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1. 发明申请

US20140336286A1 Modified Fischer-Tropsch Monolith Catalysts and Methods For Preparation and Use Thereof 审中-公开
标题翻译：改性费托复合催化剂及其制备方法
公开(公告)号：US20140336286A1
公开(公告)日：2014-11-13
申请号：US14339866
申请日：2014-07-24
申请人： Charles Leonard Kibby , Robert James Saxton, JR. , Kandaswamy Jothimurugesan , Tapan Kumar Das , Howard Steven Lacheen , Michael Bartz , Alfred Hass
发明人： Charles Leonard Kibby , Robert James Saxton, JR. , Kandaswamy Jothimurugesan , Tapan Kumar Das , Howard Steven Lacheen , Michael Bartz , Alfred Hass
IPC分类号： B01J29/76 , B01J23/89 , C07C1/04
CPC分类号： B01J29/7669 , B01J23/8986 , B01J29/061 , B01J29/064 , B01J29/068 , B01J29/072 , B01J29/076 , B01J29/7469 , B01J29/7869 , B01J35/023 , B01J35/04 , B01J37/0036 , B01J37/0203 , B01J37/0225 , B01J37/0228 , B01J37/0244 , B01J37/0246 , B01J37/0248 , B01J2229/186 , B01J2229/42 , B01J2229/60 , C07C1/0435 , C07C2529/072 , C10G2/33 , Y10T428/31678
摘要： Disclosed are hybrid synthesis gas conversion catalysts containing at least one Fischer-Tropsch component and at least one acidic component deposited on a monolith catalyst support for use in synthesis gas conversion processes and methods for preparing the catalysts. Also disclosed are synthesis gas conversion processes in which the hybrid synthesis gas conversion catalysts are contacted with synthesis gas to produce a hydrocarbon product containing at least 50 wt % C5+ hydrocarbons. Also disclosed are synthesis gas conversion processes in which at least one layer of Fischer-Tropsch component deposited onto a monolith support is alternated with at least one layer of acidic component in a fixed bed reactor.
摘要翻译：公开了含有至少一种费 - 托组分和沉积在整体催化剂载体上的至少一种酸性组分的混合合成气转化催化剂，用于合成气转化方法和制备催化剂的方法。还公开了合成气转化方法，其中混合合成气转化催化剂与合成气体接触以产生含有至少50重量％的C 5+烃的烃产物。还公开了合成气转化方法，其中沉积在整料载体上的至少一层费 - 托成分与固定床反应器中的至少一层酸性组分交替。

2. 发明申请

US20130210942A1 MODIFIED FISCHER-TROPSCH MONOLITH CATALYSTS AND METHODS FOR PREPARATION AND USE THEREOF 审中-公开
标题翻译：改性FISCHER-TROPSCH单晶催化剂及其制备和使用方法
公开(公告)号：US20130210942A1
公开(公告)日：2013-08-15
申请号：US13396466
申请日：2012-02-14
申请人： Charles Leonard Kibby , Robert James Saxton, JR. , Kandaswamy Jothimurugesan , Tapan Kumar Das , Howard Steven Lacheen , Michael Bartz , Alfred Has
发明人： Charles Leonard Kibby , Robert James Saxton, JR. , Kandaswamy Jothimurugesan , Tapan Kumar Das , Howard Steven Lacheen , Michael Bartz , Alfred Has
IPC分类号： B01J35/02 , B01J23/75 , C07C1/04 , B01J37/02
CPC分类号： B01J29/7669 , B01J23/8986 , B01J29/061 , B01J29/064 , B01J29/068 , B01J29/072 , B01J29/076 , B01J29/7469 , B01J29/7869 , B01J35/023 , B01J35/04 , B01J37/0036 , B01J37/0203 , B01J37/0225 , B01J37/0228 , B01J37/0244 , B01J37/0246 , B01J37/0248 , B01J2229/186 , B01J2229/42 , B01J2229/60 , C07C1/0435 , C07C2529/072 , C10G2/33 , Y10T428/31678
摘要： Disclosed are hybrid synthesis gas conversion catalysts containing at least one Fischer-Tropsch component and at least one acidic component deposited on a monolith catalyst support for use in synthesis gas conversion processes and methods for preparing the catalysts. Also disclosed are synthesis gas conversion processes in which the hybrid synthesis gas conversion catalysts are contacted with synthesis gas to produce a hydrocarbon product containing at least 50 wt % C5+ hydrocarbons. Also disclosed are synthesis gas conversion processes in which at least one layer of Fischer-Tropsch component deposited onto a monolith support is alternated with at least one layer of acidic component in a fixed bed reactor.
摘要翻译：公开了含有至少一种费 - 托组分和沉积在整体催化剂载体上的至少一种酸性组分的混合合成气转化催化剂，用于合成气转化方法和制备催化剂的方法。还公开了合成气转化方法，其中混合合成气转化催化剂与合成气体接触以产生含有至少50重量％的C 5+烃的烃产物。还公开了合成气转化方法，其中沉积在整料载体上的至少一层费 - 托成分与固定床反应器中的至少一层酸性组分交替。

