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1. 发明授权

US5827810A Phase stable, thickened aqueous abrasive bleaching cleanser 失效
公开(公告)号：US5827810A
公开(公告)日：1998-10-27
申请号：US670740
申请日：1996-06-24
申请人： Kevin J. Brodbeck , Aram Garabedian, Jr. , Brian P. Argo , Amy M. Penticoff , Clement K. Choy
发明人： Kevin J. Brodbeck , Aram Garabedian, Jr. , Brian P. Argo , Amy M. Penticoff , Clement K. Choy
IPC分类号： C11D1/75 , C11D3/14 , C11D3/37 , C11D3/395 , C11D17/00 , C11D3/10
CPC分类号： C11D17/0013 , C11D17/003 , C11D3/14 , C11D3/3765 , C11D3/3956 , C11D1/75
摘要： The invention provides a phase stable, thickened aqueous abrasive cleanser and a method for preparing it, said cleanser comprising: a) an effective amount of a cross-linked polyacrylate; b) an effective amount of at least one bleach-stable surfactant; c) an effective amount of a low salt, high purity hypochlorite; d) an effective amount of a pH-adjusting agent; e) an effective amount of abrasive; and f) the remainder as water.

2. 发明授权

US5529711A Phase stable, thickened aqueous abrasive bleaching cleanser 失效
标题翻译：相稳定，增稠水性磨料漂白清洁剂
公开(公告)号：US5529711A
公开(公告)日：1996-06-25
申请号：US474354
申请日：1995-06-07
申请人： Kevin J. Brodbeck , Aram Garabedian, Jr. , Brian P. Argo , Amy M. Penticoff , Clement K. Choy
发明人： Kevin J. Brodbeck , Aram Garabedian, Jr. , Brian P. Argo , Amy M. Penticoff , Clement K. Choy
IPC分类号： C11D1/75 , C11D3/14 , C11D3/37 , C11D3/395 , C11D17/00 , C11D9/20
CPC分类号： C11D17/0013 , C11D17/003 , C11D3/14 , C11D3/3765 , C11D3/3956 , C11D1/75
摘要： The invention provides a phase stable, thickened aqueous abrasive cleanser and a method for preparing it, said cleanser comprising:a) an effective amount of a cross-linked polyacrylate;b) an effective amount of at least one bleach-stable surfactant;c) an effective amount of a low salt, high purity hypochlorite;d) an effective amount of a pH-adjusting agent;e) an effective amount of abrasive; andf) the remainder as water.
摘要翻译：本发明提供一种相稳定的增稠水性磨料清洁剂及其制备方法，所述清洁剂包括：a）有效量的交联聚丙烯酸酯; b）有效量的至少一种漂白稳定的表面活性剂; c）有效量的低盐，高纯度次氯酸盐; d）有效量的pH调节剂; e）有效量的磨料; 和f）剩余部分作为水。

3. 发明授权

US6100228A Bleaching gel cleaner thickened with amine oxide, soap and solvent 失效
标题翻译：漂白凝胶清洁剂用氧化胺，皂和溶剂增稠
公开(公告)号：US6100228A
公开(公告)日：2000-08-08
申请号：US474352
申请日：1995-06-07
申请人： Brian P. Argo , Clement K. Choy , Aram Garabedian, Jr.
发明人： Brian P. Argo , Clement K. Choy , Aram Garabedian, Jr.
IPC分类号： C11D1/75 , C11D1/90 , C11D3/395 , C11D3/43 , C11D10/04 , C11D17/00 , C11D3/48 , C11D9/42 , C11D9/50
CPC分类号： C11D10/04 , C11D17/003 , C11D3/3956 , C11D3/43 , C11D1/75 , C11D1/90
摘要： The invention provides a bleaching gel cleaner and a method for preparing it, said cleaner comprising:a) an effective amount of a hypochlorite-generating compound;b) a ternary thickening system which comprises: (i) alkali metal soap; (ii) a hydrotrope selected from the group consisting of trialkylamine oxides, betaines and mixtures thereof; and (iii) a bleach stable solvent, each in amounts appropriate to create a gelled composition;c) a buffer/electrolyte in an amount effective to stabilize the hypochlorite; andd) the remainder as water.
摘要翻译：本发明提供一种漂白凝胶清洁剂及其制备方法，所述清洁剂包括：a）有效量的产生次氯酸盐的化合物; b）三元增稠系统，其包括：（i）碱金属皂; （ii）选自三烷基胺氧化物，甜菜碱及其混合物的水溶助长剂; 和（iii）漂白稳定溶剂，各自以适于产生胶凝组合物的量; c）具有有效稳定次氯酸盐的量的缓冲液/电解质; 和d）剩余部分作为水。

