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1. 发明申请

US20050107383A1 3-ARYLPHENYL SULFIDE DERIVATIVE AND INSECTICIDE AND MITICIDE 有权
公开(公告)号：US20050107383A1
公开(公告)日：2005-05-19
申请号：US10981722
申请日：2004-11-05
申请人： Keiji Toriyabe , Nobuo Takefuji , Minoru Itou , Tetsuya Hirade , Kiyotoshi Nishiyama , Mitsuharu Asahida , Yasunobu Maeda , Nobuhide Wada , Toyokazu Fujisawa , Hiroyuki Yano , Masaaki Komatsu , Osamu Tada
发明人： Keiji Toriyabe , Nobuo Takefuji , Minoru Itou , Tetsuya Hirade , Kiyotoshi Nishiyama , Mitsuharu Asahida , Yasunobu Maeda , Nobuhide Wada , Toyokazu Fujisawa , Hiroyuki Yano , Masaaki Komatsu , Osamu Tada
IPC分类号： A01N41/10 , A01N43/08 , A01N43/10 , A01N43/40 , A01N43/54 , A01N43/56 , A01N43/58 , A01N43/60 , A01N43/76 , A01N43/78 , A61K31/4164 , A61K31/4196 , A61K31/445 , A61K31/495 , A61K31/498 , A61K31/50 , A61K31/513 , A61K31/53 , C07C309/00 , C07C317/14 , C07C317/22 , C07C317/32 , C07C323/09 , C07C323/18 , C07C323/31 , C07D211/54 , C07D213/52 , C07D213/57 , C07D213/64 , C07D231/12 , C07D249/08 , C07D253/00 , C07D263/32 , C07D277/26 , C07D307/56 , C07D333/24 , C07D333/28
CPC分类号： C07D213/12 , A01N31/08 , A01N31/14 , A01N33/10 , A01N37/08 , A01N37/34 , A01N41/10 , A01N43/08 , A01N43/10 , A01N43/40 , A01N43/54 , A01N43/56 , A01N43/653 , A01N43/76 , A01N43/78 , A01N47/18 , C07C317/32 , C07C317/48 , C07C323/18 , C07C323/20 , C07C323/36 , C07C323/63 , C07D213/32 , C07D213/48 , C07D213/57 , C07D213/64 , C07D239/36 , C07D239/38 , C07D239/40 , C07D249/08 , C07D333/24
摘要： 3-Arylphenyl sulfide derivatives represented by general formula (I): (wherein R is a C2-C6 alkyl group, a C2-C6 alkenyl group, a C2-C6 alkynyl group or the like, B0 to B2 and B3 are hydrogen atoms, halogen atoms, cyano groups, C1-C4 haloalkyl groups or the like, n is 0, 1 or 2, and Ar is a phenyl ring, a pyridine ring, a thiophene ring, a pyrazole ring or the like), and insecticides and miticides containing the 3-arylphenyl sulfide derivatives as an active ingredient.
摘要翻译：由通式（I）表示的3-芳基苯基硫醚衍生物：其中R是C 2 -C 6烷基，C 2 - -C 6亚烷基，C 2 -C 6亚炔基等，B 0〜B 2个和3个3个是氢原子，卤素原子，氰基，C 1 -C 4卤代烷基或 n为0,1或2，Ar为苯环，吡啶环，噻吩环，吡唑环等），含有3-芳基苯基硫醚衍生物的杀虫剂和杀螨剂为活性成分。

