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1. 发明授权

US08097663B2 Non-aqueous pigmented inkjet inks 有权
标题翻译：非水性着色喷墨油墨
公开(公告)号：US08097663B2
公开(公告)日：2012-01-17
申请号：US12441718
申请日：2007-10-01
申请人： Katrien Bernaerts , Ivan Hoogmartens , Geert Deroover
发明人： Katrien Bernaerts , Ivan Hoogmartens , Geert Deroover
IPC分类号： C08G63/60 , C08G67/02 , C08G69/26 , C08J3/00 , C08K5/34 , C08K5/48 , C08L67/00 , C08L73/00 , C08L77/00 , C08L79/00 , C09B67/00 , C09D5/00 , C09D11/00
CPC分类号： C09D11/36 , C09D11/326
摘要： A non-aqueous inkjet ink containing a pigment includes C.I. Pigment Violet 19 and a polymeric dispersant according to Formula (I): wherein, T represents hydrogen or a polymerization terminating group; Z represents the residue of polyethyleneimine having a number-average molecular weight of at least 100; A represents an oxyalkylene carbonyl group; T-C(O)An- represents a TPOAC-chain which is bound to Z through an amide bond; and n and m are integers wherein m is at least 2 and n is from 2 to 100; wherein the polymeric dispersant fulfills the conditions of: WTPOAC>57 and NAmide≧65 mol % with WTPOAC representing the ratio of the weight percentage of TPOAC-chains over the weight percentage of amide bonds in the polymeric dispersant; NAmide representing the mol % of amide bonds based on the total nitrogen content of the polymeric dispersant; and wherein the values of WTPOAC and NAmide are calculated from the total nitrogen content determined by dry combustion of the polymeric dispersant and from the amine content determined through potentiometric titration in a mixture of CH3COOH:THF (14.5:0.5) with 0.1N aqueous perchloric acid.
摘要翻译：含有颜料的非水性喷墨油墨包括C.I. 颜料紫19和根据式（I）的聚合物分散剂：其中T表示氢或聚合终止基团; Z表示数均分子量为100以上的聚乙烯亚胺的残基; A表示氧化烯羰基; T-C（O）An-表示通过酰胺键与Z结合的TPOAC-链; 并且n和m是其中m为至少2且n为2至100的整数; 其中所述聚合物分散剂满足以下条件：WTPOAC> 55和NAmide≥65mol％，其中WTPOAC表示TPOAC链的重量百分比与聚合物分散剂中酰胺键的重量百分比的比率; 基于聚合物分散剂的总氮含量，NAmide代表酰胺键的摩尔％; 并且其中WTPOAC和NAmide的值根据通过聚合物分散剂的干燃烧确定的总氮含量和通过在CH 3 COOH:THF（14.5:0.5）与0.1N高氯酸盐的混合物中的电位滴定测定的胺含量来计算。。

2. 发明申请

US20090312463A1 NON-AQUEOUS PIGMENTED INKJET INKS 有权
标题翻译：不含水的墨水INKJET墨水
公开(公告)号：US20090312463A1
公开(公告)日：2009-12-17
申请号：US12441718
申请日：2007-10-01
申请人： Katrien Bernaerts , Ivan Hoogmartens , Geert Deroover
发明人： Katrien Bernaerts , Ivan Hoogmartens , Geert Deroover
IPC分类号： C09D11/10
CPC分类号： C09D11/36 , C09D11/326
摘要： A non-aqueous inkjet ink containing a pigment includes C.I. Pigment Violet 19 and a polymeric dispersant according to Formula (I): wherein, T represents hydrogen or a polymerization terminating group; Z represents the residue of polyethyleneimine having a number-average molecular weight of at least 100; A represents an oxyalkylene carbonyl group; T-C(O)An- represents a TPOAC-chain which is bound to Z through an amide bond; and n and m are integers wherein m is at least 2 and n is from 2 to 100; wherein characterized in that the polymeric dispersant fulfills the conditions of: WTPOAC>57 and NAmide≧65 mol % with WTPOAC representing the ratio of the weight percentage of TPOAC-chains over the weight percentage of amide bonds in the polymeric dispersant; NAmide representing the mol % of amide bonds based on the total nitrogen content of the polymeric dispersant; and wherein the values of WTPOAC and NAmide are calculated from the total nitrogen content determined by dry combustion of the polymeric dispersant and from the amine content determined through potentiometric titration in a mixture of CH3COOH:THF (14.5:0.5) with 0.1N aqueous perchloric acid.
摘要翻译：含有颜料的非水性喷墨油墨包括C.I. 颜料紫19和根据式（I）的聚合物分散剂：其中T表示氢或聚合终止基团; Z表示数均分子量为100以上的聚乙烯亚胺的残基; A表示氧化烯羰基; T-C（O）An-表示通过酰胺键与Z结合的TPOAC-链; 并且n和m是其中m为至少2且n为2至100的整数; 其特征在于，聚合物分散剂满足以下条件：WTPOAC> 55和NAmide> = 65mol％，WTPOAC代表TPOAC链的重量百分比与聚合物分散剂中酰胺键的重量百分比的比率; 基于聚合物分散剂的总氮含量，NAmide代表酰胺键的摩尔％; 并且其中WTPOAC和NAmide的值根据通过聚合物分散剂的干燃烧确定的总氮含量和通过在CH 3 COOH:THF（14.5:0.5）与0.1N高氯酸盐的混合物中的电位滴定测定的胺含量来计算。。