4. 发明授权

US5554321A Thickened aqueous abrasive cleanser with improved rinsability 失效
标题翻译：增稠水性磨料清洁剂，具有改善的漂洗性能
公开(公告)号：US5554321A
公开(公告)日：1996-09-10
申请号：US522046
申请日：1995-08-31
申请人： Clement K. Choy , Brian P. Argo , Kevin J. Brodbeck , Lynn M. Hearn
发明人： Clement K. Choy , Brian P. Argo , Kevin J. Brodbeck , Lynn M. Hearn
IPC分类号： C11D3/14 , C11D3/37 , C11D3/395 , C11D17/00 , C11D1/75 , C11D3/02
CPC分类号： C11D17/0013 , C11D3/14 , C11D3/3765 , C11D3/3956
摘要： A method of making a hard surface abrasive scouring cleanser, in steps comprising making an aqueous solution of nonionic surfactant and pH adjusting agent; making a slurry of water and a calcium carbonate abrasive, and allowing the slurry to degas; adding the slurry of to the aqueous solution slowly with gentle mixing and allowing the resultant mixture to degas; and adding a quantity of cross-linked polyacrylate and any other adjunct ingredients. The cleanser has no significant syneresis, undue viscosity or yield stress increase, stably suspends abrasives, and has excellent rinsing characteristics.
摘要翻译：一种制备硬表面磨料清洗剂的方法，包括制备非离子表面活性剂和pH调节剂的水溶液; 制备水和碳酸钙研磨剂的浆料，并使浆料脱气; 将浆料缓慢加入到水溶液中，并轻轻搅拌，并使得到的混合物脱气; 并加入一定量的交联聚丙烯酸酯和任何其他辅助成分。清洁剂没有显着的脱水收缩，不适当的粘度或屈服应力增加，稳定地悬浮研磨剂，并且具有优异的漂洗特性。

