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    • 5. 发明授权
    • Propylene polymer and block copolymer
    • 丙烯聚合物和嵌段共聚物
    • US06545099B2
    • 2003-04-08
    • US09899134
    • 2001-07-06
    • Tetsunori ShinozakiKazumitsu KawakitaMamoru Kioka
    • Tetsunori ShinozakiKazumitsu KawakitaMamoru Kioka
    • C08F29300
    • C08F297/083C08F10/06C08F110/06C08F297/06C08F2500/15C08F2500/09C08F2500/12C08F2500/18C08F2500/26
    • Disclosed are a propylene polymer having a high crystallinity of a boiled heptane-insoluble component contained therein, a high stereoregularity and an extremely long mesochain (continuous propylene units wherein directions of &agr;-methyl carbons are the same as each other), and a process for preparing said polymer. Also disclosed are a propylene block copolymer containing a crystalline polypropylene portion having a high crystallinity of a boiled heptane-insoluble component contained therein, a high stereoregularity and an extremely long mesochain, and a process for preparing said copolymer. Further disclosed is a propylene polymer composition comprising the above propylene polymer or propylene block copolymer and at least one stabilizer selected from a phenol type stabilizer, an organophosphite type stabilizer, a thioether type stabilizer, a hindered amine type stabilizer and a metallic salt of higher aliphatic acid. The propylene polymer of the invention is excellent in rigidity, heat resistance and moisture resistance, and can be favorably used for sheet, film, filament, injection molded product, blow molded product, etc. The propylene block polymer of the invention is well-balanced between rigidity, heat resistance and moisture resistance, and can be favorably used for sheet, filament, injection molded product, blow molded product, etc.
    • 公开了具有高沸点庚烷不溶性组分的高结晶度丙烯聚合物,高立构规整性和极长的分散信号(其中α-甲基碳的方向彼此相同的连续丙烯单元),以及 制备所述聚合物。 还公开了含有其中所含的沸腾庚烷不溶性组分具有高结晶度的结晶聚丙烯部分,高立构规整性和极长的间轴的丙烯嵌段共聚物以及制备所述共聚物的方法。 还公开了一种丙烯聚合物组合物,其包含上述丙烯聚合物或丙烯嵌段共聚物和至少一种选自酚类稳定剂,有机亚磷酸酯类稳定剂,硫醚型稳定剂,受阻胺型稳定剂和高级脂肪族金属盐 酸。 本发明的丙烯聚合物的刚性,耐热性和耐湿性优异,可有利地用于片材,薄膜,长丝,注塑产品,吹塑产品等。本发明的丙烯嵌段聚合物是均衡的 在刚性,耐热性和耐湿性之间,可以有利地用于片材,长丝,注塑产品,吹塑产品等。
    • 6. 发明授权
    • Propylene polymer, propylene block copolymer, process for preparing said polymer and said block copolymer, and propylene polymer composition
    • 丙烯聚合物,丙烯嵌段共聚物,制备所述聚合物和所述嵌段共聚物的方法以及丙烯聚合物组合物
    • US06284857B1
    • 2001-09-04
    • US08351136
    • 1994-11-30
    • Tetsunori ShinozakiKazumitsu KawakitaMamoru Kioka
    • Tetsunori ShinozakiKazumitsu KawakitaMamoru Kioka
    • C08F1006
    • C08F297/083C08F10/06C08F110/06C08F297/06C08F2500/15C08F2500/09C08F2500/12C08F2500/18C08F2500/26
    • Disclosed are a propylene polymer having a high crystallinity of a boiled heptane-insoluble component contained therein, a high stereoregularity and an extremely long mesochain (continuous propylene units wherein directions of &agr;-methyl carbons are the same as each other), and a process for preparing said polymer. Further disclosed is a propylene polymer composition comprising the above propylene polymer and at least one stabilizer selected from a phenol type stabilizer, an organophosphite type stabilizer, a thioether type stabilizer, a hindered amine type stabilizer and a metallic salt of higher aliphatic acid. The propylene polymer of the invention is excellent in rigidity, heat resistance and moisture resistance, and can be favorably used for sheet, film, filament, injection molded product, blow molded product, etc. The propylene polymer composition of the invention has excellent properties of the propylene polymer or the propylene block copolymer, and moreover is excellent in heat stability during the molding stage, long-term heat stability and weathering resistance. The propylene polymer composition can be favorably used for sheet, film, filament, injection molded product, blow molded product, etc.
