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1. 发明授权

US06323302B1 Carbonic acid diester, aromatic polycarbonate and facilities, and preparation thereof 有权
标题翻译：碳酸二酯，芳族聚碳酸酯和设备及其制备
公开(公告)号：US06323302B1
公开(公告)日：2001-11-27
申请号：US09445824
申请日：1999-12-14
申请人： Katsushi Sasaki , Wataru Funakoshi , Toru Sawaki , Masumi Hirata , Hiroaki Kaneko , Masanori Abe , Masasi Simonaru , Hidemi Takemoto , Jyuhou Matsuo , Yoshiki Matsuoka
发明人： Katsushi Sasaki , Wataru Funakoshi , Toru Sawaki , Masumi Hirata , Hiroaki Kaneko , Masanori Abe , Masasi Simonaru , Hidemi Takemoto , Jyuhou Matsuo , Yoshiki Matsuoka
IPC分类号： C08G6400
CPC分类号： C08G64/307
摘要： Aromatic polycarbonate having a reduced discoloration and improved heat stability, hue, etc. is provided by keeping a pressure in a raw material melting vessel and the linear velocity of a gas in a transporting piping in a specific range, keeping the concentration of a nitrogen-containing basic compound in a specific range, recycling a byproduct containing specific amounts of impurities, suppressing the amounts of a nitrogen-containing basic compound, metallic elements and a silicic acid derivative in the carbonic acid diester at specific values or less, prescribing the material quality of the reaction facilities, and/or forming an oxide layer at the inner wall surfaces of the reaction facilities.
摘要翻译：通过将原料熔融容器中的压力和输送管道中的气体的线速度保持在特定范围来提供具有减少变色和改善的热稳定性，色相等的芳族聚碳酸酯，保持氮气浓度，含有特定范围的碱性化合物，回收含有特定量的杂质的副产物，抑制碳酸二酯中的含氮碱性化合物，金属元素和硅酸衍生物的量在特定值以下，规定材料质量的反应设备，和/或在反应设备的内壁表面形成氧化物层。

2. 发明授权

US5516878A Process for the production of aromatic polycarbonate 失效
标题翻译：生产芳香族聚碳酸酯的方法
公开(公告)号：US5516878A
公开(公告)日：1996-05-14
申请号：US386086
申请日：1995-02-09
申请人： Katsushi Sasaki , Wataru Funakoshi , Masumi Hirata , Masanori Abe , Hiroaki Kaneko
发明人： Katsushi Sasaki , Wataru Funakoshi , Masumi Hirata , Masanori Abe , Hiroaki Kaneko
IPC分类号： C08G64/30 , C08G64/00
CPC分类号： C08G64/307
摘要： A process for the production of an aromatic polycarbonate, which comprises polycondensing an aromatic dihydroxy compound and a diaryl carbonate in the presence, as a polycondensation catalyst, of at least one alkali metal salt selected from the group consisting of alkali metal salts of ate-complexes of a metal element, which is silicon, germanium, stannum or plumbum, and alkali metal salts of oxoacids of said metal elements. The above aromatic polycarbonate is almost free from being colored, is also almost free from a decrease in polymerization degree when molded, and is further almost free from forming branches and insolubles.
摘要翻译：一种制备芳族聚碳酸酯的方法，该方法包括在作为缩聚催化剂存在下将芳族二羟基化合物和碳酸二芳基酯缩聚至少一种碱金属盐，所述碱金属盐选自由以下组成的组：碱金属盐金属元素，其是硅，锗，锡或铅，以及所述金属元素的含氧酸的碱金属盐。上述芳香族聚碳酸酯几乎没有着色，在成型时也几乎没有聚合度的降低，而且几乎不会形成分支和不溶物。

3. 发明授权

US06448365B1 Aromatic polycarbonate composition 有权
标题翻译：芳香族聚碳酸酯组合物
公开(公告)号：US06448365B1
公开(公告)日：2002-09-10
申请号：US09959830
申请日：2001-11-08
申请人： Wataru Funakoshi , Masumi Hirata , Hiroaki Kaneko , Yuichi Kageyama , Toru Sawaki , Katsushi Sasaki
发明人： Wataru Funakoshi , Masumi Hirata , Hiroaki Kaneko , Yuichi Kageyama , Toru Sawaki , Katsushi Sasaki
IPC分类号： C08G6400
CPC分类号： G11B7/2534 , C08G64/06 , C08G64/14 , C08G64/307 , C08K5/52 , C08L69/00
摘要： An aromatic polycarbonate composition which contains 0.05 to 65 ppm of bonded phosphorus atoms to polycarbonate chains and free phosphorus compounds consisting of a tervalent phosphorus compound and a pentavalent phosphorus compound in a specific ratio. It is excellent in transparency, color stability and residence stability at the time of molding and is suitably used in disk substrates.
摘要翻译：一种芳族聚碳酸酯组合物，其含有0.05〜65ppm的键合磷原子与聚碳酸酯链，并且由特定比例的三价磷化合物和五价磷化合物组成的游离磷化合物。在成型时透明度，颜色稳定性和停留稳定性优异，适用于盘基材。

