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1. 发明授权

US5430086A Rubber composition for tire treads 失效
标题翻译：轮胎胎面橡胶组合物
公开(公告)号：US5430086A
公开(公告)日：1995-07-04
申请号：US165164
申请日：1993-12-10
申请人： Yuichi Saito , Toru Fukumoto , Shuji Imaoka , Keisaku Yamamoto , Kizuku Wakatsuki , Mitsuji Tsuji
发明人： Yuichi Saito , Toru Fukumoto , Shuji Imaoka , Keisaku Yamamoto , Kizuku Wakatsuki , Mitsuji Tsuji
IPC分类号： B60C1/00 , C08K3/04 , C08L9/06
CPC分类号： C08K3/04 , B60C1/0016 , C08L9/06 , C08L2205/02 , C08L7/00 , C08L9/00 , C08L9/08 , Y10S152/905
摘要： A rubber composition for tire treads comprising a rubber component consisting essentially of (A) 20 to 100% by weight of a solution-polymerized styrene-butadiene copolymer rubber having a Mooney viscosity ML.sub.1+4 of 30 to 200 at 100.degree. C. prepared by copolymerization of styrene, butadiene and a polyvinyl aromatic compound followed by coupling with a trifunctional or tetrafunctional coupling agent, and (B) 0 to 80% by weight of at least one rubber selected from the group consisting of an emulsion-polymerized styrene-butadiene rubber, a butadiene rubber, natural rubber and a synthetic polyisoprene rubber; and (C) 50 to 250 parts by weight of a carbon black having an iodine adsorption number of not less than 60 mg/g and an oil absorption of not less than 110 ml/100 g per 100 parts by weight of said rubber component; the tan .delta. peak temperature Tg of the cured product of said rubber composition being from -40.degree. to +5.degree. C. The tread rubber composition can be processed without causing bagging with a good dispersibility of carbon black and provides tires having a low rolling resistance and a high grip characteristic.
摘要翻译：一种用于轮胎胎面的橡胶组合物，其包含基本上由（A）20-100重量％的在100℃下门尼粘度ML1 + 4为30至200的溶液聚合的苯乙烯 - 丁二烯共聚物橡胶组成的橡胶组分，其由苯乙烯，丁二烯和聚乙烯基芳族化合物的共聚合，然后与三官能或四官能偶联剂偶合，和（B）0至80重量％的至少一种选自乳液聚合的苯乙烯 - 丁二烯橡胶丁二烯橡胶，天然橡胶和合成聚异戊二烯橡胶; 和（C）每100重量份所述橡胶组分50至250重量份的碘吸附数不小于60mg / g和吸油量不小于110ml / 100g的炭黑; 所述橡胶组合物的固化产物的tanδ峰值温度Tg为-40℃至+5℃。胎面橡胶组合物可以在不引起炭黑的良好分散性的情况下进行加工而且具有低滚动阻力的轮胎和高抓地力特性。

