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1. 发明申请

US20100243458A1 Stamper, Method for Producing the Same, Method for Producing Molded Material, and Prototype Aluminum Mold for Stamper 审中-公开
标题翻译：压模，其制造方法，生产模制材料的方法和用于压模的原型铝模具
公开(公告)号：US20100243458A1
公开(公告)日：2010-09-30
申请号：US12739083
申请日：2008-10-24
申请人： Katsuhiro Kojima , Eiko Okamoto , Yoshihiro Uozu , Seiji Tone , Hideki Masuda , Takashi Yanagishita , Hiroaki Kita , Hisakazu Ito , Kota Shirai , Masayuki Saeki
发明人： Katsuhiro Kojima , Eiko Okamoto , Yoshihiro Uozu , Seiji Tone , Hideki Masuda , Takashi Yanagishita , Hiroaki Kita , Hisakazu Ito , Kota Shirai , Masayuki Saeki
IPC分类号： C25D11/18 , C25D11/12 , C25D11/16 , B28B3/02
CPC分类号： B29C33/3814 , B29C33/38 , B29C35/0888 , B29C35/10 , B29C39/148 , B29C43/222 , B29C59/046 , B29C2035/0827 , B29C2059/023 , B29K2905/02 , C25D5/02 , C25D9/06 , C25D11/04 , C25D11/12 , C25D11/18 , G02B1/118
摘要： Disclosed herein are a stamper which has anodized alumina formed on the surface thereof and which will not cause macroscopic unevenness or color unevenness on the transcribed surface; a method for producing the same; and a method for producing a molded material without macroscopic unevenness or color unevenness on the transcribed surface thereof by using such a stamper. The stamper includes alumina which has a microasperity structure and which is formed by anodization on the surface of a prototype aluminum mold having an aluminum purity of 99.5% or more, an average crystal-grain diameter of 1 mm or less, and an arithmetic mean surface roughness Ra of 0.05 μm or less. The use of this stamper enables the production of a molded material which does not have macroscopic unevenness or color unevenness on the transcribed surface thereof and which is suitable for use as an antireflection article and the like.
摘要翻译：本文公开了在其表面上形成有阳极化氧化铝的压模，并且不会在转录表面上造成宏观的不均匀或颜色不均匀; 其制造方法; 以及通过使用这样的压模在其转录表面上制造没有宏观不均匀或颜色不均匀的模塑材料的方法。压模包括氧化铝，其具有微细结构，并且通过在铝纯度为99.5％以上，平均晶粒直径为1mm以下的原型铝模具的表面上阳极氧化而形成的氧化铝，以及算术平均表面粗糙度Ra为0.05μm以下。使用该压模能够制造在其转录表面上不具有宏观不均匀性或颜色不均匀性并适合用作抗反射制品等的模塑材料。

2. 发明授权

US08939752B2 Mold, process for producing mold, and process for producing sheet 有权
公开(公告)号：US08939752B2
公开(公告)日：2015-01-27
申请号：US12308746
申请日：2007-06-28
申请人： Yoshihiro Uozu , Eiko Okamoto , Katsuhiro Kojima , Satoshi Sakuma , Hideki Masuda , Takashi Yanagishita
发明人： Yoshihiro Uozu , Eiko Okamoto , Katsuhiro Kojima , Satoshi Sakuma , Hideki Masuda , Takashi Yanagishita
IPC分类号： C25D11/12 , B29C33/38 , B29C59/04 , C25D1/10 , C25D11/16 , C25D1/20 , C25D11/04 , C25D1/00 , G02B1/11 , B29C35/08 , B29C59/02
CPC分类号： B29C33/3842 , B29C33/38 , B29C35/0888 , B29C59/046 , B29C2059/023 , C25D1/006 , C25D1/10 , C25D1/20 , C25D11/045 , C25D11/12 , C25D11/16 , G02B1/118
摘要： A mold comprising alumina having a microscopic pattern, in which distances between adjacent recesses or salients therein are not longer than wavelength of visible light, formed by anodic oxidation on a surface of an aluminum pre-mold without a rolling mark, wherein height or depth difference at a crystal grain boundary is 300 nm or less.

