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1. 发明申请

US20070100124A1 Titanium-containing solution, catalyst for polyester preparation, process for preparation of polyester resin, and blow molded product comprising polyester 审中-公开
标题翻译：含钛溶液，聚酯制备用催化剂，聚酯树脂的制造方法以及包含聚酯的吹塑成型体
公开(公告)号：US20070100124A1
公开(公告)日：2007-05-03
申请号：US10560923
申请日：2004-06-16
申请人： Ken Maeda , Takashi Nabeta , Tokio Nagayama , Hideshi Hori
发明人： Ken Maeda , Takashi Nabeta , Tokio Nagayama , Hideshi Hori
IPC分类号： C08G63/00
CPC分类号： C08G63/85 , B29C49/0005 , B29K2067/00 , Y02P20/584
摘要： The present invention provides a titanium-containing solution having excellent storage stability and containing the titanium component at a high concentration; a catalyst for polyester preparation exhibiting excellent supply uniformity and high catalyst performance, which does not have adverse effect on the quality of the aliphatic diols to be recovered and recycled; and a catalyst for polyester preparation having high catalyst activity and high molding stability. The invention also provides a process for preparation of a polyester resin using the catalyst, and a blow molded product comprising the polyester resin. A first embodiment of the invention is a titanium-containing solution which contains titanium, an aliphatic diol and a polyhydric alcohol having a valency of 3 or greater. A second embodiment of the invention is a titanium-containing solution which has the titanium particle size in the solution within a specific range.
摘要翻译：本发明提供了具有优异的储存稳定性并且含有高浓度的钛成分的含钛溶液; 用于聚酯制备的催化剂，其表现出优异的供应均匀性和高催化剂性能，对待回收和再循环的脂族二醇的质量没有不利影响; 和具有高催化剂活性和高成型稳定性的聚酯制备用催化剂。本发明还提供了使用该催化剂制备聚酯树脂的方法和包含聚酯树脂的吹塑制品。本发明的第一个实施方案是含有钛，脂肪族二醇和三价以上的多元醇的含钛溶液。本发明的第二个实施方案是一种含钛溶液，其溶液中的钛颗粒尺寸在特定范围内。

2. 发明授权

US07300998B2 Polyester resin and catalyst for polyester production, process for producing polyester resin with the catalyst, polyester resin obtained with the catalyst, and hollow molded container comprising the polyester resins 有权
标题翻译：用于聚酯生产的聚酯树脂和催化剂，用催化剂生产聚酯树脂的方法，用催化剂获得的聚酯树脂和包含聚酯树脂的中空成型容器
公开(公告)号：US07300998B2
公开(公告)日：2007-11-27
申请号：US10504529
申请日：2003-02-13
申请人： Hideshi Hori , Fujito Ehara , Shouji Hiraoka , Ken Maeda , Tomohiro Suzuki , Nobumasa Mukai
发明人： Hideshi Hori , Fujito Ehara , Shouji Hiraoka , Ken Maeda , Tomohiro Suzuki , Nobumasa Mukai
IPC分类号： C08G63/02
CPC分类号： C08G63/82 , C08G63/80 , C08G63/83 , C08G63/84 , C08G63/85 , Y10T428/1352
摘要： The object of the present invention is to provide a high quality polyester resin having high productivity, stability and safety, a catalyst for polyester production with high catalytic activity, a method for producing the polyester resin with the catalyst, a polyester resin obtained with the catalyst, and a hollow molded container having the polyester resin. The polyester resin of the present invention satisfies specific parameters regarding polymerizability, stability, and metal content. The catalyst for polyester production satisfies specific parameters. The catalyst particularly preferably has: (a) a solid titanium-containing compound which has a maximum solubility in ethylene glycol of 1,000 ppm or more in terms of converted titanium amount when dissolved in ethylene glycol with heating at 150° C., and which has titanium, oxygen, carbon, and hydrogen, and optionally an alkali metal, and has a Ti—O—C bond; and (b) an alkali metal compound, the molar ratio of the alkali metal atoms to the titanium atom in the catalyst being in the range of 20/1 to 0.1/1.
摘要翻译：本发明的目的是提供一种具有高生产率，稳定性和安全性的高品质聚酯树脂，具有高催化活性的聚酯生产催化剂，用催化剂生产聚酯树脂的方法，用催化剂得到的聚酯树脂和具有聚酯树脂的中空成型容器。本发明的聚酯树脂满足关于聚合性，稳定性和金属含量的具体参数。聚酯生产催化剂满足具体参数。催化剂特别优选具有：（a）当在150℃下加热溶解在乙二醇中时，以乙二醇的最大溶解度为1000ppm以上的钛的固体含量的化合物，钛，氧，碳和氢，以及任选的碱金属，并具有Ti-OC键; 和（b）碱金属化合物，催化剂中碱金属原子与钛原子的摩尔比在20/1至0.1 / 1的范围内。

