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1. 发明授权

US6077978A Direct polyoxyalkylation of glycerine with double metal cyanide catalysis 失效
标题翻译：甘油双金属氰化物催化直接聚氧化烷基化
公开(公告)号：US6077978A
公开(公告)日：2000-06-20
申请号：US932613
申请日：1997-09-17
申请人： Kenneth G. McDaniel , Mark J. Perry , John E. Hayes
发明人： Kenneth G. McDaniel , Mark J. Perry , John E. Hayes
IPC分类号： C08G65/26 , C08G65/10 , C07C43/11
CPC分类号： C08G65/2663 , C08G65/2696
摘要： Acidification, neutralization, or removal of basic impurities from acid sensitive low molecular weight starter or acidification of a reactor heel prior to addition of acid sensitive low molecular weight starter allows direct oxyalkylation of continuously added acid sensitive low molecular weight starter to produce polyoxyalkylene acid sensitive low molecular weight starter-initiated or co-initiated polyols in the presence of a double metal cyanide catalyst. The preferred acid sensitive low molecular weight starter is glycerine.
摘要翻译：在加入酸敏感低分子量起始剂之前，酸化，中和或从酸敏感低分子量起始剂中除去碱性杂质或反应器脚跟的酸化使得连续加入的酸敏感低分子量起始物的直接烷氧基化产生聚氧化烯酸敏感性低分子量起始物起始或共引发的多元醇在双金属氰化物催化剂存在下进行。优选的酸敏低分子量起动剂是甘油。

2. 发明授权

US07977501B2 Polyether carbonate polyols made via double metal cyanide (DMC) catalysis 有权
标题翻译：通过双金属氰化物（DMC）催化制备的聚醚碳酸酯多元醇
公开(公告)号：US07977501B2
公开(公告)日：2011-07-12
申请号：US11491680
申请日：2006-07-24
申请人： Karl W. Haider , Kenneth G. McDaniel , John E. Hayes , Jianzhong Shen
发明人： Karl W. Haider , Kenneth G. McDaniel , John E. Hayes , Jianzhong Shen
IPC分类号： C07C69/96 , C08G64/02 , C08G64/32
CPC分类号： C08G64/183 , C08G64/32 , C08G65/2663
摘要： The present invention relates to a polyether carbonate polyol made by copolymerizing a starter molecule with carbon dioxide, at a pressure ranging from about 10 psia to about 2,000 psia, and an alkylene oxide, at a temperature ranging from about 50° C. to about 190° C. and in the presence of from about 0.001 wt. % to about 0.2 wt. % of a substantially non-crystalline double metal cyanide (DMC) catalyst, wherein the polyol has an incorporated carbon dioxide content of from about 1 wt. % to about 40 wt. %, wherein the ratio of cyclic carbonate by-product to total carbonate is less than about 0.3 and wherein the weight percentages are based on the weight of the polyol. The inventive polyether carbonate polyols may find use in producing polyurethane foams, elastomers, coatings, sealants and adhesives with improved properties.
摘要翻译：本发明涉及一种聚醚碳酸酯多元醇，其通过将起始分子与二氧化碳在约10psia至约2,000psia的压力和烯化氧的温度范围内共聚而制备，温度为约50℃至约190℃ 在约0.001wt。％至约0.2wt。％的基本上非结晶的双金属氰化物（DMC）催化剂，其中所述多元醇具有约1wt。％至约40wt。％，其中环状碳酸酯副产物与总碳酸盐的比例小于约0.3，并且其中重量百分比基于多元醇的重量。本发明的聚醚碳酸酯多元醇可用于生产具有改进性能的聚氨酯泡沫，弹性体，涂料，密封剂和粘合剂。

