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    • 8. 发明申请
    • PROCESS FOR MANUFACTURING NI-BASE ALLOY AND NI-BASE ALLOY
    • 制造NI-BASE合金和NI-BASE合金的工艺
    • US20110171058A1
    • 2011-07-14
    • US13063414
    • 2009-09-25
    • Chuya AokiToshihiro UeharaTakehiro Ohno
    • Chuya AokiToshihiro UeharaTakehiro Ohno
    • C22C19/05C21D11/00C22F1/10
    • C22B9/04C22B9/18C22B9/20C22B23/06C22C19/055C22F1/02C22F1/10
    • Provided is an Ni-base alloy excellent in strength, ductility and other properties through the resolution of micro-segregation. Also provided is a process for manufacturing an Ni-base alloy containing by mass C: 0.15% or less, Si: 1% or less, Mn: 1% or less, Cr: 10 to 24%, Mo+(½)W (where Mo may be contained either alone or as an essential component): 5 to 17%, Al: 0.5 to 1.8%, Ti: 1 to 2.5%, Mg: 0.02% or less, and either B: 0.02% or less and/or Zr: 0.2% or less at an Al/(Al+0.56Ti) ratio of 0.45 to 0.70 with the balance consisting of Ni and impurities, which comprises subjecting, at least one time, an Ni-base alloy material which is prepared by vacuum melting and has the above composition to homogenization heat treatment at 1160 to 1220° C. for 1 to 100 hours. The Mo segregation ratio of the alloy is controlled to 1 to 1.17 by the homogenization heat treatment.
    • 提供了通过分离微分离而具有优异的强度,延展性等特性的Ni基合金。 还提供了以质量计C:0.15%以下,Si:1%以下,Mn:1%以下,Cr:10〜24%,Mo +(1/2)W(其中, Mo可以单独或作为必要成分含有):5〜17%,Al:0.5〜1.8%,Ti:1〜2.5%,Mg:0.02%以下,B:0.02%以下和/或 Zr:在Al /(Al + 0.56Ti)比为0.45〜0.70的情况下为0.2%以下,余量由Ni和杂质组成,其中包括至少一次将真空制备的Ni基合金材料 熔化并具有上述组成以在1160至1220℃进行均化热处理1至100小时。 通过均质化热处理将合金的Mo偏析比控制在1〜1.17。
    • 9. 发明授权
    • Manufacturing process of nickel-based alloy having improved hot sulfidation-corrosion resistance
    • 具有改善的耐热硫化 - 耐腐蚀性的镍基合金的制造方法
    • US06447624B2
    • 2002-09-10
    • US09825948
    • 2001-04-05
    • Toshiaki NonomuraTakehiro OhnoToshihiro UeharaHiroshi YakuwaMatsuho MiyasakaShuhei NakahamaShigeru Sawada
    • Toshiaki NonomuraTakehiro OhnoToshihiro UeharaHiroshi YakuwaMatsuho MiyasakaShuhei NakahamaShigeru Sawada
    • C22F110
    • C22C19/055C22C19/056C22F1/10
    • A manufacturing method, particularly a heat treatment method of a Ni-based alloy having sulfidation-corrosion resistance used for component members of corrosion-resistant high-temperature equipment, that is, Waspaloy (a trademark of United Technologies) or its improved Ni-based alloy wherein the high temperature sulfidation-corrosion resistance of the alloy can be improved while maintaining hot strength properties is disclosed. A Ni-based alloy used for the method consists essentially of 0.005 to 0.1% C, 18 to 21% Cr, 12 to 15% Co, 3.5 to 5.0% Mo, not more than 3.25% Ti and 1.2 to 4.0% Al (expressed in mass percentage), with the balance substantially comprising Ni. In the manufacturing method of a Ni-based alloy having improved sulfidation-corrosion resistance, the alloy is, after solution heat treatment, subjected to stabilizing treatment at a temperature not lower than 860° C. and not higher than 920° C. for 1 to 16 hours, and aging treatment at a temperature not lower than 680° C. and not higher than 760° C. for 4 to 48 hours.
    • 特别是具有耐腐蚀性高的设备的组件的耐硫化性的Ni基合金的热处理方法,即Waspaloy(United Technologies的商标)或其改进的Ni基 合金,其中可以提高合金的高温耐硫化腐蚀性,同时保持热强度性能。 用于该方法的Ni基合金主要由0.005至0.1%的C,18至21%的Cr,12至15%的Co,3.5至5.0%的Mo,不超过3.25%的Ti和1.2至4.0%的Al(表达 以质量百分比表示),余量基本上包含Ni。 在具有改善的耐硫化腐蚀性的Ni基合金的制造方法中,在固溶热处理之后,合金在不低于860℃且不高于920℃的温度下进行稳定处理1 至16小时,并在不低于680℃且不高于760℃的温度下老化处理4至48小时。
    • 10. 发明授权
    • Steel for separators of solid-oxide type fuel cells
    • 用于固体氧化物型燃料电池分离器的钢
    • US06776956B2
    • 2004-08-17
    • US10132571
    • 2002-04-26
    • Toshihiro UeharaAkihiro TojiTakehiro Ohno
    • Toshihiro UeharaAkihiro TojiTakehiro Ohno
    • C22C3818
    • H01M8/0204C22C38/004C22C38/005C22C38/06C22C38/50H01M8/021H01M8/0228H01M8/0232
    • Provided is a steel for separators of solid-oxide type fuel cells, which forms oxide films having good electrical conductivity at 700 to 950° C. or so, has good oxidation resistance and, in particular, resistance to exfoliation even in the case of long hours of use, is excellent in impact properties at room temperature, shows a small difference in thermal expansion from the electrolyte, and is inexpensive. This steel for separators of solid-oxide fuel cells includes, by mass %, not more than 0.2% C, not more than 1.0% Si, not more than 1.0% Mn, not more than 2% Ni, 15 to 30% Cr, not more than 1% Al, one or more elements selected from the group of not more than 0.5% Y, not more than 0.2% REM and not more than 1% Zr, and the balance of Fe and unavoidable impurities. In this steel, amounts of S, O, N and B in the unavoidable impurities are restricted to not more than 0.015%, not more than 0.010%, not more than 0.050% and not more than 0.0050%, respectively, the following equation is satisfied: (0+2S)/(0.27Y+0.035Zr+0.16REM)≦2.0, Furthermore, in this steel, the hardness is not more than 280 HV and the average ferrite grain size number is not less than ASTM No. 2, which provides fine grains.
    • 本发明提供一种固体氧化物型燃料电池用隔板的钢,其形成在700〜950℃左右的导电性良好的氧化膜,具有良好的抗氧化性,特别是长时间耐剥离性 使用时间小,室温下的冲击性优异,与电解质的热膨胀差异小,成本低廉。 用于固体氧化物型燃料电池用隔板的钢中,以质量%计不超过0.2%C,1.0%以下的Si,1.0%以下的Mn,2%以下的Ni,15〜30%的Cr, 不大于1%的Al,选自不超过0.5%Y,不超过0.2%REM和不超过1%Zr的一种或多种元素,余量为Fe和不可避免的杂质。 在这种钢中,不可避免的杂质中的S,O,N和B的量分别限制在不大于0.015%,不大于0.010%,不大于0.050%和不大于0.0050%,下面的等式是 满意:此外,在该钢中,硬度为280HV以下,平均铁素体晶粒尺寸数不小于提供细晶粒的ASTM No.2。