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1. 发明授权

US5968994A High strength porous film of polypropylene and process for producing same 失效
标题翻译：聚丙烯的高强度多孔膜及其制造方法
公开(公告)号：US5968994A
公开(公告)日：1999-10-19
申请号：US837726
申请日：1997-04-22
申请人： Akinao Hashimoto , Kazuo Yagi , Hitoshi Mantoku
发明人： Akinao Hashimoto , Kazuo Yagi , Hitoshi Mantoku
IPC分类号： C08J9/00 , B29C55/00 , B29C55/12 , B29C55/28 , B29K23/00 , B29K105/04 , B29L7/00 , C08J5/18 , B29C49/08
CPC分类号： C08J5/18 , B29C55/005 , B29K2023/12 , B29K2105/04 , C08J2323/12 , Y10T428/249978
摘要： A process for producing a porous film of polypropylene comprises subjecting (1) an air-impermeable biaxially stretched film of polypropylene resin comprised predominantly of polypropylene having a crystallinity of at least 40% or (2) an air-impermeable inflation film of polypropylene resin comprised predominantly of polypropylene having a crystallinity of at least 46.5%, in the substantial absence of a plasticizer or a solvent, to a thermal treatment in the presence of a first liquid substantially incapable of dissolving the film while fixing the film in two orthogonal directions for making the film porous.
摘要翻译：制造聚丙烯多孔膜的方法包括：（1）主要由结晶度至少为40％的聚丙烯组成的聚丙烯树脂的不透气双轴拉伸膜，或（2）包含聚丙烯树脂的不透气膨胀膜主要是在基本上不存在增塑剂或溶剂的情况下，具有至少46.5％的结晶度的聚丙烯在基本上不能溶解薄膜的第一液体的存在下进行热处理，同时在两个正交方向上固定薄膜薄膜多孔。

2. 发明授权

US6048607A Porous film of high molecular weight polyolefin and process for producing same 失效
标题翻译：高分子量聚烯烃多孔薄膜及其制造方法
公开(公告)号：US6048607A
公开(公告)日：2000-04-11
申请号：US972449
申请日：1997-11-18
申请人： Akinao Hashimoto , Kazuo Yagi , Hitoshi Mantoku
发明人： Akinao Hashimoto , Kazuo Yagi , Hitoshi Mantoku
IPC分类号： B29C47/24 , B29C55/00 , B29C71/02 , C08J5/18 , H01M2/16 , B32B27/32
CPC分类号： C08J5/18 , B29C47/0026 , B29C47/24 , B29C55/005 , B29C71/02 , H01M2/1653 , B29K2023/00 , B29K2105/04 , C08J2323/02 , C08J2323/04 , Y10S521/918
摘要： The present invention relates to a porous or microporous film of a high molecular weight polyolefin excellent in strength and air-permeability and suitable for use in filtering materials, separators for aqueous electrolyte batteries, separator films for batteries, separator films for electrolytic capacitors, and air-permeable films; for moisture-permeable water-proof use such as paper diapers and house-wrapping films; and for other uses such as cloths, package and printing, as well as a process for producing same. The feature of the present invention resides in an aspect that the film is composed of fibrils comprising extended-chain crystals and lamellar crystals and/or fibrils comprising helicoidal crystals.This porous film of a high molecular weight polyolefin is produced by subjecting an air-impermeable film of a high molecular weight polyolefin to thermal treatment followed by, if necessary, a stretching treatment and/or a thermosetting treatment.
摘要翻译：本发明涉及高分子量聚烯烃的多孔或微孔膜，其强度和透气性优异，适用于过滤材料，水性电解质电池用隔膜，电池用隔膜，电解电容器用隔膜和空气不透水膜用于透湿防水用途，如纸尿布和房屋包装膜; 以及其他用途如布，包装和印刷，以及其制造方法。本发明的特征在于该膜由包含延伸链晶体和层状晶体的原纤维和/或包含螺旋晶体的原纤维构成。高分子量聚烯烃的多孔膜通过对高分子量聚烯烃的不透气膜进行热处理，如果需要，进行拉伸处理和/或热固化处理来制造。