3. 发明申请

US20080021154A1 Polyether carbonate polyols made via double metal cyanide (DMC) catalysis 有权
标题翻译：通过双金属氰化物（DMC）催化制备的聚醚碳酸酯多元醇
公开(公告)号：US20080021154A1
公开(公告)日：2008-01-24
申请号：US11491680
申请日：2006-07-24
申请人： Karl W. Haider , Kenneth G. McDaniel , John E. Hayes , Jianzhong Shen
发明人： Karl W. Haider , Kenneth G. McDaniel , John E. Hayes , Jianzhong Shen
IPC分类号： C08G63/48
CPC分类号： C08G64/183 , C08G64/32 , C08G65/2663
摘要： The present invention relates to a polyether carbonate polyol made by copolymerizing a starter molecule with carbon dioxide, at a pressure ranging from about 10 psia to about 2,000 psia, and an alkylene oxide, at a temperature ranging from about 50° C. to about 190° C. and in the presence of from about 0.001 wt. % to about 0.2 wt. % of a substantially non-crystalline double metal cyanide (DMC) catalyst, wherein the polyol has an incorporated carbon dioxide content of from about 1 wt. % to about 40 wt. %, wherein the ratio of cyclic carbonate by-product to total carbonate is less than about 0.3 and wherein the weight percentages are based on the weight of the polyol. The inventive polyether carbonate polyols may find use in producing polyurethane foams, elastomers, coatings, sealants and adhesives with improved properties.
摘要翻译：本发明涉及一种聚醚碳酸酯多元醇，其通过将起始分子与二氧化碳在约10psia至约2,000psia的压力和烯化氧的温度范围内共聚而制备，温度为约50℃至约190℃ 在约0.001wt。％至约0.2wt。％的基本上非结晶的双金属氰化物（DMC）催化剂，其中所述多元醇具有约1wt。％至约40wt。％，其中环状碳酸酯副产物与总碳酸盐的比例小于约0.3，并且其中重量百分比基于多元醇的重量。本发明的聚醚碳酸酯多元醇可用于生产具有改进性能的聚氨酯泡沫，弹性体，涂料，密封剂和粘合剂。

4. 发明授权

US5854386A Stabilizers for polymer polyols 失效
标题翻译：聚合物多元醇的稳定剂
公开(公告)号：US5854386A
公开(公告)日：1998-12-29
申请号：US918081
申请日：1997-08-25
申请人： Jianzhong Shen , Kenneth G. McDaniel , John E. Hayes , Uli B. Holeschovsky , Harry R. Hinney
发明人： Jianzhong Shen , Kenneth G. McDaniel , John E. Hayes , Uli B. Holeschovsky , Harry R. Hinney
IPC分类号： C08G65/10 , C08G65/26 , C08G59/00
CPC分类号： C08G18/635 , C08F2/40 , C08G18/636 , C08G65/10 , C08G65/2609 , C08G65/2615 , C08G65/2663 , C08G65/2696
摘要： Unique, well defined polyethers containing both hydroxyl-functionality and unsaturation-functionality are prepared by oxyalkylating an unsaturated monomer having at least one oxyalkylatable hydrogen in the presence of an effective amount of a double metal cyanide complex catalyst, optionally, when necessary, in the presence of a free radical polymerization inhibitor. The resulting polyethers are eminently suitable for such uses as polymer polyol stabilizers or stabilizer precursors, and both in situ and ex situ impact modifiers for thermoplastics.
摘要翻译：含有羟基官能度和不饱和官能度的独特的，明确定义的聚醚通过在有效量的双金属氰化物配合物催化剂存在下，任选地，在必要时在存在下，使存在有至少一个可氧化烷基化氢的不饱和单体进行烷氧基化，的自由基聚合抑制剂。所得聚醚特别适用于聚合物多元醇稳定剂或稳定剂前体以及热塑性塑料的原位和非原位冲击改性剂。