2. 发明申请

US20090170883A1 3-ARYLPHENYL SULFIDE DERIVATIVE AND INSECTICIDE AND MITICIDE 有权
公开(公告)号：US20090170883A1
公开(公告)日：2009-07-02
申请号：US12269549
申请日：2008-11-12
申请人： Keiji Toriyabe , Nobuo Takefuji , Minoru Itou , Tetsuya Hirade , Kiyotoshi Nishiyama , Mitsuharu Asahida , Yasunobu Maeda , Nobuhide Wada , Toyokazu Fujisawa , Hiroyuki Yano , Masaaki Komatsu , Osamu Tada
发明人： Keiji Toriyabe , Nobuo Takefuji , Minoru Itou , Tetsuya Hirade , Kiyotoshi Nishiyama , Mitsuharu Asahida , Yasunobu Maeda , Nobuhide Wada , Toyokazu Fujisawa , Hiroyuki Yano , Masaaki Komatsu , Osamu Tada
IPC分类号： A01N41/02 , C07C317/14 , A01N43/653 , C07D249/08 , C07D231/10 , A01N43/56 , C07C255/49 , A01N37/34 , A01N43/40 , C07D213/57 , A01N43/54 , C07D239/02 , A01P7/02 , A01P7/04
CPC分类号： C07D213/12 , A01N31/08 , A01N31/14 , A01N33/10 , A01N37/08 , A01N37/34 , A01N41/10 , A01N43/08 , A01N43/10 , A01N43/40 , A01N43/54 , A01N43/56 , A01N43/653 , A01N43/76 , A01N43/78 , A01N47/18 , C07C317/32 , C07C317/48 , C07C323/18 , C07C323/20 , C07C323/36 , C07C323/63 , C07D213/32 , C07D213/48 , C07D213/57 , C07D213/64 , C07D239/36 , C07D239/38 , C07D239/40 , C07D249/08 , C07D333/24
摘要： 3-Arylphenyl sulfide derivatives represented by general formula (I): (wherein R is a C2-C6 alkyl group, a C2-C6 alkenyl group, a C2-C6 alkynyl group or the like, B0 to B2 and B3 are hydrogen atoms, halogen atoms, cyano groups, C1-C4 haloalkyl groups or the like, n is 0, 1 or 2, and Ar is a phenyl ring, a pyridine ring, a thiophene ring, a pyrazole ring or the like), and insecticides and miticides containing the 3-arylphenyl sulfide derivatives as an active ingredient.
摘要翻译：由通式（I）表示的3-芳基苯基硫醚衍生物：其中R为C2-C6烷基，C2-C6烯基，C2-C6炔基等，B0至B2和B3为氢原子，卤素原子，氰基，C 1〜C 4卤代烷基等，n为0,1或2，Ar为苯环，吡啶环，噻吩环，吡唑环等），杀虫剂和杀螨剂含有3-芳基苯基硫醚衍生物作为活性成分。