3. 发明申请

US20100029813A1 NON-AQUEOUS PIGMENTED INKJET INKS 有权
标题翻译：不含水的墨水INKJET墨水
公开(公告)号：US20100029813A1
公开(公告)日：2010-02-04
申请号：US12441725
申请日：2007-10-01
申请人： Geert Deroover , Katrien Bernaerts , Ivan Hoogmartens
发明人： Geert Deroover , Katrien Bernaerts , Ivan Hoogmartens
IPC分类号： C09D11/10
CPC分类号： C09D11/101
摘要： A non-aqueous inkjet ink includes a benzimidazolone pigment and a polymeric dispersant according to Formula (I): wherein, T represents hydrogen or a polymerization terminating group; Z represents the residue of polyethyleneimine having a number-average molecular weight of at least 100; A represents an oxyalkylene carbonyl group; T-C(O)An- represents a TPOAC-chain which is bound to Z through an amide bond; and n and m are integers wherein m is at least 2 and n is from 2 to 100; the polymeric dispersant fulfills the conditions of: WTPOAC>57 and NAmide≧65 mol % wherein WTPOAC represents the ratio of the weight percentage of TPOAC-chains over the weight percentage of amide bonds in the polymeric dispersant; NAmide represents the mol % of amide bonds based on the total nitrogen content of the polymeric dispersant; and the values of WTPOAC and NAmide are calculated from the total nitrogen content determined by dry combustion of the polymeric dispersant and from the amine content determined through potentiometric titration in a mixture of CH3COOH:THF (14.5:0.5) with 0.1N aqueous perchloric acid.
摘要翻译：非水性喷墨油墨包括苯并咪唑酮颜料和根据式（I）的聚合物分散剂：其中T表示氢或聚合终止基团; Z表示数均分子量为100以上的聚乙烯亚胺的残基; A表示氧化烯羰基; T-C（O）An-表示通过酰胺键与Z结合的TPOAC-链; 并且n和m是其中m为至少2且n为2至100的整数; 聚合物分散剂满足以下条件：WTPOAC> 57和NAmide> = 65mol％，其中WTPOAC表示TPOAC链的重量百分比与聚合物分散剂中酰胺键的重量百分比的比率; 基于聚合物分散剂的总氮含量，NAmide表示酰胺键的摩尔％; 并且从通过聚合物分散剂的干燃烧确定的总氮含量和通过在CH 3 COOH:THF（14.5:0.5）与0.1N高氯酸的混合物中的电位滴定测定的胺含量计算WTPOAC和NAmide的值。

