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1. 发明申请

US20120015238A1 NON-AQUEOUS ELECTROLYTE SECONDARY CELL 有权
标题翻译：非水溶性电解质二次电池
公开(公告)号：US20120015238A1
公开(公告)日：2012-01-19
申请号：US13182088
申请日：2011-07-13
申请人： Keisuke Minami , Toyoki Fujihara , Yasuhiro Yamauchi , Toshiyuki Nohma
发明人： Keisuke Minami , Toyoki Fujihara , Yasuhiro Yamauchi , Toshiyuki Nohma
IPC分类号： H01M2/02
CPC分类号： H01M10/0525 , H01M2/166 , H01M2/1673 , H01M10/0566 , H01M10/0587
摘要： There is provided a non-aqueous electrolyte secondary cell that exhibits excellent cycle characteristics over a wide temperature range from low to high temperature. This object can be realized by adopting the following configuration.The non-aqueous electrolyte secondary cell comprises a positive electrode having a positive electrode active material composed of a lithium transition metal composite oxide, a negative electrode having a negative electrode active material composed of carbon material, a non-aqueous electrolyte solution, and an outer body in which the positive electrode, the negative electrode and the non-aqueous electrolyte solution are housed; the mass of the non-aqueous electrolyte solution per cell capacity of the non-aqueous electrolyte secondary cell is 10.0 to 12.0 g/Ah; and the volume of the non-aqueous electrolyte solution per void volume in the outer body is 70 to 85%.
摘要翻译：提供了在从低温到高温的宽温度范围内表现出优异的循环特性的非水电解质二次电池。该对象可以通过采用以下配置来实现。非水电解质二次电池包括具有由锂过渡金属复合氧化物构成的正极活性物质的正极，具有由碳材料构成的负极活性物质的负极，非水电解液，外部容纳正极，负极和非水电解质溶液的主体; 非水电解质二次电池的电池容量的非水电解液的质量为10.0〜12.0g / Ah; 并且外体中的每个空隙体积的非水电解液的体积为70〜85％。

2. 发明授权

US07871728B2 Nonaqueous electrolyte secondary battery 有权
标题翻译：非水电解质二次电池
公开(公告)号：US07871728B2
公开(公告)日：2011-01-18
申请号：US12275351
申请日：2008-11-21
申请人： Keisuke Minami , Toyoki Fujihara , Yasuhiro Yamauchi , Toshiyuki Nohma
发明人： Keisuke Minami , Toyoki Fujihara , Yasuhiro Yamauchi , Toshiyuki Nohma
IPC分类号： H01M4/62
CPC分类号： H01M4/625 , H01M2/263 , H01M4/131 , H01M4/1391 , H01M4/485 , H01M4/505 , H01M4/525 , H01M4/661 , H01M10/0587 , H01M2004/021
摘要： A nonaqueous electrolyte secondary battery of the present invention includes a positive electrode plate 21 having an uncoated part along at least one long side of a continuous positive electrode substrate 211 coated with a positive electrode mixture layer 212 containing a positive electrode active material. In the nonaqueous electrolyte secondary battery, the positive electrode mixture layer 212 includes a lithium transition-metal compound capable of insertion and separation of lithium ion and 5 to 15% by mass of a conductive material with respect to the positive electrode mixture, the conductive material contains 70% by mass or more of flaked graphite particles with an average particle diameter (D50) of 5 to 30 μm and an average thickness of 0.1 to 1.0 μm with respect to the whole amount of the conductive materials, and a packing density of the positive electrode mixture layer is 2.00 to 2.80 g/cc.
摘要翻译：本发明的非水电解质二次电池包括正极板21，其具有涂覆有包含正极活性物质的正极合剂层212的连续正极基板211的至少一个长边的未涂覆部分。在非水电解质二次电池中，正极合剂层212包括相对于正极合剂而能够插入和分离锂离子的锂过渡金属化合物和5〜15质量％的导电性材料，导电性材料相对于导电材料的总量，平均粒径（D50）为5〜30μm，平均厚度为0.1〜1.0μm的片状石墨粒子含有70质量％以上，正极合剂层为2.00〜2.80g / cc。