    • 公开了具有高沸点庚烷不溶性组分的高结晶度丙烯聚合物,高立构规整性和极长的分散信号(其中α-甲基碳的方向彼此相同的连续丙烯单元),以及 制备所述聚合物。 进一步公开的是包含上述丙烯聚合物和至少一种选自酚类稳定剂,有机亚磷酸酯类稳定剂,硫醚型稳定剂,受阻胺型稳定剂和高级脂肪酸的金属盐的稳定剂的丙烯聚合物组合物。 本发明的丙烯聚合物的刚性,耐热性和耐湿性优异,可有利地用于片材,薄膜,长丝,注塑产品,吹塑制品等。本发明的丙烯聚合物组合物具有优异的性能 丙烯聚合物或丙烯嵌段共聚物,并且在成型阶段的热稳定性,长期的热稳定性和耐候性也优异。 丙烯聚合物组合物可有利地用于片材,薄膜,长丝,注塑产品,吹塑产品等。
    • 7. 发明授权
    • Propylene polymer, propylene block copolymer, process for preparing said polymer and said block copolymer, and propylene polymer composition
    • 丙烯聚合物,丙烯嵌段共聚物,制备所述聚合物和所述嵌段共聚物的方法以及丙烯聚合物组合物
    • US06630559B2
    • 2003-10-07
    • US09899135
    • 2001-07-06
    • Tetsunori ShinozakiKazumitsu KawakitaMamoru Kioka
    • Tetsunori ShinozakiKazumitsu KawakitaMamoru Kioka
    • C08F4642
    • C08F297/083C08F10/06C08F110/06C08F297/06C08F2500/15C08F2500/09C08F2500/12C08F2500/18C08F2500/26
    • Disclosed are a propylene polymer having a high crystallinity of a boiled heptane-insoluble component contained therein, a high stereoregularity and an extremely long mesochain (continuous propylene units wherein directions of {acute over (&agr;)}-methyl carbons are the same as each other), and a process for preparing said polymer. Further disclosed is a propylene polymer composition comprising the above propylene polymer and at least one stabilizer selected from a phenol type stabilizer, an organophosphite type stabilizer, a thioether type stabilizer, a hindered amine type stabilizer a metallic salt of higher aliphatic acid. The propylene block polymer of the invention is well-balanced between rigidity, heat resistance and moisture resistance, and can be favorably used for sheet, filament, injection molded product, blow molded product, etc. The propylene polymer composition of the invention has excellent properties of the propylene polymer of or the propylene block copolymer, and moreover is excellent in heat stability during the molding stage, long-term heat stability and weathering resistance. The propylene polymer composition can be favorably used for sheet, film, filament, injection mold product, blow molded product, etc.
    • 公开了具有高沸点庚烷不溶性组分的高结晶度丙烯聚合物,高立构规整性和极长的分散信号(其中α-甲基碳的方向彼此相同的连续丙烯单元),以及 制备所述聚合物。 还公开了包含上述丙烯聚合物和至少一种选自酚类稳定剂,有机亚磷酸酯型稳定剂,硫醚型稳定剂,受阻胺型稳定剂,高级脂肪酸金属盐的稳定剂的丙烯聚合物组合物。 本发明的丙烯嵌段聚合物在刚性,耐热性和耐湿性之间的平衡性良好,可有利地用于片材,长丝,注塑产品,吹塑产品等。本发明的丙烯聚合物组合物具有优异的性能 丙烯嵌段共聚物的丙烯聚合物,而且在成型阶段的热稳定性,长期的热稳定性和耐候性优异。 丙烯聚合物组合物可有利地用于片,膜,丝,注塑产品,吹塑产品等。
    • 8. 发明授权
    • Propylene polymer, propylene block copolymer, process for preparing said polymer and said block copolymer, and propylene polymer composition
    • 丙烯聚合物,丙烯嵌段共聚物,制备所述聚合物和所述嵌段共聚物的方法以及丙烯聚合物组合物
    • US06274678B1
    • 2001-08-14
    • US08351548
    • 1994-12-07
    • Tetsunori ShinozakiKazumitsu KawakitaMamoru Kioka
    • Tetsunori ShinozakiKazumitsu KawakitaMamoru Kioka
    • C08F1006
    • C08F297/083C08F10/06C08F110/06C08F297/06C08F2500/15C08F2500/09C08F2500/12C08F2500/18C08F2500/26
    • Disclosed are a propylene block copolymer containing a crystalline polypropylene portion having a high crystallinity of a boiled heptane-insoluble component contained therein, a high stereoregularity and an extremely long mesochain, and a process for preparing said copolymer. Further disclosed is a propylene polymer composition comprising the above propylene block copolymer and at least one stabilizer selected from a phenol type stabilizer, an organophosphite type stabilizer, a thioether type stabilizer, a hindered amine type stabilizer and a metallic salt of higher aliphatic acid. The propylene block polymer of the invention is well-balanced between rigidity, heat resistance and moisture resistance, and can be favorably used for sheet, filament, injection molded product, blow molded product, etc. The propylene polymer composition of the invention has excellent properties of the propylene polymer or the propylene block copolymer, and moreover is excellent in heat stability during the molding stage, long-term heat stability and weathering resistance.
