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1. 发明授权

US08911531B2 Hydrometallurgical plant of nickel laterite ore and operation method thereof 有权
标题翻译：镍红土矿冶炼厂及其操作方法
公开(公告)号：US08911531B2
公开(公告)日：2014-12-16
申请号：US13394202
申请日：2010-10-01
申请人： Osamu Nakai , Toru Kitazaki , Shinichi Heguri , Yoshitomo Ozaki , Keisuke Shibayama
发明人： Osamu Nakai , Toru Kitazaki , Shinichi Heguri , Yoshitomo Ozaki , Keisuke Shibayama
IPC分类号： C22B3/04 , C22B3/00 , C22B3/02
CPC分类号： C22B23/04 , C22B3/02 , C22B23/0407 , Y02P10/234
摘要： A hydrometallurgical plant for nickel laterite ore extraction having a plurality of treatment facility lines wherein the plant is capable of minimizing a decrease in throughput when line failure occurs and efficiently restoring normal operation status Each line of the treatment facility includes a pretreatment step, a leaching step, a solid-liquid separation step, a neutralization step, a zinc removal step, a sulfurization step and a detoxification step. The lines are coupled by pipelines, each having a valve, installed after the solid-liquid separation step for sending a liquid from the solid-liquid separation step to the neutralization step in each line and/or after the sulfurization step for sending a liquid from the sulfurization step to the detoxification step in each line.
摘要翻译：一种用于镍红土矿石提取的湿法冶金设备，其具有多个处理设备线，其中所述设备能够最小化发生线路故障时的吞吐量的降低并且有效地恢复正常操作状态。处理设备的每一行包括预处理步骤，浸出步骤固液分离工序，中和工序，脱锌工序，硫化工序和脱毒工序。这些管线通过管道连接，每个管道具有阀，其在固液分离步骤之后安装，用于将液体从固 - 液分离步骤发送到每一行中的中和步骤和/或在硫化步骤之后将液体从将硫化步骤进行到每一行的排毒步骤。

2. 发明申请

US20100018350A1 Hydrometallurgical process for a nickel oxide ore 有权
标题翻译：氧化镍矿石的湿法冶金工艺
公开(公告)号：US20100018350A1
公开(公告)日：2010-01-28
申请号：US12458677
申请日：2009-07-20
申请人： Keisuke Shibayama , Yoshitomo Ozaki , Osamu Nakai
发明人： Keisuke Shibayama , Yoshitomo Ozaki , Osamu Nakai
IPC分类号： C22B23/00 , C22B1/00 , C22B5/00
CPC分类号： C22B23/043 , C22B23/0461
摘要： The hydrometallurgical process for a nickel oxide ore comprising a step (1) for obtaining an aqueous solution of crude nickel sulfate by High Pressure Acid Leach of a nickel oxide ore; a step (2) for obtaining a zinc free final solution formed; a step (3) for obtaining a waste solution; and a step (4) for scrubbing a hydrogen sulfide gas in exhaust gas, wherein utilization efficiency of hydrogen sulfide gas is enhanced while maintaining nickel recovery rate.It is characterized in that at least one kind of the following operations (a) to (d) is adopted. (a) to adjust total volume (m3) of the sulfurization reactor (B) in the above step (3), at a ratio of 0.2 to 0.9, relative to input mass (kg/h) of nickel to be introduced; (b) to evaporate, under negative pressure, slurry in the above step (3), and to add hydrogen sulfide gas recovered to the above step (3); (c) to reuse exhaust gas from the sulfurization reactor in the above step (3), and add it to the step (2); and (d) to subject the waste solution in the above step (3) and exhaust gas in the above step (4) to countercurrent contact, then to introduce the exhaust gas to the scrubber again and to charge waste solution from the scrubber into the sulfurization reactor in the step (3).
摘要翻译：一种氧化镍矿石的湿法冶金方法，包括通过氧化镍矿的高压酸浸获得粗硫酸镍水溶液的步骤（1）用于获得形成的无锌最终溶液的步骤（2）; 用于获得废液的步骤（3）; 以及用于洗涤废气中的硫化氢气体的步骤（4），其中提高硫化氢气体的利用效率，同时保持镍回收率。其特征在于采用以下操作（a）至（d）中的至少一种。（a）相对于导入的镍的输入质量（kg / h）以0.2〜0.9的比例调节上述工序（3）中的硫化反应器（B）的总体积（m3）（b）在负压下蒸发上述步骤（3）中的浆料，并加入回收到上述步骤（3）中的硫化氢气体; （c）在上述步骤（3）中重新利用来自硫化反应器的废气，并将其添加到步骤（2）中; 和（d）使上述步骤（3）中的废液和上述步骤（4）中的废气逆流接触，然后再次将废气引入洗涤器，并将来自洗涤器的废液送入步骤（3）中的硫化反应器。