2. 发明授权

US5290878A Butadiene copolymer and process for preparing same 失效
标题翻译：丁二烯共聚物及其制备方法
公开(公告)号：US5290878A
公开(公告)日：1994-03-01
申请号：US72488
申请日：1993-06-07
申请人： Keisaku Yamamoto , Kizuku Wakatsuki , Mitsuji Tsuji , Yuichi Saito
发明人： Keisaku Yamamoto , Kizuku Wakatsuki , Mitsuji Tsuji , Yuichi Saito
IPC分类号： C08C19/42 , C08F8/00 , C08F36/00 , C08F36/06 , C08F236/06 , C08F236/10 , C08K5/00 , C08L9/00 , C08F8/42
CPC分类号： C08F236/10
摘要： An elastomeric butadiene copolymer prepared by a process which comprises copolymerizing butadiene, a polyvinyl aromatic compound and optionally styrene in a hydrocarbon solvent in the presence of an organolithium polymerization initiator and subjecting the resulting copolymer having lithium at the polymer end or ends to a coupling reaction with a trifunctional or tetrafunctional coupling agent, said butadiene copolymer satisfying the following conditions: (a) the content of styrene is at most 50% by weight, (b) the content of vinyl bonds in the butadiene portion is from 10 to 90% by weight, (c) the molecular weight distribution curve obtained by a high performance liquid chromatography has at least three peaks, and 5 to 60% by weight of all the polymer chains have a molecular weight which is at least 5 times the molecular weight in terms of standard polystyrene corresponding to the peak appearing on the lowest molecular weight side of the high performance liquid chromatogram, and (d) the Mooney viscosity (ML.sub.1+4, 100.degree. C.) is from 30 to 200. The butadiene copolymer has an improved processability with excellent resilience, wet grip property, abrasion resistance and mechanical properties, and is suitable for tire use.
摘要翻译：一种弹性体丁二烯共聚物，该方法包括在有机锂聚合引发剂存在下，使丁二烯，聚乙烯基芳族化合物和任选的苯乙烯在烃溶剂中共聚，并将所得到的聚合物末端或末端的锂共聚物与所述丁二烯共聚物满足以下条件：（a）苯乙烯含量至多为50重量％，（b）丁二烯部分中的乙烯基键含量为10〜90重量％，（c）通过高效液相色谱获得的分子量分布曲线具有至少三个峰，并且所有聚合物链的5至60重量％的分子量的分子量至少为分子量的5倍对应于在高效液相色谱的最低分子量侧出现的峰的标准聚苯乙烯，和（d）t 门尼粘度（ML1 + 4,100℃）为30〜200。丁二烯共聚物具有优异的回弹性，湿抓地性，耐磨性和机械性能的加工性，适用于轮胎使用。

3. 发明授权

US5189108A Modified polymer rubber and process for preparing the same 失效
标题翻译：改性聚合物橡胶及其制备方法
公开(公告)号：US5189108A
公开(公告)日：1993-02-23
申请号：US625924
申请日：1990-12-14
申请人： Akio Imai , Mitsuji Tsuji , Takashi Sanada , Keisaku Yamamoto
发明人： Akio Imai , Mitsuji Tsuji , Takashi Sanada , Keisaku Yamamoto
IPC分类号： C08F255/04 , C08F255/06 , C08F279/02 , C08F291/00 , C08F291/02
CPC分类号： C08F255/04 , C08F255/06 , C08F279/02
摘要： A modified polymer rubber is obtained by(1) graft-polymerizing at least one grafting monomer to a shreaded rubbery polymer (A) in an aqueous suspension at a temperature of 30.degree.-130.degree. C. to obtain a graft polymer, and(2) kneading the graft polymer with at least one polymerizable monomer in the presence of a free radical initiator at a temperature of 180.degree.-280.degree. C. This process does not cause gel formation and is advantageous in manufacturing cost.The modified polymer rubber thus obtained is excellent in processability and storage stability, and highly useful as a compatibilizer for various resins.