5. 发明申请

US20100331517A1 POLYETHER CARBONATE POLYOLS MADE VIA DOUBLE METAL CYANDIE (DMC) CATALYSIS 有权
标题翻译：聚碳酸酯多元醇通过双金属氰化物（DMC）催化
公开(公告)号：US20100331517A1
公开(公告)日：2010-12-30
申请号：US12880231
申请日：2010-09-13
申请人： Karl W. Haider , Kenneth G. McDaniel , John E. Hayes , Jianzhong Shen
发明人： Karl W. Haider , Kenneth G. McDaniel , John E. Hayes , Jianzhong Shen
IPC分类号： C08G64/02
CPC分类号： C08G64/183 , C08G64/32 , C08G65/2663
摘要： The present invention relates to a polyether carbonate polyol made by copolymerizing a starter molecule with carbon dioxide, at a pressure ranging from about 10 psia to about 2,000 psia, and an alkylene oxide, at a temperature ranging from about 50° C. to about 190° C. and in the presence of from about 0.001 Wt. % to about 0.2 wt. % of a substantially non-crystalline double metal cyanide (DMC) catalyst, wherein the polyol has an incorporated carbon dioxide content of from about 1 wt. % to about 40 wt. %, wherein the ratio of cyclic carbonate by-product to total carbonate is less than about 0.3 and wherein the weight percentages are based on the weight of the polyol. The inventive polyether carbonate polyols may find use in producing polyurethane foams, elastomers, coatings, sealants and adhesives with improved properties.
摘要翻译：本发明涉及一种聚醚碳酸酯多元醇，其通过将起始分子与二氧化碳在约10psia至约2,000psia的压力和烯化氧的温度范围内共聚而制备，温度为约50℃至约190℃ 在约0.001Wt的存在下。％至约0.2wt。％的基本上非结晶的双金属氰化物（DMC）催化剂，其中所述多元醇具有约1wt。％至约40wt。％，其中环状碳酸酯副产物与总碳酸盐的比例小于约0.3，并且其中重量百分比基于多元醇的重量。本发明的聚醚碳酸酯多元醇可用于生产具有改进性能的聚氨酯泡沫，弹性体，涂料，密封剂和粘合剂。

6. 发明授权

US5990232A Stabilizers for polymer polyols 失效
标题翻译：聚合物多元醇的稳定剂
公开(公告)号：US5990232A
公开(公告)日：1999-11-23
申请号：US918207
申请日：1997-08-25
申请人： Jianzhong Shen , Kenneth G. McDaniel , John E. Hayes , Uli B. Holeschovsky , Harry R. Hinney
发明人： Jianzhong Shen , Kenneth G. McDaniel , John E. Hayes , Uli B. Holeschovsky , Harry R. Hinney
IPC分类号： C08G18/48 , C08G18/63 , C08G65/26 , C08L71/02 , C08K5/06
CPC分类号： C08G65/2663 , C08G18/4866 , C08G18/633 , C08G18/636 , C08G65/2615 , C08G65/2642 , C08L71/02
摘要： Unique, well defined polyethers containing both hydroxyl-functionality and unsaturation-functionality are prepared by oxyalkylating an unsaturated monomer having at least two free carboxylic acid groups in the presence of an effective amount of a double metal cyanide complex catalyst, optionally, when necessary, in the presence of a free radical polymerization inhibitor. The resulting polyethers are eminently suitable for such uses as polymer polyol stabilizers or stabilizer precursors, and both in situ and ex situ impact modifiers for thermoplastics.
摘要翻译：含有羟基官能度和不饱和官能度的独特的，明确定义的聚醚通过在有效量的双金属氰化物配合物催化剂存在下，任选地，必要时，在至少两个游离羧酸基团的存在下，在存在自由基聚合抑制剂。所得聚醚特别适用于聚合物多元醇稳定剂或稳定剂前体以及热塑性塑料的原位和非原位冲击改性剂。