3. 发明申请

US20130074653A1 METHOD FOR PRODUCING RAW MATERIAL FOR FERRONICKEL SMELTING FROM LOW GRADE NICKEL OXIDE ORE 有权
标题翻译：低铬镍氧化物铁矿石生产原料的方法
公开(公告)号：US20130074653A1
公开(公告)日：2013-03-28
申请号：US13701951
申请日：2011-07-13
申请人： Hiroshi Kobayashi , Osamu Nakai , Keisuke Shibayama , Takayuki Nakai , Yoshitomo Ozaki , Norihisa Toki , Junichi Takahashi , Toshirou Tan
发明人： Hiroshi Kobayashi , Osamu Nakai , Keisuke Shibayama , Takayuki Nakai , Yoshitomo Ozaki , Norihisa Toki , Junichi Takahashi , Toshirou Tan
IPC分类号： C22B1/02
CPC分类号： C22B1/02 , C22B3/0005 , C22B3/12 , C22B3/44 , C22B23/005 , C22B23/021 , C22B23/023 , C22B23/0461 , Y02P10/234
摘要： Provided is a method for producing ferronickel from a nickel sulfide or a mixed sulfide containing nickel and cobalt, obtained by hydrometallurgy of nickel oxide ore or obtained from scraps or products in process. The method for producing a ferronickel raw material is to form the ferronickel raw material from a nickel sulfide or a mixed sulfide containing nickel sulfide and cobalt sulfide, wherein treatments are performed through the following steps: (1) redissolution step, (2) deferrization step, (3) solvent extraction step, (4) hydroxylation step, (5) roasting step, and (6) washing and calcining step.
摘要翻译：本发明提供从镍硫化物或含有镍和钴的混合硫化物制备镍铁的方法，其通过氧化镍矿石的湿法冶金得到，或从废渣或产品中获得。镍铁原料的制造方法是从硫化镍或硫化镍和硫化钴的混合硫化物形成镍铁原料，其中通过以下步骤进行处理：（1）再溶解步骤，（2）脱铁步骤，（3）溶剂萃取步骤，（4）羟基化步骤，（5）焙烧步骤，和（6）洗涤和煅烧步骤。

4. 发明授权

US08343447B2 Hydrometallurgical process for a nickel oxide ore 有权
标题翻译：氧化镍矿石的湿法冶金工艺
公开(公告)号：US08343447B2
公开(公告)日：2013-01-01
申请号：US12458677
申请日：2009-07-20
申请人： Keisuke Shibayama , Yoshitomo Ozaki , Osamu Nakai
发明人： Keisuke Shibayama , Yoshitomo Ozaki , Osamu Nakai
IPC分类号： B01D19/00 , B01D43/00 , B01D53/52 , C01G9/08 , C01G51/00 , C01G53/11
CPC分类号： C22B23/043 , C22B23/0461
摘要： A hydrometallurgical process for a nickel oxide ore comprising obtaining an aqueous solution of crude nickel sulfate by high pressure acid leaching of a nickel oxide ore; obtaining a zinc free final solution by sulfurization of the solution; obtaining a waste solution; and scrubbing hydrogen sulfide gas from an exhaust gas. The process is characterized by at least one of the following operations: Adjusting the total volume (m3) of a sulfurization reactor to a ratio of 0.2-0.9 (m3/kg/h) relative to the input mass (kg/h) of the nickel to be introduced to the reactor; and/or subjecting the waste solution and the exhaust gas to countercurrent contact, then introducing the exhaust gas back to the scrubber and charging the waste solution from the scrubber into the sulfurization reactor.
摘要翻译：一种用于镍氧化物矿石的湿法冶金方法，包括通过高压酸洗镍氧化物矿石获得粗硫酸镍水溶液; 通过溶液硫化获得无锌的最终溶液; 获得废液; 并从废气中洗涤硫化氢气体。该方法的特征在于以下操作中的至少一个：将硫化反应器的总体积（m3）相对于输入质量（kg / h）的比例调整为0.2-0.9（m3 / kg / h）将镍引入反应器; 和/或使废溶液和废气进行逆流接触，然后将废气引回到洗涤器中，并将废液从洗涤器装入硫化反应器中。

