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1. 发明授权

US4604278A Production of ammonium tetrathiomolybdate 失效
标题翻译：四硫代钼酸铵的生产
公开(公告)号：US4604278A
公开(公告)日：1986-08-05
申请号：US734985
申请日：1985-05-17
申请人： Kenneth T. Reilly , Robin W. Munn , Henry E. Hoffman , Alan D. Douglas
发明人： Kenneth T. Reilly , Robin W. Munn , Henry E. Hoffman , Alan D. Douglas
IPC分类号： C01G39/00 , C01G39/06
CPC分类号： C01G39/006 , C01G39/06
摘要： A process is disclosed for producing ammonium tetrathiomolybdate. The process involves reacting an ammoniacal molybdate solution with hydrogen sulfide gas, the solution and the gas being in a closed system and the flow of the gas being regulated at an elevated pressure to form a slurry consisting essentially of a solid essentially all of which is ammonium tetrathiomolybdate containing a portion of the starting molybdenum and a mother liquor containing the balance of the molybdenum. The slurry is then cooled to ambient temperature and the solid is removed from the major portion of the mother liquor. The solid is then washed with water and with alcohol followed by removal of the resulting respective water and alcohol washes to remove the remaining portion of the mother liquor and soluble impurities from the solid. The resulting washed solid is then dried at ambient temperature to form the final ammonium tetrathiomolybdate.
摘要翻译：公开了用于生产四硫代钼酸铵的方法。该方法包括使氨基钼酸盐溶液与硫化氢气体反应，溶液和气体处于封闭系统中，并且气体的流动在升高的压力下调节以形成基本上由固体组成的浆料，其基本上全部为铵含有起始钼的一部分的四硫钼酸盐和含有余量的钼的母液。然后将浆液冷却至环境温度，并将固体从母液的主要部分除去。然后将固体用水和醇洗涤，然后除去所得的各自的水和醇洗涤剂以从固体中除去母液的剩余部分和可溶性杂质。然后将所得洗涤的固体在环境温度下干燥以形成最终的四硫代钼酸铵。

2. 发明授权

US4889703A Process for producing tungstosilicic acid 失效
标题翻译：钨硅酸生产工艺
公开(公告)号：US4889703A
公开(公告)日：1989-12-26
申请号：US368078
申请日：1989-06-16
申请人： Kenneth T. Reilly , Alan D. Douglas , Henry E. Hoffman
发明人： Kenneth T. Reilly , Alan D. Douglas , Henry E. Hoffman
IPC分类号： C01B33/20
CPC分类号： C01B33/20
摘要： A process is disclosed for producing tungstosilicic acid which involves adding sodium silicate to a first solution of sodium tungstate while assuring that the pH of the resulting mixture is from about 2 to about 6, the pH adjustments being made with a cation exchange resin on the hydrogen cycle, to produce a second solution. The solids are removed from the second solution which is digested at a temperature of greater than about 50.degree. C. and then contacted with a cation exchange resin on the hydrogen cycle to produce a third solution which is essentially a tungstosilicic acid solution containing at least about 99% by weight of the starting tungsten as tungstosilicic acid.
摘要翻译：公开了一种用于生产钨硅酸的方法，其涉及向第一钨酸钠溶液中加入硅酸钠，同时确保得到的混合物的pH为约2至约6，pH调节用氢阳离子交换树脂循环，产生第二个解决方案。从第二溶液中除去固体，其在大于约50℃的温度下被消化，然后在氢循环上与阳离子交换树脂接触以产生基本上是含有至少约 99重量％的起始钨作为钨硅酸。

3. 发明授权

US4521381A Recovery of rhenium 失效
标题翻译：回收铼
公开(公告)号：US4521381A
公开(公告)日：1985-06-04
申请号：US669126
申请日：1984-11-07
申请人： Alan D. Douglas , Kenneth T. Reilly
发明人： Alan D. Douglas , Kenneth T. Reilly
IPC分类号： C01G41/00 , C01G47/00 , C22B3/38 , C22B61/00
CPC分类号： C22B61/00 , C01G41/00 , C01G47/003 , C22B3/0068 , Y02P10/234
摘要： In a process is disclosed for recovering rhenium from tungsten and rhenium bearing material by oxidizing and fusing the starting material, solubilizing the tungsten and rhenium values, passing the resulting solution through a strongly basic anion exchange resin to retain the rhenium, removing the rhenium from the resin with an organic stripping liquid of tributylphosphate and hydrochloric acid, washing the remaining rhenium off the resin with water, combining the water and organic to form a two phase system in which the organic phase contains the major portion of the rhenium, and contacting with aqueous ammonia to strip values.
摘要翻译：在公开了用于通过氧化和熔融起始材料，增溶钨和铼值从钨和铼轴承材料中回收铼的方法，使所得溶液通过强碱性阴离子交换树脂以保持铼，从铼中除去铼树脂与磷酸三丁酯和盐酸的有机剥离液，用水将剩余的铼从树脂中洗涤，将水和有机物洗涤，形成两相体系，其中有机相含有铼的主要部分，并与水相接触氨去除值。