4. 发明授权

US4812527A Rubber composition for tire treads containing dicarboxylic acid diester coupled block polymers 失效
标题翻译：含有二羧酸二酯偶联嵌段聚合物的轮胎胎面橡胶组合物
公开(公告)号：US4812527A
公开(公告)日：1989-03-14
申请号：US112989
申请日：1987-10-27
申请人： Hiroyoshi Takao , Nabuyuki Yoshida , Akio Imai , Mitsuji Tsuji , Yuichi Saito
发明人： Hiroyoshi Takao , Nabuyuki Yoshida , Akio Imai , Mitsuji Tsuji , Yuichi Saito
IPC分类号： B60C1/00 , C08F297/04 , C08L53/00 , C08L53/02
CPC分类号： C08F297/044 , B60C1/0016 , Y10S152/905
摘要： A rubber composition suitable for tire treads having well-balanced excellent wet skid characteristic, ice skid characteristic and rolling characteristic, and an excellent processability, which comprises a rubber component containing at least 20% by weight of a block copolymer consisting essentially of a block A and a block B, obtained by conducting polymerization of an aromatic vinyl compound and a conjugated diene compound in a hydrocarbon solvent in the presence of an organolithium initiator and modifying with a coupling agent, and satisfying the following conditions (A) to (E);(A) the block A having a content of an aromatic vinyl compound of at most 5% by weight and a content of 1,2-bonds in the conjugated diene component of at least 10% by weight,(B) the block B having a content of an aromatic vinyl compound of 25 to 50% by weight and a content of 1,2-bonds in the conjugated diene component of at least 10% by weight,(C) a content of the block A in the block copolymer being from 20 to 80% by weight,(D) a content of the aromatic vinyl compound in the block copolymer being from 5 to 30% by weight and a content of 1,2-bonds in the conjugated diene component of the block copolymer being from 20 to 60% by weight, and(E) at least 40% by weight of the polymer chains of the block copolymer being a branched polymer formed by modification with a dicarboxylic acid diester.
摘要翻译：一种适用于轮胎胎面的橡胶组合物，具有平衡优异的湿滑特性，防滑特性和滚动特性，以及优异的加工性，其包含含有至少20重量％的基本上由块A 和通过在有机锂引发剂的存在下在烃溶剂中进行芳族乙烯基化合物和共轭二烯化合物的聚合而获得的嵌段B，并且用偶联剂进行改性，并满足以下条件（A）〜（E）; （A）具有至多5重量％的芳族乙烯基化合物含量的嵌段A和共轭二烯组分中的1,2-键的含量为至少10重量％，（B）嵌段B具有芳香族乙烯基化合物的含量为25〜50重量％，共轭二烯成分中的1,2-键含量为10重量％以上，（C）嵌段共聚物中的嵌段A的含量为 20〜80重量％，（D）嵌段共聚物中芳香族乙烯基化合物的含量为5〜30重量％，嵌段共聚物的共轭二烯成分中的1,2-键含量为 20至60重量％，和（E）至少40重量％的嵌段共聚物的聚合物链是通过用二羧酸二酯改性形成的支化聚合物。

5. 发明授权

US4918142A Rubber composition of tire tread containing block copolymer coupled with dicarboxylic acid ester 失效
标题翻译：含有二羧酸酯的嵌段共聚物的轮胎胎面橡胶组合物
公开(公告)号：US4918142A
公开(公告)日：1990-04-17
申请号：US320836
申请日：1989-03-08
申请人： Yuichi Saito , Takuzoh Yabuta , Hiroyoshi Takao , Akio Imai , Mitsuji Tsuji
发明人： Yuichi Saito , Takuzoh Yabuta , Hiroyoshi Takao , Akio Imai , Mitsuji Tsuji
IPC分类号： B29D30/52 , B60C1/00 , C08F297/04 , C08L21/00 , C08L53/00 , C08L53/02
CPC分类号： C08L21/00 , B60C1/0016 , C08F297/044 , C08L53/02 , C08L9/06
摘要： A rubber composition suitable for tire treads having well-balanced excellent steering stability in cornering, wet skid characteristic, ice skid characteristic and rolling characteristic, and an excellent processability, which comprises a rubber component containing a block copolymer consisting essentially of a block A and a block B, obtained by conducting polymerization of an aromatic vinyl compound and a conjugated diene compound in a hydrocarbon solvent in the presence of an organolithium initiator and modifying with a coupling agent, and satisfying the following conditions (A) to (E);(A) the block A having a content of an aromatic vinyl compound of 5 to 29% by weight and a content of 1,2-bonds in the conjugated diene component of 25 to 55% by weight,(B) the block B having a content of an aromatic vinyl compound of 35 to 60% by weight and a content of 1,2-bonds in the conjugated diene component of 20 to 70% by weight,(C) the content of the block A in the block copolymer being from 20 to 80% by weight,(D) the average content of the aromatic vinyl compound in the block copolymer being from 20 to 40% by weight and the average content of 1,2-bonds in the conjugated diene component of the block copolymer being from 20 to 60% by weight, and(E) at least 40% by weight of the polymer chains of the block copolymer being a branched polymer formed by modification with a trifunctional or tetrafunctional coupling agent.
摘要翻译：一种适用于轮胎胎面的橡胶组合物，其具有平衡优异的转弯转向稳定性，防滑特性，防滑特性和滚动特性以及优异的加工性能，其包括含有基本上由块A和嵌段B，其通过在有机锂引发剂的存在下在烃溶剂中进行芳族乙烯基化合物和共轭二烯化合物的聚合而获得，并且用偶联剂进行改性，并满足以下条件（A）至（E）; （A）具有5〜29重量％的芳族乙烯基化合物的含量和共轭二烯组分中的1,2-键含量为25〜55重量％的嵌段A，（B）嵌段B具有 35〜60重量％的芳香族乙烯基化合物的含量和共轭二烯成分中的1,2-键含量为20〜70重量％，（C）嵌段共聚物中嵌段A的含量为 20〜80重量％，（D）嵌段共聚物中芳族乙烯基化合物的平均含量为20〜40重量％，嵌段共聚物的共轭二烯成分中的1,2-键的平均含量为20〜60重量％，（E）嵌段共聚物的聚合物链的至少40重量％为通过三官能或四官能偶合剂改性形成的支链聚合物。