3. 发明授权

US4870136A Molecular oriented, silane-crosslinked ultra-high-molecular-weight polyethylene molded article and process for preparation thereof 失效
标题翻译：分子取向，硅烷交联的超高分子量聚乙烯模塑制品及其制备方法
公开(公告)号：US4870136A
公开(公告)日：1989-09-26
申请号：US934701
申请日：1986-11-25
申请人： Kazuo Yagi , Hitoshi Mantoku
发明人： Kazuo Yagi , Hitoshi Mantoku
IPC分类号： C08F255/02 , C08L23/06 , C08L43/04 , D01F6/04 , D01F11/06
CPC分类号： C08F255/02 , C08L23/06 , C08L43/04 , D01F11/06 , D01F6/04 , C08L2207/068 , C08L2312/08 , C08L51/06 , C08L91/00
摘要： If ultra-high-molecular-weight polyethylene having an intrinsic viscosity (.eta.) of at least 5 dl/g is grafted with a silane compound in the presence of a radical initiator and extrusion-molded and the extrudate is impregnated with a silanol condensation catalyst after or during drawing and is then exposed to water to effect crosslinking, there is obtained a novel molecularly oriented molded articles in which increase of the melting temperature, which is not observed in conventional draw-molded or crosslinked molded articles of polyethylene, can be attained, and even if this molecularly oriented molded article is exposed to a temperature of 180.degree. C. for 10 minutes, the molded article is not fused but the shape is retained and even after this heat history, a high strength retention ratio can be maintained. In this draw-molded article, the adhesiveness and creep resistance are prominently improved while high elastic modulus and high tensile strength inherent to a draw-molded article of ultra-high-molecular-weight polyethylene are retained.
摘要翻译：如果特性粘度（η）至少为5dl / g的超高分子量聚乙烯在自由基引发剂的存在下用硅烷化合物接枝并挤出成型，挤出物用硅烷醇缩合催化剂在拉伸之后或之后，然后暴露于水以进行交联，得到新的分子取向模制品，其中可以获得在常规的拉伸模制或交联的聚乙烯模制品中未观察到的熔融温度的升高即使将该分子取向成型体在180℃的温度下暴露10分钟，也不会熔融成型制品，但是保持其形状，即使在该热历史之后，也能够保持高强度保持率。在该拉伸成型品中，保持了超高分子量聚乙烯的拉伸成形品固有的高弹性模量和高拉伸强度，显着提高了粘合性和抗蠕变性。

4. 发明授权

US5882518A Microporous film of high molecular weight polyolefin and process for producing same 失效
标题翻译：高分子量聚烯烃微孔薄膜及其制造方法
公开(公告)号：US5882518A
公开(公告)日：1999-03-16
申请号：US683221
申请日：1996-07-18
申请人： Kazuo Yagi , Hitoshi Mantoku , Akinao Hashimoto
发明人： Kazuo Yagi , Hitoshi Mantoku , Akinao Hashimoto
IPC分类号： B01D67/00 , B01D71/26 , B29C55/00 , B29C71/02 , C08J5/18 , B01D39/00
CPC分类号： C08J5/18 , B01D67/0023 , B01D67/0027 , B01D71/26 , B29C55/005 , B29C71/02 , B01D2323/06 , B01D2325/20 , B01D2325/24 , B01D2325/40 , B29K2023/0683 , B29K2105/04 , B29K2995/0041 , B29K2995/0053 , C08J2323/00
摘要： A microporous film of high molecular weight polyolefin useful in the prepration of filter mediums or non-aqueous battery separators and a process for producing the film are disclosed. The microporous film of high molecular weight polyolefin contains leaf vein-like fibrils as a main constituent on each of which fibrils indeterminate-form crystallites of not more than 1 .mu.m in size flocculate and has an intrinsic viscosity, �.eta.!, of 4 dl/g or more and, preferably, has:(a) a void content of 25% or more;(b) a gas permeability of 1900 sec/100 cc or less;(c) a tensile strength of 0.05 GPa or more; and(d) a gas impermeability-acquiring temperature of 140.degree. C. or lower. The microporous film is produced by subjecting a high molecular weight, biaxially oriented polyolefin film of 60% or more in crystallinity to a heat treatment and, if necessary, to a stretch treatment to thereby melt or dissolve the indeterminate-form portion of the film, then crystallizing it onto the fibrils as crystallites.
摘要翻译：公开了一种用于制备过滤介质或非水电池隔板的高分子量聚烯烃微孔薄膜及其制造方法。高分子量聚烯烃的微多孔膜含有叶静脉状原纤维作为主要成分，其中每种原纤维不确定形式的微晶尺寸不大于1μm，其絮凝物的特性粘度η为4dl g以上，优选具有：（a）25％以上的空隙率; （b）1900秒/ 100cc以下的透气度; （c）抗张强度为0.05GPa以上; 和（d）140℃以下的不透气性获取温度。微孔膜是通过对结晶度为60％以上的高分子量双轴取向聚烯烃膜进行热处理而制成的，如果需要，进行拉伸处理，从而熔融或溶解膜的不定形部分，然后将其结晶到原纤维上作为微晶。