3. 发明申请

US20050107576A1 Polyester resin and catalyst for polyester production, process for producing polyester resin with the catalyst, polyester resin obtained with the catalyst, and hollow molded container comprising the polyester resins 有权
标题翻译：用于聚酯生产的聚酯树脂和催化剂，用催化剂生产聚酯树脂的方法，用催化剂获得的聚酯树脂和包含聚酯树脂的中空成型容器
公开(公告)号：US20050107576A1
公开(公告)日：2005-05-19
申请号：US10504529
申请日：2003-02-13
申请人： Hideshi Hori , Fujito Ehara , Shouji Hiraoka , Ken Maeda , Tomohiro Suzuki , Nobumasa Mukai
发明人： Hideshi Hori , Fujito Ehara , Shouji Hiraoka , Ken Maeda , Tomohiro Suzuki , Nobumasa Mukai
IPC分类号： C08G63/80 , C08G63/82 , C08G63/83 , C08G63/84 , C08G63/85 , C08G63/78
CPC分类号： C08G63/82 , C08G63/80 , C08G63/83 , C08G63/84 , C08G63/85 , Y10T428/1352
摘要： The object of the present invention is to provide a high quality polyester resin having high productivity, stability and safety, a catalyst for polyester production with high catalytic activity, a method for producing the polyester resin with the catalyst, a polyester resin obtained with the catalyst, and a hollow molded container comprising the polyester resin. The polyester resin of the present invention satisfies specific parameters regarding polymerizability, stability, and metal content. The catalyst for polyester production satisfies specific parameters. The catalyst particularly preferably comprises: (a) a solid titanium-containing compound which has a maximum solubility in ethylene glycol of 1,000 ppm or more in terms of converted titanium amount when dissolved in ethylene glycol with heating at 150° C., and which comprises titanium, oxygen, carbon, and hydrogen, and optionally alkali metal, and has a Ti—O—C bond; and (b) an alkali metal compound, the molar ratio of the alkali metal atoms to the titanium atom in the catalyst being in the range of 20/1 to 0.1/1.
摘要翻译：本发明的目的是提供一种具有高生产率，稳定性和安全性的高品质聚酯树脂，具有高催化活性的聚酯生产催化剂，用催化剂生产聚酯树脂的方法，用催化剂得到的聚酯树脂和包含聚酯树脂的中空成型容器。本发明的聚酯树脂满足关于聚合性，稳定性和金属含量的具体参数。聚酯生产催化剂满足具体参数。催化剂特别优选包括：（a）当在150℃下加热溶解在乙二醇中时，以乙二醇的最大溶解度为1000ppm以上的固体含钛化合物以转化的钛量计，其包含钛，氧，碳和氢，以及任选的碱金属，并具有Ti-OC键; 和（b）碱金属化合物，催化剂中碱金属原子与钛原子的摩尔比在20/1至0.1 / 1的范围内。

