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    • 1. 发明申请
    • Vulcanizable rubber mixture and rubber products comprising the same
    • 可硫化的橡胶混合物和包含它们的橡胶制品
    • US20100292406A1
    • 2010-11-18
    • US12801525
    • 2010-06-14
    • Katharina HerzogIsabel AlbersCarla ReckerJürgen WagemannMarc LaschetChristoph RoseBoris Mergell
    • Katharina HerzogIsabel AlbersCarla ReckerJürgen WagemannMarc LaschetChristoph RoseBoris Mergell
    • C08F297/04C08F297/00
    • B65G15/32B29B7/7495B60C1/0016C08F8/00C08K3/013C08K5/548C08L21/00C08L53/00C08L53/025C08F297/04C08L2666/24
    • The invention relates to a vulcanizable rubber mixture and to its use for rubber products which need good grip in wet conditions or in icy conditions, in particular vehicle tires and vehicle tire treads, but also technical rubber products like belts on conveyor systems which can have exposure to weathering, technical hoses, or vibration dampers and impact dampers.The vulcanizable rubber mixture comprises at least one block copolymer functionalized at least at one chain end (terminally) for binding to fillers, at least one filler and, if appropriate, additives and is characterized in that the mixture comprises from 10 to 100 phr of a statistically or microsequentially polymerized copolymer comprising a conjugated diene and an aromatic vinyl compound, and which has, polymerized onto at least one end of said main chain copolymer, a terminally functionalized block of different structure to the main chain, which structure is homopolymeric or copolymeric, from 5 to 250 monomer units long, and composed of at least one of the mers of the main chain copolymer, with the provision that the glass transition temperatures on the one hand of the main chain and on the other hand of the terminal block or block polymer are different.
    • 本发明涉及一种可硫化的橡胶混合物及其在湿条件或冰冷条件下,特别是车辆轮胎和车辆轮胎胎面上需要良好抓地力的橡胶产品的用途,而且涉及可以具有曝光的输送机系统上的技术橡胶产品 耐候性,技术软管,或减振器和冲击阻尼器。 可硫化的橡胶混合物包含至少一个至少在一个链末端(末端)官能化的嵌段共聚物,用于结合填料,至少一种填料,如果合适的话,添加剂,其特征在于该混合物包含10-100phr的 包括共轭二烯和芳族乙烯基化合物的统计学或微序列聚合共聚物,并且其已经在所述主链共聚物的至少一端聚合到主链上具有不同结构的末端官能化嵌段,该结构是均聚或共聚的, 长度为5至250个单体单元,并且由主链共聚物的至少一个组成,其中主链的一方的玻璃化转变温度和另一方面的端子块或块 聚合物不同。
    • 5. 发明申请
    • Tire composition with improved vulcanizing agent
    • 具有改进硫化剂的轮胎组合物
    • US20100108239A1
    • 2010-05-06
    • US12290427
    • 2008-10-30
    • Carla ReckerWilliam Michael YorkThomas KramerKatharina HerzogBoris MergellRichard W. Cruse
    • Carla ReckerWilliam Michael YorkThomas KramerKatharina HerzogBoris MergellRichard W. Cruse
    • B29D30/00C08K3/22C08L25/10C08L7/00C08L9/00C08L23/18C08K3/04
    • B60C1/0016B29B7/7495C08K3/013C08K5/0025C08K5/36C08K5/372C08K5/42C08K5/549C08L21/00
    • A tire composition with a Shore A hardness, according to DIN 53 505 and ASTM D2240, of not less than 40 and not greater than 95 and a glass-transition temperature Tg (E″max), according to DIN 53 513 with a specified temperature sweep of −80° C. to +80° C. and a specified compression of 10+0.2% at 10 Hz, not less than −80° C. and not greater than 0° C., with improved abrasion performance, in particular for pneumatic tires, has the following composition: at least one vulcanizable diene rubber selected from natural rubbers, synthetic polyisoprene rubbers, polyisobutylene rubbers, polybutadiene rubbers (BR), and random styrene-butadiene rubbers; from 35 to 300 phr of at least one active filler selected from carbon blacks, silicas, silicon based fillers, and metal oxides, of which at least 10 phr must be carbon blacks, silicas, or some combination thereof; from 0 to 250 phr of other or further additives; from 0.1·10−3 to 42·10−3 mhr (mol per hundred parts of rubber) of a vulcanizing agent which crosslinks with a functionality>4; and from 0.1 to 10 phr of at least one vulcanization accelerator.