3. 发明授权

US08293396B2 Non-aqueous electrolyte secondary cell 有权
标题翻译：非水电解质二次电池
公开(公告)号：US08293396B2
公开(公告)日：2012-10-23
申请号：US13182088
申请日：2011-07-13
申请人： Keisuke Minami , Toyoki Fujihara , Yasuhiro Yamauchi , Toshiyuki Nohma
发明人： Keisuke Minami , Toyoki Fujihara , Yasuhiro Yamauchi , Toshiyuki Nohma
IPC分类号： H01M6/32
CPC分类号： H01M10/0525 , H01M2/166 , H01M2/1673 , H01M10/0566 , H01M10/0587
摘要： The non-aqueous electrolyte secondary cell comprises a positive electrode having a positive electrode active material composed of a lithium transition metal composite oxide, a negative electrode having a negative electrode active material composed of carbon material, a non-aqueous electrolyte solution, and an outer body in which the positive electrode, the negative electrode and the non-aqueous electrolyte solution are housed; the mass of the non-aqueous electrolyte solution per cell capacity of the non-aqueous electrolyte secondary cell is 10.0 to 12.0 g/Ah; and the volume of the non-aqueous electrolyte solution per void volume in the outer body is 70 to 85%.
摘要翻译：非水电解质二次电池包括具有由锂过渡金属复合氧化物构成的正极活性物质的正极，具有由碳材料构成的负极活性物质的负极，非水电解液，外部容纳正极，负极和非水电解质溶液的主体; 非水电解质二次电池的电池容量的非水电解液的质量为10.0〜12.0g / Ah; 并且外体中的每个空隙体积的非水电解液的体积为70〜85％。

4. 发明申请

US20090142651A1 NONAQUEOUS ELECTROLYTE SECONDARY BATTERY 有权
标题翻译：非电解电解质二次电池
公开(公告)号：US20090142651A1
公开(公告)日：2009-06-04
申请号：US12275351
申请日：2008-11-21
申请人： Keisuke Minami , Toyoki Fujihara , Yasuhiro Yamauchi , Toshiyuki Nohma
发明人： Keisuke Minami , Toyoki Fujihara , Yasuhiro Yamauchi , Toshiyuki Nohma
IPC分类号： H01M10/24
CPC分类号： H01M4/625 , H01M2/263 , H01M4/131 , H01M4/1391 , H01M4/485 , H01M4/505 , H01M4/525 , H01M4/661 , H01M10/0587 , H01M2004/021
摘要： A nonaqueous electrolyte secondary battery of the present invention includes a positive electrode plate 21 having an uncoated part along at least one long side of a continuous positive electrode substrate 211 coated with a positive electrode mixture layer 212 containing a positive electrode active material. In the nonaqueous electrolyte secondary battery, the positive electrode mixture layer 212 includes a lithium transition-metal compound capable of insertion and separation of lithium ion and 5 to 15% by mass of a conductive material with respect to the positive electrode mixture, the conductive material contains 70% by mass or more of flaked graphite particles with an average particle diameter (D50) of 5 to 30 μm and an average thickness of 0.1 to 1.0 μm with respect to the whole amount of the conductive materials, and a packing density of the positive electrode mixture layer is 2.00 to 2.80 g/cc.
摘要翻译：本发明的非水电解质二次电池包括正极板21，其具有涂覆有包含正极活性物质的正极合剂层212的连续正极基板211的至少一个长边的未涂覆部分。在非水电解质二次电池中，正极合剂层212包括相对于正极合剂而能够插入和分离锂离子的锂过渡金属化合物和5〜15质量％的导电性材料，导电性材料相对于导电性材料的总量，含有平均粒径（D50）为5〜30μm，平均厚度为0.1〜1.0μm的片状石墨粒子的70质量％以上，正极合剂层为2.00〜2.80g / cc。