4. 发明授权

US08552138B2 Polyester resin, production process therefor and use thereof 失效
标题翻译：聚酯树脂，其生产工艺及其用途
公开(公告)号：US08552138B2
公开(公告)日：2013-10-08
申请号：US12920804
申请日：2009-03-03
申请人： Shinichi Usugi , Ryohei Ogawa , Hideshi Hori , Akifumi Kagayama
发明人： Shinichi Usugi , Ryohei Ogawa , Hideshi Hori , Akifumi Kagayama
IPC分类号： C08G18/22 , C08G18/10
CPC分类号： C08G63/912 , C08G18/0895 , C08G18/4263 , C08G18/428 , C08G18/73 , C08G18/757 , C08G18/758 , C08G18/7642 , C08G63/6852 , C08G69/44
摘要： Polyester resins (C) of the invention have a practically sufficient high molecular weight and a high crystallinity and have an amide group in the molecular chain. Processes for producing the polyester resins are also disclosed. In detail, the polyester resins (C) have a practically sufficient high molecular weight and a high crystallinity and have a biodegradable amide group in the molecular chain. Processes for producing the polyester resins are also disclosed.The polyester resins (C) are obtained by reacting an aliphatic polyester resin (A) and a polyisocyanate compound (B) in the presence of an amidation catalyst and contain a specific structural unit.
摘要翻译：本发明的聚酯树脂（C）具有实际足够的高分子量和高结晶度，并且在分子链中具有酰胺基。还公开了制备聚酯树脂的方法。详细地说，聚酯树脂（C）具有实际足够的高分子量和高结晶度，并且在分子链中具有可生物降解的酰胺基。还公开了制备聚酯树脂的方法。聚酯树脂（C）通过在酰胺化催化剂存在下使脂肪族聚酯树脂（A）和多异氰酸酯化合物（B）反应而得到，并含有特定的结构单元。

5. 发明申请

US20110040065A1 POLYESTER RESIN, PRODUCTION PROCESS THEREFOR AND USE THEREOF 失效
标题翻译：聚酯树脂，其生产工艺及其使用
公开(公告)号：US20110040065A1
公开(公告)日：2011-02-17
申请号：US12920804
申请日：2009-03-03
申请人： Shinichi Usugi , Ryohei Ogawa , Hideshi Hori
发明人： Shinichi Usugi , Ryohei Ogawa , Hideshi Hori
IPC分类号： C08G18/22 , C08G18/10
CPC分类号： C08G63/912 , C08G18/0895 , C08G18/4263 , C08G18/428 , C08G18/73 , C08G18/757 , C08G18/758 , C08G18/7642 , C08G63/6852 , C08G69/44
摘要： Polyester resins (C) of the invention have a practically sufficient high molecular weight and a high crystallinity and have an amide group in the molecular chain. Processes for producing the polyester resins are also disclosed. In detail, the polyester resins (C) have a practically sufficient high molecular weight and a high crystallinity and have a biodegradable amide group in the molecular chain. Processes for producing the polyester resins are also disclosed.The polyester resins (C) are obtained by reacting an aliphatic polyester resin (A) and a polyisocyanate compound (B) in the presence of an amidation catalyst and contain a specific structural unit.
摘要翻译：本发明的聚酯树脂（C）具有实际足够的高分子量和高结晶度，并且在分子链中具有酰胺基。还公开了制备聚酯树脂的方法。详细地说，聚酯树脂（C）具有实际足够的高分子量和高结晶度，并且在分子链中具有可生物降解的酰胺基。还公开了制备聚酯树脂的方法。聚酯树脂（C）通过在酰胺化催化剂存在下使脂肪族聚酯树脂（A）和多异氰酸酯化合物（B）反应而得到，并含有特定的结构单元。