4. 发明授权

US4604265A Recovery of tungsten and rhenium 失效
标题翻译：回收钨和铼
公开(公告)号：US4604265A
公开(公告)日：1986-08-05
申请号：US768388
申请日：1985-08-22
申请人： Alan D. Douglas , Kenneth T. Reilly , John E. Landmesser , Richard E. Landry , Martin B. MacInnis
发明人： Alan D. Douglas , Kenneth T. Reilly , John E. Landmesser , Richard E. Landry , Martin B. MacInnis
IPC分类号： C01G41/02 , C01G47/00 , C22B34/36 , C22B61/00
CPC分类号： C22B34/36 , C01G41/02 , C22B61/00 , C01P2006/12 , C01P2006/80
摘要： A process is disclosed for recovering tungsten and rhenium from a tungsten and rhenium source. The process involves firing the source in an oxidizing atmosphere at a sufficient temperature for a sufficient time to convert the tungsten and rhenium to their respective oxides, to remove a portion of the rhenium as volatilized oxide, and to form a first fired material containing essentially all of the tungsten and the remaining portion of the rhenium, increasing the surface area of the resulting oxidized tungsten, and firing the first fired material in an oxidizing atmosphere at a sufficient temperature for a sufficient time to remove essentially all of the remaining portion of the rhenium as volatilized oxidized rhenium and to form an essentially rhenium-free oxidized tungsten.
摘要翻译：公开了从钨和铼源回收钨和铼的方法。该方法包括在氧化气氛中在足够的温度下将该源烧制足够的时间以将钨和铼转化成其各自的氧化物，以除去作为挥发的氧化物的一部分铼，并形成基本上全部含有的第一烧制材料的钨和剩余部分的铼，增加所得到的氧化钨的表面积，并且在足够的温度下在氧化气氛中焙烧第一烧制材料足够的时间以基本上除去剩余部分的铼作为挥发的氧化铼并形成基本上不含铼的氧化钨。

5. 发明授权

US4599223A Separation of tungsten from rhenium 失效
标题翻译：钨与铼的分离
公开(公告)号：US4599223A
公开(公告)日：1986-07-08
申请号：US737758
申请日：1985-05-28
申请人： Alan D. Douglas , Kenneth T. Reilly , Martin B. MacInnis , John A. Powers , James N. Christini
发明人： Alan D. Douglas , Kenneth T. Reilly , Martin B. MacInnis , John A. Powers , James N. Christini
IPC分类号： C01G41/02 , C01G47/00 , C22B34/36 , C22B61/00 , C01G41/00
CPC分类号： C22B61/00 , C01G41/02 , C01G47/00 , C22B34/36 , C01P2006/80
摘要： A process is disclosed for separating tungsten from a solution containing tungstate and perrhenate ions. The process involves reacting a sufficient amount of hydrochloric acid with the solution at a sufficient temperature to form a solid containing essentially all of the tungsten and a liquor containing essentially all of the rhenium, and separating the solid from the liquor.
摘要翻译：公开了从含有钨酸盐和高铼酸根离子的溶液中分离钨的方法。该方法包括使足够量的盐酸与溶液在足够的温度下反应以形成含有基本上所有钨的固体和含有基本上所有铼的液体，并将该固体与液体分离。