4. 发明申请

US20090270537A1 NON-AQUEOUS PIGMENTED INKJET INKS 有权
标题翻译：不含水的墨水INKJET墨水
公开(公告)号：US20090270537A1
公开(公告)日：2009-10-29
申请号：US12441719
申请日：2007-10-02
申请人： Ivan Hoogmartens , Katrien Bernaerts , Geert Deroover
发明人： Ivan Hoogmartens , Katrien Bernaerts , Geert Deroover
IPC分类号： C09D11/10 , C08K5/3492
CPC分类号： C09D11/101
摘要： A non-aqueous inkjet ink includes C.I. Pigment Yellow 150 and a polymeric dispersant according to Formula (I): wherein, T represents hydrogen or a polymerization terminating group; Z represents the residue of polyethyleneimine having a number-average molecular weight of at least 100; A represents an oxyalkylene carbonyl group; T-C(O)An- represents a TPOAC-chain which is bound to Z through an amide bond; and n and m are integers wherein m is at least 2 and n is from 2 to 100; the polymeric dispersant fulfills the conditions of: WTPOAC>57 and NAmide≧65 mol % wherein WTPOAC represents the ratio of the weight percentage of TPOAC-chains over the weight percentage of amide bonds in the polymeric dispersant; NAmide represents the mol % of amide bonds based on the total nitrogen content of the polymeric dispersant; and the values of WTPOAC and NAmide are calculated from the total nitrogen content determined by dry combustion of the polymeric dispersant and from the amine content determined through potentiometric titration in a mixture of CH3COOH:THF (14.5:0.5) with 0.1N aqueous perchloric acid.
摘要翻译：非水性喷墨油墨包括C.I. 颜料黄150和根据式（I）的聚合物分散剂：其中，T表示氢或聚合终止基团; Z表示数均分子量为100以上的聚乙烯亚胺的残基; A表示氧化烯羰基; T-C（O）An-表示通过酰胺键与Z结合的TPOAC-链; 并且n和m是其中m为至少2且n为2至100的整数; 聚合物分散剂满足以下条件：WTPOAC> 57和NAmide> = 65mol％，其中WTPOAC表示TPOAC链的重量百分比与聚合物分散剂中酰胺键的重量百分比的比率; 基于聚合物分散剂的总氮含量，NAmide表示酰胺键的摩尔％; 并且从通过聚合物分散剂的干燃烧确定的总氮含量和通过在CH 3 COOH:THF（14.5:0.5）与0.1N高氯酸的混合物中的电位滴定测定的胺含量计算WTPOAC和NAmide的值。

5. 发明授权

US08138238B2 Non-aqueous pigmented inkjet inks 有权
标题翻译：非水性着色喷墨油墨
公开(公告)号：US08138238B2
公开(公告)日：2012-03-20
申请号：US12441719
申请日：2007-10-02
申请人： Ivan Hoogmartens , Katrien Bernaerts , Geert Deroover
发明人： Ivan Hoogmartens , Katrien Bernaerts , Geert Deroover
IPC分类号： C07D243/08 , C08G63/60 , C08G67/02 , C08G69/26 , C08J3/00 , C08K5/34 , C08K5/48 , C08L67/00 , C08L73/00 , C08L77/00 , C08L79/00 , C09D5/00 , C09D11/00
CPC分类号： C09D11/101
摘要： A non-aqueous inkjet ink includes C.I. Pigment Yellow 150 and a polymeric dispersant according to Formula (I): wherein, T represents hydrogen or a polymerization terminating group; Z represents the residue of polyethyleneimine having a number-average molecular weight of at least 100; A represents an oxyalkylene carbonyl group; T-C(O)An- represents a TPOAC-chain which is bound to Z through an amide bond; and n and m are integers wherein m is at least 2 and n is from 2 to 100; the polymeric dispersant fulfills the conditions of: WTPOAC>57 and NAmide≧65 mol % wherein WTPOAC represents the ratio of the weight percentage of TPOAC-chains over the weight percentage of amide bonds in the polymeric dispersant; NAmide represents the mol % of amide bonds based on the total nitrogen content of the polymeric dispersant; and the values of WTPOAC and NAmide are calculated from the total nitrogen content determined by dry combustion of the polymeric dispersant and from the amine content determined through potentiometric titration in a mixture of CH3COOH:THF (14.5:0.5) with 0.1N aqueous perchloric acid.
摘要翻译：非水性喷墨油墨包括C.I. 颜料黄150和根据式（I）的聚合物分散剂：其中，T表示氢或聚合终止基团; Z表示数均分子量为100以上的聚乙烯亚胺的残基; A表示氧化烯羰基; T-C（O）An-表示通过酰胺键与Z结合的TPOAC-链; 并且n和m是其中m为至少2且n为2至100的整数; 聚合物分散剂满足以下条件：WTPOAC> 57和NAmide≥65mol％其中WTPOAC表示TPOAC链的重量百分比与聚合物分散剂中酰胺键的重量百分比的比率; 基于聚合物分散剂的总氮含量，NAmide表示酰胺键的摩尔％; 并且从通过聚合物分散剂的干燃烧确定的总氮含量和通过在CH 3 COOH:THF（14.5:0.5）与0.1N高氯酸的混合物中的电位滴定测定的胺含量计算WTPOAC和NAmide的值。

