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    • 1. 发明授权
    • Magnetic recording medium
    • 磁记录介质
    • US4880692A
    • 1989-11-14
    • US171360
    • 1988-03-21
    • Katsumi RyokeMasatoshi TakahashiAkihiro HashimotoTsutomu OkitaKazuko Hanai
    • Katsumi RyokeMasatoshi TakahashiAkihiro HashimotoTsutomu OkitaKazuko Hanai
    • C09D5/23C09D127/04C09D127/06C09D175/00C09D175/04G11B5/73G11B5/735
    • G11B5/735Y10S428/90Y10T428/25Y10T428/265
    • A magnetic recording medium comprising a support having provided on one surface thereof a magnetic recording layer containing ferromagnetic particles dispersed in a binder and on the other surface thereof a backing layer, wherein said binder comprises a vinyl chloride/vinyl acetate copolymer reisn containing at least one group represented by formula (I) or (II): ##STR1## wherein X represents a --COO-- group, a --CONH-- group, or a --C.sub.6 H.sub.4 -- group; x represents an integer of from 1 to 10; R.sub.1, R.sub.2, and R.sub.3 each represents a hydrogen atom, an alkyl group having from 1 to 10 carbon atoms, or an alkyl derivative having from 1 to 10 carbon atoms, or R.sub.1, R.sub.2, and R.sub.3 may be combined to each other to form a heterocycric ring; and Y.sup..crclbar. represents a halogen atom, ClO.sub.4.sup..crclbar., or HgI.sub.3.sup..crclbar. ; or Y.sup..crclbar. is bound to R.sub.2, R.sub.2 represents an alkylene group having from 1 to 10 carbon atoms, and Y.sup..crclbar. represents a --COO.sup..crclbar. group, an --SO.sub.3.sup..crclbar. group, or an --OSO.sub.3.sup..crclbar. group.
    • 一种磁记录介质,其包括在其一个表面上设置有包含分散在粘合剂中的铁磁颗粒的磁记录层和在其另一表面上的背衬层的支撑体,其中所述粘合剂包括含有至少一个的氯乙烯/乙酸乙烯酯共聚物 (I)或(II)表示的基团:其中X表示-COO-基团,-CONH-基团或-C 6 H 4 - 基团; x表示1〜10的整数, R1,R2和R3各自表示氢原子,具有1至10个碳原子的烷基或具有1至10个碳原子的烷基衍生物,或者R1,R2和R3可以彼此结合形成 杂环; Y( - )表示卤素原子,ClO 4( - )或HgI 3( - ); 或Y( - )与R 2结合,R 2表示具有1〜10个碳原子的亚烷基,Y( - )表示-COO( - )基,-SO 3( - )基或-OSO 3( - )组。
    • 2. 发明授权
    • Magnetic recording medium
    • 磁记录介质
    • US4880693A
    • 1989-11-14
    • US170225
    • 1988-03-21
    • Katsumi RyokeMasatoshi TakahashiAkihiro HashimotoTsutomu OkitaTakashi Yoneyama
    • Katsumi RyokeMasatoshi TakahashiAkihiro HashimotoTsutomu OkitaTakashi Yoneyama
    • C09D5/23C09D127/04C09D127/06C09D175/00C09D175/04G11B5/73G11B5/735
    • G11B5/735Y10S428/90Y10T428/25
    • A magnetic recording medium comprising a support having provided on one surface thereof a magnetic recording layer and on the other surface thereof a backing layer containing non-magnetic particles dispersed in a binder, wherein said binder comprises a vinyl chloride/vinyl acetate copolymer resin containing at least one group represented by formula (I) or (II): ##STR1## wherein X represents a --COO-- group, a --CONH-- group, or a --C.sub.6 H.sub.4 -- group; n represents an integer of from 1 to 10; R.sub.1, R.sub.2, and R.sub.3 each represents a hydrogen atom, an alkyl group having from 1 to 10 carbon atoms, or an alkyl derivative having from 1 to 10 carbon atoms, or R.sub.1, R.sub.2, and R.sub.3 may be combined to each other to form a heterocycric ring; and Y.sup..crclbar. represents a halogen atom, ClO.sub.4.sup..crclbar., or HgI.sub.3.sup..crclbar. ; or Y.sup..crclbar. is bound to R.sub.2, R.sub.2 represents an alkylene group having from 1 to 10 carbon atoms, and Y.sup..crclbar. represents a --COO.sup..crclbar. group, an --SO.sub.3.sup..crclbar. group, or an --OSO.sub.3.sup..crclbar. group.