5. 发明授权

US08747787B2 Method for producing raw material for ferronickel smelting from low grade nickel oxide ore 有权
标题翻译：低品位氧化镍矿冶炼镍铁原料生产方法
公开(公告)号：US08747787B2
公开(公告)日：2014-06-10
申请号：US13701951
申请日：2011-07-13
申请人： Hiroshi Kobayashi , Osamu Nakai , Keisuke Shibayama , Takayuki Nakai , Yoshitomo Ozaki , Norihisa Toki , Junichi Takahashi , Toshirou Tan
发明人： Hiroshi Kobayashi , Osamu Nakai , Keisuke Shibayama , Takayuki Nakai , Yoshitomo Ozaki , Norihisa Toki , Junichi Takahashi , Toshirou Tan
IPC分类号： C22B23/00
CPC分类号： C22B1/02 , C22B3/0005 , C22B3/12 , C22B3/44 , C22B23/005 , C22B23/021 , C22B23/023 , C22B23/0461 , Y02P10/234
摘要： Provided is a method for producing ferronickel from a nickel sulfide or a mixed sulfide containing nickel and cobalt, obtained by hydrometallurgy of nickel oxide ore or obtained from scraps or products in process. The method for producing a ferronickel raw material is to form the ferronickel raw material from a nickel sulfide or a mixed sulfide containing nickel sulfide and cobalt sulfide, wherein treatments are performed through the following steps: (1) redissolution step, (2) deferrization step, (3) solvent extraction step, (4) hydroxylation step, (5) roasting step, and (6) washing and calcining step.
摘要翻译：本发明提供从镍硫化物或含有镍和钴的混合硫化物制备镍铁的方法，其通过氧化镍矿石的湿法冶金得到，或从废渣或产品中获得。镍铁原料的制造方法是从硫化镍或硫化镍和硫化钴的混合硫化物形成镍铁原料，其中通过以下步骤进行处理：（1）再溶解步骤，（2）脱铁步骤，（3）溶剂萃取步骤，（4）羟化步骤，（5）焙烧步骤，和（6）洗涤和煅烧步骤。