3. 发明申请

US20140031194A1 Integral Synthesis Gas Conversion Catalyst Extrudates and Methods For Preparing and Using Same. 审中-公开
标题翻译：积分合成气转化催化剂挤出物及其制备方法。
公开(公告)号：US20140031194A1
公开(公告)日：2014-01-30
申请号：US14041074
申请日：2013-09-30
申请人： Kandaswamy Jothimurugesan , Robert James Saxton , Howard Steven Lacheen , Tapan Kumar Das
发明人： Kandaswamy Jothimurugesan , Robert James Saxton , Howard Steven Lacheen , Tapan Kumar Das
IPC分类号： B01J29/76
CPC分类号： B01J29/7669 , B01J23/8913 , B01J29/043 , B01J29/044 , B01J29/045 , B01J29/7469 , B01J35/0006 , B01J37/0009 , B01J37/035 , B01J2229/186 , B01J2229/42 , C10G2/334 , C10G2/341 , Y02E60/324
摘要： Methods for preparing integral synthesis gas conversion catalyst extrudates including an oxide of a Fischer-Tropsch (FT) metal component and a zeolite component are disclosed. The oxide of the FT metal component is precipitated from a solution into crystallites having a particle size between about 2 nm and about 30 nm. The oxide of the FT metal component is combined with a zeolite powder and a binder material, and the combination is extruded to form integral catalyst extrudates. The oxide of the FT metal component in the resulting catalyst is in the form of reduced crystallites located outside the zeolite channels. No appreciable ion exchange of FT metal occurs within the zeolite channels. The acid site density of the integral catalyst extrudate is at least about 80% of the zeolite acid site density.
摘要翻译：公开了制备包含费 - 托（FT）金属组分和沸石组分的氧化物的整体合成气转化催化剂挤出物的方法。 FT金属成分的氧化物从溶液中沉淀成粒径在约2nm至约30nm之间的微晶。将FT金属成分的氧化物与沸石粉末和粘合剂材料组合，将其组合挤出成一体的催化剂挤出物。所得催化剂中FT金属组分的氧化物为位于沸石通道外部的微晶形式。在沸石通道内不发生明显的FT金属离子交换。整体催化剂挤出物的酸性位点密度为沸石酸性位点密度的至少约80％。

4. 发明授权

US09192921B1 Support for Fischer-Tropsch catalyst having improved activity 有权
标题翻译：支持具有改善活性的费 - 托催化剂
公开(公告)号：US09192921B1
公开(公告)日：2015-11-24
申请号：US14691797
申请日：2015-04-21
申请人： Kandaswamy Jothimurugesan , Howard Steven Lacheen
发明人： Kandaswamy Jothimurugesan , Howard Steven Lacheen
IPC分类号： B01J27/198 , B01J37/02 , B01J37/08 , B01J37/16 , C10G2/00
CPC分类号： B01J27/198 , B01J23/83 , B01J35/002 , B01J35/006 , B01J35/1038 , B01J35/1042 , B01J37/0207 , B01J37/024 , B01J37/16 , C10G2/33 , C10G2/332
摘要： A process is disclosed for preparing a Fischer-Tropsch catalyst precursor and a catalyst made from the precursor. The process includes contacting an alumina catalyst support material with a first solution containing a vanadium compound and a phosphorus compound, to obtain a modified catalyst support material. The modified catalyst support material is calcined at a temperature of at least 500° C. The calcined modified catalyst support has a pore volume of at least 0.4 cc/g. The modified catalyst support is less soluble in acid solutions than an equivalent unmodified catalyst support. The modified catalyst support is contacted with a second solution which includes a precursor compound of an active cobalt catalyst component and glutaric acid to obtain a catalyst precursor. The catalyst precursor is reduced to activate the catalyst precursor to obtain the Fischer-Tropsch catalyst. The catalyst has enhanced hydrothermal stability and good activity.
摘要翻译：公开了制备费 - 托催化剂前体和由前体制备的催化剂的方法。该方法包括使氧化铝催化剂载体材料与含有钒化合物和磷化合物的第一溶液接触，以获得改性的催化剂载体材料。改性的催化剂载体材料在至少500℃的温度下煅烧。煅烧的改性催化剂载体的孔体积至少为0.4cc / g。改性的催化剂载体在酸溶液中比相当的未改性的催化剂载体更难溶解。改性的催化剂载体与包含活性钴催化剂组分的前体化合物和戊二酸的第二溶液接触以获得催化剂前体。催化剂前体被还原以活化催化剂前体以获得费 - 托催化剂。该催化剂具有增强的水热稳定性和良好的活性。