    • 一种磁记录介质,包括在其一个表面上设置有磁记录层的支撑体,在另一表面上具有包含分散在粘合剂中的非磁性颗粒的背衬层,其中所述粘合剂包含氯乙烯/乙酸乙烯酯共聚物树脂,其含有 (I)或(II)表示的至少一个基团:其中X表示-COO-基团,-CONH-基团或-C 6 H 4 - 基团; n表示1〜10的整数, R1,R2和R3各自表示氢原子,具有1至10个碳原子的烷基或具有1至10个碳原子的烷基衍生物,或者R1,R2和R3可以彼此结合形成 杂环; Y( - )表示卤素原子,ClO 4( - )或HgI 3( - ); 或Y( - )与R 2结合,R 2表示具有1〜10个碳原子的亚烷基,Y( - )表示-COO( - )基,-SO 3( - )基或-OSO 3( - )组。
    • 5. 发明授权
    • Magnetic recording medium
    • 磁记录介质
    • US4788103A
    • 1988-11-29
    • US39860
    • 1987-04-20
    • Tsutomu OkitaKazuko HanaiYasuyuki Yamada
    • Tsutomu OkitaKazuko HanaiYasuyuki Yamada
    • C08G18/08C09D5/23C09D175/00C09D175/06G11B5/702
    • G11B5/7021C08G18/0819Y10S428/90Y10T428/256Y10T428/257Y10T428/31609
    • A magnetic recording medium is described, comprising a non-magnetic support having provided thereon a magnetic layer containing ferromagnetic fine particles dispersed in a binder including a polyurethane resin containing (1) as a main polymer chain a polyester polyol containing an alcoholic and acid components comprising at least one of (A) at least one alcoholic component selected from alicyclic divalent alcohol and aromatic divalent alcohol in an amount of 50 mol % or more based on the total amount of alcoholic components or (B) at least one acid component selected from alicyclic dicarboxylic acid and aromatic dicarboxylic acid in an amount of 50 mol % or more based on the total amount of acid components, and (2) at least one polyisocyanate selected from tolylene diisocyanate, diphenyl-methane-4,4'-diisocyanate, isophrorone diisocyanate, dicyclohexylmethane-4,4'-diisocyanate, and p-phenylene diisocyanate in an amount of 5 mol % or more based on the total amount of all alcoholic components and all acid components, and further containing (3) a polar group selected from --SO.sub.3 M, --CO.sub.2 M, and --PO.sub.3 M.sub.2, wherein M represents an H, Na, or K atom, in an amount of from 0.03 to 2 wt % based on the total amount of the polyurethane resin.
    • 描述了一种磁记录介质,其包括非磁性载体,其上设置有包含分散在包含含有(1)主要聚合物链的聚氨酯树脂的粘合剂的粘合剂中的铁磁性细颗粒的磁性层,所述聚酯多元醇含有含有醇和酸组分的聚酯多元醇, (A)至少一种选自脂环族二元醇和芳族二价醇的至少一种醇成分,其量为基于醇组分总量的50mol%或更多,或(B)至少一种选自脂环族的酸成分 二羧酸和芳族二羧酸的含量相对于酸成分总量为50摩尔%以上,(2)至少一种选自甲苯二异氰酸酯,二苯基甲烷-4,4'-二异氰酸酯,异佛尔酮二异氰酸酯 ,二环己基甲烷-4,4'-二异氰酸酯和对苯二异氰酸酯,相对于所有酒精组合物的总量为5摩尔%以上 并且还含有(3)选自-SO 3 M,-CO 2 M和-PO 3 M 2的极性基团,其中M代表H,Na或K原子,其量为0.03至2重量%,基于 对聚氨酯树脂的总量。
    • 7. 发明授权
    • Radiation-setting composition containing (meth)acrylic copolymers containing acid groups
    • 含有酸基的(甲基)丙烯酸共聚物的辐射固化组合物
    • US06191184B1
    • 2001-02-20
    • US09303568
    • 1999-05-03
    • Nobuo SuzukiTsutomu OkitaYoshihisa Masaki
    • Nobuo SuzukiTsutomu OkitaYoshihisa Masaki
    • C08F250
    • C08F265/06G02F1/133345G02F1/13394C08F2/02
    • Radiation-setting compositions suitable for the formation of LCD spacers or protective layers which are excellent in photosetting properties (requiring no heat-setting) and development properties, have high adhesiveness to substrates and excellent mechanical characteristics, remain stable over a long storage time and show excellent working condition-dependency. Such a radiation-setting composition for the formation of LCD spacers or protective layers comprises a (meth)acrylic acid-based copolymer having an acid value of 30 to 200 and a glass transition temperature of −30 to 180° C., a (meth)acrylate-based compound obtained by copolymerizing a monomer having a specific structure with a monomer at least having an acidic group, a radiation-sensitive compound and a solvent.