6. 发明申请

US20100034716A1 Separation method for zinc sulfide 有权
标题翻译：硫化锌分离方法
公开(公告)号：US20100034716A1
公开(公告)日：2010-02-11
申请号：US12458796
申请日：2009-07-23
申请人： Osamu Nakai , Yoshitomo Ozaki , Keisuke Shibayama , Takao Ooishi , Satoshi Matsumoto
发明人： Osamu Nakai , Yoshitomo Ozaki , Keisuke Shibayama , Takao Ooishi , Satoshi Matsumoto
IPC分类号： C01G9/08
CPC分类号： C01G9/08 , C01G53/00 , C01G53/11 , C22B15/0093 , C22B19/26 , C22B23/043 , C22B23/0461 , Y02P10/234 , Y02P10/236
摘要： The separation method for zinc sulfide, in the hydrometallurgical process by a High Pressure Acid Leach for nickel oxide ore comprising leaching and solid/liquid separation step, neutralization step, zinc removal step, and nickel recovery step, which can inhibit clogging of a filter cloth and reduce a frequency of washing operation and replacement operation of a filter cloth by improving filtration performance of zinc sulfide, and inhibit decrease of nickel recovery ratio, in the zinc removal step in which zinc sulfide is formed by adding a sulfurizing agent to the neutralization final liquid containing zinc as well as nickel and cobalt and zinc sulfide is separated to obtain a mother liquid for nickel recovery containing nickel and cobalt.The separation method for zinc sulfide of the present invention is characterized in that in the above-described neutralization step, the leach residue is added to the leach liquor, and pH of the neutralization final liquid is adjusted so as to fall to the range from 3.0 to 3.5, and in the zinc removal step, the suspended solid comprising the neutralized precipitate and the leaching reside are kept remained in said neutralization final liquid so that turbidity thereof falls in the range from 100 to 400 NTU.
摘要翻译：硫化锌的分离方法，在通过高压酸浸法进行的氧化镍矿石的湿法冶金工艺中，包括浸出和固/液分离步骤，中和步骤，锌除去步骤和镍回收步骤，其可以抑制滤布堵塞通过提高硫化锌的过滤性能来降低洗涤操作和更换操作的频率，并且通过在中和最终添加硫化剂的锌硫化物的除锌步骤中抑制镍回收率的降低分离含有锌以及镍和钴和硫化锌的液体，以获得含镍和钴的镍回收母液。本发明的硫化锌的分离方法的特征在于，在上述中和工序中，将浸出残渣加入到浸出液中，调节中和最终液体的pH，使其降至3.0 至3.5，并且在锌去除步骤中，将包含中和的沉淀物和浸出的悬浮固体保持在所述中和最终液体中，使得其浊度在100至400NTU的范围内。

7. 发明申请

US20100028227A1 Hydrometallurgical process for nickel oxide ore 审中-公开
标题翻译：氧化镍矿石的冶金工艺
公开(公告)号：US20100028227A1
公开(公告)日：2010-02-04
申请号：US12458718
申请日：2009-07-21
申请人： Keisuke Shibayama , Osamu Nakai , Yoshitomo Ozaki
发明人： Keisuke Shibayama , Osamu Nakai , Yoshitomo Ozaki
IPC分类号： C01G53/00
CPC分类号： C22B23/043 , C01G53/11 , C22B15/0093 , C22B23/0407 , C22B23/0453 , C22B23/0461 , Y02P10/236
摘要： The hydrometallurgical Process for a nickel oxide ore, which is capable of preventing inevitable operation shutdown of a leaching step and maintaining high operation efficiency as a whole process, in a trouble of the steps other than the leaching step, in a hydrometallurgical Process for a nickel oxide ore using a High Pressure Acid Leach.It is characterized in that, the hydrometallurgical Process for a nickel oxide ore using a High Pressure Acid Leach equipment equipped with the following means (a) to (c), in a trouble of the steps other than the above leaching step, the leached slurry discharged from the means (c), which is used in the above High Pressure Acid Leach equipment, is subjected to self-circulation inside the High Pressure Acid Leach equipment, by transferring to the means (a), which is used in the above High Pressure Acid Leach equipment, as well as by shutdown of receiving the ore slurry and the addition of sulfuric acid, in the above leaching step: means (a) to preliminarily increase temperature and pressure of the ore slurry; means (b) to form the leached slurry, by the addition of sulfuric acid to the ore slurry with preliminarily increased temperature and pressure, and leaching under blow of high-pressure steam and high-pressure air; means (c) to eliminate a pressurized state of the leached slurry formed.
摘要翻译：用于镍氧化物矿石的湿法冶金方法，其能够防止浸出步骤的不可避免的操作停止并且在整个过程中保持高的操作效率，除了浸出步骤之外的步骤中，在湿法冶金方法中用于镍氧化矿石使用高压酸浸。其特征在于，使用装备有以下方法（a）至（c））的高压酸浸设备的氧化镍矿石的湿法冶金方法，在上述浸出步骤之外的步骤中，浸出的浆料从上述高压酸浸设备中使用的装置（c）排出的高压酸浸设备在高压酸浸设备中进行自我循环，转移到上述高温酸浸设备中使用的（a）在上述浸出步骤中，压力酸浸设备，以及关闭接收矿浆和加入硫酸，是指（a）预先提高矿浆的温度和压力; 表示（b）通过在预先升高的温度和压力下向矿浆中加入硫酸，并在高压蒸气和高压空气吹扫下浸出，形成浸出的浆料; 意味着（c）消除形成的浸出浆料的加压状态。