6. 发明授权

US5559185A Thermoplastic resin composition 失效
标题翻译：热塑性树脂组合物
公开(公告)号：US5559185A
公开(公告)日：1996-09-24
申请号：US372863
申请日：1995-01-13
申请人： Hiroomi Abe , Taichi Nishio , Yasurou Suzuki , Mitsuji Tsuji , Takashi Sanada
发明人： Hiroomi Abe , Taichi Nishio , Yasurou Suzuki , Mitsuji Tsuji , Takashi Sanada
IPC分类号： C08L51/04 , C08L63/00 , C08L71/12 , C08L77/00 , C08L13/02 , C08L25/06
CPC分类号： C08L71/123 , C08L51/04 , C08L71/12 , C08L77/00 , C08L63/00
摘要： A thermoplastic resin composition superior in impact resistance, heat resistance, flexural rigidity, processability and solvent resistance which comprises: (A) 100 parts by weight of a resin composition comprising 5-95% by weight of a polyphenylene ether, or a polyphenylene ether and polystyrene, and 95-5% by weight of a polyamide resin; (B) 5-50 parts by weight of a modified saturated rubber obtained by grafting 5-100 parts by weight of an aromatic vinyl compound on 100 parts by weight of a saturated type rubber and allowing 0.05-10 parts by weight of a compatibilizing agent to react with said rubber; and (c) 0.05-20 parts by weight of a compatibilizing agent.
摘要翻译：耐冲击性，耐热性，弯曲刚性，加工性和耐溶剂性优异的热塑性树脂组合物，其特征在于：（A）100重量份含有5-95重量％聚苯醚或聚苯醚的树脂组合物，聚苯乙烯和95-5重量％的聚酰胺树脂; （B）5-50重量份通过在100重量份的饱和型橡胶上接枝5-100重量份的芳族乙烯基化合物而获得的改性饱和橡胶，并且允许0.05-10重量份的相容剂与所述橡胶反应; 和（c）0.05-20重量份的相容剂。