3. 发明申请

US20050171097A1 3-Arylphenyl sulfide derivative and insecticide and miticide 有权
标题翻译： 3-芳基苯硫醚衍生物和杀虫剂和杀螨剂
公开(公告)号：US20050171097A1
公开(公告)日：2005-08-04
申请号：US11098440
申请日：2005-04-05
申请人： Keiji Toriyabe , Nobuo Takefuji , Minoru Itou , Tetsuya Hirade , Kiyotoshi Nishiyama , Mitsuharu Asahida , Yasunobu Maeda , Nobuhide Wada , Toyokazu Fujisawa , Hiroyuki Yano , Masaaki Komatsu , Osamu Tada
发明人： Keiji Toriyabe , Nobuo Takefuji , Minoru Itou , Tetsuya Hirade , Kiyotoshi Nishiyama , Mitsuharu Asahida , Yasunobu Maeda , Nobuhide Wada , Toyokazu Fujisawa , Hiroyuki Yano , Masaaki Komatsu , Osamu Tada
IPC分类号： A01N41/10 , A01N43/08 , A01N43/10 , A01N43/40 , A01N43/54 , A01N43/56 , A01N43/58 , A01N43/60 , A01N43/76 , A01N43/78 , A61K31/4164 , A61K31/4196 , A61K31/445 , A61K31/495 , A61K31/498 , A61K31/50 , A61K31/513 , A61K31/53 , C07C309/00 , C07C317/14 , C07C317/22 , C07C317/32 , C07C323/09 , C07C323/18 , C07C323/31 , C07D211/54 , C07D213/52 , C07D213/57 , C07D213/64 , C07D231/12 , C07D249/08 , C07D253/00 , C07D263/32 , C07D277/26 , C07D307/56 , C07D333/24 , C07D333/28
CPC分类号： C07D213/12 , A01N31/08 , A01N31/14 , A01N33/10 , A01N37/08 , A01N37/34 , A01N41/10 , A01N43/08 , A01N43/10 , A01N43/40 , A01N43/54 , A01N43/56 , A01N43/653 , A01N43/76 , A01N43/78 , A01N47/18 , C07C317/32 , C07C317/48 , C07C323/18 , C07C323/20 , C07C323/36 , C07C323/63 , C07D213/32 , C07D213/48 , C07D213/57 , C07D213/64 , C07D239/36 , C07D239/38 , C07D239/40 , C07D249/08 , C07D333/24
摘要： 3-Arylphenyl sulfide derivatives represented by general formula (I): (wherein R is a C2-C6 alkyl group, a C2-C6 alkenyl group, a C2-C6 alkynyl group or the like, B0 to B2 and B3 are hydrogen atoms, halogen atoms, cyano groups, C1-C4 haloalkyl groups or the like, n is 0, 1 or 2, and Ar is a phenyl ring, a pyridine ring, a thiophene ring, a pyrazole ring or the like), and insecticides and miticides containing the 3-arylphenyl sulfide derivatives as an active ingredient.
摘要翻译：由通式（I）表示的3-芳基苯基硫醚衍生物：其中R是C 2 -C 6烷基，C 2 - -C 6亚烷基，C 2 -C 6亚炔基等，B 0〜B 2个和3个3个是氢原子，卤素原子，氰基，C 1 -C 4卤代烷基或 n为0,1或2，Ar为苯环，吡啶环，噻吩环，吡唑环等），含有3-芳基苯基硫醚衍生物的杀虫剂和杀螨剂为活性成分。

4. 发明授权

US06509354B1 3-arylphenyl sulfide derivative and insecticide and miticide 有权
标题翻译： 3-芳基苯基硫化物衍生物和杀虫剂和杀螨剂
公开(公告)号：US06509354B1
公开(公告)日：2003-01-21
申请号：US09673633
申请日：2000-10-27
申请人： Keiji Toriyabe , Nobuo Takefuji , Minoru Itou , Tetsuya Hirade , Kiyotoshi Nishiyama , Mitsuharu Asahida , Yasunobu Maeda , Nobuhide Wada , Toyokazu Fujisawa , Hiroyuki Yano , Masaaki Komatsu , Osamu Tada
发明人： Keiji Toriyabe , Nobuo Takefuji , Minoru Itou , Tetsuya Hirade , Kiyotoshi Nishiyama , Mitsuharu Asahida , Yasunobu Maeda , Nobuhide Wada , Toyokazu Fujisawa , Hiroyuki Yano , Masaaki Komatsu , Osamu Tada
IPC分类号： A61K31445
CPC分类号： C07D213/12 , A01N31/08 , A01N31/14 , A01N33/10 , A01N37/08 , A01N37/34 , A01N41/10 , A01N43/08 , A01N43/10 , A01N43/40 , A01N43/54 , A01N43/56 , A01N43/653 , A01N43/76 , A01N43/78 , A01N47/18 , C07C317/32 , C07C317/48 , C07C323/18 , C07C323/20 , C07C323/36 , C07C323/63 , C07D213/32 , C07D213/48 , C07D213/57 , C07D213/64 , C07D239/36 , C07D239/38 , C07D239/40 , C07D249/08 , C07D333/24
摘要： 3-Arylphenyl sulfide derivatives represented by general formula (I): (wherein R is a C2-C6 alkyl group, a C2-C6 alkenyl group, a C2-C6 alkynyl group or the like, B0 to B2 and B3 are hydrogen atoms, halogen atoms, cyano groups, C1-C4 haloalkyl groups or the like, n is 0, 1 or 2, and Ar is a phenyl ring, a pyridine ring, a thiophene ring, a pyrazole ring or the like), and insecticides and miticides containing the 3-arylphenyl sulfide derivatives as an active ingredient.
摘要翻译：由通式（I）表示的3-芳基苯基硫醚衍生物:(其中R为C2-C6烷基，C2-C6烯基，C2-C6炔基等，B0至B2和B3为氢原子，卤素原子，氰基，C 1〜C 4卤代烷基等，n为0,1或2，Ar为苯环，吡啶环，噻吩环，吡唑环等），杀虫剂和杀螨剂含有3-芳基苯基硫醚衍生物作为活性成分。