5. 发明申请

US20140023898A1 NON-AQUEOUS ELECTROLYTE SECONDARY CELL 审中-公开
标题翻译：非水溶性电解质二次电池
公开(公告)号：US20140023898A1
公开(公告)日：2014-01-23
申请号：US13550974
申请日：2012-07-17
申请人： Keisuke Minami , Toyoki Fujihara , Toshiyuki Nohma
发明人： Keisuke Minami , Toyoki Fujihara , Toshiyuki Nohma
IPC分类号： H01M10/36
CPC分类号： H01M10/0587 , H01M2/1673 , H01M4/0435 , H01M4/133 , H01M4/139 , H01M4/366 , H01M4/661 , H01M2010/4292
摘要： The present invention aims to productively provide a non-aqueous electrolyte secondary cell having excellent safety and high capacity. The above object can be achieved by adopting the following configuration. The non-aqueous electrolyte secondary cell comprises a wound electrode assembly formed by winding a positive electrode having a positive electrode active material layer, a negative electrode having a negative electrode active material layer and a separator separating the positive and negative electrodes, wherein: the filling density of the positive electrode active material layer is 2.0-2.8 g/cc; the filling density of the negative electrode active material layer is 1.0-1.5 g/cc; each thickness of the positive electrode and the negative electrode is 100-200 μm; the thickness of the separator is 10-30% of each thickness of the positive and negative electrodes; and the air permeability per unit thickness of the separator is 7.0-27.0 sec/100 cc•μm.
摘要翻译：本发明的目的在于提供一种具有优异的安全性和高容量的非水电解质二次电池。上述目的可以通过采用以下配置来实现。非水电解质二次电池包括卷绕电极组件，其通过卷绕具有正极活性物质层的正极，具有负极活性物质层的负极和分离正极和负极的隔膜而形成，其中：填充正极活性物质层的密度为2.0〜2.8g / cc; 负极活性物质层的填充密度为1.0〜1.5g / cc，正极和负极的每个厚度为100-200μm; 隔板的厚度为正极和负极的每个厚度的10-30％; 隔膜每单位厚度的透气度为7.0-27.0秒/ 100cc.mum。

6. 发明申请

US20070212607A1 Nonaqueous electrolyte secondary battery 有权
标题翻译：非水电解质二次电池
公开(公告)号：US20070212607A1
公开(公告)日：2007-09-13
申请号：US11714132
申请日：2007-03-06
申请人： Toyoki Fujihara , Atsushi Yanai , Naoya Nakanishi , Toshiyuki Nohma , Keisuke Minami
发明人： Toyoki Fujihara , Atsushi Yanai , Naoya Nakanishi , Toshiyuki Nohma , Keisuke Minami
IPC分类号： H01M4/48 , H01M4/50 , H01M4/52
CPC分类号： H01M4/131 , H01M4/133 , H01M4/1391 , H01M4/505 , H01M4/525 , H01M10/0525 , H01M10/0587 , H01M2004/028
摘要： A nonaqueous electrolyte secondary battery 10 according to an embodiment of the present invention includes a positive electrode 11 having a positive electrode active material that can intercalate and deintercalate lithium, a negative electrode 12 having a negative electrode active material that can intercalate and deintercalate lithium, and a nonaqueous electrolyte having lithium ion conductivity. The positive electrode active material is a layered lithium transition metal composite oxide (for example, one represented by Li1+x(NiyCozMn1-y-z)1-xO2 (where 0≦x≦0.15, 0.1≦y≦0.6, and 0≦z≦0.5)) to which an IVa group element (Zr) and a Va group element (Nb) are added. According to these features, it is possible to provide a nonaqueous electrolyte secondary battery with a selected element to be added to the lithium transition metal composite oxide to reduce the I-V resistance (improve the I-V characteristic), and thereby improving the output/input characteristics.
摘要翻译：根据本发明实施方式的非水电解质二次电池10包括具有能够插入和脱嵌锂的正极活性物质的正极11，具有可插入和脱嵌锂的负极活性物质的负极12，以及具有锂离子传导性的非水电解质。正极活性物质是层状锂过渡金属复合氧化物（例如，由Li 1+ x Ni（Ni y）y Co z 1≤x≤0.2（其中0≤x≤0.15,0.1≤y≤0.6）和 0 <= z <= 0.5）），添加IVa族元素（Zr）和Va族元素（Nb）。根据这些特征，可以提供具有添加到锂过渡金属复合氧化物中的选定元素的非水电解质二次电池，以降低I-V电阻（提高I-V特性），从而提高输出/输入特性。