8. 发明申请

US20120161374A1 HYDROMETALLURGICAL PLANT OF NICKEL LATERITE ORE AND OPERATION METHOD THEREOF 有权
标题翻译：镍矿石水泥矿石工程及其操作方法
公开(公告)号：US20120161374A1
公开(公告)日：2012-06-28
申请号：US13394202
申请日：2010-10-01
申请人： Osamu Nakai , Toru Kitazaki , Shinichi Heguri , Yoshitomo Ozaki , Keisuke Shibayama
发明人： Osamu Nakai , Toru Kitazaki , Shinichi Heguri , Yoshitomo Ozaki , Keisuke Shibayama
IPC分类号： C22B3/04 , C22B3/02
CPC分类号： C22B23/04 , C22B3/02 , C22B23/0407 , Y02P10/234
摘要： In a hydrometallurgical plant of a nickel laterite ore having a plurality of lines of treatment facilities, the hydrometallurgical plant of the nickel laterite ore which is, even when a serious trouble will occur in said treatment facilities, capable of minimizing decrease in throughput caused by this, and restoring a normal operation state early, after eliminating the serious trouble, and an operation method thereof.A hydrometallurgical plant of a nickel laterite ore having a plurality of lines, as treatment facilities including a pretreatment step, a leaching step, a solid-liquid separation step, a neutralization step, a zinc removal step, a sulfurization step and a detoxification step as one line, wherein a coupling pipeline having a valve is installed between a liquid sending pipeline from the solid-liquid separation step to the neutralization step in each line and/or between a liquid sending pipeline from the sulfurization step to the detoxification step in each line.
摘要翻译：在具有多条处理设备的镍红土矿的湿法冶金装置中，镍红土矿石的湿法冶金设备，即使在所述处理设施中将发生严重故障，其能够最小化由此造成的吞吐量降低并且在消除严重故障之后提前恢复正常操作状态及其操作方法。一种具有多条线的镍红土矿的湿法冶金装置，作为包括预处理步骤，浸出步骤，固液分离步骤，中和步骤，除锌步骤，硫化步骤和解毒步骤的处理设备，作为一条线，其中具有阀的联接管道安装在从固液分离步骤到每行中的中和步骤的送液管道之间和/或在每一行中的从硫化步骤到排毒步骤的送液管道之间。

9. 发明授权

US07964165B2 Separation method for zinc sulfide 有权
标题翻译：硫化锌分离方法
公开(公告)号：US07964165B2
公开(公告)日：2011-06-21
申请号：US12458796
申请日：2009-07-23
申请人： Osamu Nakai , Yoshitomo Ozaki , Keisuke Shibayama , Takao Ooishi , Satoshi Matsumoto
发明人： Osamu Nakai , Yoshitomo Ozaki , Keisuke Shibayama , Takao Ooishi , Satoshi Matsumoto
IPC分类号： C22B23/00
CPC分类号： C01G9/08 , C01G53/00 , C01G53/11 , C22B15/0093 , C22B19/26 , C22B23/043 , C22B23/0461 , Y02P10/234 , Y02P10/236
摘要： The separation method for zinc sulfide, in the hydrometallurgical process by a High Pressure Acid Leach for nickel oxide ore comprising leaching and solid/liquid separation step, neutralization step, zinc removal step, and nickel recovery step, which can inhibit clogging of a filter cloth and reduce a frequency of washing operation and replacement operation of a filter cloth by improving filtration performance of zinc sulfide, and inhibit decrease of nickel recovery ratio, in the zinc removal step in which zinc sulfide is formed by adding a sulfurizing agent to the neutralization final liquid containing zinc as well as nickel and cobalt and zinc sulfide is separated to obtain a mother liquid for nickel recovery containing nickel and cobalt.The separation method for zinc sulfide of the present invention is characterized in that in the above-described neutralization step, the leach residue is added to the leach liquor, and pH of the neutralization final liquid is adjusted so as to fall to the range from 3.0 to 3.5, and in the zinc removal step, the suspended solid comprising the neutralized precipitate and the leaching reside are kept remained in said neutralization final liquid so that turbidity thereof falls in the range from 100 to 400 NTU.
摘要翻译：硫化锌的分离方法，在通过高压酸浸法进行的氧化镍矿石的湿法冶金工艺中，包括浸出和固/液分离步骤，中和步骤，锌除去步骤和镍回收步骤，其可以抑制滤布堵塞通过提高硫化锌的过滤性能来降低洗涤操作和更换操作的频率，并且通过在中和最终添加硫化剂的锌硫化物的除锌步骤中抑制镍回收率的降低分离含有锌以及镍和钴和硫化锌的液体，以获得含镍和钴的镍回收母液。本发明的硫化锌的分离方法的特征在于，在上述中和工序中，将浸出残渣加入到浸出液中，调节中和最终液体的pH，使其降至3.0 至3.5，并且在锌去除步骤中，将包含中和的沉淀物和浸出的悬浮固体保持在所述中和最终液体中，使得其浊度在100至400NTU的范围内。

