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1. 发明授权

US06294311B1 Lithographic printing plate having high chemical resistance 有权
标题翻译：平版印刷版具有高耐化学腐蚀性
公开(公告)号：US06294311B1
公开(公告)日：2001-09-25
申请号：US09469493
申请日：1999-12-22
申请人： Ken-ichi Shimazu , Jayanti Patel , Jianbing Huang , Nishith Merchant , Mathias Jarek
发明人： Ken-ichi Shimazu , Jayanti Patel , Jianbing Huang , Nishith Merchant , Mathias Jarek
IPC分类号： G03F7004
CPC分类号： B41C1/1016 , B41C2210/02 , B41C2210/06 , B41C2210/14 , B41C2210/22 , B41C2210/24 , B41C2210/262 , B41N3/00
摘要： Imageable elements useful as lithographic printing members are disclosed. The elements contain a substrate, an underlayer, and a top layer. The underlayer contains a combination of polymeric materials that provides resistance both to fountain solution and to aggressive washes, such as a UV wash. The underlayer can be used in either thermally imageable or photochemically imageable elements.
摘要翻译：公开了可用作平版印刷构件的可成像元件。元件包含基底，底层和顶层。底层包含聚合材料的组合，其提供对润版液和侵蚀性洗涤（例如UV洗涤）的电阻。底层可用于可热成像或光电化学成像的元件。

2. 发明申请

US20120141942A1 METHOD OF PREPARING LITHOGRAPHIC PRINTING PLATES 审中-公开
标题翻译：制备平版印刷板的方法
公开(公告)号：US20120141942A1
公开(公告)日：2012-06-07
申请号：US12959432
申请日：2010-12-03
申请人： Domenico Balbinot , Mathias Jarek , Jianbing Huang , Ting Tao , Christopher D. Simpson
发明人： Domenico Balbinot , Mathias Jarek , Jianbing Huang , Ting Tao , Christopher D. Simpson
IPC分类号： G03F7/20
CPC分类号： G03F7/322 , B41C1/1008 , B41C1/1016 , B41C2201/02 , B41C2201/14 , B41C2210/04 , B41C2210/06 , B41C2210/10 , B41C2210/12 , B41C2210/22 , B41C2210/24 , B41C2210/266 , G03F7/033 , G03F7/035
摘要： Lithographic printing plates are prepared by imaging and developing negative-working lithographic printing plate precursors that include certain particulate polymeric binders in the photosensitive imageable layer. Such particulate polymeric binders are poly(urethane-acrylic) hybrids. Development is carried out using a working strength developer that includes one or more organic solvents in a total amount of at least 7 weight % and an anionic surfactant in an amount of at least 5 weight %.
摘要翻译：通过成像和显影在光敏可成像层中包含某些颗粒聚合物粘合剂的负性平版印刷版前体制备平版印刷版。这种颗粒聚合物粘合剂是聚（氨基甲酸酯 - 丙烯酸）混合物。使用包含总量至少7重量％的一种或多种有机溶剂和至少5重量％的阴离子表面活性剂的工作强度显影剂进行显影。

3. 发明授权

US09029063B2 Negative-working lithographic printing plate precursors 有权
标题翻译：负性平版印刷版前体
公开(公告)号：US09029063B2
公开(公告)日：2015-05-12
申请号：US13239435
申请日：2011-09-22
申请人： Domenico Balbinot , Harald Baumann , Udo Dwars , Mathias Jarek , Christopher D. Simpson
发明人： Domenico Balbinot , Harald Baumann , Udo Dwars , Mathias Jarek , Christopher D. Simpson
IPC分类号： G03F7/00 , G03F7/26 , G03F7/029 , G03F7/031
CPC分类号： G03F7/029 , B41C1/1008 , B41C2210/04 , B41C2210/06 , B41C2210/08 , B41C2210/22 , B41C2210/24 , B41C2210/266 , G03F7/031
摘要： A lithographic printing plate precursor comprises an imagable layer comprising a free radically polymerizable component, an initiator composition capable of generating free radicals upon exposure to imaging infrared radiation, an infrared radiation absorbing dye comprising an infrared radiation absorbing cation and a counter anion, and a polymeric binder. The salt formed between the infrared radiation absorbing cation and a tetraphenyl borate has solubility in 2-methoxy propanol at 20° C. that is greater than or equal to 3.5 g/l. The use of these infrared radiation absorbing dyes in the imagable layers provides a reduced tendency of these dyes to crystallize in the presence of tetraaryl borate counter anions.
摘要翻译：平版印刷版前体包括可成像层，其包含可自由基聚合的组分，在暴露于成像红外辐射时能够产生自由基的引发剂组合物，包含红外辐射吸收阳离子和抗衡阴离子的红外辐射吸收染料，以及聚合物粘合剂在红外辐射吸收阳离子和四苯基硼酸盐之间形成的盐在20℃下在2-甲氧基丙醇中具有大于或等于3.5g / l的溶解度。在可成像层中使用这些红外辐射吸收染料提供这些染料在硼酸四芳基酯阴离子存在下结晶的趋势。