7. 发明申请

US20140023919A1 NON-AQUEOUS ELECTROLYTE SECONDARY CELL 审中-公开
标题翻译：非水溶性电解质二次电池
公开(公告)号：US20140023919A1
公开(公告)日：2014-01-23
申请号：US13550744
申请日：2012-07-17
申请人： Keisuke Minami , Toyoki Fujihara , Toshiyuki Nohma
发明人： Keisuke Minami , Toyoki Fujihara , Toshiyuki Nohma
IPC分类号： H01M4/02
CPC分类号： H01M10/4235 , H01M2/263 , H01M2/36 , H01M4/131 , H01M4/1391 , H01M4/505 , H01M4/525 , H01M4/5825 , H01M4/667 , H01M4/70 , H01M10/052 , H01M10/0587 , H01M2004/021 , Y02T10/7011
摘要： The present invention aims to provide the following non-aqueous electrolyte secondary cell having excellent safety. A non-aqueous electrolyte secondary cell comprises an electrode assembly having positive and negative electrodes. The positive electrode has a core exposed portion (formed by exposing at least one side edge of a belt-shaped core along the longitudinal direction of the core), a active material layer formed on the core, and a protective layer (formed on the core exposed portion near the active material layer and having a lower conductivity than the core). The negative electrode has first and second negative electrode core exposed portions, in which both side edges of a belt-shaped negative electrode core are exposed along the longitudinal direction of the core, and a negative electrode active material layer formed on the negative electrode core. And the whole of the second negative electrode core exposed portion is opposite to the protective layer.
摘要翻译：本发明的目的在于提供以下具有优异安全性的非水电解质二次电池。非水电解质二次电池包括具有正极和负极的电极组件。正极具有芯部露出部（通过沿着芯的长度方向露出带状芯的至少一个侧边缘而形成），形成在芯上的活性物质层和形成在芯上的保护层暴露部分靠近活性材料层并且具有比芯更低的导电性）。负极具有第一和第二负极芯露出部分，其中带状负极芯的两个侧边缘沿着芯的纵向方向露出，并且负极活性材料层形成在负极芯上。并且整个第二负电极芯暴露部分与保护层相反。

8. 发明申请

US20140023915A1 NON-AQUEOUS ELECTROLYTE SECONDARY CELL 审中-公开
标题翻译：非水溶性电解质二次电池
公开(公告)号：US20140023915A1
公开(公告)日：2014-01-23
申请号：US13550750
申请日：2012-07-17
申请人： Tetsuya Matsuda , Keisuke Minami , Toyoki Fujihara , Toshiyuki Nohma
发明人： Tetsuya Matsuda , Keisuke Minami , Toyoki Fujihara , Toshiyuki Nohma
IPC分类号： H01M10/056
CPC分类号： H01M4/366 , H01M2/16 , H01M10/052 , H01M10/0567 , H01M10/0568 , H01M2300/0025 , Y02T10/7011
摘要： The present invention aims to productively provide a non-aqueous electrolyte secondary cell having high capacity. This object can be achieved by adopting the following configuration. A non-aqueous electrolyte secondary cell comprises a non-aqueous electrolyte and an electrode assembly having a positive electrode, a negative electrode and a separator; the positive electrode has a positive electrode core and a positive electrode active material layer; the negative electrode has a negative electrode core and a negative electrode active material layer; a protective layer is provided on the positive electrode active material layer and/or the negative electrode active material layer; the total thickness of the protective layers is 10 to 40% of that of the separator; a porosity of the protective layer is larger than that of any of the positive and negative electrode active material layer; and the non-aqueous electrolyte contains a non-aqueous solvent and two or more kinds of lithium compounds.
摘要翻译：本发明的目的在于提供一种具有高容量的非水电解质二次电池。该对象可以通过采用以下配置来实现。非水电解质二次电池包括非水电解质和具有正极，负极和隔板的电极组件; 正极具有正极芯和正极活性物质层; 负极具有负极芯和负极活性物质层; 在正极活性物质层和/或负极活性物质层上设置保护层，保护层的总厚度为隔膜的10〜40％。保护层的孔隙率大于正极活性物质层和负极活性物质层中的任一个的孔隙率。非水电解质含有非水溶剂和两种以上的锂化合物。