10. 发明授权

US5888462A Method of solvent extraction of nickel sulfate solutions 失效
标题翻译：溶剂萃取硫酸镍溶液的方法
公开(公告)号：US5888462A
公开(公告)日：1999-03-30
申请号：US67019
申请日：1998-04-28
申请人： Susumu Makino , Naoyuki Tsuchida , Masaki Imamura , Kazuyuki Takaishi , Yoshitomo Ozaki
发明人： Susumu Makino , Naoyuki Tsuchida , Masaki Imamura , Kazuyuki Takaishi , Yoshitomo Ozaki
IPC分类号： C01G53/10 , C22B3/20 , C22B3/26 , C22B23/00 , B01D11/00 , C01B17/00
CPC分类号： C22B23/0453 , C22B3/0005 , Y02P10/234
摘要： A method of solvent extraction of a nickel sulfate solution uses a multi-stage, counter-current, organic solvent extraction system composed of at least two extractors connected in series, and includes a first extraction step of feeding a crude nickel sulfate solution that contains sodium and ammonium impurities into a second-stage extractor, wherein it is treated in countercurrent flow and at a pH of 6.5 to 7.0 with an organic extractant fed into the second-stage extractor from the first-stage extractor, to thereby extract some of nickel in the crude nickel sulfate solution into the organic extractant; and a second extraction step of transferring the nickel-containing, organic phase to an organic phase-scrubbing step to remove sodium and ammonium, while transferring the nickel sulfate solution, from the first extraction step and from which some of nickel has been removed, to the first-stage extractor, wherein it is treated in countercurrent flow and at a pH of 5.5 to 6.5 with a fresh organic extractant, to thereby extend the remaining nickel in the nickel sulfate solution into the organic extractant. The nickel-containing organic phase from the second extraction step is divided into two portions, one portion being fed into the second-stage extractor while the other portion is transferred to a by-pass, organic phase-scrubbing step it to remove sodium and ammonium.
摘要翻译：硫酸镍溶液的溶剂萃取方法使用由串联连接的至少两个萃取器组成的多级，逆流有机溶剂萃取系统，包括第一提取步骤，将含有钠的粗硫酸镍溶液和铵杂质进入第二级提取器，其中以逆流流动并且在6.5至7.0的pH下用从第一级萃取器进料到第二级萃取器中的有机萃取剂进行处理，从而提取一些镍将粗硫酸镍溶液加入有机萃取剂中; 以及第二提取步骤，将含镍的有机相转移到有机相洗涤步骤以除去钠和铵，同时从第一提取步骤将镍硫酸盐溶液从其中除去一些镍转移到第一级萃取器，其中以逆流流动并且在5.5至6.5的pH下用新鲜的有机萃取剂处理，从而将硫酸镍溶液中的剩余的镍延伸到有机萃取剂中。将来自第二提取步骤的含镍有机相分为两部分，一部分进料到第二阶段萃取器中，而另一部分转移到旁路有机相洗涤步骤中以除去钠和铵。

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