7. 发明授权

US07473677B2 High productivity process for alkylphenol ethoxylates 有权
标题翻译：烷基酚乙氧基化物的高生产率工艺
公开(公告)号：US07473677B2
公开(公告)日：2009-01-06
申请号：US11787351
申请日：2007-04-16
申请人： Kenneth G. McDaniel , James R. Reese, II
发明人： Kenneth G. McDaniel , James R. Reese, II
IPC分类号： C11D1/72 , C11D13/00 , C07C41/01 , C07C43/164
CPC分类号： C08G65/2696 , C08G65/2612 , C08G65/2663
摘要： The present invention provides a process for the production of an alkylphenol ethoxylate involving charging a portion of product from a previous preparation (a “heel”) or an ethoxylate to a reactor, optionally, charging from about 0.2 wt. % to an amount equal to or greater than the weight of the heel of an alkylphenol starter to the reactor, charging ethylene oxide to activate a double metal cyanide (“DMC”) catalyst, adding the alkylphenol starter simultaneously with ethylene oxide for a portion of the process and continuing ethylene oxide addition following completion of the simultaneous alkylphenol starter and ethylene oxide addition. The process of the present invention provides significant improvements in cycle time and safety in producing ethoxylates which may find use in or as surfactants.
摘要翻译：本发明提供了一种制备烷基酚乙氧基化物的方法，其包括将来自先前制备物（“脚后跟”）或乙氧基化物的一部分产物装入反应器，任选地，将约0.2wt。％至等于或大于烷基酚起始物到反应器的后跟的重量的量，加入环氧乙烷以活化双金属氰化物（“DMC”）催化剂，将烷基酚起始物与环氧乙烷同时加入一部分完成同时烷基酚起始物和环氧乙烷添加后的方法和持续的环氧乙烷添加。本发明的方法提供循环时间和生产乙氧基化物的安全性方面的显着改进，其可用于或作为表面活性剂。

8. 发明申请

US20080167501A1 High productivity alkoxylation processes 审中-公开
标题翻译：高生产率烷氧基化方法
公开(公告)号：US20080167501A1
公开(公告)日：2008-07-10
申请号：US11893452
申请日：2007-08-16
申请人： Kenneth G. McDaniel
发明人： Kenneth G. McDaniel
IPC分类号： C07C41/01
CPC分类号： C08G65/2696 , C08G65/2606 , C08G65/2651 , C08G65/266 , C08G65/2663
摘要： The present invention provides a continuous process for the preparation of a polyoxyalkylene polyether product of number average molecular weight N employing continuous addition of starter, involving a) establishing in a continuous reactor a first portion of a catalyst/initial starter mixture effective initiate polyoxyalkylation of the initial starter after introduction of alkylene oxide into the continuous reactor, b) continuously introducing into the continuous reactor one or more alkylene oxides, c) continuously introducing into the continuous reactor one or more continuously added starters which may be the same or different than said initial starter, d) continuously introducing into the reactor fresh catalyst and/or further catalyst/further starter mixture such that the catalytic activity is maintained, wherein the catalyst is selected from the group consisting of modified oxides and hydroxides of calcium, strontium and barium, lanthanum phosphates or lanthanide series (rare earth) phosphates and hydrotalcites and synthetic hydrotalcites, e) polyoxyalkylating combined starters by continuously practicing at least steps b) through d) herein until a polyoxyalkylene polyether product of number average molecular weight N is obtained and f) continuously removing the polyoxyalkylene polyether product from the continuous reactor. Modified-calcium hydroxide or modified calcium oxide and lanthanum phosphate catalysts exhibit catch-up kinetics and are thus useful for the production of polyalkylene oxides using the continuous and CAOS processes.
摘要翻译：本发明提供了连续加入起始物制备数均分子量为N的聚氧化烯聚醚产物的连续方法，该方法包括：a）在连续反应器中建立第一部分催化剂/初始起动剂混合物，有效引发聚氧烷基化将烯化氧引入连续反应器中的初始起始物，b）连续地向连续反应器中引入一种或多种烯化氧，c）连续地向连续反应器中引入一个或多个连续添加的起始器，其可以与所述初始化合物相同或不同起始物，d）连续向反应器中引入新鲜催化剂和/或其它催化剂/进一步起动混合物以保持催化活性，其中催化剂选自钙，锶和钡的改性氧化物和氢氧化物，镧磷酸盐或镧系（稀土）磷酸盐和水滑石和合成水滑石，e）通过连续实施至少步骤b）至d）在本文中直到形成数均分子量为N的聚氧化亚烷基聚醚产物并且f）从连续反应器中连续除去聚氧化烯聚醚产物。改性氢氧化钙或改性氧化钙和磷酸镧催化剂表现出追赶动力学，因此可用于使用连续和CAOS方法生产聚环氧烷。