6. 再颁专利

USRE40571E1 Catalyst for polyester production, process for producing polyester using the catalyst, polyester obtained by the process, and uses of the polyester 有权
标题翻译：用于聚酯生产的催化剂，使用催化剂生产聚酯的方法，通过该方法获得的聚酯和聚酯的用途
公开(公告)号：USRE40571E1
公开(公告)日：2008-11-11
申请号：US10942080
申请日：2004-09-16
申请人： Takeshi Ohmatsuzawa , Fujito Ehara , Hideshi Hori , Kazuo Toyota , Kenzaburou Fukutani , Junichi Imuta , Akiyoshi Shimizu , Takayuki Onogi , Seiji Noda , Masayuki Sakai , Shoji Hiraoka , Koji Nakamachi , Michio Tsugawa , Satoru Miyazoe
发明人： Takeshi Ohmatsuzawa , Fujito Ehara , Hideshi Hori , Kazuo Toyota , Kenzaburou Fukutani , Junichi Imuta , Akiyoshi Shimizu , Takayuki Onogi , Seiji Noda , Masayuki Sakai , Shoji Hiraoka , Koji Nakamachi , Michio Tsugawa , Satoru Miyazoe
IPC分类号： C08G63/82
CPC分类号： C08G63/85 , C08G63/183 , C08G63/82 , C08G63/88
摘要： The present invention provides a catalyst for polyester production capable of producing a polyester with high catalytic activity, a process for producing a polyester using the catalyst and a polyester produced thereby. The catalyst comprises a solid titanium compound obtained by dehydro-drying a hydrolyzate obtained by hydrolysis of a titanium halide and which has a molar ratio (OH/Ti) of a hydroxyl group (OH) to titanium (Ti) exceeding 0.09 and less than 4. In the process, the polyester is obtained by polycondensing an aromatic dicarboxylic acid, or an ester-forming derivative thereof, and an aliphatic diol, or ester-forming derivative thereof, in the presence of the catalyst. The resulting polyester has excellent transparency and tint, a titanium content of 1 to 100 ppm, a magnesium content of 1 to 200 ppm and a magnesium to titanium weight ratio of not less than 0.01.
摘要翻译：本发明提供一种能够生产具有高催化活性的聚酯的聚酯生产催化剂，使用该催化剂生产聚酯的方法和由其制备的聚酯。催化剂包括通过将卤化钛水解得到的水解产物脱水干燥得到的固体钛化合物，其羟基（OH）与钛（Ti）的摩尔比（OH / Ti）超过0.09且小于4 在该方法中，聚酯是通过在催化剂存在下使芳族二羧酸或其成酯衍生物和脂肪族二醇或其成酯衍生物缩聚得到的。所得聚酯具有优异的透明度和色调，钛含量为1〜100ppm，镁含量为1〜200ppm，镁与钛的重量比为0.01以上。

7. 发明授权

US06451959B1 Catalyst for polyester production, process for producing polyester using the catalyst, polyester obtained by the process, and uses of the polyester 有权
标题翻译：用于聚酯生产的催化剂，使用催化剂生产聚酯的方法，通过该方法获得的聚酯和聚酯的用途
公开(公告)号：US06451959B1
公开(公告)日：2002-09-17
申请号：US10024319
申请日：2001-12-21
申请人： Takeshi Ohmatsuzawa , Fujito Ehara , Hideshi Hori , Kazuo Toyota , Kenzaburou Fukutani , Junichi Imuta , Akivoshi Shimizu , Takayuki Onogi , Seiji Noda , Masayuki Sakai , Shoji Hiraoka , Koji Nakamachi , Michio Tsugawa , Satoru Miyazoe
发明人： Takeshi Ohmatsuzawa , Fujito Ehara , Hideshi Hori , Kazuo Toyota , Kenzaburou Fukutani , Junichi Imuta , Akivoshi Shimizu , Takayuki Onogi , Seiji Noda , Masayuki Sakai , Shoji Hiraoka , Koji Nakamachi , Michio Tsugawa , Satoru Miyazoe
IPC分类号： C08G6382
CPC分类号： C08G63/88 , C08G63/183 , C08G63/82 , C08G63/85
摘要： The present invention provides a catalyst for polyester production capable of producing a polyester with high catalytic activity, a process for producing a polyester using the catalyst and a polyester produced thereby. The catalyst comprises a solid titanium compound obtained by dehydro-drying a hydrolyzate obtained by hydrolysis of a titanium halide and which has a molar ratio (OH/Ti) of a hydroxyl group (OH) to titanium (Ti) exceeding 0.09 and less than 4. In the process, the polyester is obtained by polycondensing an aromatic dicarboxylic acid, or an ester-forming derivative thereof, and an aliphatic diol, or ester-forming derivative thereof, in the presence of the catalyst. The resulting polyester has excellent transparency and tint, a titanium content of 1 to 100 ppm, a magnesium content of 1 to 200 ppm and a magnesium to titanium weight ratio of not less than 0.01.
摘要翻译：本发明提供一种能够生产具有高催化活性的聚酯的聚酯生产催化剂，使用该催化剂生产聚酯的方法和由其制备的聚酯。催化剂包括通过将卤化钛水解得到的水解产物脱水干燥得到的固体钛化合物，其羟基（OH）与钛（Ti）的摩尔比（OH / Ti）超过0.09且小于4 在该方法中，聚酯是通过在催化剂存在下使芳族二羧酸或其成酯衍生物和脂肪族二醇或其成酯衍生物缩聚得到的。所得聚酯具有优异的透明度和色调，钛含量为1〜100ppm，镁含量为1〜200ppm，镁与钛的重量比为0.01以上。

