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    • 4. 发明授权
    • Charge control agent, manufacturing process therefor and toner
    • 充电控制剂,其制造工艺和调色剂
    • US06197467B1
    • 2001-03-06
    • US09064661
    • 1998-04-22
    • Shun-ichiro YamanakaKazuaki SukataMasashi Yasumatsu
    • Shun-ichiro YamanakaKazuaki SukataMasashi Yasumatsu
    • G03G900
    • G03G9/09783G03G9/091
    • Charge control agent comprising a metal complex salt compound having a monoazo compound as a ligand, wherein the metal complex salt compound is amorphous, and which is excellent in charge control properties, heat resistance and light fastness, good in dispersibility in, and wettability with, toner resins, hardly damages the photoreceptor when used in a toner, and is unlikely to drop from toner particles during charging; process for manufacturing the charge control agent, comprising subjecting a crystalline metal complex salt compound having a monoazo compound as a ligand to wet milling in an organic solvent, or dissolving the crystalline metal complex salt compound in an organic solvent, and subsequently re-dispersing it in water; and toner for developing electrostatic images comprising said charge control agent, a toner resin, and a coloring agent, and method of use thereof.
    • 电荷控制剂,其包含具有单偶氮化合物作为配体的金属络盐化合物,其中所述金属配盐化合物是无定形的,并且电荷控制性,耐热性和耐光性优异,分散性和润湿性优异, 调色剂树脂在调色剂中使用时几乎不损害感光体,并且在充电期间不容易从调色剂颗粒中脱落;制备电荷控制剂的方法包括使具有单偶氮化合物的结晶金属络盐化合物作为配体进行湿磨 在有机溶剂中,或将结晶金属配盐化合物溶解在有机溶剂中,随后将其再分散在水中; 用于显影包含所述电荷控制剂的静电图像的调色剂,调色剂树脂和着色剂及其使用方法。
    • 5. 发明授权
    • Charge control agent and toner for developing electrostatic images
    • 电荷控制剂和用于显​​影静电图像的调色剂
    • US5501932A
    • 1996-03-26
    • US219613
    • 1994-03-29
    • Shuji SugawaraKazuaki SukataShun-ichiro Yamanaka
    • Shuji SugawaraKazuaki SukataShun-ichiro Yamanaka
    • C09K3/00G03G9/097
    • G03G9/09783G03G9/09758G03G9/09775Y10S430/104
    • A positive charge control agent whose active ingredient is a complex salt compound of the amine derivative represented by the following formula 1!: ##STR1## wherein X.sup.a, X.sup.1, X.sup.2 and X.sup.3 independently represent --O-- or --S--;L.sup.1 represents a divalent group selected from the group consisting of alkylene groups having 1 to 4 carbon atoms which are branched or not branched, cycloalkylene groups, and monocyclic or polycyclic arylene groups which have or do not have a substituent;A.sup.1, A.sup.2 and A.sup.3 independently represent hydrogen, an alkyl group, a cycloalkyl group, an aralkyl group, a monocyclic or polycyclic aryl group which has or does not have a substituent or a residue of a nitrogen-containing heterocyclic compound having an --OH group or an --SH group;p represents an integer from 1 to 4;q represents an integer from 0 to 20;K1.multidot.A1 represents an organic or inorganic salt capable of forming a complex with an amine derivative, in which K1 is a cation selected from the group consisting of alkali metal ions, alkaline earth metal ions, ammonium ions and pyridinium ions, and A1 is an anion of an organic or inorganic acid.
    • 一种正电荷控制剂,其活性成分是由下式[1]表示的胺衍生物的络盐化合物:其表示-O-或-S-; L1表示选自具有或不具有支链的亚烷基,具有或不具有支链的亚环烷基,以及具有或不具有取代基的单环或多环亚芳基的二价基团; A1,A2和A3独立地表示氢,烷基,环烷基,芳烷基,具有或不具有取代基的单环或多环芳基或具有-OH基团的含氮杂环化合物的残基 或-SH基团; p表示1〜4的整数, q表示0〜20的整数, K1xA1表示能够与胺衍生物形成络合物的有机或无机盐,其中K1为选自碱金属离子,碱土金属离子,铵离子和吡啶鎓离子的阳离子,A1为 有机或无机酸。
    • 8. 发明授权
    • Toner for developing electrostatic images
    • 用于显影静电图像的调色剂
    • US5470685A
    • 1995-11-28
    • US219614
    • 1994-03-29
    • Shuji SugawaraKazuaki SukataShun-ichiro Yamanaka
    • Shuji SugawaraKazuaki SukataShun-ichiro Yamanaka
    • G03G9/097
    • G03G9/09741G03G9/09733G03G9/09758G03G9/09783
    • A toner for developing electrostatic images contains at least one complex salt compound obtained by treating with an alkali metal salt, alkaline earth metal salt, alkali metal hydroxide, alkaline earth metal hydroxide, ammonium salt or pyridinium salt, an ether linkage group containing compound of the formulaA.sup.1 --X--[(--L--X--).sub.m --(--Ar--X--).sub.n ]--A.sup.2[I]wherein(--L--X--) represents an oxyalkylene group or a thioarylene group,(--Ar--X--) represents an oxyarylene group or a thioarylene group,[(--L--X--).sub.m --(--Ar--X--).sub.n ] represents a combination of m units of (--L--X--) and n units of (--Ar--X--) bound in a given order,m and n independently represent an integer of 0 or more, and when n is 0, m is 3 or more, and when m is 0, n is 1 or more,X represents --O-- or --S--,L represents an alkylene group having 1 to 4 carbon atoms which is branched or not branched or a cycloalkylene group,Ar represents a monocyclic or polycyclic arylene group which does or does not have a substituent or a --(CH.sub.2).sub.a --Ax--(CH.sub.2).sub.a -- group in which a represents an integer from 1 to 4 and Ax represents a monocyclic or polycyclic arylene group which does or does not have a substituent, andA.sup.1 and A.sup.2 independently represent hydrogen, an alkyl group, a cycloalkyl group, a monocyclic or polycyclic aryl group which has or does not have a substituent, an aralkyl group or a residue of a nitrogen-containing heterocyclic compound having an --OH group or an --SH group.
