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1. 发明授权

US5763643A Preparation of alkyl esters of (meth)acrylic acid 失效
标题翻译：（甲基）丙烯酸烷基酯的制备
公开(公告)号：US5763643A
公开(公告)日：1998-06-09
申请号：US708722
申请日：1996-09-05
申请人： Karl Gerhard Baur , Ulrich Annen , Herbert Exner , Michael Fried , Ulrich Rauh
发明人： Karl Gerhard Baur , Ulrich Annen , Herbert Exner , Michael Fried , Ulrich Rauh
IPC分类号： C07C67/08 , C07C67/327 , C07C69/54 , C07C67/30
CPC分类号： C07C67/327
摘要： A process for the preparation of C.sub.1 -C.sub.4 -alkyl esters of (meth)acrylic acid from esters of the formula I ##STR1## and in case from esters of the formula (II) ##STR2## where R.sup.1 is hydrogen or --CH.sub.3, R.sup.2 and R.sup.3 are each C.sub.1 -C.sub.4 -alkyl, and n is an integer >0, in the liquid phase and in the presence of an acid at reduced pressure and with continuous removal of the cleavage products.
摘要翻译：由式I（I）的酯制备（甲基）丙烯酸的C 1 -C 4烷基酯的方法，在式（II）的酯的情况下，其中R 1是氢或-CH 3，R 2和R 3各自为C 1 -C 4烷基，n为0以上的整数，在减压下，在酸存在下，并连续除去裂解产物。

2. 发明授权

US5663421A Separation of a diester of (meth)acrylic acid with a C.sub.4 -C.sub.6 -alkanediol 失效
标题翻译：（甲基）丙烯酸的二酯与C4-C6-链烷二醇的分离
公开(公告)号：US5663421A
公开(公告)日：1997-09-02
申请号：US541703
申请日：1995-10-10
申请人： Toni Dockner , Helmut Lermer , Ulrich Rauh , Gerhard Nestler
发明人： Toni Dockner , Helmut Lermer , Ulrich Rauh , Gerhard Nestler
IPC分类号： C07C57/07 , C07C67/08 , C07C67/58 , C07C69/54 , C07C67/48
CPC分类号： C07C67/58
摘要： A diester of (meth)acrylic acid with a C.sub.4 -C.sub.6 -alkanediol is separated from a mixture which essentially consists of the C.sub.4 -C.sub.6 -alkanediol, the monoester of (meth)acrylic acid with the C.sub.4 -C.sub.6 -alkanediol and the diester of (meth)acrylic acid with the C.sub.4 -C.sub.6 -alkanediol by extraction with an organic solvent in the presence of water, by a process in which the diester-containing mixture is added continuously in the middle section of an extraction column and in addition water and the organic extracting agent are passed continuously countercurrent in the extraction column.
摘要翻译：（甲基）丙烯酸与C4-C6-链烷二醇的二酯与C4-C6-链烷二醇，（甲基）丙烯酸与C4-C6-链烷二醇的单酯和（甲基）丙烯酸与C4-C6-链烷二醇的有机溶剂在水的存在下萃取，其中将含二酯的混合物连续加入萃取塔的中间部分，另外加入水和有机提取剂在提取塔中持续逆流通过。

3. 发明授权

US07074955B2 Safe operation of a continuous heterogeneously catalyzed gas-phase partial oxidation of at least one organic compound 有权
标题翻译：至少一种有机化合物的连续不均匀催化气相部分氧化的安全操作
公开(公告)号：US07074955B2
公开(公告)日：2006-07-11
申请号：US10459782
申请日：2003-06-12
申请人： Ulrich Hammon , Jochen Meschke , Ulrich Rauh , Klaus Joachim Müller-Engel , Peter Schlemmer , Volker Schliephake
发明人： Ulrich Hammon , Jochen Meschke , Ulrich Rauh , Klaus Joachim Müller-Engel , Peter Schlemmer , Volker Schliephake
IPC分类号： C07C51/16
CPC分类号： C07C51/215 , C07C45/33 , C07C45/34 , C07C45/35 , C07C51/252 , C07C47/22 , C07C57/04
摘要： A continuously operated heterogeneously catalyzed gas-phase partial oxidation of at least one organic compound in an oxidation reactor is operated safely by a process in which an explosion diagram for the feed gas mixture is deposited as the basis of a cut-out mechanism in a computer.
摘要翻译：在氧化反应器中连续操作的至少一种有机化合物的气相部分氧化被安全地通过其中沉积原料气体混合物的爆炸图作为计算机中的切断机构的基础的方法来操作。