6. 发明授权

US08093312B2 Non-aqueous pigmented inkjet inks 有权
标题翻译：非水性着色喷墨油墨
公开(公告)号：US08093312B2
公开(公告)日：2012-01-10
申请号：US12441725
申请日：2007-10-01
申请人： Geert Deroover , Katrien Bernaerts , Ivan Hoogmartens
发明人： Geert Deroover , Katrien Bernaerts , Ivan Hoogmartens
IPC分类号： C08G63/60 , C08G67/02 , C08G69/26 , C08J3/00 , C08K5/00 , C08K5/23 , C08L67/00 , C08L73/00 , C08L77/00 , C08L79/00 , C09B67/00 , C09D5/00 , C09D11/00
CPC分类号： C09D11/101
摘要： A non-aqueous inkjet ink includes a benzimidazolone pigment and a polymeric dispersant according to Formula (I): wherein, T represents hydrogen or a polymerization terminating group; Z represents the residue of polyethyleneimine having a number-average molecular weight of at least 100; A represents an oxyalkylene carbonyl group; T-C(O)An- represents a TPOAC-chain which is bound to Z through an amide bond; and n and m are integers wherein m is at least 2 and n is from 2 to 100; the polymeric dispersant fulfills the conditions of: WTPOAC>57 and NAmide≧65 mol % wherein WTPOAC represents the ratio of the weight percentage of TPOAC-chains over the weight percentage of amide bonds in the polymeric dispersant; NAmide represents the mol % of amide bonds based on the total nitrogen content of the polymeric dispersant; and the values of WTPOAC and NAmide are calculated from the total nitrogen content determined by dry combustion of the polymeric dispersant and from the amine content determined through potentiometric titration in a mixture of CH3COOH:THF (14.5:0.5) with 0.1N aqueous perchloric acid.
摘要翻译：非水性喷墨油墨包括苯并咪唑酮颜料和根据式（I）的聚合物分散剂：其中T表示氢或聚合终止基团; Z表示数均分子量为100以上的聚乙烯亚胺的残基; A表示氧化烯羰基; T-C（O）An-表示通过酰胺键与Z结合的TPOAC-链; 并且n和m是其中m为至少2且n为2至100的整数; 聚合物分散剂满足以下条件：WTPOAC> 57和NAmide≥65mol％其中WTPOAC表示TPOAC链的重量百分比与聚合物分散剂中酰胺键的重量百分比的比率; 基于聚合物分散剂的总氮含量，NAmide表示酰胺键的摩尔％; 并且从通过聚合物分散剂的干燃烧确定的总氮含量和通过在CH 3 COOH:THF（14.5:0.5）与0.1N高氯酸的混合物中的电位滴定测定的胺含量计算WTPOAC和NAmide的值。