3. 发明申请

US20090194914A1 Mold, process for producing mold, and process for producing sheet 有权
标题翻译：模具，模具生产工艺和生产板材的工艺
公开(公告)号：US20090194914A1
公开(公告)日：2009-08-06
申请号：US12308746
申请日：2007-06-28
申请人： Yoshihiro Uozu , Eiko Okamoto , Katsuhiro Kojima , Satoshi Sakuma , Hideki Masuda , Takashi Yanagishita
发明人： Yoshihiro Uozu , Eiko Okamoto , Katsuhiro Kojima , Satoshi Sakuma , Hideki Masuda , Takashi Yanagishita
IPC分类号： B29C35/08 , C25D5/00
CPC分类号： B29C33/3842 , B29C33/38 , B29C35/0888 , B29C59/046 , B29C2059/023 , C25D1/006 , C25D1/10 , C25D1/20 , C25D11/045 , C25D11/12 , C25D11/16 , G02B1/118
摘要： A mold comprising alumina having a microscopic pattern, in which distances between adjacent recesses or salients therein are not longer than wavelength of visible light, formed by anodic oxidation on a surface of an aluminum pre-mold without a rolling mark, wherein height or depth difference at a crystal grain boundary is 300 nm or less.
摘要翻译：一种模具，其具有微观图案的氧化铝，其中相邻的凹部或其中的光线之间的距离不超过在没有滚动标记的铝预成型件的表面上通过阳极氧化形成的可见光波长，其中高度或深度差在晶界处为300nm以下。

4. 发明授权

US08034434B2 Transparent molded body and antireflective member using the same 有权
标题翻译：透明成型体及使用其的防反射构件
公开(公告)号：US08034434B2
公开(公告)日：2011-10-11
申请号：US12526195
申请日：2008-02-08
申请人： Satoshi Sakuma , Eiko Okamoto , Yoshihiro Uozu
发明人： Satoshi Sakuma , Eiko Okamoto , Yoshihiro Uozu
IPC分类号： B32B3/00 , B32B3/30 , G02F1/00
CPC分类号： G02B1/118 , B05D3/067 , B08B17/06 , G02B27/0006 , Y10S428/913 , Y10T428/24355 , Y10T428/2457 , Y10T428/24612
摘要： The present transparent molded body is a transparent molded body including a transparent substrate and an uneven layer composed of a cured product of an active energy ray-curable composition formed on at least one surface of the transparent substrate, wherein the uneven layer has an uneven structure having a gap between the adjacent convex portions equal to or less than the wavelength of a visible light, the water contact angle of the surface of the uneven layer is equal to or less than 25°, and the modulus of elasticity of the surface of the uneven layer is equal to or more than 200 MPa.
摘要翻译：本发明的透明成型体是透明的成型体，其具有透明基板和由形成在透明基板的至少一个面上的活性能量射线固化性组合物的固化物构成的不平坦层，在相邻的凸部之间具有等于或小于可见光的波长的间隙，不平坦层的表面的水接触角等于或小于25°，并且表面的弹性模量不平坦层等于或大于200MPa。

5. 发明申请

US20100323165A1 TRANSPARENT MOLDED BODY AND ANTIREFLECTIVE MEMBER USING THE SAME 有权
标题翻译：透明模制身体和使用该模具的反选择成员
公开(公告)号：US20100323165A1
公开(公告)日：2010-12-23
申请号：US12526195
申请日：2008-02-08
申请人： Satoshi Sakuma , Eiko Okamoto , Yoshihiro Uozu
发明人： Satoshi Sakuma , Eiko Okamoto , Yoshihiro Uozu
IPC分类号： G02B1/11 , B32B3/30 , B32B27/32
CPC分类号： G02B1/118 , B05D3/067 , B08B17/06 , G02B27/0006 , Y10S428/913 , Y10T428/24355 , Y10T428/2457 , Y10T428/24612
摘要： The present transparent molded body is a transparent molded body including a transparent substrate and an uneven layer composed of a cured product of an active energy ray-curable composition formed on at least one surface of the transparent substrate, wherein the uneven layer has an uneven structure having a gap between the adjacent convex portions equal to or less than the wavelength of a visible light, the water contact angle of the surface of the uneven layer is equal to or less than 25°, and the modulus of elasticity of the surface of the uneven layer is equal to or more than 200 MPa.
摘要翻译：本发明的透明成型体是透明的成型体，其具有透明基板和由形成在透明基板的至少一个面上的活性能量射线固化性组合物的固化物构成的不平坦层，在相邻的凸部之间具有等于或小于可见光的波长的间隙，不平坦层的表面的水接触角等于或小于25°，并且表面的弹性模量不平坦层等于或大于200MPa。