7. 发明授权

US4957976A Process for preparing diene polymer rubbers 失效
标题翻译：二烯聚合物橡胶的制备方法
公开(公告)号：US4957976A
公开(公告)日：1990-09-18
申请号：US415380
申请日：1989-09-29
申请人： Hiroyoshi Takao , Akio Imai , Tomoski Seki , Mitsuji Tsuji
发明人： Hiroyoshi Takao , Akio Imai , Tomoski Seki , Mitsuji Tsuji
IPC分类号： C08C19/42
CPC分类号： C08C19/42
摘要： A process for preparing modified diene polymer rubbers having an increased impact resilience and a reduced hardness at low temperatures and useful as rubber materials for automobile tires and other industries which comprises producing an alkali metal-containing conjugated diene polymer, and reacting the alkali metal-containing polymer with a modifier selected from the group consisting of a nitro compound, a phosphoryl chloride compound of the formula: ##STR1## wherein R.sup.1 to R.sup.4 are independently an alkyl group, and an aminosilane compound of the formula: ##STR2## wherein R.sup.5 to R.sup.7 are independently an alkyl group or an alkoxyl group, R.sup.8 and R.sup.9 are independently an alkyl group, and n is an integer, said alkali metal-containing diene polymer being prepared by a living anionic polymerization using an alkali metal-based catalyst or by an addition reaction of a diene polymer having conjugated diene units and an alkali metal-based catalyst in a hydrocarbon solvent. The modified diene polymers can be incorporated with usual rubber additives to provide rubber compositions for various purposes, and the cured products shown an increased impact resilience and a reduced hardness at low temperatures.
摘要翻译：一种制备改性二烯聚合物橡胶的方法，该改性二烯聚合物橡胶在低温下具有增加的冲击弹性和降低的硬度，并且可用作汽车轮胎和其它工业的橡胶材料，其包括制备含碱金属的共轭二烯聚合物，并使含碱金属的聚合物，其选自硝基化合物，下式的磷酰氯化合物：其中R 1至R 4独立地为烷基，并且具有下式的氨基硅烷化合物：（IMAGE）（ 2）其中R5至R7独立地为烷基或烷氧基，R8和R9独立地为烷基，n为整数，所述含碱金属的二烯聚合物通过使用碱金属 - 或通过在烃溶剂中具有共轭二烯单元的二烯聚合物和碱金属类催化剂的加成反应。改性二烯聚合物可与通常的橡胶添加剂结合以提供用于各种目的的橡胶组合物，并且固化产物显示了在低温下增加的冲击弹性和降低的硬度。

8. 发明授权

US06583254B2 Propylene-based polymer and film made of the same 有权
标题翻译：丙烯基聚合物和由其制成的膜
公开(公告)号：US06583254B2
公开(公告)日：2003-06-24
申请号：US09983272
申请日：2001-10-23
申请人： Mitsuji Tsuji , Kenichiro Yada , Syunji Yunoki
发明人： Mitsuji Tsuji , Kenichiro Yada , Syunji Yunoki
IPC分类号： C08F11006
CPC分类号： C08J5/18 , C08F210/06 , C08J2323/10 , C08L23/14 , C08F210/08 , C08F2500/12 , C08F2500/20 , C08F2500/26
摘要： A propylene-based polymer having a melt flow rate of 0.1 to 20 g/10 min. and a melting point Tm (° C.) measured by using a differential scanning calorimeter (DSC) of 147 to 159° C., in which the half width HW (° C.) of the melting peak measured by using a differential scanning calorimeter (DSC) and the melting point Tm (° C.) satisfy the relation: HW≦(188−Tm)/5.
摘要翻译：熔体流动速率为0.1〜20g / 10分钟的丙烯类聚合物。和通过使用差示扫描量热计（DSC）为147至159℃测量的熔点Tm（℃），其中通过使用差示扫描量热计测量的熔融峰的半峰宽HW（℃）（DSC）和熔点Tm（℃）满足关系：HW <=（188-Tm）/ 5。