5. 发明授权

US4902460A Process for preparation of molecularly oriented, silane-crosslinked ultra-high-molecular-weight polyethylene molded article 失效
标题翻译：制备分子取向硅烷交联超高分子量聚乙烯模塑制品的方法
公开(公告)号：US4902460A
公开(公告)日：1990-02-20
申请号：US181698
申请日：1988-04-14
申请人： Kazuo Yagi , Hitoshi Mantoku
发明人： Kazuo Yagi , Hitoshi Mantoku
IPC分类号： C08F255/02 , C08L23/06 , C08L43/04 , D01F6/04 , D01F11/06
CPC分类号： C08F255/02 , C08L23/06 , C08L43/04 , D01F11/06 , D01F6/04 , C08L2207/068 , C08L2312/08 , C08L51/06 , C08L91/00
摘要： If ultra-high-molecular-weight polyethylene having an intrinsic viscosity (.beta.) of at least 5 dl/g is grafted with a silane compound in the presence of a radical initiator and extrusion-molded and the extrudate is impregnated with a silanol condensation catalyst after or during drawing and is then exposed to water to effect crosslinking, there is obtained a novel molecularly oriented molded article in which increase of the melting temperature, which is not observed in conventional drawmolded or crosslinked molded articles of polyethylene, can be attained, and even if this molecularly oriented molded article is exposed to a temperature of 180.degree. C. for 10 minutes, the molded article is not fused but the shape is retained and even after this heat history, a high strength retention ratio can be maintained. In this draw-molded article, the adhesiveness and creep resistance are prominently improved while high elastic modulus and high tensile strength inherent to a drawmolded article of ultra-high-molecular-weight polyethylene are retained.

6. 发明授权

US5840235A Biaxially oriented film of high molecular weight polyethylene, process for preparing the same, surface-modified biaxially oriented film of high molecular weight polyethylene and process for preparing the same 失效
标题翻译：高分子量聚乙烯双轴取向薄膜，其制备方法，高分子量聚乙烯的表面改性双轴取向薄膜及其制备方法
公开(公告)号：US5840235A
公开(公告)日：1998-11-24
申请号：US920882
申请日：1997-08-29
申请人： Kazuo Yagi , Hitoshi Mantoku , Akinao Hashimoto , Isaburo Higashi , Yoshinori Akana
发明人： Kazuo Yagi , Hitoshi Mantoku , Akinao Hashimoto , Isaburo Higashi , Yoshinori Akana
IPC分类号： B01D39/16 , B01D67/00 , B01D69/02 , B01D71/26 , B29C55/00 , B29C55/12 , B29C59/00 , C08J5/18 , C08J9/00 , D02J1/06
CPC分类号： C08J5/18 , B01D39/1661 , B01D39/1692 , B01D67/0027 , B01D67/003 , B01D67/009 , B01D67/0093 , B01D69/02 , B01D71/26 , B29C55/005 , B29C55/12 , B01D2323/06 , B01D2323/08 , B01D2323/20 , B01D2323/34 , B29C59/00 , B29K2023/0683 , C08J2323/04 , Y10S264/47
摘要： Biaxially oriented films from high molecular weight polyethylene are characterized by a gas permeable structure formed from random-arranged microfibrils. The films have coefficients of static friction and kinetic friction of not more than 1.0. The biaxially oriented films are further characterized by service smoothness as well as tensile (tangent) modulus and tensile strength. The films may be used for lamination, filter, or for packaging for moisture absorbers. The biaxially oriented films may be obtained by extracting a hydrocarbon plasticizer from a sheet formed from the high molecular weight polyethylene and a hydrocarbon plasticizer, stretching the resulting sheet to obtain an oriented film having a specific surface area of at least 70 m.sup.2 /g and a fibril structure, and heating the oriented film under a standard length constraint to reduce the oriented film in specific area by at least 20 m.sup.2 /g.
摘要翻译：来自高分子量聚乙烯的双轴取向膜的特征在于由随机排列的微原纤维形成的透气结构。该膜具有不大于1.0的静摩擦系数和动摩擦系数。双轴取向膜的特征还在于维护平滑度以及拉伸（切线）模量和拉伸强度。膜可用于层压，过滤或用于吸湿剂的包装。双轴取向膜可以通过从由高分子量聚乙烯和烃类增塑剂形成的片材中提取烃增塑剂，拉伸得到的片材，得到比表面积为70m 2 / g以上的取向膜，原纤维结构，并且在标准长度约束条件下加热定向膜以将特定面积中的定向膜减少至少20m 2 / g。