9. 发明授权

US09231245B2 Positive electrode plate for nonaqueous electrolyte secondary battery, method for manufacturing the positive electrode plate, nonaqueous electrolyte secondary battery, and method for manufacturing the battery 有权
标题翻译：非水电解质二次电池用正极板，正极板的制造方法，非水电解质二次电池及其制造方法
公开(公告)号：US09231245B2
公开(公告)日：2016-01-05
申请号：US14006828
申请日：2012-03-15
申请人： Tetsuya Matsuda , Naoki Ogawa , Keisuke Minami , Toyoki Fujihara , Toshiyuki Nohma
发明人： Tetsuya Matsuda , Naoki Ogawa , Keisuke Minami , Toyoki Fujihara , Toshiyuki Nohma
IPC分类号： H01M4/62 , H01M4/139 , H01M4/36 , H01M4/02
CPC分类号： H01M4/139 , H01M4/366 , H01M4/623 , H01M2004/028 , H01M2220/20 , Y02E60/122 , Y02P70/54
摘要： A positive electrode plate for a nonaqueous electrolyte secondary battery, the positive electrode plate including: a positive electrode substrate; a positive electrode active material layer formed on the positive electrode substrate; and a positive electrode substrate exposed portion on which the positive electrode active material layer is not formed, the positive electrode substrate exposed portion having a region that is adjacent to the positive electrode active material layer and has a protective layer formed thereon, the positive electrode active material layer and the protective layer containing polyvinylidene fluoride, and the weight average molecular weight Mw of the polyvinylidene fluoride contained in the protective layer being larger than the weight average molecular weight Mw of the polyvinylidene fluoride contained in the positive electrode active material layer. Thus, a high reliable nonaqueous electrolyte secondary battery where the widths of the positive electrode material and the protective layers are stable can be provided.
摘要翻译：一种非水电解质二次电池用正极板，所述正极板包括：正极基板; 形成在正极基板上的正极活性物质层; 和没有形成正极活性物质层的正极基板暴露部分，正电极基板露出部分具有与正极活性物质层相邻的区域，其上形成有保护层，正极活性物质材料层和含有聚偏二氟乙烯的保护层，并且保护层中所含的聚偏二氟乙烯的重均分子量Mw大于正极活性物质层中所含的聚偏二氟乙烯的重均分子量Mw。因此，可以提供正极材料和保护层的宽度稳定的高可靠性非水电解质二次电池。

10. 发明授权

US07544443B2 Nonaqueous electrolyte secondary battery 有权
标题翻译：非水电解质二次电池
公开(公告)号：US07544443B2
公开(公告)日：2009-06-09
申请号：US11714132
申请日：2007-03-06
申请人： Toyoki Fujihara , Atsushi Yanai , Naoya Nakanishi , Toshiyuki Nohma , Keisuke Minami
发明人： Toyoki Fujihara , Atsushi Yanai , Naoya Nakanishi , Toshiyuki Nohma , Keisuke Minami
IPC分类号： H01M4/58
CPC分类号： H01M4/131 , H01M4/133 , H01M4/1391 , H01M4/505 , H01M4/525 , H01M10/0525 , H01M10/0587 , H01M2004/028
摘要： A nonaqueous electrolyte secondary battery 10 according to an embodiment of the present invention includes a positive electrode 11 having a positive electrode active material that can intercalate and deintercalate lithium, a negative electrode 12 having a negative electrode active material that can intercalate and deintercalate lithium, and a nonaqueous electrolyte having lithium ion conductivity. The positive electrode active material is a layered lithium transition metal composite oxide (for example, one represented by Li1+x(NiyCozMn1−y−z)1−xO2 (where 0≦x≦0.15, 0.1≦y≦0.6, and 0≦z≦0.5)) to which an IVa group element (Zr) and a Va group element (Nb) are added. According to these features, it is possible to provide a nonaqueous electrolyte secondary battery with a selected element to be added to the lithium transition metal composite oxide to reduce the I-V resistance (improve the I-V characteristic), and thereby improving the output/input characteristics.
摘要翻译：根据本发明实施方式的非水电解质二次电池10包括具有能够插入和脱嵌锂的正极活性物质的正极11，具有可插入和脱嵌锂的负极活性物质的负极12，以及具有锂离子传导性的非水电解质。正极活性物质是层状锂过渡金属复合氧化物（例如，由Li1 + x（NiyCozMn1-yz）1-xO2（其中0 <= x <= 0.15,0.1 <= y <= 0.6）和 0 <= z <= 0.5）），添加IVa族元素（Zr）和Va族元素（Nb）。根据这些特征，可以提供具有添加到锂过渡金属复合氧化物中的选定元素的非水电解质二次电池，以降低I-V电阻（提高I-V特性），从而提高输出/输入特性。

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