5. 发明授权

US5470499A Thickened aqueous abrasive cleanser with improved rinsability 失效
标题翻译：增稠水性磨料清洁剂，具有改善的漂洗性能
公开(公告)号：US5470499A
公开(公告)日：1995-11-28
申请号：US125949
申请日：1993-09-23
申请人： Clement K. Choy , Brian P. Argo , Kevin J. Brodbeck , Lynn M. Hearn
发明人： Clement K. Choy , Brian P. Argo , Kevin J. Brodbeck , Lynn M. Hearn
IPC分类号： C11D3/14 , C11D3/37 , C11D3/395 , C11D17/00 , C11D7/22
CPC分类号： C11D17/0013 , C11D3/14 , C11D3/3765 , C11D3/3956
摘要： The invention is a hard surface abrasive scouring cleanser having no significant syneresis, undue viscosity or yield stress increase, stably suspends abrasives, and has excellent rinsing characteristics. Furthermore, the present invention provides a stably suspended abrasive scouring cleanser which uses relatively small amounts of surfactants, thus lowering the total cost of producing these cleansers. The lesser amount of surfactant also affords the cleanser a milder feel and lower unaesthetic surfactant odor, while also requiring lower levels of fragrance. The absence of solvents results in a less irritating product as well.In one aspect the invention comprises, in aqueous solution:(a) a cross-linked polyacrylate;(b) at least one nonionic surfactant;(c) a pH adjusting agent; and(d) a calcium carbonate abrasive.In a further aspect the invention comprises, in aqueous solution:(a) a cross-linked polyacrylate thickener;(b) a mixed surfactant system which comprises one anionic surfactant and an amine oxide nonionic surfactant;(c) a pH adjusting agent;(d) a hydrotrope; and(e) a particulate abrasive.
摘要翻译：本发明是不具有显着的脱水收缩，过度粘度或屈服应力增加，稳定地悬浮研磨剂并且具有优异的漂洗特性的硬表面磨料清洗剂。此外，本发明提供了使用相对少量表面活性剂的稳定悬浮的磨料清洗剂，从而降低了生产这些清洁剂的总成本。较少量的表面活性剂也为清洁剂提供温和的感觉和较低的不美观的表面活性剂气味，同时还需要较低的香味水平。没有溶剂会导致刺激性较小的产品。一方面，本发明在水溶液中包含：（a）交联聚丙烯酸酯; （b）至少一种非离子表面活性剂; （c）pH调节剂; 和（d）碳酸钙研磨剂。在另一方面，本发明在水溶液中包含：（a）交联的聚丙烯酸酯增稠剂; （b）包含一种阴离子表面活性剂和氧化胺非离子表面活性剂的混合表面活性剂体系; （c）pH调节剂; （d）水溶助长剂; 和（e）颗粒磨料。

6. 发明授权

US5731276A Thickened aqueous cleaning composition and methods of preparation thereof and cleaning therewith 失效
标题翻译：增稠的水性清洁组合物及其制备方法和清洗
公开(公告)号：US5731276A
公开(公告)日：1998-03-24
申请号：US688563
申请日：1996-07-30
申请人： Brian P. Argo , Clement K. Choy
发明人： Brian P. Argo , Clement K. Choy
IPC分类号： C11D3/04 , C11D3/02 , C11D3/12 , C11D3/395 , C11D17/00
CPC分类号： C11D3/046 , C11D17/003 , C11D3/1213 , C11D3/3956
摘要： The present invention provides an abrasive-free cleaning composition which includes, in aqueous solution, a bleach, a colloidal thickener, and a source of divalent ionic calcium. The composition further includes at least one surfactant which is effective to provide cleaning activity and, in association with the colloidal thickener, thickening. The composition also includes an electrolyte/buffer which is effective to promote an environment in which the thickener and the surfactant associate to provide proper thickening. The inventive cleaning composition, with its ionic calcium source, has desirable viscosity and rheological properties, and demonstrates significant viscosity stability, rheological stability, phase stability and bleach stability. The cleaning composition maintains these desirable properties under typical storage conditions as well as over extended times and at elevated temperatures. The present invention also provides a method of preparing an abrasive-free cleaning composition and a method of cleaning a substrate with an abrasive-free cleaning composition.
摘要翻译：本发明提供了一种无磨料清洁组合物，其在水溶液中包含漂白剂，胶体增稠剂和二价离子钙源。所述组合物还包含至少一种有效提供清洁活性的表面活性剂，并且与胶体增稠剂相关联，增稠。该组合物还包括有效促进增稠剂和表面活性剂缔合以提供适当增稠的环境的电解质/缓冲剂。具有其离子钙源的本发明清洁组合物具有所需的粘度和流变性能，并且显示出显着的粘度稳定性，流变稳定性，相稳定性和漂白稳定性。清洁组合物在典型的储存条件以及延长的时间和升高的温度下保持这些期望的性能。本发明还提供了一种制备无磨料清洁组合物的方法和用无磨料清洁组合物清洗基材的方法。

