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    • 5. 发明授权
    • Use of methanofullerne derivatives as resist materials and method for forming a resist layer
    • 使用甲基呋喃衍生物作为抗蚀剂材料和形成抗蚀剂层的方法
    • US08034546B2
    • 2011-10-11
    • US11662904
    • 2005-09-19
    • Alex RobinsonJon Andrew PreeceRichard Edward Palmer
    • Alex RobinsonJon Andrew PreeceRichard Edward Palmer
    • G03F7/16G03F7/20G03F7/30
    • B82Y30/00G03F7/0382Y10S430/115Y10S430/122Y10S430/126
    • The use as a resist material of a methanofullerene derivative having a plurality of open-ended addends, and to a method for forming a patterned resist layer on a substrate using the methanofullerene derivatives. The methanofullerene derivatives can be represented by the formal C2x(CR1R2)m where x is at least 10, m is at least 2, each addend represented by CR1R2 is the same or different, and wherein each R1 and R2 is each a monovalent organic group, or a divalent organic group which forms a ring structure by being joined to the fullerene shell, or where both R1 and R2 of an addend are divalent groups, they may be mutually joined to form a ring structure, save that at least two of R1 or two of R2 are monovalent, or a mixture of such derivatives. The use of any methanofullerene derivative which has been chemically amplified for formation of a patterned resist layer. The essential step of the method is forming a coating layer comprising the methanofullerene derivative on the substrate surface, the methanofullerene derivative being chemically amplified by including in the coating layer at least one additional component which increases the sensitivity of the exposed layer to actinic radiation which is subsequently used to pattern the layer.
    • 作为具有多个开口加数的亚甲基富勒烯衍生物的抗蚀剂材料的用途,以及使用甲基富勒烯衍生物在基板上形成图案化抗蚀剂层的方法。 甲基富勒烯衍生物可以由正式的C2x(CR1R2)m表示,其中x为至少10,m为至少2,由CR 1 R 2表示的每个加成物相同或不同,并且其中每个R 1和R 2各自为一价有机基团 或通过与富勒烯壳连接而形成环结构的二价有机基团,或其中加成的R1和R2均为二价基团,则它们可以相互连接形成环结构,除了R1中的至少两个 或两个R 2是单价的,或这些衍生物的混合物。 使用已化学放大以形成图案化抗蚀剂层的任何甲基富勒烯衍生物。 该方法的基本步骤是在基材表面上形成包含甲基富勒烯衍生物的涂层,通过在涂层中包括至少一种附加组分将化学扩增的亚甲基富勒烯衍生物增加曝光层对光化辐射的敏感性, 随后用于对图层进行图案化。
    • 6. 发明授权
    • Resist material and method for forming a patterned resist layer on a substrate
    • 用于在衬底上形成图案化抗蚀剂层的抗蚀材料和方法
    • US07670749B2
    • 2010-03-02
    • US11663017
    • 2005-09-19
    • Richard Edward PalmerAlex RobinsonJon Andrew Preece
    • Richard Edward PalmerAlex RobinsonJon Andrew Preece
    • G03F7/004G03F7/30
    • G03F7/0382Y10S430/106Y10S430/115Y10S430/122
    • A method for the formation of a patterned resist layer on a substrate surface by patternwise irradiation with actinic radiation. The first step of the method is formation of a coating layer comprising a substituted triphenylene compound having a diameter of between 1 and 3 nm, a sensitizer which increases the sensitivity of the exposed layer to the actinic radiation used in a subsequent irradiation step and a cross-linker on the substrate surface. Subsequently the coating layer is irradiated patternwise, and unirradiated areas of the coating layer are removed. A resist material comprising a solution of: (i) as the principal resist material a triphenylene derivative having a diameter of from 1 to 3 rim, (ii) a sensitizer which increases the sensitivity of the resist material to actinic radiation, and (iii) a cross-linker capable of cross-linking molecules of the triphenyl derivative, the cross-linker optionally being constituted by a moiety attached to the triphenylene derivative.
    • 通过用光化辐射的图案照射在衬底表面上形成图案化抗蚀剂层的方法。 该方法的第一步是形成包含直径为1至3nm的取代的三亚苯化合物的涂层,增加曝光层对随后照射步骤中使用的光化辐射的敏感性的增感剂和十字 在基材表面上连接。 随后,图案地照射涂层,并且去除涂层的未照射区域。 抗蚀剂材料,其包含以下溶液:(i)作为主要抗蚀剂材料,具有1至3个边缘直径的三亚苯衍生物,(ii)增加抗蚀剂材料对光化辐射的敏感性的敏化剂,和(iii) 能够交联三苯基衍生物分子的交联剂,该交联剂任选地由连接于该三亚苯衍生物的部分构成。