    • 适用于形成具有优异的光固化性能(不需要热定型)和显影性能的LCD间隔物或保护层的辐射固化组合物,对基材的粘附性和优异的机械特性在长时间保存时保持稳定,并显示出 这种用于形成LCD间隔物或保护层的辐射定型组合物包括酸值为30至200,玻璃化转变温度为-30至180°的(甲基)丙烯酸基共聚物 C.,通过使具有特定结构的单体与至少具有酸性基团的单体,辐射敏感性化合物和溶剂共聚获得的(甲基)丙烯酸酯类化合物。
    • 9. 发明授权
    • Process for producing a magnetic recording medium
    • 磁记录介质的制造方法
    • US4980199A
    • 1990-12-25
    • US537725
    • 1990-06-14
    • Tsutomu OkitaYutaka Kakuishi
    • Tsutomu OkitaYutaka Kakuishi
    • C09D5/23C09D127/04C09D127/06C09D175/00C09D175/04G11B5/702G11B5/842
    • G11B5/842G11B5/7022G11B5/7023Y10S428/90
    • A process for producing a magnetic recording medium is disclosed, comprising steps of (1) kneading ferromagnetic fine powders and binders with solvents, (2) optionally adding further the binders and the solvents to disperse the powders and (3) coating the resulting magnetic coating composition on a non-magnetic support, wherein the ferromagnetic fine powders have a crystallite size of not larger than 500 .ANG., the binders have at least one polar group selected from the group consisting of --SO.sub.3 M, --OSO.sub.3 M, --PO.sub.3 M.sub.2, --OPO.sub.3 M.sub.2 and --COOM (wherein M is hydrogen atom, an alkali metal or ammonium) and at least one epoxy group in the molecule and a step of adding a fatty acid having 12 to 26 carbon atoms is carried out after the dispersing step (2). Preferably, a step of crushing the ferromagnetic powders is additionally carried out before the kneading step (1).
    • 公开了一种制造磁记录介质的方法,包括以下步骤:(1)将铁磁性细粉末和粘结剂与溶剂混合,(2)任选地加入粘合剂和溶剂以分散粉末,和(3)涂覆所得磁性涂层 组成在非磁性载体上,其中铁磁细粉末的微晶尺寸不大于500,粘合剂具有至少一个选自-SO 3 M,-OSO 3 M,-PO 3 M 2,-OPO 3 M 2和 在分散步骤(2)之后进行-COOM(其中M是氢原子,碱金属或铵)和至少一个分子中的环氧基和加入具有12-26个碳原子的脂肪酸的步骤。 优选地,在捏合步骤(1)之前另外进行粉碎铁磁粉末的步骤。
    • 10. 发明授权
    • Magnetic recording medium
    • 磁记录介质
    • US4959263A
    • 1990-09-25
    • US195224
    • 1988-05-18
    • Masashi AonumaTsutomu OkitaHiroshi HashimotoHiroaki ArakiKiyotaka FukinoKiyomi Ejiri
    • Masashi AonumaTsutomu OkitaHiroshi HashimotoHiroaki ArakiKiyotaka FukinoKiyomi Ejiri
    • G11B5/702G11B5/712G11B5/714
    • G11B5/7026G11B5/712G11B5/714Y10S428/90Y10T428/257
    • A magnetic recording medium is described, comprising a nonmagnetic support having thereon a magnetic layer containing a binder which is cross-linkable or polymerizable by radiation irradiation and ferromagnetic particles, the ferromagnetic particles being metal or metal alloy particles mainly comprising iron having a crystal size of 300 .ANG. or less, having an atomic ratio of oxygen atoms to iron atoms of from 1.6 to 3.0 on the surface of the particles, and the magnetic layer having been irradiated with radiation, and comprising a nonmagnetic support having thereon a magnetic layer containing a binder comprising thermoplastic resins, thermosetting resins, reactive type resins and mixtures thereof and ferromagnetic particles, said ferromagnetic particles being metal or metal alloy particles mainly comprising iron having a crystal size of 250 .ANG. or less, and having an atomic ratio of oxygen atoms to iron atoms of from 1.6 to 3.0 on the surface of said particles.
    • 描述了一种磁记录介质,其包括其上具有含有可通过辐射照射和铁磁性颗粒可交联或可聚合的粘合剂的磁性层的非磁性载体,所述铁磁颗粒是主要包含具有晶体尺寸的铁的金属或金属合金颗粒 300或更小,在颗粒表面上的氧原子与铁原子的原子比为1.6至3.0,并且已经辐照辐照的磁性层,并且包含其上具有含有粘合剂的磁性层的非磁性载体 包括热塑性树脂,热固性树脂,反应型树脂及其混合物和铁磁颗粒,所述铁磁性颗粒是主要包含结晶尺寸为250或更小的铁并且具有氧原子与铁原子的原子比的金属或金属合金颗粒 在所述颗粒的表面上为1.6至3.0。