7. 发明授权

US5346641A Thickened aqueous abrasive cleanser with improved colloidal stability 失效
标题翻译：增稠的水性磨料清洁剂具有改善的胶体稳定性
公开(公告)号：US5346641A
公开(公告)日：1994-09-13
申请号：US110342
申请日：1993-08-20
申请人： Brian P. Argo , Clement K. Choy
发明人： Brian P. Argo , Clement K. Choy
IPC分类号： C11D1/02 , C11D1/14 , C11D1/24 , C11D1/66 , C11D1/75 , C11D3/12 , C11D3/395 , C11D10/04 , C11D9/20 , C11D9/12
CPC分类号： C11D3/1213 , C11D10/04 , C11D3/1233 , C11D3/3956 , C11D1/02 , C11D1/14 , C11D1/24 , C11D1/66 , C11D1/75
摘要： A thickened aqueous abrasive scouring cleanser containing bleach which is capable of stably suspending abrasives, has excellent bleach half-life stability, little or no syneresis and maintains these advantages over extended times and at elevated temperatures and comprises, in aqueous solution:(a) a colloidal aluminum oxide thickener having average particle size of no greater than about one micron;(b) at least one surfactant which can, in association with the aluminum oxide, provide proper rheology and cleaning;(c) an electrolyte/buffer to promote the environment in which the aluminum oxide and surfactant can associate to provide proper rheology;(d) a halogen bleach;(e) a particulate abrasive having average particle size of about 40 to 800 microns to provide scouring action; and(f) a viscosity stabilizing amount of a multivalent metal salt.
摘要翻译：含有能够稳定地悬浮研磨剂的漂白剂的增稠含水磨料清洗剂具有优异的漂白剂半衰期稳定性，很少或没有脱水收缩，并且在延长的时间和升高的温度下保持这些优点，并且在水溶液中包含：（a）平均粒度不大于约1微米的胶体氧化铝增稠剂; （b）至少一种与氧化铝结合可提供适当流变学和清洁的表面活性剂; （c）电解质/缓冲剂，以促进氧化铝和表面活性剂可以缔合的环境以提供适当的流变性; （d）卤素漂白剂; （e）平均粒径为约40至800微米的颗粒磨料以提供冲刷作用; 和（f）多价金属盐的粘度稳定量。

8. 发明授权

US06294511B1 Thickened aqueous composition for the cleaning of a ceramic surface and methods of preparation thereof and cleaning therewith 失效
标题翻译：用于清洁陶瓷表面的增稠水性组合物及其制备方法和清洁
公开(公告)号：US06294511B1
公开(公告)日：2001-09-25
申请号：US08967911
申请日：1997-11-12
申请人： Brian P. Argo , Clement K. Choy , Shona L. Nelson
发明人： Brian P. Argo , Clement K. Choy , Shona L. Nelson
IPC分类号： C11D304
CPC分类号： C11D3/046 , C11D3/1213 , C11D3/3956 , C11D17/003
摘要： The present invention provides an abrasive-free cleaning composition which includes, in aqueous solution, a bleach, a colloidal thickener, and a source of divalent ionic calcium. The composition further includes at least one surfactant which is effective to provide cleaning activity and, in association with the colloidal thickener, thickening. The composition also includes an electrolyte/buffer which is effective to promote an environment in which the thickener and the surfactant associate to provide proper thickening. The inventive cleaning composition, with its ionic calcium source, has desirable viscosity and rheological properties, and demonstrates significant viscosity stability, rheological stability, phase stability and bleach stability. The cleaning composition maintains these desirable properties under typical storage conditions as well as over extended times and at elevated temperatures. The present invention also provides a method of preparing an abrasive-free cleaning composition and a method of cleaning a substrate with an abrasive-free cleaning composition. The present invention further provides a composition having the above-mentioned advantages, which is particularly useful in the cleaning of ceramic substrates, such as toilet bowls, and has additional advantages for this application.
摘要翻译：本发明提供了一种无磨料清洁组合物，其在水溶液中包含漂白剂，胶体增稠剂和二价离子钙源。所述组合物还包含至少一种有效提供清洁活性的表面活性剂，并且与胶体增稠剂相关联，增稠。该组合物还包括有效促进增稠剂和表面活性剂缔合以提供适当增稠的环境的电解质/缓冲剂。具有其离子钙源的本发明清洁组合物具有所需的粘度和流变性能，并且显示出显着的粘度稳定性，流变稳定性，相稳定性和漂白稳定性。清洁组合物在典型的储存条件以及延长的时间和升高的温度下保持这些期望的性能。本发明还提供了一种制备无磨料清洁组合物的方法和用无磨料清洁组合物清洗基材的方法。本发明还提供了具有上述优点的组合物，其特别可用于陶瓷基材如马桶碗的清洁，并且对于该应用具有额外的优点。