7. 发明授权

US5650451A Biaxially oriented film of high molecular weight polyethylene, process for preparing the same, surface modified biaxially oriented film of high molecular weight polyethylene and process for preparing the same 失效
标题翻译：高分子量聚乙烯的双轴取向膜，其制备方法，高分子量聚乙烯的表面改性双轴取向膜及其制备方法
公开(公告)号：US5650451A
公开(公告)日：1997-07-22
申请号：US661149
申请日：1996-06-10
申请人： Kazuo Yagi , Hitoshi Mantoku , Akinao Hashimoto , Isaburo Higashi , Yoshinori Akana
发明人： Kazuo Yagi , Hitoshi Mantoku , Akinao Hashimoto , Isaburo Higashi , Yoshinori Akana
IPC分类号： B01D39/16 , B01D67/00 , B01D69/02 , B01D71/26 , B29C55/00 , B29C55/12 , B29C59/00 , C08J5/18 , C08F110/02
CPC分类号： C08J5/18 , B01D39/1661 , B01D39/1692 , B01D67/0027 , B01D67/003 , B01D67/009 , B01D67/0093 , B01D69/02 , B01D71/26 , B29C55/005 , B29C55/12 , B01D2323/06 , B01D2323/08 , B01D2323/20 , B01D2323/34 , B29C59/00 , B29K2023/0683 , C08J2323/04 , Y10S264/47
摘要： Biaxially oriented films from high molecular weight polyethylene are characterized by a gas permeable structure formed from random-arranged microfibrils. The films have coefficients of static friction and kinetic friction of not more than 1.0. The biaxially oriented films are further characterized by service smoothness as well as tensile (tangent) modulus and tensile strength. The films may be used for lamination, filter, or for packaging for moisture absorbers. The biaxially oriented films may be obtained by extracting a hydrocarbon plasticizer from a sheet formed from the high molecular weight polyethylene and a hydrocarbon plasticizer, stretching the resulting sheet to obtain an oriented film having a specific surface area of at least 70 m.sup.2 /g and a fibril structure, and heating the oriented film under a standard length constraint to reduce the oriented film in specific area by at least 20 m.sup.2 /g.
摘要翻译：来自高分子量聚乙烯的双轴取向膜的特征在于由随机排列的微原纤维形成的透气结构。该膜具有不大于1.0的静摩擦系数和动摩擦系数。双轴取向膜的特征还在于维护平滑度以及拉伸（切线）模量和拉伸强度。膜可用于层压，过滤或用于吸湿剂的包装。双轴取向膜可以通过从由高分子量聚乙烯和烃类增塑剂形成的片材中提取烃增塑剂，拉伸得到的片材，得到比表面积为70m 2 / g以上的取向膜，原纤维结构，并且在标准长度约束条件下加热定向膜以将特定面积中的定向膜减少至少20m 2 / g。

