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    • 2. 发明授权
    • Process for preparing ethylene-vinyl alcohol copolymer composition, and process for producing ethylene-vinyl alcohol copolymer pellets
    • 制备乙烯 - 乙烯醇共聚物组合物的方法,以及生产乙烯 - 乙烯醇共聚物颗粒的方法
    • US08765037B2
    • 2014-07-01
    • US12810463
    • 2008-12-22
    • Keisuke FujimuraYasufumi BeniyaAkio HaraoYoshiharu NagaoShinji Okamoto
    • Keisuke FujimuraYasufumi BeniyaAkio HaraoYoshiharu NagaoShinji Okamoto
    • B29B9/12
    • B29B9/12C08J3/12C08J3/215C08J2323/08C08J2329/04C08K3/32C08K3/38C08K5/09
    • An ethylene-vinyl alcohol copolymer (EVOH) composition preparation process is provided, which comprises the steps of: feeding an EVOH alcohol solution into a tower type apparatus, the EVOH alcohol solution comprising 100 parts by weight of an EVOH and not less than 300 parts by weight of an alcohol having a carbon number of not greater than 4; bringing the EVOH alcohol solution into contact with water, and feeding out a part of the alcohol together with water from the apparatus to provide an EVOH water/alcohol mixture solution comprising 100 parts by weight of the EVOH, 10 to 200 parts by weight of the alcohol and 50 to 200 parts by weight of water; bringing the EVOH water/alcohol mixture solution into contact with water in an agitator container with stirring, and feeding out a part or all of the alcohol together with water from the container to provide an EVOH composition comprising 100 parts by weight of the EVOH, less than 10 parts by weight of the alcohol and 20 to 100 parts by weight of water. This preparation process makes it possible to efficiently replace the alcohol in the EVOH alcohol solution with water to provide a lower water content EVOH composition.
    • 提供乙烯 - 乙烯醇共聚物(EVOH)组合物制备方法,其包括以下步骤:将EVOH醇溶液进料到塔式设备中,EVOH醇溶液包含100重量份EVOH和不少于300份 重量的碳数不大于4的醇; 使EVOH醇溶液与水接触,并将一部分醇与来自该装置的水一起送出,以提供EVOH水/醇混合物溶液,其包含100重量份EVOH,10至200重量份的 醇和50〜200重量份的水; 使EVOH水/醇混合物溶液在搅拌容器中与水接触,并从容器中将水一部分或全部与水一起供给,以提供EVOH组合物,其包含100重量份EVOH,更少 大于10重量份的醇和20至100重量份的水。 该制备方法使得可以用水有效地代替EVOH醇溶液中的醇以提供较低的含水量的EVOH组合物。
    • 4. 发明申请
    • PROCESS FOR PREPARING ETHYLENE-VINYL ALCOHOL COPOLYMER COMPOSITION, AND PROCESS FOR PRODUCING ETHYLENE-VINYL ALCOHOL COPOLYMER PELLETS
    • 制备乙烯 - 乙烯醇共聚物组合物的方法以及生产乙烯 - 乙烯醇共聚物颗粒的方法
    • US20100314791A1
    • 2010-12-16
    • US12810463
    • 2008-12-22
    • Keisuke FujimuraYasufumi BeniyaAkio HaraoYoshiharu NagaoShinji Okamoto
    • Keisuke FujimuraYasufumi BeniyaAkio HaraoYoshiharu NagaoShinji Okamoto
    • B29B9/02C08L31/02
    • B29B9/12C08J3/12C08J3/215C08J2323/08C08J2329/04C08K3/32C08K3/38C08K5/09
    • An ethylene-vinyl alcohol copolymer (EVOH) composition preparation process is provided, which comprises the steps of: feeding an EVOH alcohol solution into a tower type apparatus, the EVOH alcohol solution comprising 100 parts by weight of an EVOH and not less than 300 parts by weight of an alcohol having a carbon number of not greater than 4; bringing the EVOH alcohol solution into contact with water, and feeding out a part of the alcohol together with water from the apparatus to provide an EVOH water/alcohol mixture solution comprising 100 parts by weight of the EVOH, 10 to 200 parts by weight of the alcohol and 50 to 200 parts by weight of water; bringing the EVOH water/alcohol mixture solution into contact with water in an agitator container with stirring, and feeding out a part or all of the alcohol together with water from the container to provide an EVOH composition comprising 100 parts by weight of the EVOH, less than 10 parts by weight of the alcohol and 20 to 100 parts by weight of water. This preparation process makes it possible to efficiently replace the alcohol in the EVOH alcohol solution with water to provide a lower water content EVOH composition.