4. 发明授权

US06562936B1 Apparatus and method for producing resin 有权
标题翻译：树脂生产设备及方法
公开(公告)号：US06562936B1
公开(公告)日：2003-05-13
申请号：US09786523
申请日：2001-06-11
申请人： Kazuki Hatono , Masumi Hirata , Hiroaki Kaneko , Toru Sawaki , Wataru Funakoshi , Katsushi Sasaki , Masasi Simonaru , Kouji Kiyoshige
发明人： Kazuki Hatono , Masumi Hirata , Hiroaki Kaneko , Toru Sawaki , Wataru Funakoshi , Katsushi Sasaki , Masasi Simonaru , Kouji Kiyoshige
IPC分类号： C08G6400
CPC分类号： B29C47/767 , B29C47/0009 , B29C47/38 , B29C47/402 , C08G64/205 , C08G64/307
摘要： A method of producing a polycarbonate or the like which is excellent in hydrolysis and heat stability such as a reduction in molecular weight at the time of molding and color retention and moldability such as releasability and transferability, rarely experiences residence deterioration such as coloring, crosslinking and gel formation and has an extremely small content of foreign matter by employing a special structure for an opening in the side surface of a horizontal cylindrical vacuum resin treating apparatus, supplying a molten polycarbonate into a unidirectional rotary intermeshing double-screw extruder under specific conditions, adding a specific agent under specific conditions and cleaning the inner surface of a production apparatus by a specific method.
摘要翻译：水解和热稳定性优异的聚碳酸酯等的制造方法，例如成型时的分子量的降低和保色性以及脱模性和转印性等成型性，很少发生着色，交联等的停留劣化，凝胶形成，并且通过采用水平圆筒形真空树脂处理装置的侧表面中的开口的特殊结构，并且在特定条件下将熔融聚碳酸酯供给到单向旋转啮合双螺杆挤出机中，并且具有非常少的异物含量，在特定条件下的特定试剂，并通过具体方法清洗生产装置的内表面。

5. 发明授权

US5668202A Process for production of stabilized polycarbonate 失效
标题翻译：生产稳定化聚碳酸酯的方法
公开(公告)号：US5668202A
公开(公告)日：1997-09-16
申请号：US665817
申请日：1996-06-19
申请人： Masumi Hirata , Wataru Funakoshi , Katsushi Sasaki
发明人： Masumi Hirata , Wataru Funakoshi , Katsushi Sasaki
IPC分类号： C08G64/20 , C08G64/30 , C08G64/40 , C08K5/36 , C08K5/41 , C08K5/42 , C08K5/50 , C08L69/00
CPC分类号： C08K5/42 , C08G64/307 , C08K5/41 , C08K5/50 , Y10S524/911 , Y10S524/912 , Y10S524/913
摘要： A process for the production of a stabilized polycarbonate which comprises melt-polycondensing an aromatic dihydroxy compound and a carbonic acid diester in the presence of a polycondensation catalyst and then, after the reaction mixture shows an intrinsic viscosity of at least 0.1, adding at least one stabilizer selected from the group consisting of specific compounds having a sulfonates group sulfonic acid anhydride group or a sulfate group in an amount of 0.01 to 500 ppm of a polycarbonate to be formed, to form a polycarbonate having a desired intrinsic viscosity.
摘要翻译：一种制备稳定化聚碳酸酯的方法，其包括在缩聚催化剂存在下使芳族二羟基化合物和碳酸二酯熔融缩聚，然后在反应混合物的特性粘度至少为0.1之后，加入至少一种选自具有磺酸基磺酸酐基的特定化合物或硫酸酯基的稳定剂，其量为所形成的聚碳酸酯的0.01至500ppm，以形成具有所需特性粘度的聚碳酸酯。