9. 发明授权

US5240544A Adhesive composition 失效
标题翻译：粘合剂组合物
公开(公告)号：US5240544A
公开(公告)日：1993-08-31
申请号：US870120
申请日：1992-04-17
申请人： Yoshio Tanimoto , Nobuyuki Yoshida , Mitsuji Tsuji , Eiichi Usuda , Kouji Satou
发明人： Yoshio Tanimoto , Nobuyuki Yoshida , Mitsuji Tsuji , Eiichi Usuda , Kouji Satou
IPC分类号： C08F8/32 , C09J151/06
CPC分类号： C09J151/06 , C08F8/32
摘要： An adhesive composition comprising a modified, ethylene/.alpha.-olefin copolymer rubber or a modified, ethylene/.alpha.-olefin/non-conjugated diene copolymer rubber containing 0.1-10% by weight of at least one member selected from the group consisting of an acid anhydride and a dicarboxylic acid, and, if necessary, as an amine compound,(i) 0.2-2 moles of a dialkylamine per mole of the acid anhydride in said modified copolymer rubber when said modified copolymer rubber contains no dicarboxylic acid;(ii) 0.2-2 moles of a polyamine compound per mole of the total amount of the acid anhydride and the dicarboxylic acid in said modified copolymer rubber; or(iii) 0.2-2 moles of a dialkylamine per mole of the acid anhydride in said modified copolymer rubber and 0.2-2 moles of a polyamine compound per mole of the acid anhydride in said modified copolymer rubber when said modified copolymer rubber contains no dicarboxylic acid. The above adhesive composition exhibits good adhesion for rubber compositions, particularly low unsaturated, non-polar rubber compositions and fibers, and is excellent in storage stability.
摘要翻译：一种粘合剂组合物，其包含改性的乙烯/α-烯烃共聚物橡胶或改性的乙烯/α-烯烃/非共轭二烯共聚物橡胶，其含有0.1-10重量％的至少一种选自酸酸酐和二羧酸，如果需要，作为胺化合物，（i）当所述改性共聚物橡胶不含二羧酸时，所述改性共聚物橡胶中每摩尔酸酐为0.2-2摩尔二烷基胺; （ii）每摩尔所述改性共聚物橡胶中酸酐和二羧酸的总量为0.2-2摩尔多胺化合物; 或（iii）当所述改性共聚物橡胶中不含二羧酸时，所述改性共聚物橡胶中每摩尔酸酐为0.2-2摩尔二烷基胺/每摩尔酸酐为0.2-2摩尔多胺化合物酸。上述粘合剂组合物对橡胶组合物，特别是低不饱和，非极性橡胶组合物和纤维表现出良好的粘合性，并且储存稳定性优异。

10. 发明授权

US4966940A Vulcanized, ethylene/alpha-olefin copolymer rubber composition 失效
标题翻译：硫化乙烯/α-烯烃共聚橡胶组合物
公开(公告)号：US4966940A
公开(公告)日：1990-10-30
申请号：US360451
申请日：1989-06-02
申请人： Mitsuji Tsuji , Eiichi Usuda , Masashi Aoshima
发明人： Mitsuji Tsuji , Eiichi Usuda , Masashi Aoshima
IPC分类号： C08L23/08 , C08L23/16 , C08L23/26 , C08L51/06 , C08L77/00
CPC分类号： C08L51/06 , C08L23/16 , C08L77/00 , C08L2312/00
摘要： A vulcanized, ethylene/.alpha.-olefin copolymer rubber composition obtained by vulcanizing an unvulcanized rubber composition comprising 100 parts by weight of a rubber composition consisting of 0-99% by weight of an ethylene/.alpha.-olefin copolymer rubber and 100-1% by weight of an ethylene/.alpha.-olefin copolymer rubber containing an .alpha.,.beta.-unsaturated carboxylic acid and/or a derivative thereof; and 5-100 parts by weight of a polyamide resin, wherein an ethylene/.alpha.-olefin copolymer rubber is at least one selected from ethylene/.alpha.-olefin copolymers and ethylene/.alpha.-olefin/non-conjugated diene copolymers. The vulcanized, ethylene/.alpha.-olefin copolymer rubber composition of the present invention has a high hardness and is excellent in weather resistance and thermal resistance as compared with natural rubbers and general-purpose rubbers.

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