5. 发明授权

US06858639B2 3-Arylphenyl sulfide derivative and insecticide and miticide 有权
标题翻译： 3-芳基苯硫醚衍生物和杀虫剂和杀螨剂
公开(公告)号：US06858639B2
公开(公告)日：2005-02-22
申请号：US10121833
申请日：2002-04-15
申请人： Keiji Toriyabe , Nobuo Takefuji , Minoru Itou , Tetsuya Hirade , Kiyotoshi Nishiyama , Mitsuharu Asahida , Yasunobu Maeda , Nobuhide Wada , Toyokazu Fujisawa , Hiroyuki Yano , Masaaki Komatsu , Osamu Tada
发明人： Keiji Toriyabe , Nobuo Takefuji , Minoru Itou , Tetsuya Hirade , Kiyotoshi Nishiyama , Mitsuharu Asahida , Yasunobu Maeda , Nobuhide Wada , Toyokazu Fujisawa , Hiroyuki Yano , Masaaki Komatsu , Osamu Tada
IPC分类号： A01N41/10 , A01N43/08 , A01N43/10 , A01N43/40 , A01N43/54 , A01N43/56 , A01N43/58 , A01N43/60 , A01N43/76 , A01N43/78 , A61K31/4164 , A61K31/4196 , A61K31/445 , A61K31/495 , A61K31/498 , A61K31/50 , A61K31/513 , A61K31/53 , C07C309/00 , C07C317/14 , C07C317/22 , C07C317/32 , C07C323/09 , C07C323/18 , C07C323/31 , C07D211/54 , C07D213/52 , C07D213/57 , C07D213/64 , C07D231/12 , C07D249/08 , C07D253/00 , C07D263/32 , C07D277/26 , C07D307/56 , C07D333/24 , C07D333/28 , A07N43/56
CPC分类号： C07D213/12 , A01N31/08 , A01N31/14 , A01N33/10 , A01N37/08 , A01N37/34 , A01N41/10 , A01N43/08 , A01N43/10 , A01N43/40 , A01N43/54 , A01N43/56 , A01N43/653 , A01N43/76 , A01N43/78 , A01N47/18 , C07C317/32 , C07C317/48 , C07C323/18 , C07C323/20 , C07C323/36 , C07C323/63 , C07D213/32 , C07D213/48 , C07D213/57 , C07D213/64 , C07D239/36 , C07D239/38 , C07D239/40 , C07D249/08 , C07D333/24
摘要： 3-Arylphenyl sulfide derivatives represented by general formula (I): (wherein R is a C2-C6 alkyl group, a C2-C6 alkenyl group, a C2-C6 alkynyl group or the like, B0 to B2 and B3 are hydrogen atoms, halogen atoms, cyano groups, C1-C4 haloalkyl groups or the like, n is 0, 1 or 2, and Ar is a phenyl ring, a pyridine ring, a thiophene ring, a pyrazole ring or the like), and insecticides and miticides containing the 3-arylphenyl sulfide derivatives as an active ingredient.
摘要翻译：由通式（I）表示的3-芳基苯基硫醚衍生物:(其中R为C2-C6烷基，C2-C6烯基，C2-C6炔基等，B0至B2和B3为氢原子，卤素原子，氰基，C 1〜C 4卤代烷基等，n为0,1或2，Ar为苯环，吡啶环，噻吩环，吡唑环等），杀虫剂和杀螨剂含有3-芳基苯基硫醚衍生物作为活性成分。