    • 根据DIN 53505和ASTM D2240,具有不低于40且不大于95的肖氏A硬度和根据DIN 53 513的玻璃化转变温度Tg(E“max)的具有特定温度的轮胎组合物 扫描-80°C至+ 80°C,在10 Hz,不低于-80°C和不高于0°C的特定压缩10 + 0.2%,具有改进的耐磨性能 对于充气轮胎具有以下组成:至少一种选自天然橡胶,合成聚异戊二烯橡胶,聚异丁烯橡胶,聚丁二烯橡胶(BR)和无规苯乙烯 - 丁二烯橡胶的可硫化二烯橡胶; 35至300phr的至少一种选自炭黑,二氧化硅,硅基填料和金属氧化物的活性填料,其中至少10phr必须是炭黑,二氧化硅或其一些组合; 0至250phr的其它或其它添加剂; 0.1〜10-3〜42×10-3 mhr(摩尔/百份橡胶)的功能> 4交联的硫化剂; 和0.1至10phr的至少一种硫化促进剂。
    • 6. 发明授权
    • Tire composition with improved vulcanizing agent
    • 具有改进硫化剂的轮胎组合物
    • US08182626B2
    • 2012-05-22
    • US12290427
    • 2008-10-30
    • Carla ReckerWilliam Michael YorkThomas KramerKatharina HerzogBoris MergellRichard W. Cruse
    • Carla ReckerWilliam Michael YorkThomas KramerKatharina HerzogBoris MergellRichard W. Cruse
    • B29C35/00B29C35/02C08J3/24
    • B60C1/0016B29B7/7495C08K3/013C08K5/0025C08K5/36C08K5/372C08K5/42C08K5/549C08L21/00
    • A tire composition with a Shore A hardness, according to DIN 53 505 and ASTM D2240, of not less than 40 and not greater than 95 and a glass-transition temperature Tg (E″max), according to DIN 53 513 with a specified temperature sweep of −80° C. to +80° C. and a specified compression of 10+0.2% at 10 Hz, not less than −80° C. and not greater than 0° C., with improved abrasion performance, in particular for pneumatic tires, has the following composition: at least one vulcanizable diene rubber selected from natural rubbers, synthetic polyisoprene rubbers, polyisobutylene rubbers, polybutadiene rubbers (BR), and random styrene-butadiene rubbers; from 35 to 300 phr of at least one active filler selected from carbon blacks, silicas, silicon based fillers, and metal oxides, of which at least 10 phr must be carbon blacks, silicas, or some combination thereof; from 0 to 250 phr of other or further additives; from 0.1·10−3 to 42·10−3 mhr (mol per hundred parts of rubber) of a vulcanizing agent which crosslinks with a functionality>4; and from 0.1 to 10 phr of at least one vulcanization accelerator.
    • 根据DIN 53505和ASTM D2240,具有不低于40且不大于95的肖氏A硬度和根据DIN 53 513的玻璃化转变温度Tg(E“max)的具有特定温度的轮胎组合物 扫描-80°C至+ 80°C,在10 Hz,不低于-80°C和不高于0°C的特定压缩10 + 0.2%,具有改进的耐磨性能 对于充气轮胎具有以下组成:至少一种选自天然橡胶,合成聚异戊二烯橡胶,聚异丁烯橡胶,聚丁二烯橡胶(BR)和无规苯乙烯 - 丁二烯橡胶的可硫化二烯橡胶; 35至300phr的至少一种选自炭黑,二氧化硅,硅基填料和金属氧化物的活性填料,其中至少10phr必须是炭黑,二氧化硅或其一些组合; 0至250phr的其它或其它添加剂; 0.1〜10-3〜42×10-3 mhr(摩尔/百份橡胶)的功能> 4交联的硫化剂; 和0.1至10phr的至少一种硫化促进剂。