8. 发明申请

US20120095169A1 POLYLACTIC ACID-BASED RESIN, PROCESS FOR PRODUCING POLYLACTIC ACID-BASED RESIN, POLYLACTIC ACID RESIN COMPOSITION, STEREOCOMPLEX POLYLACTIC ACID RESIN COMPOSITION AND PROCESS FOR PRODUCING STEREOCOMPLEX POLYLACTIC ACID RESIN COMPOSITION 审中-公开
标题翻译：聚酰胺酸树脂，聚酰胺酸树脂生产方法，聚酯酸树脂组合物，立体聚酰胺酸树脂组合物及其制备方法多异氰酸酯树脂组合物
公开(公告)号：US20120095169A1
公开(公告)日：2012-04-19
申请号：US13380025
申请日：2009-06-30
申请人： Ryohei Ogawa , Shinichi Usugi , Hirokazu Mizuma , Yoshiyuki Totani , Masashi Tsuji , Akira Hasegawa , Hideshi Hori
发明人： Ryohei Ogawa , Shinichi Usugi , Hirokazu Mizuma , Yoshiyuki Totani , Masashi Tsuji , Akira Hasegawa , Hideshi Hori
IPC分类号： C08G18/42 , C08L67/04 , C08G18/73
CPC分类号： C08L67/04 , C08G18/428 , C08G18/73 , C08G18/757 , C08G63/912 , C08L75/06
摘要： The invention provides a polylactic acid-based resin having a high molecular weight, high heat resistance and an amide bond in its molecular chain, a production process and a use thereof. The polylactic acid-based resin comprises a constituting unit represented by the following formula (1) and which is obtained by allowing a polyisocyanate compound to react with a mixture comprising at least a poly (L-lactic acid) in which the percentage of the terminal functional group which is a carboxyl group exceeds 50% and a poly (D-lactic acid) in which the percentage of the terminal functional group which is a carboxyl group exceeds 50%. (in the formula (1), R is a polyisocyanate residue and represents an aliphatic hydrocarbon group having 1 to 20 carbon atoms, a hydrocarbon group having an alicyclic structure and 3 to 20 carbon atoms or a hydrocarbon group having an aromatic ring and 6 to 20 carbon atoms.)
摘要翻译：本发明提供了在其分子链中具有高分子量，高耐热性和酰胺键的聚乳酸类树脂，其制备方法及其用途。聚乳酸类树脂包括由下式（1）表示的构成单元，其通过使多异氰酸酯化合物与至少含有末端的百分比的聚（L-乳酸）的混合物反应而获得，作为羧基的官能团超过50％，作为羧基的末端官能团的比例超过50％的聚（D-乳酸）。（式（1）中，R为多异氰酸酯残基，表示碳原子数1〜20的脂肪族烃基，具有脂环结构，碳原子数3〜20的烃基或具有芳香环的烃基，6〜 20个碳原子）

9. 发明授权

US06649731B2 Catalysts for polyester production, process for producing polyester, and polyester 有权
公开(公告)号：US06649731B2
公开(公告)日：2003-11-18
申请号：US10110920
申请日：2002-04-18
申请人： Hideshi Hori , Fujito Ehara , Akiyoshi Shimizu , Nobumasa Mukai , Shoji Hiraoka
发明人： Hideshi Hori , Fujito Ehara , Akiyoshi Shimizu , Nobumasa Mukai , Shoji Hiraoka
IPC分类号： C08G6378
CPC分类号： C08G63/85 , C08G63/183 , C08G63/82
摘要： By the present invention, there are provided a catalyst for polyester preparation, which comprises a solid titanium compound containing titanium, oxygen, carbon and hydrogen and having a Ti—O bond and which has a maximum solubility in ethylene glycol, as measured when the catalyst is dissolved in ethylene glycol under heating at 150° C., of not less than 3,000 ppm in terms of a titanium atom, a catalyst for polyester preparation, which comprises a titanium-containing solution wherein a contact product of a hydrolyzate of a titanium halide or a hydrolyzate of a titanium alkoxide with a polyhydric alcohol is dissolved in ethylene glycol in an amount of 3,000 to 100,000 ppm in terms of a titanium atom, a process for preparing a polyester using the catalyst, and a polyester prepared by the process. According to the present invention, a polyester can be prepared with a higher catalytic activity as compared with a case of using a conventional catalyst, and a polyester having better transparency, better hue and lower acetaldehyde content can be obtained as compared with a process using an antimony compound as a polycondensation catalyst.

