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    • 1. 发明申请
    • METHOD FOR EXTRACTING POLYCHLORINATED BIPHENYLS
    • 提取多氯联苯的方法
    • US20100116023A1
    • 2010-05-13
    • US12593483
    • 2008-03-21
    • Katsuhisa HondaTomofumi Takahashi
    • Katsuhisa HondaTomofumi Takahashi
    • G01N30/02
    • G01N33/2835B01D15/00B01J20/103B01J20/3204B01J20/3236G01N30/462G01N30/6039G01N30/88G01N2030/8845G01N2030/8854Y10T436/25375Y10T436/255
    • A column 1 is formed which includes a first column 10 in which an upper layer 14 made of sulfuric acid silica gel and a lower layer 15 made of silver nitrate silica gel are stacked and packed and a second column 20 packed with an alumina layer 23 and connected detachably to the lower end part of the first column 10. An oily liquid containing polychlorinated biphenyls, such as an electric insulating oil, is added to the upper layer 14 and then kept for a predetermined time in a state heated to at least 35° C. An aliphatic hydrocarbon solvent such as n-hexane is supplied to the upper layer 14 having been cooled to ordinary temperature. As a result, polychlorinated biphenyls captured by the first column 10 are dissolved in the aliphatic hydrocarbon solvent and then flows to the second column 20. The polychlorinated biphenyls are captured by that part of the alumina layer 23 which is located near the inlet of the second column 20. The second column 20 is then detached from the first column 10. A hydrophobic solvent such as toluene is supplied to and passed through the second column 20 in a direction opposite to the direction in which n-hexane was passed. Thus, an extract containing the polychlorinated biphenyls dissolved in a small amount of the hydrophobic solvent is obtained. The time taken to obtain the polychlorinated-biphenyls extract after addition of the oily liquid to the first column 10 is generally as short as about 2 to 10 hours.
    • 形成柱1,其包括第一塔10,其中由硫酸硅胶制成的上层14和由硝酸银硅胶制成的下层15堆叠并填充,第二塔20填充有氧化铝层23和 可拆卸地连接到第一塔10的下端部。将含有多氯联苯(例如电绝缘油)的油状液体添加到上层14中,然后在加热至至少35°的状态下保持预定时间 C.将正己烷等脂肪族烃溶剂供给到已经冷却至常温的上层14。 结果,将由第一塔10捕获的多氯联苯溶解在脂族烃溶剂中,然后流到第二塔20.多氯联苯被位于第二塔10的入口附近的部分氧化铝层23捕获 然后将第二塔20与第一塔10分离。将疏水性溶剂如甲苯以与正己烷通过的方向相反的方向被供给并通过第二塔20。 因此,得到溶解在少量疏水性溶剂中的含有多氯联苯的提取物。 将油性液体加入第一塔10后获得多氯联苯提取物所需的时间通常为约2至10小时。
    • 3. 发明授权
    • Method for extracting polychlorinated biphenyls
    • 多氯联苯萃取方法
    • US08329473B2
    • 2012-12-11
    • US12593483
    • 2008-03-21
    • Katsuhisa HondaTomofumi Takahashi
    • Katsuhisa HondaTomofumi Takahashi
    • G01N30/02
    • G01N33/2835B01D15/00B01J20/103B01J20/3204B01J20/3236G01N30/462G01N30/6039G01N30/88G01N2030/8845G01N2030/8854Y10T436/25375Y10T436/255
    • Column which includes a first column with an upper layer of H2SO4 silica gel and a lower layer AgNO3 silica gel and a second column packed with alumina, connected detachably to a lower end of the first column. An oily liquid containing polychlorinated biphenyls, is added to the upper layer and heated. An aliphatic hydrocarbon solvent is supplied to the upper layer, whereby polychlorinated biphenyls captured by the first column are dissolved in the aliphatic hydrocarbon and then flow to the second column. The polychlorinated biphenyls are captured by the alumina which is located near the inlet of the second column, which is then detached from the first column. A hydrophobic solvent is passed through the second column in a direction opposite to the direction in which the aliphatic hydrocarbon was passed, providing an extract containing the polychlorinated biphenyls dissolved in a small amount of the hydrophobic solvent.
    • 柱,其包括具有上层H 2 SO 4硅胶和下层AgNO 3硅胶的第一柱和填充有氧化铝的第二柱,其可拆卸地连接到第一塔的下端。 将含有多氯联苯的油状液体加入上层并加热。 将脂肪族烃溶剂供给到上层,由此将第一塔捕获的多氯联苯溶解在脂族烃中,然后流入第二塔。 多氯联苯被位于第二塔入口附近的氧化铝捕获,然后与第一塔分离。 使疏水性溶剂沿与脂肪烃通过方向相反的方向通过第二塔,提供含有溶解在少量疏水性溶剂中的多氯联苯的提取物。