9. 发明授权

US6034208A Copolymers useful as cement additives and a process for their preparation 失效
标题翻译：可用作水泥添加剂的共聚物及其制备方法
公开(公告)号：US6034208A
公开(公告)日：2000-03-07
申请号：US74673
申请日：1998-05-08
申请人： Kenneth G. McDaniel , Edward T. Shawl , Xinhau Zhou
发明人： Kenneth G. McDaniel , Edward T. Shawl , Xinhau Zhou
IPC分类号： C08G65/10 , C08G65/26 , C08G59/00
CPC分类号： C08G18/635 , C08F2/40 , C08G18/636 , C08G65/10 , C08G65/2609 , C08G65/2615 , C08G65/2663 , C08G65/2696
摘要： Unique, well defined macromonomers containing hydroxyl-functionality, unsaturation-functionality, and polyoxyalkylene segments are prepared by oxyalkylating an unsaturated initiator molecule having at least one oxyalkylatable hydrogen in the presence of an effective amount of a double metal cyanide complex catalyst, optionally, when necessary, in the presence of a free radical polymerization inhibitor. The resulting unsaturated macromonomers are eminently suitable for such uses as copolymerization with ethylenically unsaturated monomers containing carboxylic acid-based groups such as acrylic acid to form effective superplasticizers and water reducers for cement and concrete applications.
摘要翻译：含有羟基官能团，不饱和官能度和聚氧化烯链段的独特的，明确定义的大单体通过在有效量的双金属氰化物配合物催化剂存在下，任选地，当需要时，使具有至少一个可氧化烷基化氢的不饱和引发剂分子在自由基聚合抑制剂存在下进行。所得的不饱和大单体非常适用于与含有羧酸基团的烯属不饱和单体如丙烯酸共聚形成用于水泥和混凝土应用的有效超增塑剂和减水剂的用途。

10. 发明授权

US4642319A Modified terephthalic ester polyols and rigid foams therefrom 失效
标题翻译：改性对苯二甲酸酯多元醇及其刚性泡沫
公开(公告)号：US4642319A
公开(公告)日：1987-02-10
申请号：US821319
申请日：1986-01-22
申请人： Kenneth G. McDaniel
发明人： Kenneth G. McDaniel
IPC分类号： C08G18/42 , C08G18/46 , C08G18/14 , C08G18/32 , C08G18/34
CPC分类号： C08G18/4219 , C08G18/4213 , C08G18/4615 , C08G2101/0025 , C08G2105/02 , Y10S521/902
摘要： The preparation of isocyanurate foams from a recycled polyethylene terephthalate polyol modified with aromatic amino polyols, sucrose polyols, ethoxylated alphamethyl glucosides, alkoxylated glycerine or alkoxylated sorbitol is disclosed. These modified foams exhibit improved fluorocarbon solubility. The foams may be used for building roofing and sheathing applications.
摘要翻译：公开了由芳族氨基多元醇，蔗糖多元醇，乙氧基化α-甲基葡糖苷，烷氧基化甘油或烷氧基化山梨醇改性的再循环聚对苯二甲酸乙二醇酯多元醇制备异氰脲酸酯泡沫。这些改性泡沫表现出改善的氟碳溶解度。泡沫可用于建筑屋顶和护套应用。

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