4. 发明授权

US06657088B2 Temperature measurements in tubular reactors during treatment of fluid masses 有权
标题翻译：管状反应器在流体质量处理过程中的温度测量
公开(公告)号：US06657088B2
公开(公告)日：2003-12-02
申请号：US09988135
申请日：2001-11-19
申请人： Volker Schliephake , Ulrich Hammon , Ulrich Rauh , Armin Schraut
发明人： Volker Schliephake , Ulrich Hammon , Ulrich Rauh , Armin Schraut
IPC分类号： C07C4500
CPC分类号： B01J8/06 , B01J19/0013 , B01J2208/00044 , B01J2208/0007 , B01J2208/00097 , B01J2219/00058 , B01J2219/00065
摘要： A method for measuring the temperature of fluid masses being treated in a tubular reactor apparatus which comprises carrying out the treatment in reactor apparatus comprises at least two same-type tubular reactors which are filled with solid particles, at least one tubular reactor containing a temperature measuring unit, the tubular reactors being designed such that both the ratio of the mass of the solid particles to the free cross-sectional area of the respective tubular reactor and the pressure drop measured by an inert gas being conducted transversely to the free cross-sectional area are each substantially identical across the respective tubular reactor. The apparatus is suitable for treating fluid masses while generating or consuming thermal energy, the temperature being measured.
摘要翻译：用于测量在管式反应器设备中处理的流体质量的温度的方法包括在反应器设备中进行处理包括至少两个相同类型的管状反应器，其填充有固体颗粒，至少一个管式反应器，其包含温度测量单元，管式反应器被设计成使得固体颗粒的质量与各管式反应器的自由横截面积的比率和通过惰性气体测量的压降横向于自由横截面积在相应的管式反应器中各自基本相同。该装置适用于在产生或消耗热能，待测温度的同时处理流体物质。

5. 发明授权

US06333011B1 Apparatus for measuring temperatures in tubular reactors 失效
标题翻译：用于测量管式反应器中的温度的装置
公开(公告)号：US06333011B1
公开(公告)日：2001-12-25
申请号：US09064310
申请日：1998-04-23
申请人： Volker Schliephake , Ulrich Hammon , Ulrich Rauh , Armin Schraut
发明人： Volker Schliephake , Ulrich Hammon , Ulrich Rauh , Armin Schraut
IPC分类号： B01J806
CPC分类号： B01J8/06 , B01J19/0013 , B01J2208/00044 , B01J2208/0007 , B01J2208/00097 , B01J2219/00058 , B01J2219/00065
摘要： A reactor apparatus comprises at least two same-type tubular reactors which are filled with solid particles, at least one tubular reactor containing a temperature measuring unit, the tubular reactors being designed such that both the ratio of the mass of the solid particles to the free cross-sectional area of the respective tubular reactor and the pressure drop measured by an inert gas being conducted transversely to the free cross-sectional area are identical across the respective tubular reactor. The apparatus is suitable for treating fluid masses while generating or consuming thermal energy, the temperature being measured.
摘要翻译：反应器装置包括填充有固体颗粒的至少两个相同类型的管式反应器，至少一个包含温度测量单元的管状反应器，该管式反应器设计成使得固体颗粒的质量与自由各管式反应器的横截面面积和通过横向于自由横截面积进行的惰性气体测量的压降在相应的管式反应器中是相同的。该装置适用于在产生或消耗热能，待测温度的同时处理流体物质。