6. 发明授权

US07767626B2 3-arylphenyl sulfide derivative and insecticide and miticide 有权
标题翻译： 3-芳基苯基硫化物衍生物和杀虫剂和杀螨剂
公开(公告)号：US07767626B2
公开(公告)日：2010-08-03
申请号：US12269549
申请日：2008-11-12
申请人： Keiji Toriyabe , Nobuo Takefuji , Minoru Itou , Tetsuya Hirade , Kiyotoshi Nishiyama , Mitsuharu Asahida , Yasunobu Maeda , Nobuhide Wada , Toyokazu Fujisawa , Hiroyuki Yano , Masaaki Komatsu , Osamu Tada
发明人： Keiji Toriyabe , Nobuo Takefuji , Minoru Itou , Tetsuya Hirade , Kiyotoshi Nishiyama , Mitsuharu Asahida , Yasunobu Maeda , Nobuhide Wada , Toyokazu Fujisawa , Hiroyuki Yano , Masaaki Komatsu , Osamu Tada
IPC分类号： C07D333/08 , A01N43/00
CPC分类号： C07D213/12 , A01N31/08 , A01N31/14 , A01N33/10 , A01N37/08 , A01N37/34 , A01N41/10 , A01N43/08 , A01N43/10 , A01N43/40 , A01N43/54 , A01N43/56 , A01N43/653 , A01N43/76 , A01N43/78 , A01N47/18 , C07C317/32 , C07C317/48 , C07C323/18 , C07C323/20 , C07C323/36 , C07C323/63 , C07D213/32 , C07D213/48 , C07D213/57 , C07D213/64 , C07D239/36 , C07D239/38 , C07D239/40 , C07D249/08 , C07D333/24
摘要： 3-Arylphenyl sulfide derivatives represented by general formula (I): (wherein R is a C2-C6 alkyl group, a C2-C6 alkenyl group, a C2-C6 alkynyl group or the like, B0 to B2 and B3 are hydrogen atoms, halogen atoms, cyano groups, C1-C4 haloalkyl groups or the like, n is 0, 1 or 2, and Ar is a phenyl ring, a pyridine ring, a thiophene ring, a pyrazole ring or the like), and insecticides and miticides containing the 3-arylphenyl sulfide derivatives as an active ingredient.
摘要翻译：由通式（I）表示的3-芳基苯基硫醚衍生物：其中R为C2-C6烷基，C2-C6烯基，C2-C6炔基等，B0至B2和B3为氢原子，卤素原子，氰基，C 1〜C 4卤代烷基等，n为0,1或2，Ar为苯环，吡啶环，噻吩环，吡唑环等），杀虫剂和杀螨剂含有3-芳基苯基硫醚衍生物作为活性成分。

7. 发明授权

US07612105B2 3-arylphenyl sulfide derivative and insecticide and miticide 有权
标题翻译： 3-芳基苯基硫化物衍生物和杀虫剂和杀螨剂
公开(公告)号：US07612105B2
公开(公告)日：2009-11-03
申请号：US11098440
申请日：2005-04-05
申请人： Keiji Toriyabe , Nobuo Takefuji , Minoru Itou , Tetsuya Hirade , Kiyotoshi Nishiyama , Mitsuharu Asahida , Yasunobu Maeda , Nobuhide Wada , Toyokazu Fujisawa , Hiroyuki Yano , Masaaki Komatsu , Osamu Tada
发明人： Keiji Toriyabe , Nobuo Takefuji , Minoru Itou , Tetsuya Hirade , Kiyotoshi Nishiyama , Mitsuharu Asahida , Yasunobu Maeda , Nobuhide Wada , Toyokazu Fujisawa , Hiroyuki Yano , Masaaki Komatsu , Osamu Tada
IPC分类号： A01N43/653 , C07D249/08
CPC分类号： C07D213/12 , A01N31/08 , A01N31/14 , A01N33/10 , A01N37/08 , A01N37/34 , A01N41/10 , A01N43/08 , A01N43/10 , A01N43/40 , A01N43/54 , A01N43/56 , A01N43/653 , A01N43/76 , A01N43/78 , A01N47/18 , C07C317/32 , C07C317/48 , C07C323/18 , C07C323/20 , C07C323/36 , C07C323/63 , C07D213/32 , C07D213/48 , C07D213/57 , C07D213/64 , C07D239/36 , C07D239/38 , C07D239/40 , C07D249/08 , C07D333/24
摘要： 3-Arylphenyl sulfide derivatives represented by general formula (I): (wherein R is a C2-C6 alkyl group, a C2-C6 alkenyl group, a C2-C6 alkynyl group or the like, B0 to B2 and B3 are hydrogen atoms, halogen atoms, cyano groups, C1-C4 haloalkyl groups or the like, n is 0, 1 or 2, and Ar is a phenyl ring, a pyridine ring, a thiophene ring, a pyrazole ring or the like), and insecticides and miticides containing the 3-arylphenyl sulfide derivatives as an active ingredient.
摘要翻译：由通式（I）表示的3-芳基苯基硫醚衍生物：其中R为C2-C6烷基，C2-C6烯基，C2-C6炔基等，B0至B2和B3为氢原子，卤素原子，氰基，C 1〜C 4卤代烷基等，n为0,1或2，Ar为苯环，吡啶环，噻吩环，吡唑环等），杀虫剂和杀螨剂含有3-芳基苯基硫醚衍生物作为活性成分。