6. 发明授权

US06777083B1 Plastic optical fiber, optical fiber cable, optical fiber cable with plug, method for producing methyl methacrylate based polymer and method for producing plastic optical fiber 有权
公开(公告)号：US06777083B1
公开(公告)日：2004-08-17
申请号：US09622057
申请日：2000-10-12
申请人： Hirotoshi Mizota , Tomonari Murakami , Yoshihiro Uozu , Shigeaki Sasaki , Koji Ishizaka , Takeshi Kitayama , Tatsuyuki Takayanagi , Jun-ichiro Atarashi , Yasukazu Yoshida , Masaharu Yanai , Motomu Oh-Kita
发明人： Hirotoshi Mizota , Tomonari Murakami , Yoshihiro Uozu , Shigeaki Sasaki , Koji Ishizaka , Takeshi Kitayama , Tatsuyuki Takayanagi , Jun-ichiro Atarashi , Yasukazu Yoshida , Masaharu Yanai , Motomu Oh-Kita
IPC分类号： D02G300
CPC分类号： C08F20/14 , C08F2/02 , C08F4/04 , G02B6/02033 , Y10T428/2929 , Y10T428/2938 , Y10T428/2967
摘要： This invention provides a process for manufacturing a methyl methacrylate polymer comprising the steps of feeding a monomer containing at least 80 wt % of methyl methacrylate and a radical polymerization initiator represented formula (III) to a reactor; polymerizing the material at a polymerization temperature of 110 to 160° C. under the conditions satisfying particular equations between an initiator concentration and a polymerization temperature; feeding a reaction mixture taken out from the reactor to a devolatilization step (feeding step); and separating and removing volatiles from the reaction mixture (devolatilization step). A methyl methacrylate polymer having adequately good optical properties and a plastic optical fiber having improved transmission performance can be prepared according to this invention.

7. 发明授权

US5390274A Distributed graded index type optical transmission plastic article and method of manufacturing same 失效
标题翻译：分布式折射率型光传输塑料制品及其制造方法
公开(公告)号：US5390274A
公开(公告)日：1995-02-14
申请号：US908603
申请日：1992-07-30
申请人： Nobuhiko Toyoda , Yoshihiko Mishina , Ryuji Murata , Yoshihiro Uozu , Masaaki Oda , Teruta Ishimaru
发明人： Nobuhiko Toyoda , Yoshihiko Mishina , Ryuji Murata , Yoshihiro Uozu , Masaaki Oda , Teruta Ishimaru
IPC分类号： G02B3/00 , G02B6/02 , G02B6/028 , G02B6/06 , G02B6/18
CPC分类号： G02B6/02038 , G02B6/06 , Y10S359/90
摘要： A distributed refractive index type optical transmission plastic article has a circular cross section of a radius r.sub.0 which is in a range of 0.4 to 0.6 mm. A refractive index distribution of the optical transmission article substantially approximates a predetermined ideal refractive index distribution curve at least in a range of 0.25r.sub.0 to 0.70r.sub.0 extending from a center axis toward a peripheral surface of the article. A refractive index n.sub.0 at a central part of the article is in a range of 1.4 to 1.6. The article has a refractive index distribution constant of larger than 0.15 mm.sup.-1 and smaller than 0.3 mm.sup.-1, and a modulation transfer function of at least 55%. This optical transmission article is made from uncured liquid substances each having a viscosity of between 10.sup.3 and 10.sup.8 poises. N (N.gtoreq.2) uncured liquid substances having refractive indexes n of n.sub.1 >n.sub.2 >n.sub.3 . . . n.sub.N when cured are arranged in such a way that the refractive indexes n are successively reduced from a central portion toward a peripheral portion, and concentrically laminated one upon the other to form an uncured strand fiber. The substances between adjacent layers of the fiber are mutually diffused. During the diffusion or thereafter, the uncured strand fiber is cured, thereby completing the production of the optical transmission article.
摘要翻译： PCT No.PCT / JP89 / 00991 Sec。 371日期1991年5月24日 102（e）日期1991年5月24日PCT提交1989年9月29日PCT公布。公开号WO91 / 05275 日期：1991年04月18日。分布折射型光传输塑料制品具有半径r0的圆形横截面，其范围为0.4至0.6mm。光传输物品的折射率分布基本上接近预定的理想折射率分布曲线，该曲线至少在从中心轴向制品的外周表面延伸的0.25r0至0.70r0的范围内。制品中心部分的折射率n0在1.4至1.6的范围内。该制品的折射率分布常数大于0.15mm-1且小于0.3mm -1，调制传递函数至少为55％。该光学透射物品由粘度为103〜108泊的未固化液体物质制成。 N（N> / = 2）折射率n为n1> n2> n3的未固化液体物质。的。的。固化时的nN以折射率n从中心部分朝向周边部分依次减少，并且彼此同心地层叠以形成未固化的纤维束。纤维相邻层之间的物质相互扩散。在扩散过程中或此后，未固化的股线纤维被固化，从而完成光学传输制品的生产。