6. 发明授权

US5728272A Separation by rectification of unsaturated carboxylic acids from solvents 失效
标题翻译：通过不饱和羧酸从溶剂中的精馏分离
公开(公告)号：US5728272A
公开(公告)日：1998-03-17
申请号：US696193
申请日：1996-08-13
申请人： Ulrich Hammon , Volker Schliephake , Wolfgang Pies , Ulrich Rauh
发明人： Ulrich Hammon , Volker Schliephake , Wolfgang Pies , Ulrich Rauh
IPC分类号： C07B63/00 , C07C51/44 , C07C57/04 , C07C57/07 , B01D3/00 , B01D59/00
CPC分类号： C07C51/44 , Y10S203/22
摘要： In a process for the separation by rectification of unsaturated carboxylic acids from solvents in which the acids were absorbed after the synthesis reaction, the rectification is briefly interrupted and the rectification column is flushed with a basic solution. The interruption is carried out at regular time intervals. The basic solution used is an aqueous solution of alkali metal and/or alkaline earth metal hydroxide, preferably NaOH, KOH, Ca(OH).sub.2 or their anhydrous oxides; alkaline polar organic solvents as amines or amides can be used, too.
摘要翻译：在由合成反应后吸收酸的溶剂中分离不饱和羧酸的方法中，精馏被短暂中断，精馏塔用碱性溶液冲洗。中断是以规律的时间间隔进行的。使用的碱性溶液是碱金属和/或碱土金属氢氧化物，优选NaOH，KOH，Ca（OH）2或其无水氧化物的水溶液; 也可以使用作为胺或酰胺的碱性极性有机溶剂。

7. 发明授权

US5618971A Separation of a mono(meth)acrylate of a C.sub.4 -C.sub.6 alkanediol from an aqueous solution containing a mono(methacrylate) of a C.sub.4 -C.sub.6 alkanediol and the said C.sub.4 -C.sub.6 alkanediol 失效
标题翻译：从包含C4-C6链烷二醇单（甲基丙烯酸酯）和所述C4-C6链烷二醇的水溶液中分离C4-C6链烷二醇单（甲基）丙烯酸酯
公开(公告)号：US5618971A
公开(公告)日：1997-04-08
申请号：US539771
申请日：1995-10-05
申请人： Toni Dockner , Helmut Lermer , Ulrich Rauh , Gerhard Nestler
发明人： Toni Dockner , Helmut Lermer , Ulrich Rauh , Gerhard Nestler
IPC分类号： B01D11/04 , C07B61/00 , C07C67/08 , C07C67/58 , C07C69/54 , C07C67/48
CPC分类号： C07C67/58
摘要： A process for the separation of a mono(meth)acrylate of a C.sub.4 -C.sub.6 alkanediol from an aqueous solution containing a mono(meth)acrylate of a C.sub.4 -C.sub.6 alkanediol and the said C.sub.4 -C.sub.6 alkanediol, by extraction with an organic solvent, in which the extracting agent used is an organic solvent selected from the group comprising esters of C.sub.1 -C.sub.4 alkanecarboxylic acids and C.sub.1 -C.sub.5 alkanols, single and mixed dialkyl ethers having from 4 to 8 C atoms, and mixtures of such organic solvents.
摘要翻译：通过用有机溶剂萃取从含有C4-C6链烷二醇和所述C4-C6链烷二醇的单（甲基）丙烯酸酯的水溶液中分离C4-C6链烷二醇单（甲基）丙烯酸酯的方法，其中使用的萃取剂是选自C1-C4链烷羧酸和C1-C5链烷醇的酯，具有4至8个C原子的单一和混合二烷基醚以及这些有机溶剂的混合物的有机溶剂。

