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    • 10. 发明授权
    • Liquid absorption agent
    • 液体吸收剂
    • US5300606A
    • 1994-04-05
    • US31022
    • 1993-03-11
    • Toshiyuki AizawaHitoshi NakamuraYoshikazu Hosoda
    • Toshiyuki AizawaHitoshi NakamuraYoshikazu Hosoda
    • A61L15/60B01J20/26C04B24/26C08F226/02C08F236/02
    • C08F226/02A61L15/60B01J20/26C04B24/26
    • A liquid absorption agent for water or organic solvents comprising, as a main component, a crosslinked N-vinylcarboxylic acid amide resin comprising the backbone chain of a homopolymer or copolymer comprising repeating units of the formula shown below crosslinked with a crosslinking agent: ##STR1## wherein R.sup.1, R.sup.2, and R.sup.3 independently represent a hydrogen atom or methyl;X represents a group --COOY, wherein Y represents a hydrogen atom, an alkali metal, C.sub.1 -C.sub.6 alkyl, or lower alkyl substituted with hydroxyl, dialkylamino or quaternary ammonium group; a group --CONHZ, wherein Z represents a hydrogen atom or lower alkyl substituted with a dialkylamino group, quaternary ammonium group, sulfonic acid or an alkali metal salt thereof; cyano, 2-ketopyrrolidinyl, lower alkoxy, lower acyl, lower acyloxy or lower alkyl substituted with sulfonic acid or an alkali metal salt thereof, with a proviso that when R.sup.3 is methyl, X is not cyano, 2-ketopyrrolidinyl, lower alkoxy, lower alkylcarbonyl, lower alkoxycarbonyl and lower alkyl substituted with sulfonic acid or a salt thereof;M represents a hydrogen atom or an alkali metal;p represents 0 or 1; anda molar ratio of m:n is 50-100:50-0.
    • 一种用于水或有机溶剂的液体吸收剂,其包含作为主要成分的交联的N-乙烯基羧酸酰胺树脂,其包含均匀聚合物或共聚物的主链,所述主链包含下式所示的重复单元与交联剂交联:(* CHEMICAL 结构*)其中R1,R2和R3独立地表示氢原子或甲基; X表示基团-COOY,其中Y表示氢原子,碱金属,C1-C6烷基或被羟基,二烷基氨基或季铵基团取代的低级烷基; 基团-CONHZ,其中Z表示氢原子或被二烷基氨基取代的低级烷基,季铵基,磺酸或其碱金属盐; 氰基,2-酮吡咯烷基,低级烷氧基,低级酰基,低级酰氧基或被磺酸或其碱金属盐取代的低级烷基,条件是当R 3为甲基时,X不为氰基,2-酮吡咯烷基,低级烷氧基,低级 烷基羰基,低级烷氧基羰基和被磺酸取代的低级烷基或其盐; M表示氢原子或碱金属; p表示0或1; m:n的摩尔比为50〜100:50〜0。