8. 发明授权

US07142754B2 Plastic optical fiber, plastic optical fiber cables, optical fiber cables with plugs with copolymer 有权
标题翻译：塑料光纤，塑料光纤电缆，带有共聚物插头的光纤电缆
公开(公告)号：US07142754B2
公开(公告)日：2006-11-28
申请号：US10169126
申请日：2000-12-27
申请人： Yoshihiro Tsukamoto , Yasushi Kawaharada , Kikue Irie , Tetsuya Jigami , Jun Okumura , Yoshihiro Uozu
发明人： Yoshihiro Tsukamoto , Yasushi Kawaharada , Kikue Irie , Tetsuya Jigami , Jun Okumura , Yoshihiro Uozu
IPC分类号： G02B6/16
CPC分类号： G02B6/02033 , C08F220/22 , G02B1/048 , G02B6/3807 , C08L33/16 , C08F220/18 , C08F220/14
摘要： This invention relates to a copolymer prepared by polymerizing at least a vinyl compound (A) which gives a homopolymer with a refractive index of 1.50 or more, a fluoroalkyl (meth)acrylate (B) represented by the following formula (1) and methyl methacrylate (C), wherein a weight ratio of monomer (A) component/monomer (B) component ((A)/(B)) in the copolymer is within the range of 0.2 to 1; as well as a plastic optical fiber and a plastic optical fiber cable comprising a clad made of the copolymer. This invention can provide a plastic optical fiber and a plastic optical fiber cable exhibiting a reduced transmission loss, minimizing increase in a transmission loss even when being held as a bobbin-wound form, exhibiting a reduced bend loss and can transmit a wide-band data. (In the above formula, X represents H or CH3; and Rf represents fluoroalkyl having 7 to 14 carbon atoms both inclusive and 13 to 25 fluorine atoms both inclusive.).
摘要翻译：本发明涉及通过聚合至少一种得到折射率为1.50以上的均聚物的乙烯基化合物（A），由下式（1）表示的（甲基）丙烯酸氟烷基酯（B）和甲基丙烯酸甲酯（C），其中共聚物中单体（A）成分/单体（B）成分（（A）/（B））的重量比在0.2〜1的范围内; 以及包括由共聚物制成的包层的塑料光纤和塑料光缆。本发明可以提供塑料光纤和塑料光纤电缆，其表现出降低的传输损耗，即使当被保持为绕线形式时，传输损耗的增加最小化，弯曲损耗减小并且可以传输宽带数据。（在上式中，X表示H或CH 3，Rf表示碳原子数为7〜14的氟代烷基，含有13〜25个氟原子。

