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    • 4. 发明授权
    • Method of producing photoelectric conversion element, photoelectric conversion element and photoelectrochemical cell
    • 光电转换元件,光电转换元件和光电化学电池的制造方法
    • US09419318B2
    • 2016-08-16
    • US13578905
    • 2011-03-22
    • Katsumi KobayashiKeizo Kimura
    • Katsumi KobayashiKeizo Kimura
    • H01L51/48H01L51/46H01M14/00
    • H01M14/005C09B57/10
    • A method of producing a photoelectric conversion element, which contains an electrically conductive support, a photosensitive layer having porous semiconductor fine particles that have adsorbed a dye formed on the support, a charge transfer layer; and a counter electrode; containing the steps of: applying a dispersion liquid, in which the content of solids excluding semiconductor fine particles is 1% by mass or less based on the total amount of the dispersion liquid, on the support, to form a coating; heating the coating, to obtain porous semiconductor fine particles; and sensitizing the porous semiconductor fine particles by a dye having a structure represented by Formula (1): M(LL1)m1(LL2)m2(X)m3·CI  Formula (1) wherein M represents a metal atom, LL1, LL2, and X each are a ligand, CI represents a counter ion, m1 represents an integer of 1 to 3, m2 and m3 each represent an integer of 0 to 2.
    • 一种制造含有导电载体的光电转换元件的方法,具有吸附形成在载体上的染料的多孔半导体微粒的感光层,电荷转移层; 和对电极; 包括以下步骤:将不含半导体细颗粒的固体含量相对于分散液的总量为1质量%以下的分散液涂布在载体上,形成涂膜; 加热涂层,得到多孔半导体细颗粒; 通过具有由式(1)表示的结构的染料使多孔半导体微粒致敏:M(LL1)m1(LL2)m2(X)m3·CI式(1)其中M表示金属原子,LL1,LL2, 并且X各自为配体,CI表示抗衡离子,m1表示1〜3的整数,m 2,m 3表示0〜2的整数。
    • 6. 发明授权
    • Infrared absorbing composition, infrared absorbing ink, recorded article, image recording method, and image detecting method
    • 红外吸收组合物,红外吸收油墨,记录物,图像记录方法和图像检测方法
    • US08608842B2
    • 2013-12-17
    • US13106546
    • 2011-05-12
    • Katsumi KobayashiKeizo Kimura
    • Katsumi KobayashiKeizo Kimura
    • C09D11/00C09B47/04G02B5/22
    • C09D11/36C09B47/063C09D5/32C09D7/20C09D7/63C09D11/037C09D11/101C09D11/328Y10T428/24802
    • An infrared absorbing composition including a compound that is represented by formula (1) and has solubility of 30 mg/mL or less in toluene at 25° C., an organic solvent having a solubility parameter of from 7.3 to 12.1, and a resin is disclosed. In formula (1), each of R1 to R16 independently represents a hydrogen atom or a substituent group, provided that at least one of R1 to R16 represents an R17—X— group or that the compound represented by formula (1) contains at least one condensed-ring structure in which any adjacent two of R1 to R16 form a ring; X represents —S—, —NH—, —NR18—, or —O—; each of R17 and R18 independently represents an aliphatic group or an aryl group; and M represents two atoms selected from the group consisting of hydrogen atoms and monovalent metal atoms, or a divalent metal atom, or a divalent substituted metal atom moiety including a trivalent or tetravalent metal atom and a substituent group.
    • 一种红外吸收组合物,其包含式(1)表示的化合物,在25℃下在甲苯中的溶解度为30mg / mL以下,溶解度参数为7.3〜12.1的有机溶剂和树脂为 披露 在式(1)中,R 1〜R 16各自独立地表示氢原子或取代基,条件是R 1〜R 16中的至少一个表示R 17 -X-或式(1)表示的化合物至少含有 一个稠环结构,其中R 1至R 16中的任何相邻的两个形成环; X表示-S - , - NH - , - NR 18 - 或-O-; R 17和R 18各自独立地表示脂族基或芳基; M表示选自氢原子和一价金属原子的两个原子,或二价金属原子,或包含三价或四价金属原子和取代基的二价取代金属原子部分。
    • 7. 发明申请
    • METHOD OF PRODUCING PHOTOELECTRIC CONVERSION ELEMENT, PHOTOELECTRIC CONVERSION ELEMENT AND PHOTOELECTROCHEMICAL CELL
    • 生产光电转换元件,光电转换元件和光电化学电池的方法
    • US20120305905A1
    • 2012-12-06
    • US13578905
    • 2011-03-21
    • Katsumi KobayashiKeizo Kimura
    • Katsumi KobayashiKeizo Kimura
    • H01L51/48H01L51/46
    • H01M14/005C09B57/10
    • A method of producing a photoelectric conversion element, which contains an electrically conductive support, a photosensitive layer having porous semiconductor fine particles that have adsorbed a dye formed on the support, a charge transfer layer; and a counter electrode; containing the steps of: applying a dispersion liquid, in which the content of solids excluding semiconductor fine particles is 1% by mass or less based on the total amount of the dispersion liquid, on the support, to form a coating; heating the coating, to obtain porous semiconductor fine particles; and sensitizing the porous semiconductor fine particles by a dye having a structure represented by Formula (1): M(LL1)m1(LL2)m2(X)m3·CI  Formula (1) wherein M represents a metal atom, LL1, LL2, and X each are a ligand, CI represents a counter ion, m1 represents an integer of 1 to 3, m2 and m3 each represent an integer of 0 to 2.
    • 一种制造含有导电载体的光电转换元件的方法,具有吸附形成在载体上的染料的多孔半导体微粒的感光层,电荷转移层; 和对电极; 包括以下步骤:将不含半导体细颗粒的固体含量相对于分散液的总量为1质量%以下的分散液涂布在载体上,形成涂膜; 加热涂层,得到多孔半导体细颗粒; 通过具有由式(1)表示的结构的染料使多孔半导体微粒致敏:M(LL1)m1(LL2)m2(X)m3·CI式(1)其中M表示金属原子,LL1,LL2, 并且X各自为配体,CI表示抗衡离子,m1表示1〜3的整数,m 2,m 3表示0〜2的整数。