    • 公开了含有其中含有沸腾庚烷不溶性组分的高结晶度的结晶聚丙烯部分,高立体规则性和极长的间时针的丙烯嵌段共聚物以及制备所述共聚物的方法。 进一步公开的是包含上述丙烯嵌段共聚物和至少一种选自酚型稳定剂,有机亚磷酸酯型稳定剂,硫醚型稳定剂,受阻胺型稳定剂和高级脂肪酸的金属盐的稳定剂的丙烯聚合物组合物。 本发明的丙烯嵌段聚合物在刚性,耐热性和耐湿性之间的平衡性良好,可有利地用于片材,长丝,注塑产品,吹塑产品等。本发明的丙烯聚合物组合物具有优异的性能 的丙烯聚合物或丙烯嵌段共聚物,而且在成型阶段的热稳定性,长期的热稳定性和耐候性也优异。
    • 10. 发明授权
    • Process for preparing solid titanium catalyst component, olefin polymerization catalyst, and olefin polymerization process
    • 固体钛催化剂组分,烯烃聚合催化剂和烯烃聚合方法的制备方法
    • US06323150B1
    • 2001-11-27
    • US09131837
    • 1998-08-10
    • Shinichi KojohTsuneo YashikiKazumitsu KawakitaMasao NakanoSadahiko Matsuura
    • Shinichi KojohTsuneo YashikiKazumitsu KawakitaMasao NakanoSadahiko Matsuura
    • B01J3100
    • C08F10/00C08F4/651C08F4/6543
    • Disclosed is a process for preparing a solid titanium catalyst component, comprising the steps of (I) contacting a liquid magnesium compound with a liquid titanium compound to precipitate a solid in the contact liquid (&bgr;), and adding an electron donor (d-i) selected from the group consisting of a polycarboxylic ester and a polyether compound to the contact liquid (&bgr;) during the time from beginning to end of the solid precipitation, to form a solid product (&agr;); and (II) contacting the solid product (&agr;) obtained after completion of the solid precipitation with an electron donor (d-ii) selected from the group consisting of a polycarboxylic ester and a polyether compound, to prepare a solid titanium catalyst component. According to the process, a solid titanium catalyst component capable of polymerizing an olefin with high activity and capable of preparing an olefin polymer of high stereoregularity can be prepared. Also disclosed are an olefin polymerization catalyst containing a solid titanium catalyst component obtained by the above process and an olefin polymerization process using the olefin polymerization catalyst.
    • 公开了一种制备固体钛催化剂组分的方法,包括以下步骤:(I)使液体镁化合物与液体钛化合物接触以沉淀接触液体中的固体(β),并加入选择的电子给体(di) 从固体沉淀开始到结束的时间期间由聚羧酸酯和聚醚化合物组成接触液(β),形成固体产物(α); 和(II)使固体沉淀完成后得到的固体产物(α)与选自多羧酸酯和聚醚化合物的电子给体(d-ii)接触,制备固体钛催化剂组分。 根据该方法,可以制备能够使活性高的烯烃聚合并能够制备具有高立构规整性的烯烃聚合物的固体钛催化剂组分。 还公开了含有通过上述方法获得的固体钛催化剂组分和使用烯烃聚合催化剂的烯烃聚合方法的烯烃聚合催化剂。