6. 发明授权

US4584185A Recovery of tungsten and rhenium 失效
标题翻译：回收钨和铼
公开(公告)号：US4584185A
公开(公告)日：1986-04-22
申请号：US768252
申请日：1985-08-22
申请人： Alan D. Douglas , Kenneth T. Reilly
发明人： Alan D. Douglas , Kenneth T. Reilly
IPC分类号： C01G41/02 , C01G47/00 , C22B34/36 , C22B61/00 , C01G41/00
CPC分类号： C01G47/00 , C01G41/02 , C22B34/36 , C22B61/00
摘要： A process is disclosed for recovering tungsten and rhenium from a tungsten and rhenium bearing solution. The process involves adding sufficient hydrochloric acid to the solution to form a first precipitate containing essentially all of the tungsten and a first mother liquor having an acid concentration of at least about 1.25 normal, and containing the major portion the rhenium, followed by separating the first precipitate from the first mother liquor. A source of sulfide ions is then added to the first mother liquor with agitation for a sufficient time and with the amount of sulfide ions being sufficient to form a second precipitate containing essentially all of the rhenium which was in the first mother liquor, and a second mother liquor, followed by separation of the second precipitate from the second mother liquor.
摘要翻译：公开了从钨和铼轴承溶液中回收钨和铼的方法。该方法包括向溶液中加入足够的盐酸以形成含有基本上所有钨的第一沉淀物和含有至少约1.25正常酸浓度的第一母液，并且含有主要部分的铼，然后分离出第一从第一母液中沉淀出来。然后将硫化物离子源搅拌加入到第一母液中足够的时间，并且硫化物离子的量足以形成含有基本上所有在第一母液中的铼的第二沉淀物，第二次母液，然后从第二母液中分离出第二沉淀物。

7. 发明授权

US4557906A Recovery of rhenium 失效
标题翻译：回收铼
公开(公告)号：US4557906A
公开(公告)日：1985-12-10
申请号：US669125
申请日：1984-11-07
申请人： Alan D. Douglas , Kenneth T. Reilly , John E. Landmesser
发明人： Alan D. Douglas , Kenneth T. Reilly , John E. Landmesser
IPC分类号： C01G41/00 , C01G47/00 , C22B34/30 , C22B61/00
CPC分类号： C01G41/003 , C01G47/003 , C22B3/42 , C22B34/30 , C22B61/00 , Y02P10/234
摘要： In a process for recovering rhenium, a starting material containing tungsten and rhenium is reacted with sodium hydroxide and an oxidizing reactant to form a fused solid. The fused solid is dissolved in water to solubilize the tungsten and rhenium values and then pass through an anion exchange resin to remove the rhenium values and form a solution containing the tungsten values. The resin is stripped to obtain the rhenium values from the resin.
摘要翻译：在回收铼的方法中，将含有钨和铼的原料与氢氧化钠和氧化反应物反应以形成熔融固体。将熔融的固体溶解在水中以溶解钨和铼的值，然后通过阴离子交换树脂以除去铼值并形成含有钨值的溶液。剥离树脂以从树脂获得铼值。

8. 发明授权

US4603043A Controllable nitrate fusion 失效
标题翻译：可控硝酸盐融合
公开(公告)号：US4603043A
公开(公告)日：1986-07-29
申请号：US707253
申请日：1985-03-01
申请人： Alan D. Douglas , Kenneth T. Reilly , John E. Landmesser
发明人： Alan D. Douglas , Kenneth T. Reilly , John E. Landmesser
IPC分类号： C01G41/00
CPC分类号： C01G41/00
摘要： A process for converting tungsten bearing material to sodium tungstate by adding an oxidizing reactant in small increments to a heated mixture of fused sodium hydroxide and the tungsten bearing material while the temperature is maintained at from about 500.degree. C. to about 700.degree. C.
摘要翻译：通过在温度保持在约500℃至约700℃的温度下，以小增量将氧化反应物加入熔融氢氧化钠和含钨材料的加热混合物中，将含钨材料转化为钨酸钠的方法。