4. 发明授权

US08329382B2 Method of processing elements with coalesced particles 失效
标题翻译：用合并颗粒处理元件的方法
公开(公告)号：US08329382B2
公开(公告)日：2012-12-11
申请号：US12552362
申请日：2009-09-02
申请人： Mathias Jarek , Domenico Balbinot
发明人： Mathias Jarek , Domenico Balbinot
IPC分类号： G03F7/00 , G03F7/26 , B41F7/00
CPC分类号： B41C1/1025 , B41C2201/04 , B41C2201/14 , B41C2210/04 , B41C2210/06 , B41C2210/08 , B41C2210/22 , B41C2210/24 , B41N3/08
摘要： Imageable elements can be imaged and then processed using a solution containing core-shell particles that are designed to complex with non-coalesced particles in the non-exposed regions of imaged element. A separate development step is not needed, but the non-coalesced particles and complexed core-shell particles can be removed from the resulting printing plate before using the resulting lithographic printing plate for printing.
摘要翻译：可成像元件可以成像，然后使用含有核 - 壳颗粒的溶液进行成像，该溶液设计成与成像元件的非曝光区域中的非聚结颗粒复合。不需要单独的显影步骤，但是在使用所得的平版印刷版进行印刷之前，可以从得到的印刷版中除去非聚结颗粒和络合的核 - 壳颗粒。

5. 发明申请

US20100248097A1 NEGATIVE-WORKING THERMAL IMAGEABLE ELEMENTS 有权
标题翻译：负责工作的热图像元件
公开(公告)号：US20100248097A1
公开(公告)日：2010-09-30
申请号：US12412400
申请日：2009-03-27
申请人： Mathias Jarek , Domenico Balbinot
发明人： Mathias Jarek , Domenico Balbinot
IPC分类号： G03F7/004 , G03F7/20
CPC分类号： B41C1/1025 , B41C2201/04 , B41C2201/14 , B41C2210/04 , B41C2210/06 , B41C2210/22 , B41C2210/24 , B41C2210/26 , B41C2210/264 , B41C2210/266 , B41M5/366
摘要： Negative-working imageable elements have a hydrophilic substrate and a single thermally-sensitive imageable layer. This layer can include an infrared radiation absorbing compound and polymeric particles that coalesce upon thermal imaging. These coalesceable polymeric particles comprise a thermoplastic polymer and a colorant to provide improved visible contrast between exposed and non-exposed regions in the imaged element, such as lithographic printing plates.
摘要翻译：负性可成像元件具有亲水基材和单一的热敏可成像层。该层可以包括红外辐射吸收化合物和在热成像时聚结的聚合物颗粒。这些可聚结聚合物颗粒包括热塑性聚合物和着色剂，以在成像元件（例如平版印刷版）中的曝光区域和非曝光区域之间提供改善的可见对比度。