9. 发明授权

US5279755A Thickening aqueous abrasive cleaner with improved colloidal stability 失效
标题翻译：增稠的水性研磨清洁剂具有改善的胶体稳定性
公开(公告)号：US5279755A
公开(公告)日：1994-01-18
申请号：US760626
申请日：1991-09-16
申请人： Clement K. Choy , Brian P. Argo
发明人： Clement K. Choy , Brian P. Argo
IPC分类号： C09K3/14 , C11D3/12 , C11D3/20 , C11D3/395 , C11D17/00 , C09K5/00 , C11D9/42
CPC分类号： C11D17/0013 , C09K3/1463 , C11D3/1213 , C11D3/2079 , C11D3/3956
摘要： A thickened aqueous abrasive scouring cleanser containing bleach which is capable of stably suspending abrasives, has excellent bleach half-life stability, little or no syneresis and maintains these advantages over extended times and at elevated temperatures and comprises, in aqueous solution:(a) a colloidal aluminum oxide thickener having average particle size of no greater than about one micron;(b) at least one surfactant which can, in association with the aluminum oxide, provide proper rheology and cleaning;(c) an electrolyte/buffer to promote the environment in which the aluminum oxide and surfactant can associate to provide proper rheology;(d) a halogen bleach;(e) a particulate abrasive having average particle size of about 40 to 800 microns to provide scouring action; and(f) a phase stabilizing amount of a multivalent metal salt of a C.sub.16-22 fatty acid.
摘要翻译：含有能够稳定地悬浮研磨剂的漂白剂的增稠含水磨料清洗剂具有优异的漂白剂半衰期稳定性，很少或没有脱水收缩，并且在延长的时间和升高的温度下保持这些优点，并且在水溶液中包含：（a）平均粒度不大于约1微米的胶体氧化铝增稠剂; （b）至少一种与氧化铝结合可提供适当流变学和清洁的表面活性剂; （c）电解质/缓冲剂，以促进氧化铝和表面活性剂可以缔合的环境以提供适当的流变性; （d）卤素漂白剂; （e）平均粒径为约40至800微米的颗粒磨料以提供冲刷作用; 和（f）相稳定量的C16-22脂肪酸的多价金属盐。

10. 发明授权

US6096550A Method of testing a material without the use of animals to determine the potential of the material to harm animal or human tissue 失效
标题翻译：在不使用动物的情况下测试材料的方法来确定材料损害动物或人体组织的潜力
公开(公告)号：US6096550A
公开(公告)日：2000-08-01
申请号：US70449
申请日：1998-04-30
申请人： Brian P. Argo
发明人： Brian P. Argo
IPC分类号： G01N13/00 , G01N21/55 , G01N31/00
CPC分类号： B82Y30/00 , G01N13/00 , G01N21/553
摘要： A method of testing a material without the use of animals to determine the potential of the material to harm human or animal cells due to contact includes forming a biomembrane having at least some constituent matter of human or animal tissue, applying a quantity of material to the membrane, maintaining the biomembrane and quantity of material in contact for a period of time, and monitoring the change in the physical properties of the biomembrane caused by the quantity of material.
摘要翻译：在不使用动物的情况下测试材料以确定材料由于接触而危害人或动物细胞的潜力的方法包括形成具有至少一些人或动物组织构成物质的生物膜，向膜，保持材料的生物膜和数量接触一段时间，并监测由材料量引起的生物膜的物理性质的变化。

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