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    • 3. 发明授权
    • Heat-resisting aromatic polyester resin and process for preparing the
same
    • 耐热芳香族聚酯树脂及其制备方法
    • US4426511A
    • 1984-01-17
    • US313670
    • 1981-10-21
    • Masahiro AsadaMiyuki MatsuuraKazuya Yonezawa
    • Masahiro AsadaMiyuki MatsuuraKazuya Yonezawa
    • C08G63/00C08G63/19C08G63/66C08G63/68C08G63/688C08G63/87C08G63/18
    • C08G63/19C08G63/6886C08G63/87
    • A heat resisting aromatic polyester resin comprising (a) recurring units of the formula (I): ##STR1## wherein X is a bivalent group selected from the group consisting of an unsubstituted or substituted bivalent hydrocarbon group having 1 to 10 carbon atoms,--O--, --S--, --SO.sub.2 --and--CO--, and (b) recurring units of the formula (II): ##STR2## wherein X is as defined above, R and R' are a group selected from the group consisting of alkyl, aryl, aralkyl, alkoxyl, aryloxyl and phenylalkoxyl groups having 1 to 20 carbon atoms, their substituted groups, a halogen atom and a mixture thereof, p+q=1 to 8, and m and n are 0 or 1, but n is not 0 when m is 1, provided that up to 10% by mole of the total of the units: ##STR3## in the formulas (I) and (II) may be replaced with units: ##STR4## the ratio of (a)/[(a)+(b)]being from 0.05 to 0.95 by mole. The polyester resin is substantially amorphous and soluble in some organic solvents, and has an excellent heat resistance. The polyester resin is prepared by reacting terephthaloyl chloride with alkali metal salts of at least two kinds of particular bivalent phenolic compounds in the presence of a phase transfer catalyst.
    • 一种耐热性芳族聚酯树脂,其包含(a)式(I)的重复单元:其中X是选自未取代或取代的具有1-10个碳原子的二价烃基的二价基团 ,-O - , - S - , - SO 2 - 和-CO-,和(b)式(II)的重复单元:其中X如上所定义,R和R' 选自具有1至20个碳原子的烷基,芳基,芳烷基,烷氧基,芳氧基和苯基烷氧基,其取代基,卤素原子及其混合物,p + q = 1-8,m和n分别为 0或1,但当m为1时,n不为0,只要式(I)和(II)中的总数高达10摩尔%,则可以用单位代替: