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    • 1. 发明授权
    • Resistance probe for determining gas compositions and method of
producing it
    • 用于确定气体成分的电阻探针及其制备方法
    • US5334350A
    • 1994-08-02
    • US861810
    • 1992-06-19
    • Karl-Hermann FrieseWerner GruenwaldHans-Martin WiedenmannGerhard Hoetzel
    • Karl-Hermann FrieseWerner GruenwaldHans-Martin WiedenmannGerhard Hoetzel
    • G01N27/12G01N33/00G01N27/04H01C1/02H01C7/00
    • G01N27/12
    • A resistance probe is proposed for detecting gas compositions, particularly in the exhaust gases of internal combustion engines. This resistance probe has the advantage over prior art resistance probes that, with a short response time, it is considerably more aging resistant. This is accomplished in that the resistance layer configured as a semiconductor layer is introduced or sintered into recesses or slits provided for this purpose in the prefabricated sensor carrier body and above it is applied a porous, electrically non-conductive engobe or a protective layer structure in the form of a grid or raster. These measures enable the measuring gas to gain access to the semiconductor layer, but the semiconductor layer is simultaneously protected against corrosive, erosive and/or cavitative attacks from the exhaust gas.
    • PCT No.PCT / DE90 / 00909 Sec。 371日期:1992年6月19日 102(e)日期1992年6月19日PCT提交1990年11月24日PCT公布。 出版物WO91 / 09301 日期:1991年6月27日。提出了用于检测气体组成的电阻探针,特别是在内燃机的废气中。 该电阻探针具有优于现有技术的电阻探针的优点,其具有较短的响应时间,其耐老化性更强。 这是通过将构造为半导体层的电阻层引入或烧结到预制传感器载体本体中为此而设置的凹部或狭缝中,并且在其上施加多孔,非导电性或者保护层结构 网格或栅格的形式。 这些措施使得测量气体能够进入半导体层,但同时保护半导体层免受来自废气的腐蚀性,侵蚀性和/或空穴化攻击。
    • 3. 发明授权
    • Seal for a sensor element of a gas sensor
    • 气体传感器传感器元件的密封
    • US5846391A
    • 1998-12-08
    • US836425
    • 1997-04-29
    • Karl-Hermann FrieseHelmut WeylHans-Martin WiedenmannAnton Hans
    • Karl-Hermann FrieseHelmut WeylHans-Martin WiedenmannAnton Hans
    • G01N27/409G01N27/407
    • G01N27/4078
    • A seal for a sensor element for a gas sensor for determining the oxygen content in a gas to be measured including exhaust gases of internal combustion engines, the seal including a metallic housing having defined therein a longitudinal bore; a sensor element inserted into the longitudinal bore; and a sealing arrangement provided in the longitudinal bore, surrounding at least a portion of the sensor element, and comprised of at least one seal element comprised of steatite and an additional seal element comprised of boron nitride arranged in contact with one another and in a stack having a side near the gas to be measured so that, when there is one seal element comprised of steatite, the one seal element comprised of steatite is positioned on the side of the stack near the gas to be measured, and so that, when there are two seal elements comprised of steatite, the additional seal element is positioned between the two seal elements comprised of steatite, wherein the at least one seal element comprised of steatite and the additional seal element comprised of boron nitride are inserted into the longitudinal bore of the housing as deformable rings and are pressed-in therein, and wherein, during the pressing-in, the deformable rings are deformed in such a way that the at least one seal element comprised of steatite and the additional seal element comprised of boron nitride are pushed against the sensor element and the housing.
    • PCT No.PCT / DE96 / 00567 Sec。 371日期1997年04月29日 102(e)日期1997年4月29日PCT 1996年3月21日PCT公布。 公开号WO97 / 08542 日期1997年3月6日用于气体传感器的传感器元件的密封件,用于确定包括内燃机废气的待测气体中的氧含量,所述密封件包括金属壳体,其中限定有纵向孔; 插入纵向孔中的传感器元件; 以及设置在所述纵向孔中的密封装置,围绕所述传感器元件的至少一部分,并且包括至少一个由滑石组成的密封元件和由氮化硼组成的另外的密封元件,所述氮化硼彼此接触并且在堆叠 具有靠近要测量的气体的一侧,使得当存在由滑石组成的一个密封元件时,由滑石组成的一个密封元件位于靠近待测量气体的堆叠侧,并且当那里 是由滑石组成的两个密封元件,附加的密封元件位于由滑石组成的两个密封元件之间,其中由滑石组成的至少一个密封元件和由氮化硼组成的另外的密封元件被插入到 壳体作为可变形环并被压入其中,并且其中,在压入期间,可变形环以这样的方式变形,使得至少一个 由滑石组成的气体元件和由氮化硼组成的另外的密封元件被推靠在传感器元件和壳体上。
    • 4. 发明授权
    • Seal for a sensor element of a gas sensor
    • 气体传感器传感器元件的密封
    • US5795454A
    • 1998-08-18
    • US569074
    • 1995-12-04
    • Karl-Hermann FrieseHelmut WeylRomuald FriesHans-Martin WiedenmannAnton Hans
    • Karl-Hermann FrieseHelmut WeylRomuald FriesHans-Martin WiedenmannAnton Hans
    • G01N27/409G01N27/12G01N27/407F16J15/14
    • G01N27/4078G01N27/407G01N27/4077Y10S277/936Y10S277/938Y10S277/939Y10S277/941Y10S277/943
    • A seal for a sensor element of a gas sensor for determining the oxygen content in gases including exhaust gases of an internal combustion engine, which seal seals the sensor element in a longitudinal bore of a housing, the seal including a sealing stack which is positioned within the longitudinal bore of the housing and around the sensor element in use and which is comprised of two sealing bodies and an additional seal positioned between the two sealing bodies. The two sealing bodies are comprised of a pre-sintered ceramic material. The additional seal is comprised of a pre-pressed powder material and has a porosity which is lower than that of the two sealing bodies. The two sealing bodies and the additional seal are compressed together within the longitudinal bore in use, whereby at least the additional seal is deformed so that the sensor element is sealed in a gap-free manner within the longitudinal bore. The pre-pressed powder material of the additional seal may consist essentially of a ductile metal, which may be one of nickel or copper, or graphite which may be fiber-reinforced.
    • PCT No.PCT / DE94 / 00537 Sec。 371 1995年12月4日第 102(e)日期1995年12月4日PCT 1994年5月11日PCT公布。 公开号WO94 / 29710 日期1994年12月22日用于确定包括内燃机的废气在内的气体中的氧含量的气体传感器的传感器元件的密封件,该密封件将传感器元件密封在壳体的纵向孔中,所述密封件包括密封件 堆叠,其位于壳体的纵向孔内并且在使用中围绕传感器元件,并且由两个密封体和位于两个密封体之间的附加密封件组成。 两个密封体由预烧结的陶瓷材料组成。 附加密封件由预压粉末材料组成,并且具有低于两个密封体的孔隙率。 两个密封体和附加密封件在使用中在纵向孔内压缩在一起,由此至少附加的密封件变形,使得传感器元件以无间隙的方式密封在纵向孔内。 附加密封件的预压粉末材料可以由可以是镍或铜之一的延性金属或可以是纤维增强的石墨组成。
    • 5. 发明授权
    • Process for producing PTC temperature sensor elements for PTC
temperature sensor
    • 用于生产PTC温度传感器PTC温度传感器元件的工艺
    • US5172466A
    • 1992-12-22
    • US715798
    • 1991-06-14
    • Karl-Hermann FrieseHans-Martin WiedenmannGunther Stecher
    • Karl-Hermann FrieseHans-Martin WiedenmannGunther Stecher
    • G01K7/16G01J5/02G01J5/20G01K7/18G01K7/22G01N27/416G01N27/417H01C1/024H01C1/034H01C7/02
    • G01K7/183H01C7/021Y10T29/49085
    • A PTC temperature sensor and a process for producing PTC temperature sensing elements from ceramic films for a PTC temperature sensor are proposed. The PTC temperature sensing elements are so designed that the PTC resistor track is hermetically encapsulated with respect to the gas being measured and the ambient air. Ceramic films based on an insulator ceramic, in particular based on Al.sub.2 O.sub.3, and ceramic films based on a solid electrolyte can be used to produce the temperature sensing elements. The PTC temperature sensor according to the invention is distinguished, in particular, by the fact that, while the manufacturing procedure is cheap, it is not subject to aging due to the effect of varying O.sub.2 partial pressures, has a high resistance to aging of the resistance characteristic in rich and lean gas mixtures, for example in motor vehicle exhaust gases, at 300.degree.-1000.degree. C. and has a construction free from extraneous potential, is characterized by short response times owning to its low heat capacity and is suitable for incorportion in very narrow housing as a consequence of small dimensions.
    • 提出了一种用于PTC温度传感器的PTC温度传感器和用于从陶瓷膜生产PTC温度传感元件的工艺。 PTC温度感测元件被设计成使得PTC电阻轨道相对于被测量的气体和环境空气被气密地封装。 可以使用基于绝缘体陶瓷,特别是基于Al 2 O 3的陶瓷膜和基于固体电解质的陶瓷膜来制造温度感测元件。 根据本发明的PTC温度传感器的特征在于,特别是由于制造过程便宜,由于变化的O2分压的影响,其不会老化,因此具有高耐老化性 富含和贫气混合物的阻力特性,例如在机动车排气中,在300°-1000℃,具有无外力的结构,其特征在于具有低热容量的响应时间短,适用于 由于小尺寸,狭窄房屋的配额不合。
    • 6. 发明授权
    • NTC temperature sensor and process for producing NTC temperature sensing
elements
    • NTC温度传感器和生产NTC温度传感元件的工艺
    • US5142266A
    • 1992-08-25
    • US466286
    • 1990-03-26
    • Karl-Hermann FrieseGunther StecherHans-Martin Wiedenmann
    • Karl-Hermann FrieseGunther StecherHans-Martin Wiedenmann
    • G01K7/16G01K7/22G01N27/406G01N27/416H01C7/04
    • H01C7/043G01K7/223G01N27/4067
    • The NTC temperature sensor includes a NTC temperature sensing element having an NTC resistor and made of a laminated composite of ceramic films, which is so designed that the ambient air or oxygen supplied by electrolytic pumping has free access, via a channel in the laminated composite, to the NTC resistor. The NTC resistor is hermetically sealed from a gas being measured. Solid electrolyte films which conduct O.sup.-2 ions, and films based on Al.sub.2 O.sub.3 can be used to make the laminated composite. The NTC resistor characteristic curve is independent of the composition of the gas being measured. The laminated composite can be formed of at least three solid electrolyte ceramic films including a base film provided with punched-out interconnection holes and conductor tracks printed by thick film technology, an intermediate film having a punched-out channel and a channel enlargement around the ends of the conductor tracks forming the electrodes of the NTC resistor, and a covering film.
    • PCT No.PCT / DE88 / 00528 Sec。 371 1990年3月26日第 102(e)1990年3月26日PCT PCT公布1988年8月30日PCT。 出版物WO89 / 03115 日期2004年4月6日。NTC温度传感器包括NTC温度感测元件,其具有NTC电阻器并由陶瓷膜的层压复合材料制成,其被设计成使得通过电解泵送供应的环境空气或氧气可以自由通过, 一个通道在叠层复合材料中,到NTC电阻。 NTC电阻器与被测气体气密密封。 可以使用导电O-2离子的固体电解质膜和基于Al2O3的膜来制备层压复合材料。 NTC电阻特性曲线与被测气体的组成无关。 层压复合体可以由至少三个固体电解质陶瓷膜形成,该固体电解质陶瓷膜包括设置有冲孔互连孔的底膜和通过厚膜技术印刷的导体轨迹,具有冲压通道的中间膜和在端部周围的通道放大 的形成NTC电阻器的电极的导体轨迹以及覆盖膜。
    • 7. 发明授权
    • Electrochemical sensor
    • 电化学传感器
    • US5662786A
    • 1997-09-02
    • US807163
    • 1991-12-13
    • Karl-Hermann FrieseHelmut WeylWerner WielandHans-Martin Wiedenmann
    • Karl-Hermann FrieseHelmut WeylWerner WielandHans-Martin Wiedenmann
    • G01N27/407G01N27/409
    • G01N27/4075
    • The electrochemical sensor for determination of an oxygen content of exhaust gases, includes a probe element including a tube made from a raw material mixture consisting essentially of an ionically conductive solid electrolyte; an outer electrode located on the outer surface of the tube; a substantially pore-free conductor strip layer located on the outer surface, connected to the outer electrode, and extending toward the open end, the conductor strip layer having a portion in close proximity to the tube open end; and a substantially pore-free cover layer hermetically covering at least the portion of the pore-free conductor strip layer in close proximity to the open end of the tube, the cover layer being made from a cover layer material including the ionically conductive solid electrolyte. The cover layer material advantageously a sintering activity which is at least equal to that of the raw material mixture from which the tube is made. The conductor strip layer consists essentially of a ceramic supporting framework and an electron-conducting material. The ceramic ceramic binder has at least the same sintering activity as the cover layer material.
    • 用于确定废气氧含量的电化学传感器包括探针元件,其包括由基本上由离子导电固体电解质组成的原料混合物制成的管; 位于所述管的外表面上的外电极; 位于所述外表面上的基本上无孔的导体条带层,其连接到所述外电极并且朝向所述开口端延伸,所述导体带层具有紧邻所述管开口端的部分; 以及基本无孔的覆盖层,其至少密封地覆盖无孔导体带层的靠近管的开口端的部分,覆盖层由包括离子导电固体电解质的覆盖层材料制成。 覆盖层材料有利地是至少等于制造管的原料混合物的烧结活性。 导体带层基本上由陶瓷支撑框架和电子传导材料组成。 陶瓷陶瓷粘合剂具有与覆盖层材料至少相同的烧结活性。