7. 发明授权

US5945263A Antihalation dye for photothermographic recording material and a recording process therefor 失效
标题翻译：用于光热敏记录材料的抗晕染染料及其记录方法
公开(公告)号：US5945263A
公开(公告)日：1999-08-31
申请号：US862812
申请日：1997-05-30
申请人： Geert Deroover , Etienne Van Thillo , Ivan Hoogmartens , Hans Strijckers
发明人： Geert Deroover , Etienne Van Thillo , Ivan Hoogmartens , Hans Strijckers
IPC分类号： G03C1/498 , G03C1/825
CPC分类号： G03C1/49872 , G03C1/49854 , Y10S430/145
摘要： A photothermographic recording material comprising a support; a photo-addressable thermally developable element comprising a substantially light-insensitive organic silver salt, photosensitive silver halide in catalytic association with the substantially light-insensitive organic silver salt spectrally sensitized to the infrared region of the electromagnetic spectrum and a binder; and in a hydrophobic layer an antihalation dye according to the general formula (I): ##STR1## wherein R.sup.1 and R.sup.15 independently represent an alkyl group or an alkyl group substituted with at least one fluorine, chlorine, bromine or an alkoxy-, aryloxy- or ester-group; R.sup.2, R.sup.3, R.sup.16 and R.sup.17 independently represent an alkyl group; R.sup.4, R.sup.5, R.sup.6, R.sup.7, R.sup.18, R.sup.19, R.sup.20 and R.sup.21 independently represent hydrogen, chlorine, bromine, fluorine or a keto-, sulfo-, carboxy-, ester-, sulfonamide-, amide-, dialkylamino-, nitro-, cyano-, alkyl-, alkenyl-, aryl-, alkoxy- or aryloxy-group; or each of R.sup.4 together with R.sup.5, R.sup.5 together with R.sup.6, R.sup.6 together with R.sup.7, R.sup.18 together with R.sup.19, R.sup.19 together with R.sup.20 or R.sup.20 together with R.sup.21 may independently constitute the atoms necessary to complete a benzene ring; R.sup.8, R.sup.9, R.sup.10 and R.sup.11 independently represent hydrogen, an alkyl group or each of R.sup.1 together with R.sup.8, R.sup.8 together with R.sup.9, R.sup.9 together with R.sup.10, R.sup.10 together with R.sup.11 or R.sup.11 together with R.sup.15 may independently constitute the atoms necessary to complete a 5-atom or 6-atom carbocylic or heterocyclic ring; R.sup.12, R.sup.13 and R.sup.14 independently represent hydrogen, chlorine, bromine or fluorine; and A.sup.- is a fluorinated alkyl or aryl anion in which the degree of fluorination is greater than 70%; a production process therefor and a photothermographic recording process therefor.
摘要翻译：一种光热记录材料，包括载体; 一种可光寻址的可热显影元件，包括基本上不光敏的有机银盐，感光卤化银与对电磁光谱的红外区域光谱敏化的基本上不光敏的有机银盐和粘合剂催化缔合; 并且在疏水层中具有根据通式（I）的防光晕染料：其中R 1和R 15独立地表示烷基或被至少一个氟，氯，溴或烷氧基 - ，芳氧基或酯 - 取代的烷基，组; R2，R3，R16和R17独立地表示烷基; R4，R5，R6，R7，R18，R19，R20和R21独立地表示氢，氯，溴，氟或酮基，磺基，羧基，酯 - ，磺酰胺 - ，酰胺 - ，二烷基氨基 - ，硝基 - 氰基，烷基 - ，烯基 - ，芳基 - ，烷氧基 - 或芳氧基 - 或R 4与R 5，R 5，R 6，R 6一起与R 7，R 18一起与R 19，R 19一起与R 20或R 20一起与R 21一起独立地构成完成苯环所必需的原子; R 8，R 9，R 10和R 11独立地表示氢，烷基或R 1与R 8，R 8与R 9，R 9一起与R 10，R 10一起与R 11或R 11一起与R 15一起可以独立地构成完成 5-原子或6-原子碳环或杂环; R 12，R 13和R 14独立地表示氢，氯，溴或氟; A是氟化烷基或芳基阴离子，其中氟化度大于70％; 其生产方法及其光热敏记录方法。