    • 提供乙烯 - 乙烯醇共聚物(EVOH)组合物制备方法,其包括以下步骤:将EVOH醇溶液进料到塔式设备中,EVOH醇溶液包含100重量份EVOH和不少于300份 重量的碳数不大于4的醇; 使EVOH醇溶液与水接触,并将一部分醇与来自该装置的水一起送出,以提供EVOH水/醇混合物溶液,其包含100重量份EVOH,10至200重量份的 醇和50〜200重量份的水; 使EVOH水/醇混合物溶液在搅拌容器中与水接触,并从容器中将水一部分或全部与水一起供给,以提供EVOH组合物,其包含100重量份EVOH,更少 大于10重量份的醇和20至100重量份的水。 该制备方法使得可以用水有效地代替EVOH醇溶液中的醇以提供较低的含水量的EVOH组合物。
    • 5. 发明授权
    • Method of producing a vinyl acetate polymer and its saponification product
    • 乙酸乙烯酯聚合物及其皂化产物的制备方法
    • US06559254B2
    • 2003-05-06
    • US09781553
    • 2001-02-13
    • Kenji NinomiyaYoshiharu NagaoAkio HaraoKenji Kato
    • Kenji NinomiyaYoshiharu NagaoAkio HaraoKenji Kato
    • C08F1808
    • C08F18/08
    • The invention provides a process for producing a saponified vinyl acetate polymer (a saponified ethylene-vinyl acetate copolymer in particular) which features a minimum of coloration of molding pellets, a well-inhibited emanation of an odor in melt-molding, a high transparency of the product film and a low incidence of fish-eyes in the film, and a process for producing a vinyl acetate polymer (particularly an ethylene-vinyl acetate copolymer) for use as the starting material for said saponified vinyl acetate polymer having said favorable properties. In accordance with the invention, either vinyl acetate alone or vinyl acetate and one or more other monomers are polymerized in the presence of a hydroxylactone compound and a polymerization catalyst. The resulting vinyl acetate polymer (particularly the ethylene-vinyl acetate copolymer) is then saponified.
    • 本发明提供一种生产皂化的乙酸乙烯酯聚合物(特别是皂化的乙烯 - 乙酸乙烯酯共聚物)的方法,其特征在于最小的成型颗粒的着色,在熔融模塑中良好抑制的气味发散,高透明度 该薄膜中的产品薄膜和鱼眼的发生率低,以及用作所述具有良好性能的所述皂化乙酸乙烯酯聚合物的起始原料的乙酸乙烯酯聚合物(特别是乙烯 - 乙酸乙烯酯共聚物)的制备方法。 根据本发明,在羟基内酯化合物和聚合催化剂的存在下,单独使用乙酸乙烯酯或乙酸乙烯酯和一种或多种其它单体聚合。 然后将所得乙酸乙烯酯聚合物(特别是乙烯 - 乙酸乙烯酯共聚物)皂化。
    • 6. 发明授权
    • Halogen-containing thermoplastic resin composition
    • 含卤素的热塑性树脂组合物
    • US5030690A
    • 1991-07-09
    • US349464
    • 1989-05-09
    • Minoru FujitaHiroshi TakidaYoshiharu Nagao
    • Minoru FujitaHiroshi TakidaYoshiharu Nagao
    • C08L27/06C08L51/00C08L51/06
    • C08L27/06C08L51/003C08L51/06
    • This invention relates to a halogen-containing thermoplastic resin composition comprising 100 parts by weight of a halogen-containing termoplastic resin (A) and 1 to 100 parts by weight of a graft polymer (B) having a melt index of 1 to 15 g/10 min as determined at a temperature of 190.degree. C. under a load of 2.16 kg and a benzene-insoluble fraction content of not more than 30 percent by weight as obtainable by graft-polymerizing 100 parts by weight of an ethylene-vinyl acetate copolymer having a vinyl acetate content of 50 to 90 percent by weight as a substrate with 5 to 50 parts by weight of at least one monomer which, when polymerized alone, gives a homopolymer with a glass transition temperature of 65.degree. to 150.degree. C. (b2). This resin composition has markedly improved long-run moldability.
    • 本发明涉及含有卤素的热塑性树脂组合物,其包含100重量份的含卤素的活性树脂(A)和1至100重量份的熔体指数为1至15克/升的接枝聚合物(B) 10分钟,其温度为190℃,负荷2.16kg,苯不溶部分含量不超过30重量%,通过接枝聚合100重量份乙烯 - 乙酸乙烯酯共聚物 具有50至90重量%的乙酸乙烯酯含量作为基材,具有5至50重量份的至少一种单体,当单独聚合时,得到玻璃化转变温度为65℃至150℃的均聚物( b2)。 该树脂组合物长期成型性显着提高。