10. 发明授权

US06346070B1 Catalyst for polyester production, process for producing polyester using the catalyst, polyester obtained by the process, and uses of the polyester 有权
标题翻译：用于聚酯生产的催化剂，使用催化剂生产聚酯的方法，通过该方法获得的聚酯和聚酯的用途
公开(公告)号：US06346070B1
公开(公告)日：2002-02-12
申请号：US09470664
申请日：1999-12-22
申请人： Takeshi Ohmatsuzawa , Fujito Ehara , Hideshi Hori , Kazuo Toyota , Kenzaburou Fukutani , Junichi Imuta , Akiyoshi Shimizu , Takayuki Onogi , Seiji Noda , Masayuki Sakai , Shoji Hiraoka , Koji Nakamachi , Michio Tsugawa , Satoru Miyazoe
发明人： Takeshi Ohmatsuzawa , Fujito Ehara , Hideshi Hori , Kazuo Toyota , Kenzaburou Fukutani , Junichi Imuta , Akiyoshi Shimizu , Takayuki Onogi , Seiji Noda , Masayuki Sakai , Shoji Hiraoka , Koji Nakamachi , Michio Tsugawa , Satoru Miyazoe
IPC分类号： C08G6378
CPC分类号： C08G63/85 , C08G63/183 , C08G63/82 , C08G63/88
摘要： The present invention provides a catalyst for polyester production capable of producing a polyester with high catalytic activity and a process for producing a polyester using the catalyst. The catalyst for polyester production comprises a solid titanium compound which is obtained by dehydro-drying a hydrolyzate obtained by hydrolysis of a titanium halide and which has a molar ratio (OH/Ti) of a hydroxyl group (OH) to titanium (Ti) exceeding 0.09 and less than 4. The present invention also provides a method to obtain a polyester having a small increase of the acetaldehyde content during the molding. This method comprises bringing a polyester, which is obtained by the use of a titanium compound catalyst and in which the reaction has been completed, into contact with a phosphoric ester aqueous solution or the like having a concentration of not less than 10 ppm in terms of phosphorus atom. The present invention further provides a polyester having excellent transparency and tint and molded products of the polyester such as a blow molded article, a film, a sheet and a fiber. The polyester is obtained by polycondensing an aromatic dicarboxylic acid or an ester-forming derivative thereof and an aliphatic diol or an ester-forming derivative thereof in the presence of a catalyst for polyester production which comprises a polycondensation catalyst component comprising a solid titanium compound and a co-catalyst component comprising a magnesium compound. This polyester has a titanium content of 1 to 100 ppm, a magnesium content of 1 to 200 ppm and a weight ratio (Mg/Ti) of magnesium to titanium of not less than 0.01.
摘要翻译：本发明提供一种能够生产具有高催化活性的聚酯的聚酯制造催化剂和使用该催化剂生产聚酯的方法。用于聚酯生产的催化剂包括固体钛化合物，其通过脱水干燥由卤化钛水解得到的水解产物并且具有羟基（OH）与钛（Ti）的摩尔比（OH / Ti）超过钛 0.09以上且低于4.本发明还提供一种在成型时获得乙醛含量增加少的聚酯的方法。该方法包括使通过使用钛化合物催化剂获得的反应已完成的聚酯与浓度不小于10ppm的磷酸酯水溶液等接触，换算为磷原子。本发明还提供一种聚酯，其具有优异的透明度和色调，并且聚酯的成型产品如吹塑制品，薄膜，片材和纤维。在聚酯制造用催化剂的存在下，通过将芳香族二羧酸或其成酯性衍生物和脂肪族二醇或其成酯衍生物缩聚得到聚酯，该催化剂包括含有固体钛化合物的缩聚催化剂组分和助催化剂组分包含镁化合物。该聚酯的钛含量为1〜100ppm，镁含量为1〜200ppm，镁与钛的重量比（Mg / Ti）为0.01以上。

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