8. 发明授权

US5948519A Porous biaxially-oriented film comprising high molecular ethylene/.alpha.-olefin copolymer and its use 失效
标题翻译：包含高分子乙烯/α-烯烃共聚物的多孔双轴取向膜及其用途
公开(公告)号：US5948519A
公开(公告)日：1999-09-07
申请号：US740365
申请日：1996-10-28
申请人： Kazuo Yagi , Akinao Hashimoto , Hitoshi Mantoku
发明人： Kazuo Yagi , Akinao Hashimoto , Hitoshi Mantoku
IPC分类号： B01D71/26 , B01D67/00 , B29C55/00 , C08J5/18 , C08J9/00 , C08J9/26 , H01M2/16 , B32B3/26
CPC分类号： H01M2/1653 , B01D67/0027 , B01D71/76 , B29C55/005 , C08J5/18 , C08J9/26 , B01D2323/08 , B01D2323/20 , B01D2325/20 , B01D71/26 , B29K2023/0683 , B29K2105/04 , C08J2201/042 , C08J2323/16 , Y10T428/249953 , Y10T428/249958 , Y10T428/249979 , Y10T428/249981 , Y10T428/249987 , Y10T428/249993
摘要： A porous biaxially oriented film comprising a copolymer of an ethylene having an intrinsic viscosity �.eta.! of from 3.5 to 10.0 dl/g and an .alpha.-olefin having 4 to 8 carbon atoms, the content of the .alpha.-olefin being in a number of from 1.0 to 7.5 per 1000 carbon atoms and the film retaining the structure which is based upon the microfibrils when it is heat-treated at 160.degree. C. under a constrained state and is then observed at room temperature, and a separator made of this film for batteries. The porous biaxially oriented film exhibits excellent gas permeating property over a practicable temperature range, exhibits excellent mechanical strength and, particularly, tensile strength, and loses gas permeating property when a maximum practicable temperature is exceeded. The film can be favorably used as a separator for batteries.
摘要翻译：一种多孔双轴取向膜，其包含特性粘度η为3.5至10.0dl / g的乙烯和具有4至8个碳原子的α-烯烃的共聚物，所述α-烯烃的含量为多个 1.0〜7.5 / 1000个碳原子，并且当在约束状态下在160℃下进行热处理时，该膜保留基于微原纤维的结构，然后在室温下观察，并由该膜形成的隔板用于电池。多孔双轴取向膜在可行的温度范围内表现出优异的气体渗透性，表现出优异的机械强度，特别是拉伸强度，并且当超过最大可行温度时，失去气体渗透性能。该膜可以有利地用作电池的隔膜。

9. 发明授权

US5674919A Biaxially oriented film of high molecular weight polyethylene, process for preparing the same, surface-modified biaxially oriented film of high molecular weight polyethylene and process for preparing the same 失效
标题翻译：高分子量聚乙烯双轴取向薄膜，其制备方法，高分子量聚乙烯的表面改性双轴取向薄膜及其制备方法
公开(公告)号：US5674919A
公开(公告)日：1997-10-07
申请号：US463369
申请日：1995-06-05
申请人： Kazuo Yagi , Hitoshi Mantoku , Akinao Hashimoto , Isaburo Higashi , Yoshinori Akana
发明人： Kazuo Yagi , Hitoshi Mantoku , Akinao Hashimoto , Isaburo Higashi , Yoshinori Akana
IPC分类号： B01D39/16 , B01D67/00 , B01D69/02 , B01D71/26 , B29C55/00 , B29C55/12 , B29C59/00 , C08J5/18 , C08F110/02 , C08J9/00
CPC分类号： C08J5/18 , B01D39/1661 , B01D39/1692 , B01D67/0027 , B01D67/003 , B01D67/009 , B01D67/0093 , B01D69/02 , B01D71/26 , B29C55/005 , B29C55/12 , B01D2323/06 , B01D2323/08 , B01D2323/20 , B01D2323/34 , B29C59/00 , B29K2023/0683 , C08J2323/04 , Y10S264/47
摘要： Biaxially oriented films from high molecular weight polyethylene are characterized by a gas permeable structure formed from random-arranged microfibrils. The films have coefficients of static friction and kinetic friction of not more than 1.0. The biaxially oriented films are further characterized by service smoothness as well as tensile (tangent) modulus and tensile strength. The films may be used for lamination, filter, or for packaging for moisture absorbers. The biaxially oriented films may be obtained by extracting a hydrocarbon plasticizer from a sheet formed from the high molecular weight polyethylene and a hydrocarbon plasticizer, stretching the resulting sheet to obtain an oriented film having a specific surface area of at least 70 m.sup.2 /g and a fibril structure, and heating the oriented film under a standard length constraint to reduce the oriented film in specific area by at least 20 m.sup.2 /g.
摘要翻译：来自高分子量聚乙烯的双轴取向膜的特征在于由随机排列的微原纤维形成的透气结构。该膜具有不大于1.0的静摩擦系数和动摩擦系数。双轴取向膜的特征还在于维护平滑度以及拉伸（切线）模量和拉伸强度。膜可用于层压，过滤或用于吸湿剂的包装。双轴取向膜可以通过从由高分子量聚乙烯和烃类增塑剂形成的片材中提取烃增塑剂，拉伸得到的片材，得到比表面积为70m 2 / g以上的取向膜，原纤维结构，并且在标准长度约束条件下加热定向膜以将特定面积中的定向膜减少至少20m 2 / g。