9. 发明授权

US5175786A Distributed refractive index type optical transmission plastic article and method of manufacturing the same 失效
$Distributed refractive index type optical transmission plastic article and method of manufacturing the same$
标题翻译：分布式折射率型光学传输塑料制品及其制造方法
公开(公告)号：US5175786A
公开(公告)日：1992-12-29
申请号：US689942
申请日：1991-05-29
申请人： Nobuhiko Toyoda , Yoshihiko Mishina , Ryuji Murata , Yoshihiro Uozu , Masaaki Oda , Teruta Ishimaru
发明人： Nobuhiko Toyoda , Yoshihiko Mishina , Ryuji Murata , Yoshihiro Uozu , Masaaki Oda , Teruta Ishimaru
IPC分类号： B29C47/00 , G02B3/00 , G02B6/02 , G02B6/028
CPC分类号： G02B3/0087 , G02B3/00 , B29C47/00 , B29C47/0014 , G02B6/02038
摘要： A distributed refractive index type optical transmission plastic article has a circular cross section of a radius r.sub.0 between 0.4 and 0.6 mm. A refractive index distribution of the optical transmission article substantially approximates predetermined ideal refractive index distribution curve at least in a range of 0.25r.sub.0 to 0.70r.sub.0 extending from a center axis toward a peripheral face of the article. The article has a refractive index n.sub.0 between 1.4 and 1.6 for its central part, a refractive index distribution constant between 0.3 and 0.7 mm.sup.-1, and a modulation transfer function (MTF) of at least 55%. This optical transmission article is made from uncured liquid substances each having a viscosity between 10.sup.3 and 10.sup.8 poises and refractive indexes n of n.sub.1 >n.sub.2 >n.sub.3 . . . n.sub.N when cured. N (N.gtoreq.3) of such uncured liquid substances are arranged in such a way that the refractive indexes n successively decrease from a central portion toward a peripheral portion, and concentrically laminated one upon the other to form an uncured strand fiber. The substances between adjacent layers of the fiber are mutually diffused, and at the same time or thereafter, the uncured strand fiber is cured, thereby completing the production of the optical transmission article.

10. 发明授权

US07098281B2 Plastic optical fiber, optical fiber cable, optical fiber cable with plug, method for producing methyl methacrylate based polymer and method for producing plastic optical fiber 有权
标题翻译：塑料光纤，光纤电缆，带插头的光纤电缆，生产甲基丙烯酸甲酯基聚合物的方法和生产塑料光纤的方法
公开(公告)号：US07098281B2
公开(公告)日：2006-08-29
申请号：US10824524
申请日：2004-04-15
申请人： Hirotoshi Mizota , Tomonari Murakami , Yoshihiro Uozu , Shigeaki Sasaki , Koji Ishizaka , Takeshi Kitayama , Tatsuyuki Takayanagi , Jun-ichiro Atarashi , Yasukazu Yoshida , Masaharu Yanai , Motomu Oh-Kita
发明人： Hirotoshi Mizota , Tomonari Murakami , Yoshihiro Uozu , Shigeaki Sasaki , Koji Ishizaka , Takeshi Kitayama , Tatsuyuki Takayanagi , Jun-ichiro Atarashi , Yasukazu Yoshida , Masaharu Yanai , Motomu Oh-Kita
IPC分类号： C08F4/04
CPC分类号： C08F20/14 , C08F2/02 , C08F4/04 , G02B6/02033 , Y10T428/2929 , Y10T428/2938 , Y10T428/2967
摘要： This invention provides a process for manufacturing a methyl methacrylate polymer comprising the steps of feeding a monomer containing at least 80 wt % of methyl methacrylate and a radical polymerization initiator represented formula (III) to a reactor; polymerizing the material at a polymerization temperature of 110 to 160° C. under the conditions satisfying particular equations between an initiator concentration and a polymerization temperature; feeding a reaction mixture taken out from the reactor to a devolatilization step (feeding step); and separating and removing volatiles from the reaction mixture (devolatilization step). A methyl methacrylate polymer having adequately good optical properties and a plastic optical fiber having improved transmission performance can be prepared according to this invention
摘要翻译：本发明提供一种制备甲基丙烯酸甲酯聚合物的方法，包括以下步骤：将含有至少80重量％的甲基丙烯酸甲酯和式（III）的自由基聚合引发剂的单体进料到反应器中; 在聚合温度为110〜160℃，在引发剂浓度和聚合温度之间满足特定方程的条件下聚合材料; 将从反应器中取出的反应混合物进料到脱挥发分步骤（进料步骤）; 并从反应混合物中分离和除去挥发物（脱挥发分步骤）。可以根据本发明制备具有良好光学性能的甲基丙烯酸甲酯聚合物和具有改进的透射性能的塑料光纤

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