6. 发明授权

US5486555A Process for production of stabilized polycarbonate 失效
标题翻译：生产稳定化聚碳酸酯的方法
公开(公告)号：US5486555A
公开(公告)日：1996-01-23
申请号：US437980
申请日：1995-05-10
申请人： Masumi Hirata , Wataru Funakoshi , Katsushi Sasaki
发明人： Masumi Hirata , Wataru Funakoshi , Katsushi Sasaki
IPC分类号： C08G64/20 , C08G64/30 , C08G64/40 , C08K5/36 , C08K5/41 , C08K5/42 , C08K5/50 , C08L69/00 , C08K5/46
CPC分类号： C08K5/42 , C08G64/307 , C08K5/41 , C08K5/50 , Y10S524/911 , Y10S524/912 , Y10S524/913
摘要： A process for the production of a stabilized polycarbonate which comprises melt-polycondensing an aromatic dihydroxy compound and a carbonic acid diester in the presence of a polycondensation catalyst and then, after the reaction mixture shows an intrinsic viscosity of at least 0.1, adding at least one stabilizer selected from the group consisting of specific compounds having either a sulfonate group, a sulfonic acid anhydride group or a sulfate group in an amount of 0.01 to 500 ppm of a polycarbonate to be formed, to form a polycarbonate having a desired intrinsic viscosity.
摘要翻译：一种制备稳定化聚碳酸酯的方法，其包括在缩聚催化剂存在下使芳族二羟基化合物和碳酸二酯熔融缩聚，然后在反应混合物的特性粘度至少为0.1之后，加入至少一种选自具有磺酸酯基，磺酸酐基或硫酸根的特定化合物的稳定剂，其量为要形成的聚碳酸酯的0.01至500ppm，以形成具有所需特性粘度的聚碳酸酯。

7. 发明授权

US06407199B1 Polycarbonate resin composition optical recording medium, and substrate therefor 有权
标题翻译：聚碳酸酯树脂组合物光记录介质及其基材
公开(公告)号：US06407199B1
公开(公告)日：2002-06-18
申请号：US09744559
申请日：2001-01-26
申请人： Masumi Hirata , Toru Sawaki , Wataru Funakoshi , Katsushi Sasaki , Jyuhou Matsuo
发明人： Masumi Hirata , Toru Sawaki , Wataru Funakoshi , Katsushi Sasaki , Jyuhou Matsuo
IPC分类号： C08G6400
CPC分类号： C08L69/00 , C08K5/0008 , C08K5/06 , C08K5/101 , C08K5/103 , C08K5/13 , C08K5/156 , C08K5/1565 , C08K5/17 , C08K5/42 , C08K5/50 , C08K5/526 , C08K5/53 , G11B7/2534 , C08L2666/16
摘要： A polycarbonate resin composition which is excellent in thermal stability such as color retention at the time of melt molding, for example, the prevention of yellowing, and moldability such as releasability and transferability and therefore particularly suitable for the production of precision optical moldings such as optical disk substrates and lenses. The polycarbonate resin composition comprises (A) an aromatic polycarbonate, and (B) a cyclic carbonate compound, a monoester compound of a divalent aliphatic alcohol having 3 to 14 carbon.atoms and an aliphatic monocarboxylic acid having 12 to 24 carbon atoms, or an ether compound obtained by converting at least one hydroxyl group of a polyvalent aliphatic alcohol having 3 to 14 carbon atoms into an aliphatic oxy group having 1 to 18 carbon atoms, or (C) a partial ester compound of an aliphatic alcohol having a valence of 2 to 6 and 2 to 14 carbon atoms and an aliphatic monocarboxylic acid having 12 to 24 carbon atoms, a cyclic phenol compound or a compound selected from hydrochloric acid, phosphoric acid, phosphorous acid, boric acid, and amine salts and ammonium salts thereof.
摘要翻译：熔融成型时的热稳定性优异的聚碳酸酯树脂组合物，例如防止黄变，以及脱模性和转印性等成型性，因此特别适用于制造精密光学模制品如光学磁盘基板和透镜。聚碳酸酯树脂组合物包含（A）芳族聚碳酸酯和（B）环状碳酸酯化合物，具有3〜14个碳原子的二价脂肪族醇的单酯化合物和碳原子数12〜24的脂肪族一元羧酸，或通过将具有3〜14个碳原子的多元脂肪醇的至少一个羟基转化为碳原子数1〜18的脂肪族氧基而得到的醚化合物，或（C）2价的脂肪族醇的偏酯化合物碳原子数为6〜2〜14的脂肪族单羧酸，环状酚化合物或选自盐酸，磷酸，亚磷酸，硼酸及其胺盐及铵盐的化合物。