6. 发明授权

US07060415B2 Printing plate precursor comprising solvent-resistant copolymer 失效
标题翻译：包含耐溶剂共聚物的印版前体
公开(公告)号：US07060415B2
公开(公告)日：2006-06-13
申请号：US11130797
申请日：2005-05-17
申请人： Anthony P. Kitson , Kevin B. Ray , Joanne Ray , Mathias Jarek , Celin Savariar-Hauck
发明人： Anthony P. Kitson , Kevin B. Ray , Joanne Ray , Mathias Jarek , Celin Savariar-Hauck
IPC分类号： G03F7/039 , G03F7/11 , G03F7/14 , G03F7/30
CPC分类号： B41C1/1016 , B41C2210/02 , B41C2210/06 , B41C2210/14 , B41C2210/22 , B41C2210/24 , B41C2210/262 , Y10S430/111 , Y10S430/165
摘要： The present invention provides a positive-working, thermally imageable element generally comprising a multi-layered imageable coating. The invention provides an imageable element comprising a substrate, an ink-receptive top layer, and an underlayer, the underlayer including a specific copolymer described herein. The copolymer can be a polymer comprising constitutional units derived from: a) a monomer having a cyclic urea group; b) a monomer comprising an N-substituted maleimide; c) a (meth)acrylamide or (meth)acrylate monomer; and d) a (meth)acrylic acid or vinyl benzoic acid monomer. In another embodiment, the copolymer can be a polymer comprising constitutional units derived from: a) a monomer having a cyclic urea group; b) a (meth)acrylic acid or vinyl benzoic acid monomer; c) and a (meth)acrylonitrile monomer. The imageable element may be used to prepare a lithographic printing plate that is resistant to press chemistry and can optionally be baked to increase press runlength.
摘要翻译：本发明提供了通常包括多层可成像涂层的正性加工的可热成像元件。本发明提供了一种可成像元件，其包括基底，油墨接受顶层和底层，底层包括本文所述的特定共聚物。共聚物可以是包含衍生自以下的结构单元的聚合物：a）具有环状脲基团的单体; b）包含N-取代的马来酰亚胺的单体; c）（甲基）丙烯酰胺或（甲基）丙烯酸酯单体; 和d）（甲基）丙烯酸或乙烯基苯甲酸单体。在另一个实施方案中，共聚物可以是包含衍生自以下的结构单元的聚合物：a）具有环状脲基团的单体; b）（甲基）丙烯酸或乙烯基苯甲酸单体; c）和（甲基）丙烯腈单体。可成像元件可以用于制备耐压制化学的平版印刷版，并且可以任选地烘烤以增加压制长度。

7. 发明授权

US06706454B2 Method for the production of a printing plate using particle growing acceleration by an additive polymer 失效
标题翻译：使用添加剂聚合物使用颗粒生长加速的印刷版的制造方法
公开(公告)号：US06706454B2
公开(公告)日：2004-03-16
申请号：US09899741
申请日：2001-07-05
申请人： Mathias Jarek
发明人： Mathias Jarek
IPC分类号： G03F7023
CPC分类号： G03F7/0233
摘要： A coating solution useful in the preparation of printing plate precursors comprises: a) a radiation sensitive composition C comprising a phenolic resin; b) at least one thermoplastic polymer P which has a solubility in aqueous alkaline media ranging from sparingly soluble to insoluble; c) a first solvent component A which is capable of solubilizing both composition C and thermoplastic polymer P; d) a second solvent component B having a volatility less than component A, wherein component B is capable of volatilizing composition C but not thermoplastic polymer P, and composition C and thermoplastic P are homogeneously dissolved in a mixture of components A and B; and e) at least one further polymer AP having a higher molecular weight than the phenolic resin of composition C, wherein polymer AB is miscible with the phenolic resin and immiscible with thermoplastic polymer P. The coating provides a radiation-sensitive layer for the substrate, and the coating contains homogeneously distributed thermoplastic polymer particles.
摘要翻译：用于制备印版前体的涂布溶液包括：a）包含酚醛树脂的辐射敏感组合物C; b）至少一种热塑性聚合物P，其在含水碱性介质中具有从微溶到难溶的溶解度; c）能够溶解组合物C和热塑性聚合物P的第一溶剂组分A; d）挥发性小于组分A的第二溶剂组分B，其中组分B能够挥发组合物C而不是热塑性聚合物P，组合物 C和热塑性P均匀地溶解在组分A和B的混合物中; 和）与聚合物C的酚醛树脂相比具有更高分子量的至少一种聚合物AP，其中聚合物AB可与酚醛树脂混溶并与热塑性聚合物P不混溶。涂层为基底提供辐射敏感层，该涂层含有均匀分布的热塑性聚合物颗粒。

8. 发明授权

US06517988B1 Radiation-sensitive, positive working coating composition based on carboxylic copolymers 失效
标题翻译：基于羧酸共聚物的辐射敏感的正性涂料组合物
公开(公告)号：US06517988B1
公开(公告)日：2003-02-11
申请号：US09903824
申请日：2001-07-12
申请人： Gerhard Hauck , Mathias Jarek
发明人： Gerhard Hauck , Mathias Jarek
IPC分类号： G03F7021
CPC分类号： G03F7/0233
摘要： A radiation-sensitive composition, positive-working coating compositions useful for the preparation of lithographic printing plates and lithographic printing plate precursors comprising the composition are disclosed. The composition comprises at least one quinonediazide compound and at least one carboxylic copolymer. The compositions produce lithographic printing plates that show high print run stability.
摘要翻译：公开了一种辐射敏感组合物，用于制备平版印刷版的正性涂料组合物和包含该组合物的平版印刷版前体。该组合物包含至少一种醌二叠氮化合物和至少一种羧酸共聚物。该组合物产生显示高印刷运行稳定性的平版印刷版。