9. 发明授权

US4599222A Recovery of tungsten and rhenium 失效
标题翻译：回收钨和铼
公开(公告)号：US4599222A
公开(公告)日：1986-07-08
申请号：US728649
申请日：1985-04-29
申请人： Alan D. Douglas , Martin B. MacInnis , Kenneth T. Reilly
发明人： Alan D. Douglas , Martin B. MacInnis , Kenneth T. Reilly
IPC分类号： C01G41/00 , C01G47/00 , C22B3/36 , C22B34/36 , C22B61/00
CPC分类号： C01G47/003 , C01G41/003 , C22B3/0036 , C22B34/36 , C22B61/00 , Y02P10/234
摘要： A process is disclosed for recovering tungsten and rhenium from a relatively impure tungsten and rhenium solution. The process involves adjusting the pH of the solution to from about 9.0 to about 10.0 to precipitate impurities, and removing the impurities. The purified solution is adjusted to a pH of from about 0.5 to about 7.0 with a mineral acid. To the purified solution is added a solution containing sufficient hexamine to subsequently form a first hexamine tungsten solid containing the major portion of the tungsten. The hexamine solution is at essentially at the same pH as that of the pH adjusted purified solution. The resulting hexamine-tungsten-rhenium mixture is agitated at a sufficiently low temperature for a sufficient time to form the first solid and a first mother liquor containing the major portion of the rhenium. The first solid is separated from the first mother liquor.A process is disclosed for accomplishing the above in which a relatively impure tungsten and rhenium solution is purified as above. A hexamine solution which is not pH adjusted is added to the purified solution followed by adjustment of the pH of the resulting hexamine-tungsten-rhenium mixture to about 0.5 to about 7.0 as described above to form a first solid containing the major portion of the tungsten and a first mother liquor containing the major portion of the rhenium, followed by removal of the first solid from the first mother liquor.
摘要翻译：公开了从相对不纯的钨和铼溶液中回收钨和铼的方法。该方法包括将溶液的pH调节至约9.0至约10.0以沉淀杂质并除去杂质。将纯化的溶液用无机酸调节至约0.5至约7.0的pH。向纯化的溶液中加入含有足够六胺的溶液，随后形成含有主要部分钨的第一六胺钨固体。六聚氰胺溶液基本上处于与pH调节的纯化溶液相同的pH。将所得的六胺 - 铼 - 铼混合物在足够低的温度下搅拌足够的时间以形成第一固体和含有主要部分铼的第一母液。第一种固体与第一种母液分离。公开了一种完成上述方法，其中如上所述纯化相对不纯的钨和铼溶液。将未调节的六胺溶液加入到纯化溶液中，然后如上所述将所得六胺 - 钨 - 铼混合物的pH调节至约0.5至约7.0，以形成含有主要部分钨的第一固体和含有铼的主要部分的第一母液，然后从第一母液中除去第一固体。

10. 发明授权

US4816069A Method for converting cobalt to cobalt metal powder 失效
标题翻译：将钴转化为钴金属粉末的方法
公开(公告)号：US4816069A
公开(公告)日：1989-03-28
申请号：US197560
申请日：1988-05-23
申请人： Alan D. Douglas , Martin B. MacInnis , Clarence D. Vanderpool
发明人： Alan D. Douglas , Martin B. MacInnis , Clarence D. Vanderpool
IPC分类号： B22F9/02 , B22F9/04 , C22C1/04 , B02C19/12
CPC分类号： C22C1/0433 , B22F9/02 , B22F9/04
摘要： A method for converting cobalt to cobalt powder is disclosed which comprises heating a starting mixture of cobalt and zinc in a non-reacting atomosphere at a first temperature of below the boiling point of zinc up to about 900.degree. C. in a non-reacting atmosphere for a length of time sufficient to cause the alloying of a portion of the zinc and cobalt, with the weight ratio of zinc to cobalt being less than about 10. The temperature of the resulting partially alloyed mixture is slowly raised to a second temperature of from about 900.degree. C. to about 960.degree. and is maintained for a time sufficient only to form a reaction product in which essentially all of the cobalt is alloyed with zinc and to keep the evaporation of zinc to a minimum. The reaction product is then heated at a pressure below atmospheric pressure at a third temperature of no greater than about 950.degree. C. for a time sufficient to evaporate essentially all of the zinc and produce a cobalt ingot which is pulverizable when cooled to room temperature.
摘要翻译：公开了一种将钴转化为钴粉末的方法，该方法包括在非反应性气氛中，在低于沸点至少约900℃的第一温度下，在非反应性大气中加热钴和锌的起始混合物一段时间足以引起一部分锌和钴的合金化，锌与钴的重量比小于约10.所得到的部分合金化混合物的温度缓慢升至第二温度约900℃至约960℃，并保持足以仅形成反应产物的时间，其中基本上所有的钴与锌合金化并使锌的蒸发保持最小。然后将反应产物在不大于约950℃的第三温度下在低于大气压的压力下加热足以蒸发基本上所有锌的时间，并产生当冷却至室温时可粉化的钴锭。

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