8. 发明授权

US5876915A Photothermographic recording material comprising sensitizing dyes and a recording process therefor 失效
标题翻译：包含增感染料的光热记录材料及其记录方法
公开(公告)号：US5876915A
公开(公告)日：1999-03-02
申请号：US889481
申请日：1997-07-08
申请人： Geert Deroover , Ivan Hoogmartens , Hans Strijckers
发明人： Geert Deroover , Ivan Hoogmartens , Hans Strijckers
IPC分类号： G03C1/28 , G03C1/498 , G03C1/20
CPC分类号： C09B23/0066 , C09B23/0016 , C09B23/0075 , C09B23/086 , G03C1/49854 , G03C1/28 , G03C1/49863 , Y10S430/145
摘要： A photothermographic recording material comprising a support and a photo-addressable thermally developable element comprising a substantially light-insensitive organic silver salt, a reducing agent therefor in thermal working relationship therewith, photosensitive silver halide spectrally sensitized with a dye and in catalytic association with the substantially light-insensitive organic silver salt and a binder, characterized in that the dye is represented by formula (I): ##STR1## with an anion if necessary for charge compensation, wherein Z.sup.1 and Z.sup.2 independently represent S, O or Se; R.sup.1 and R.sup.13 independently represent an alkylene group; X.sup.1 and X.sup.2 independently represent a --(C.dbd.O)--R.sup.18, a --(SO.sub.2)R.sup.19 or a (S.dbd.O)--R.sup.20 group where R.sup.18, R.sup.19, and R.sup.20 independently represent an alkoxy-, aryloxy-, amino- or substituted amino-group.
摘要翻译：一种光热记录材料，其包括支持体和可光寻址的热显影元件，其包含基本上不光敏的有机银盐，与其热加工关系的还原剂，用染料光谱感光并与基本上光敏性有机银盐和粘合剂，其特征在于染料由式（I）表示：如果需要，用阴离子进行电荷补偿，其中Z1和Z2独立地表示S，O或Se; R1和R13独立地表示亚烷基; X1和X2独立地表示 - （C = O）-R18， - （SO2）R19或（S = O）-R20基团，其中R18，R19和R20独立地表示烷氧基 - ，芳氧基 - ，氨基 - 或取代氨基。

9. 发明申请

US20130050367A1 FLEXIBLE, SCRATCH RESISTANT RADIATION CURABLE INKJET INKS 有权
标题翻译：柔性，耐刮擦辐射可固化喷墨墨水
公开(公告)号：US20130050367A1
公开(公告)日：2013-02-28
申请号：US13695099
申请日：2011-06-08
申请人： Ivan Hoogmartens
发明人： Ivan Hoogmartens
IPC分类号： C09D11/10 , B41J2/01
CPC分类号： C09D11/32 , B41J2/2107 , C09D11/101
摘要： A free radical radiation curable inkjet ink containing a photoinitiator and polymerizable compounds includes at least 45 wt % of a mixture of monomers consisting of: a) 10 to 35 wt % of one or more cyclic monofunctional acrylates wherein the homopolymer thereof has a Tg larger than 20° C.; b) 10 to 30 wt % of a N-vinyl lactam and/or a vinylether acrylate; c) 10 to 30 wt % of an ethoxylated and/or propoxylated polyacrylate having a molecular weight of at least 450; wherein all wt % are based on the total weight of the inkjet ink; and wherein the Tg is determined by the DSC method in ISO 11357-2:1999.
摘要翻译：含有光引发剂和可聚合化合物的自由基可辐射固化喷墨油墨包括至少45重量％的由以下组成的单体混合物的混合物：a）10至35重量％的一种或多种环状单官能丙烯酸酯，其中其均聚物的Tg大于 20°C。 b）10〜30重量％的N-乙烯基内酰胺和/或乙烯基醚丙烯酸酯; c）10至30重量％的分子量至少为450的乙氧基化和/或丙氧基化聚丙烯酸酯; 其中所有wt％都是基于喷墨油墨的总重量; 并且其中Tg通过ISO 11357-2：1999中的DSC方法测定。

10. 发明申请

US20100047455A1 STABLE NON-AQUEOUS INKJET INKS 有权
标题翻译：稳定的无水INKJET墨水
公开(公告)号：US20100047455A1
公开(公告)日：2010-02-25
申请号：US12299312
申请日：2007-05-10
申请人： Ivan Hoogmartens
发明人： Ivan Hoogmartens
IPC分类号： B05D1/36 , C08K5/3415 , C08K7/00
CPC分类号： C09D11/40 , C09D11/322 , C09D11/36
摘要： A non-aqueous inkjet ink includes a diketopyrrolo-pyrrole pigment and at least one polyalkyleneglycol dialkylether having a molecular weight of at least 250. Also, a method for manufacturing decorative laminates using the non-aqueous inkjet ink is provided.
摘要翻译：非水性喷墨油墨包括二酮吡咯并 - 吡咯颜料和分子量至少为250的至少一种聚亚烷基二醇二烷基醚。另外，提供了一种使用非水性喷墨油墨制造装饰层压板的方法。

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