8. 发明申请

US20060205973A1 Process for preparing alkyl esters of (meth)acrylic acid 审中-公开
标题翻译：制备（甲基）丙烯酸的烷基酯的方法
公开(公告)号：US20060205973A1
公开(公告)日：2006-09-14
申请号：US11358220
申请日：2006-02-22
申请人： Thorsten Habeck , Ulrich Rauh , Thorsten Friese , Hans Martan
发明人： Thorsten Habeck , Ulrich Rauh , Thorsten Friese , Hans Martan
IPC分类号： C07C67/36
CPC分类号： C07C67/327 , C07C67/08 , C07C67/54 , C07C69/54
摘要： A process is described for continuously preparing alkyl esters of (meth)acrylic acid by reacting (meth)acrylic acid and alkanols having from 1 to 5 carbon atoms in homogeneous, liquid, solvent-free phase at elevated temperature and in the presence of an acidic esterification catalyst, in which the (meth)acrylic acid, the alkanol and the acidic esterification catalyst are fed to a reaction zone (5, 6), a reaction mixture (21) is discharged from the reaction zone (5, 6), and is introduced into a rectification unit I and separated by addition of water into a top stream (23), comprising the alkyl ester of (meth)acrylic acid, and a bottom stream (22), and a substream of the bottom stream (22) from the rectification unit I is fed to a residue dissociation unit IV, which comprises a dissociating boiler (61), and is separated therein into a top stream (29), which is recycled into the rectification unit I and a bottom stream (40), which is removed from the system, wherein the residue dissociation unit IV, as well as the dissociating boiler (61), further comprises a rectification column (62), the water content of the liquid obtained at the bottommost stage thereof being less than 0.1% by weight.
摘要翻译：描述了一种通过使（甲基）丙烯酸和具有1至5个碳原子的链烷醇在均相，液体，无溶剂相中在升高的温度和酸性存在下连续制备（甲基）丙烯酸的烷基酯的方法酯化催化剂，其中将（甲基）丙烯酸，链烷醇和酸性酯化催化剂加入到反应区（5,6）中，将反应混合物（21）从反应区（5,6）排出，被引入精馏单元I中，并通过加入包含（甲基）丙烯酸的烷基酯和底部流（22））的顶部流（23）和底部流（22）的分流而分离，来自精馏单元I的残渣解离单元IV包含解离锅炉（61），并分离成顶部物流（29），其被再循环到精馏单元I和底部流（40）中，，其从系统中移除，其中残渣解离单元IV以及解离式锅炉（61）还包括精馏塔（62），其最底部得到的液体的含水量小于0.1重量％。

9. 发明授权

US07026503B2 Method for producing (meth)acrylic acid esters 有权
标题翻译：（甲基）丙烯酸酯的制造方法
公开(公告)号：US07026503B2
公开(公告)日：2006-04-11
申请号：US10478695
申请日：2002-05-28
申请人： Gerhard Nestler , Ulrich Rauh , Jürgen Schröder
发明人： Gerhard Nestler , Ulrich Rauh , Jürgen Schröder
IPC分类号： C07C67/02
CPC分类号： C07C213/10 , C07C67/54 , C07C213/06 , Y02P20/582 , C07C69/54 , C07C219/08
摘要： Higher (meth)acrylates IV are prepared by transesterification of a lower (meth)acrylate I with a higher alcohol R2OH in the presence of a stabilizer or stabilizer mixture and of a catalyst or catalyst mixture, by a process in which the liberated lower alkanol R1OH is separated off and is fed at least partly to the preparation of the lower (meth)acrylate I.
摘要翻译：通过在稳定剂或稳定剂混合物和催化剂或催化剂混合物的存在下，通过下式（甲基）丙烯酸酯I与高级醇R 2 OH在低级（甲基）丙烯酸酯I与催化剂或催化剂混合物的存在下，释放的低级链烷醇R 1 H 2 OH的方法被分离出并且至少部分地供给到下（甲基）丙烯酸酯I的制备中。

10. 发明授权

US06348638B1 Method for removing by-products obtained when producing acrylic acid or methacrylic acids 有权
标题翻译：用于除去制备丙烯酸或甲基丙烯酸时得到的副产物的方法
公开(公告)号：US06348638B1
公开(公告)日：2002-02-19
申请号：US09147416
申请日：1998-12-21
申请人： Volker Schliephake , Ulrich Hammon , Wolfgang Pies , Ulrich Rauh
发明人： Volker Schliephake , Ulrich Hammon , Wolfgang Pies , Ulrich Rauh
IPC分类号： A62D300
CPC分类号： C07C57/04 , F23D17/00
摘要： In a process for the disposal of low, mediun, and high-boiling secondary components formed during the preparation of (meth)acrylic acid the gaseous low-boiling secondary components are burned, whilst low-boiling and medium-boiling secondary components that are dissolved in water optionally together with high-boiling secondary components treated with solvent are added.
摘要翻译：在处理在（甲基）丙烯酸制备期间形成的低，中和和高沸点次要组分的方法中，气态低沸点次级组分被燃烧，而溶解的低沸点和中沸点次要组分在水中任选加入用溶剂处理的高沸点次级组分。

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