10. 发明授权

US5624627A Process for preparing surface-modified biaxially oriented film of high molecular weight polyethylene 失效
标题翻译：制备高分子量聚乙烯表面改性双轴取向薄膜的方法
公开(公告)号：US5624627A
公开(公告)日：1997-04-29
申请号：US461949
申请日：1995-06-05
申请人： Kazuo Yagi , Hitoshi Mantoku , Akinao Hashimoto , Isaburo Higashi , Yoshinori Akana
发明人： Kazuo Yagi , Hitoshi Mantoku , Akinao Hashimoto , Isaburo Higashi , Yoshinori Akana
IPC分类号： B01D39/16 , B01D67/00 , B01D69/02 , B01D71/26 , B29C55/00 , B29C55/12 , B29C59/00 , C08J5/18 , B29C35/10 , B29C71/04
CPC分类号： C08J5/18 , B01D39/1661 , B01D39/1692 , B01D67/0027 , B01D67/003 , B01D67/009 , B01D67/0093 , B01D69/02 , B01D71/26 , B29C55/005 , B29C55/12 , B01D2323/06 , B01D2323/08 , B01D2323/20 , B01D2323/34 , B29C59/00 , B29K2023/0683 , C08J2323/04 , Y10S264/47
摘要： The biaxially oriented films of high molecular weight polyethylene is formed and its surface modified to provide a hydrophilic property to the resulting film. The film is prepared by melt-kneading the high molecular weight polyethylene with an ordinarily solid hydrocarbon plasticizer and a raw fabric sheet is formed from the resulting molten mixture. After the hydrocarbon plasticizer is extracted the resulting unstretched sheet is stretched under conditions providing a stretched film having a specific surface area of 70 m.sup.2 /g or more and a fibril structure. This stretched film is then heated under standard length constraint conditions to reduce the specific surface area of the stretched film by at least 20 m.sup.2 /g to obtain a biaxially oriented film of high molecular weight polyethylene. The surface of the film is thereafter subjected to surface modification by polymerizing a vinyl monomer having a hydrophilic group on the surface of the film whereby the film surface becomes hydrophilic, as measured by a contact angle of the film surface to a water drop at a level of not more than 90.degree.. The biaxially oriented films are further characterized by their excellent gas permeability, surface smoothness, tensile modulus and tensile strength.
摘要翻译：形成高分子量聚乙烯的双轴取向薄膜，并将其表面进行改性以提供所得薄膜的亲水性。通过将高分子量聚乙烯与通常的固体烃增塑剂熔融捏合制备膜，并由所得熔融混合物形成原料织物片。在提取烃增塑剂之后，将得到的未拉伸片材在提供比表面积为70m 2 / g以上的拉伸膜和原纤维结构的条件下拉伸。然后将该拉伸膜在标准长度约束条件下加热，以将拉伸膜的比表面积减少至少20m 2 / g，得到高分子量聚乙烯的双轴取向膜。然后通过在膜的表面上聚合具有亲水基团的乙烯基单体来使膜的表面进行表面改性，由此膜表面变为亲水性，通过膜表面与水滴的接触角测量的水平不超过90度。双轴取向膜的特征还在于其优异的透气性，表面光滑度，拉伸模量和拉伸强度。

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