8. 发明授权

US5494952A Process for production of stabilized polycarbonate 失效
标题翻译：生产稳定化聚碳酸酯的方法
公开(公告)号：US5494952A
公开(公告)日：1996-02-27
申请号：US437987
申请日：1995-05-10
申请人： Masumi Hirata , Wataru Funakoshi , Katsushi Sasaki
发明人： Masumi Hirata , Wataru Funakoshi , Katsushi Sasaki
IPC分类号： C08G64/20 , C08G64/30 , C08G64/40 , C08K5/36 , C08K5/41 , C08K5/42 , C08K5/50 , C08L69/00
CPC分类号： C08K5/42 , C08G64/307 , C08K5/41 , C08K5/50 , Y10S524/911 , Y10S524/912 , Y10S524/913
摘要： A process for the production of a stabilized polycarbonate which comprises melt-polycondensing an aromatic dihydroxy compound and a carbonic acid diester in the presence of a polycondensation catalyst and then, after the reaction mixture shows an intrinsic viscosity of at least 0.1, adding at least one stabilizer selected from the group consisting of specific compounds having a sulfanate group and a sulfonic acid anhydride group in an amount of 0.01 to 500 ppm of a polycarbonate to be formed, to form a polycarbonate having a desired intrinsic viscosity.
摘要翻译：一种制备稳定化聚碳酸酯的方法，其包括在缩聚催化剂存在下使芳族二羟基化合物和碳酸二酯熔融缩聚，然后在反应混合物的特性粘度至少为0.1之后，加入至少一种选自具有硫酸盐基和磺酸酐基团的具体化合物的稳定剂的量为0.01至500ppm的待形成的聚碳酸酯，以形成具有所需特性粘度的聚碳酸酯。

9. 发明授权

US06608165B2 Aromatic polycarbonate and production process therefor 失效
标题翻译：芳香聚碳酸酯及其生产工艺
公开(公告)号：US06608165B2
公开(公告)日：2003-08-19
申请号：US10130048
申请日：2002-05-13
申请人： Wataru Funakoshi , Hiroaki Kaneko , Yuichi Kageyama , Takanori Miyoshi , Katsushi Sasaki
发明人： Wataru Funakoshi , Hiroaki Kaneko , Yuichi Kageyama , Takanori Miyoshi , Katsushi Sasaki
IPC分类号： C08G6400
CPC分类号： C08G64/307
摘要： A polycarbonate having excellent color and stability and a production process therefor. In the production of a polycarbonate by melt polycondensing a dihydroxy compound and a carbonic acid diester in the presence of an ester exchange catalyst, the each content of an aldehyde group in the dihydroxy compound and the carbonic acid diester is reduced to 3×10−6 equivalent/mol or less.
摘要翻译：具有优异的颜色和稳定性的聚碳酸酯及其制备方法。在通过在酯交换催化剂的存在下熔融缩聚二羟基化合物和碳酸二酯来制备聚碳酸酯中，二羟基化合物中醛基的各含量碳酸二酯的含量降低至3×10 -6当量/摩尔以下。

10. 发明授权

US06423813B1 Branched aromatic polycarbonate, and production method and blow-molded article thereof 失效
标题翻译：支链芳族聚碳酸酯及其制造方法和吹塑制品
公开(公告)号：US06423813B1
公开(公告)日：2002-07-23
申请号：US09959075
申请日：2001-10-18
申请人： Wataru Funakoshi , Yuichi Kageyama , Hiroaki Kaneko , Katsushi Sasaki
发明人： Wataru Funakoshi , Yuichi Kageyama , Hiroaki Kaneko , Katsushi Sasaki
IPC分类号： C08G6400
CPC分类号： C08G64/14
摘要： A method for producing a high-quality thermoplastic branched polycarbonate which is used in blow-molding, extrusion or vacuum molding from a linear aromatic polycarbonate efficiently. The thermoplastic branched polycarbonate is produced by melt-mixing and reacting a substantially linear aromatic polycarbonate with an acid anhydride having at least two cyclic acid anhydride groups in a molecule in the presence of a basic catalyst.
摘要翻译：一种用于生产由线性芳族聚碳酸酯进行吹塑，挤出或真空成型的高品质热塑性支链聚碳酸酯的方法。通过在碱性催化剂的存在下，使分子内具有至少两个环状酸酐基团的酸酐与基本上线性的芳族聚碳酸酯熔融混合并使其反应来制造热塑性支化聚碳酸酯。

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