8. 发明授权

US07037930B2 3-arylphenyl sulfide derivative and insecticide and miticide 有权
标题翻译： 3-芳基苯基硫化物衍生物和杀虫剂和杀螨剂
公开(公告)号：US07037930B2
公开(公告)日：2006-05-02
申请号：US10981722
申请日：2004-11-05
申请人： Keiji Toriyabe , Nobuo Takefuji , Minoru Itou , Tetsuya Hirade , Kiyotoshi Nishiyama , Mitsuharu Asahida , Yasunobu Maeda , Nobuhide Wada , Toyokazu Fujisawa , Hiroyuki Yano , Masaaki Komatsu , Osamu Tada
发明人： Keiji Toriyabe , Nobuo Takefuji , Minoru Itou , Tetsuya Hirade , Kiyotoshi Nishiyama , Mitsuharu Asahida , Yasunobu Maeda , Nobuhide Wada , Toyokazu Fujisawa , Hiroyuki Yano , Masaaki Komatsu , Osamu Tada
IPC分类号： A01N43/653 , C07D249/08
CPC分类号： C07D213/12 , A01N31/08 , A01N31/14 , A01N33/10 , A01N37/08 , A01N37/34 , A01N41/10 , A01N43/08 , A01N43/10 , A01N43/40 , A01N43/54 , A01N43/56 , A01N43/653 , A01N43/76 , A01N43/78 , A01N47/18 , C07C317/32 , C07C317/48 , C07C323/18 , C07C323/20 , C07C323/36 , C07C323/63 , C07D213/32 , C07D213/48 , C07D213/57 , C07D213/64 , C07D239/36 , C07D239/38 , C07D239/40 , C07D249/08 , C07D333/24
摘要： 3-Arylphenyl sulfide derivatives represented by general formula (I): (wherein R is a C2-C6 alkyl group, a C2-C6 alkenyl group, a C2-C6 alkynyl group or the like, B0 to B2 and B3 are hydrogen atoms, halogen atoms, cyano groups, C1-C4 haloalkyl groups or the like, n is 0, 1 or 2, and Ar is a phenyl ring, a pyridine ring, a thiophene ring, a pyrazole ring or the like), and insecticides and miticides containing the 3-arylphenyl sulfide derivatives as an active ingredient.
摘要翻译：由通式（I）表示的3-芳基苯基硫醚衍生物：其中R是C 2 -C 6烷基，C 2 - -C 6亚烷基，C 2 -C 6亚炔基等，B 0〜B 2个和3个3个是氢原子，卤素原子，氰基，C 1 -C 4卤代烷基或 n为0,1或2，Ar为苯环，吡啶环，噻吩环，吡唑环等），含有3-芳基苯基硫醚衍生物的杀虫剂和杀螨剂为活性成分。