    • 用于显影静电图像的调色剂含有至少一种通过用碱金属盐,碱土金属盐,碱金属氢氧化物,碱土金属氢氧化物,铵盐或吡啶鎓盐,含醚键的化合物 式(A-X-)表示氧化烯基或硫代亚芳基,(-Ar-X-)表示式(A-X-)表示 (-LX-)m - ( - Ar-X-)n]表示(-LX-)的m个单元和(-Ar-X-)的n个单元结合在一起的组合 给定的顺序,m和n独立地表示0以上的整数,当n为0时,m为3以上,当m为0时,n为1以上,X表示-O-或-S-, L表示支链或非支链或亚环烷基具有1至4个碳原子的亚烷基,Ar表示具有或不具有取代基的单环或多环亚芳基,或 - (CH 2)a-Ax-(CH 2) )a-组,其中ar 表示1至4的整数,并且Ax表示具有或不具有取代基的单环或多环亚芳基,并且A 1和A 2独立地表示氢,烷基,环烷基,单环或多环芳基,其具有或不具有取代基, 不具有取代基,芳烷基或具有-OH基或-SH基的含氮杂环化合物的残基。
    • 9. 发明授权
    • Calix arene charge control agent and toner for developing electrostatic
images
    • Calix芳烃电荷控制剂和用于显​​影静电图像的调色剂
    • US5952145A
    • 1999-09-14
    • US905585
    • 1997-08-04
    • Shun-ichiro YamanakaKazuaki Sukata
    • Shun-ichiro YamanakaKazuaki Sukata
    • G03G9/097
    • G03G9/09733G03G9/09775
    • Charge control agent and toner for developing electrostatic images comprising such a charge control agent whose active ingredient is a calix (n) arene compound of formula I: ##STR1## wherein x+y=n; x and y each is an integer of 1 or more; n is an integer of 4-8; the x repeat units and y repeat units can be arranged in any order; R.sup.1 and R.sup.2 each is H, C.sub.1-12 alkyl, C.sub.2-12 alkenyl, C.sub.7-12 aralkyl, phenyl, C.sub.4-8 cycloalkyl, halogen, nitro, amino, alkyl- or phenyl-substituted amino, --Si(CH.sub.3).sub.3, or --SO.sub.3 H; and of the n R radicals in the --OR groups, 1 to (n-1) are H, with the remaining (n-1) to 1 being alkyl, alkenyl, phenyl, aralkyl, cycloalkyl, --COR.sup.3 �wherein R.sup.3 is H, alkyl, alkenyl, phenyl, aralkyl, or cycloalkyl!, --Si(CH.sub.3).sub.3, --(CH.sub.2).sub.m COOR.sup.4 �wherein R.sup.4 is H or lower alkyl and m is an integer of 1-3!, --(CH.sub.2 CH.sub.2 O).sub.r H �wherein r is an integer of 1-10!, or ##STR2##
    • 用于显影静电图像的电荷控制剂和调色剂,其包含这样的电荷控制剂,其活性成分是杯状(n)芳烃化合物:其中x + y = n; x和y各自为1或更大的整数; n为4-8的整数; x重复单位和y重复单位可以按任何顺序排列; R1和R2各自为H,C1-12烷基,C2-12烯基,C7-12芳烷基,苯基,C4-8环烷基,卤素,硝基,氨基,烷基或苯基取代的氨基,-Si(CH3)3, 或-SO 3 H; 和-OR基团中的n R基团,1至(n-1)为H,其余(n-1)至1为烷基,烯基,苯基,芳烷基,环烷基,-COR 3 [其中R 3为H 烷基,烯基,苯基,芳烷基或环烷基],-Si(CH3)3, - (CH2)mCOOR4 [其中R4是H或低级烷基,m是1-3的整数], - (CH2CH2O) 其中r是1-10的整数]或