9. 发明申请

US20130078575A1 NEGATIVE-WORKING LITHOGRAPHIC PRINTING PLATE PRECURSORS 有权
标题翻译：负离子平版印刷机前驱板
公开(公告)号：US20130078575A1
公开(公告)日：2013-03-28
申请号：US13239435
申请日：2011-09-22
申请人： Domenico Balbinot , Harald Baumann , Udo Dwars , Mathias Jarek , Christopher D. Simpson
发明人： Domenico Balbinot , Harald Baumann , Udo Dwars , Mathias Jarek , Christopher D. Simpson
IPC分类号： G03F7/20 , G03F7/004 , G03F7/032
CPC分类号： G03F7/029 , B41C1/1008 , B41C2210/04 , B41C2210/06 , B41C2210/08 , B41C2210/22 , B41C2210/24 , B41C2210/266 , G03F7/031
摘要： A lithographic printing plate precursor comprises an imageable layer comprising a free radically polymerizable component, an initiator composition capable of generating free radicals upon exposure to imaging infrared radiation, an infrared radiation absorbing dye comprising an infrared radiation absorbing cation and a counter anion, and a polymeric binder. The salt formed between the infrared radiation absorbing cation and a tetraphenyl borate has solubility in 2-methoxy propanol at 20° C. that is greater than or equal to 3.5 g/l. The use of these infrared radiation absorbing dyes in the imageable layers provides a reduced tendency of these dyes to crystallize in the presence of tetraaryl borate counter anions.
摘要翻译：平版印刷版前体包括可成像层，其包含可自由基聚合的组分，在暴露于成像红外辐射时能够产生自由基的引发剂组合物，包含红外辐射吸收阳离子和抗衡阴离子的红外辐射吸收染料，以及聚合物粘合剂在红外辐射吸收阳离子和四苯基硼酸盐之间形成的盐在20℃下在2-甲氧基丙醇中具有大于或等于3.5g / l的溶解度。在可成像层中使用这些红外辐射吸收染料提供这些染料在硼酸四芳基酯阴离子存在下结晶的趋势。

10. 发明申请

US20130078573A1 NEGATIVE-WORKING LITHOGRAPHIC PRINTING PLATE PRECURSORS WITH IR DYES 有权
标题翻译：负责工作的光刻印刷机前体与红外线
公开(公告)号：US20130078573A1
公开(公告)日：2013-03-28
申请号：US13239442
申请日：2011-09-22
申请人： Domenico Balbinot , Harald Baumann , Udo Dwars , Mathias Jarek , James R. Matz , Christopher D. Simpson
发明人： Domenico Balbinot , Harald Baumann , Udo Dwars , Mathias Jarek , James R. Matz , Christopher D. Simpson
IPC分类号： G03F7/20 , G03F7/032
CPC分类号： B41C1/10 , B41C1/1008 , B41C2210/04 , B41C2210/06 , B41C2210/22 , G03F7/004 , G03F7/027 , G03F7/029 , G03F7/031 , G03F7/033 , G03F7/3035
摘要： A lithographic printing plate precursor comprises an imageable layer comprising a free radically polymerizable component, an initiator composition capable of generating free radicals upon exposure to imaging infrared radiation, an infrared radiation absorbing dye that is defined by Structure (I) shown in the disclosure, which dyes comprise one or more ethylenically unsaturated polymerizable groups in an organic group that is attached to the methine chain. These infrared radiation absorbing dyes exhibit a reduced tendency to crystallize in the imageable layers in the presence of tetraaryl borate counter anions and therefore provide improved shelf life.
摘要翻译：平版印刷版前体包含可成像层，其包含可自由基聚合的组分，在暴露于成像红外辐射时能够产生自由基的引发剂组合物，由本公开中所示的结构（I）定义的红外辐射吸收染料，染料在与次甲基链连接的有机基团中包含一个或多个烯键式不饱和可聚合基团。这些红外辐射吸收染料在硼酸四芳基酯阴离子存在下，在可成像层中显示出降低的结晶倾向，因此提供了更好的保质期。

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