9. 发明授权

US06225505B1 Trifluoro methylthiomethyl benzene derivatives and process for production same 有权
标题翻译：三氟甲基硫代甲基苯衍生物和生产方法相同
公开(公告)号：US06225505B1
公开(公告)日：2001-05-01
申请号：US09463845
申请日：2000-02-01
申请人： Yoshikazu Kimura , Hidetaka Hiyoshi , Keiji Toriyabe , Nobuhide Wada
发明人： Yoshikazu Kimura , Hidetaka Hiyoshi , Keiji Toriyabe , Nobuhide Wada
IPC分类号： C07C31914
CPC分类号： C07C319/14 , C07C323/07 , C07C323/22 , C07C323/56 , C07C323/60
摘要： The present invention lies in a process for producing a trifluoromethylthiomethylbenzene derivative represented by the following general formula (2): (wherein R is a hydrogen atom, a halogen atom, an alkyl group, an alkoxy group, an alkoxycarbonyl group, a cyano group, a nitro group, or a benzoyl group which may be substituted with halogen atom, alkyl group, alkoxy group, aliphatic or aromatic acyl group, nitro group, cyano group or alkoxycarbonyl group; n is an integer of 1 to 5; when n is an integer of 2 or more, a plurality of R's may be the same of each independently different), which process comprises reacting, in acetonitrile, a benzyl halide derivative represented by the following general formula (1): (wherein R and n have the same definitions as given above; and X is a halogen atom, an alkylsulfonyloxy group or an arylsulfonyloxy group which may be substituted with alkyl group or halogen atom) with thiophosgene and potassium fluoride.
摘要翻译：本发明在于制备由以下通式（2）表示的三氟甲硫基甲基苯衍生物的方法：其中R是氢原子，卤素原子，烷基，烷氧基，烷氧基羰基，氰基，硝基或可被卤素原子，烷基，烷氧基，脂肪族或芳香族酰基，硝基，氰基或烷氧基羰基取代的苯甲酰基，n为1〜5的整数，n为1〜5的整数， 2个以上的整数，多个R可以各自独立地不同），该方法包括在乙腈中使由以下通式（1）表示的苄基卤衍生物:(其中R和n具有相同的定义如上所述; X为卤素原子，烷基磺酰氧基或可被烷基或卤原子取代的芳基磺酰氧基）与硫光气和氟化钾反应。

10. 发明授权

US08729116B2 Triazole compound having pesticidal activities 有权
标题翻译：具有杀虫活性的三唑化合物
公开(公告)号：US08729116B2
公开(公告)日：2014-05-20
申请号：US13642972
申请日：2011-05-27
申请人： Keiji Toriyabe , Jun Inoue , Masaaki Komatsu
发明人： Keiji Toriyabe , Jun Inoue , Masaaki Komatsu
IPC分类号： A61K31/4196 , C07D249/08
CPC分类号： C07D249/14 , A01N43/653 , C07B57/00
摘要： To provide a triazole compound which has remarkably excellent pesticidal activities. Optically active (+)-1-[2-fluoro-4-methyl-5-(2,2,2-trifluoroethylsulfinyl)phenyl]-5-amino-3-(trifluoromethyl)-1H-1,2,4-triazole represented by the following formula (I), which is obtainable by subjecting a racemic modification of 1-[2-fluoro-4-methyl-5-(2,2,2-trifluoroethylsulfinyl)phenyl]-5-amino-3-(trifluoromethyl)-1H-1,2,4-triazole to optical resolution:
摘要翻译：提供具有非常优异的杀虫活性的三唑化合物。光学活性（+） - 1- [2-氟-4-甲基-5-（2,2,2-三氟乙基亚磺酰基）苯基] -5-氨基-3-（三氟甲基）-1H-1,2,4-三唑由下式（I）表示，其可通过对1- [2-氟-4-甲基-5-（2,2,2-三氟乙基亚磺酰基）苯基] -5-氨基-3-（三氟甲基）-1H-1,2,4-三唑至光学拆分：

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