , Nalini C. Menon , Kevin L. Ash
发明人： Steven J. Veenman , William L. Tonar , Joel A. Stray , Leroy J. Kloeppner , David L Poll , Gary J. Dozeman , Nalini C. Menon , Kevin L. Ash
IPC分类号： G02F1/153
CPC分类号： G02F1/161 , G02F1/15 , G02F1/157 , G02F2201/50 , G02F2202/00 , G02F2202/02 , G02F2202/023
摘要： An electrochromic device including: (a) a first substantially transparent substrate having an electrically conductive material associated therewith; (b) a second substrate having an electrically conductive material associated therewith; (c) an electrochromic medium contained within a chamber positioned between the first and second substrates which includes: (1) a solvent; (2) an anodic material; and (3) a cathodic material, wherein both of the anodic and cathodic materials are electroactive and at least one of the anodic and cathodic materials is electrochromic; (d) wherein a seal member, the first substrate, the second substrate, and/or the chamber includes a plug associated with a fill port; and (e) wherein the plug is at least partially cured with an antimonate photo initiator and/or is a one- or two-part plug which comprises a resin or mixture of resins that are substantially insoluble and/or substantially immiscible with an associated electrochromic medium while in the uncured state.

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