5. 发明授权

US09364782B1 Separation of gases using GME framework type zeolites 有权
标题翻译：使用GME骨架型沸石分离气体
公开(公告)号：US09364782B1
公开(公告)日：2016-06-14
申请号：US14605557
申请日：2015-01-26
申请人： Dan Xie , Howard Steven Lacheen
发明人： Dan Xie , Howard Steven Lacheen
IPC分类号： B01D53/02 , B01D53/04 , B01D53/22 , B01D71/02 , C10L3/10 , B01D53/047
CPC分类号： B01D53/02 , B01D53/04 , B01D53/0462 , B01D53/047 , B01D53/228 , B01D71/028 , B01D2253/108 , B01D2253/1085 , B01D2256/22 , B01D2257/504 , C01B39/46 , C10L3/104 , C10L2290/542 , Y02C10/08 , Y02C10/10 , Y02E50/346 , Y02P20/152
摘要： The present disclosure relates to the selective separation of carbon dioxide (CO2) from multi-component gas feedstreams containing CO2 utilizing a GME framework type zeolite substantially free of non-GME framework type material.
摘要翻译：本公开涉及使用基本上不含非GME骨架类型材料的GME骨架型沸石从含有CO 2的多组分气体进料流中二氧化碳（CO 2）的选择性分离。

6. 发明授权

US08906311B2 Process unit for flexible production of alkylate gasoline and distillate 有权
标题翻译：用于灵活生产烷基化汽油和馏出物的处理单元
公开(公告)号：US08906311B2
公开(公告)日：2014-12-09
申请号：US13875393
申请日：2013-05-02
申请人： Hye Kyung Cho Timken , Shawn Shlomo Winter , Howard Steven Lacheen , Sven Ivar Hommeltoft
发明人： Hye Kyung Cho Timken , Shawn Shlomo Winter , Howard Steven Lacheen , Sven Ivar Hommeltoft
IPC分类号： B01J8/00 , B01J19/00 , B01D3/00 , B01J31/02 , B01J31/14 , B01J31/40 , C10G29/20 , C10G45/58 , C10G50/00
CPC分类号： B01J19/004 , B01D3/009 , B01J31/0284 , B01J31/143 , B01J31/40 , B01J2219/00006 , B01J2219/00047 , C10G29/205 , C10G45/58 , C10G50/00 , C10G2300/1051 , C10G2300/1092 , C10G2300/305 , C10G2400/02
摘要： A process unit, comprising: a) an alkylation reactor; and b) a control system that enables the alkylation reactor to be operated in an alkylate mode and in a distillate mode; wherein the alkylation reactor can switch back and forth from operating in the alkylate mode to the distillate mode.
摘要翻译：一种处理单元，包括：a）烷基化反应器; 和b）使得烷基化反应器能够以烷基化模式和馏出模式操作的控制系统; 其中烷基化反应器可以来回切换为在烷基化模式下进行至馏出物模式。

7. 发明申请

US20130243672A1 PROCESS UNIT FOR FLEXIBLE PRODUCTION OF ALKYLATE GASOLINE AND DISTILLATE 有权
标题翻译：用于柔性生产烷基醇汽油和蒸馏的方法单元
公开(公告)号：US20130243672A1
公开(公告)日：2013-09-19
申请号：US13875393
申请日：2013-05-02
申请人： Hye Kyung Cho Timken , Shawn Shlomo Winter , Howard Steven Lacheen , Sven Ivar Hommeltoft
发明人： Hye Kyung Cho Timken , Shawn Shlomo Winter , Howard Steven Lacheen , Sven Ivar Hommeltoft
IPC分类号： B01J19/00
CPC分类号： B01J19/004 , B01D3/009 , B01J31/0284 , B01J31/143 , B01J31/40 , B01J2219/00006 , B01J2219/00047 , C10G29/205 , C10G45/58 , C10G50/00 , C10G2300/1051 , C10G2300/1092 , C10G2300/305 , C10G2400/02
摘要： A process unit, comprising: a) an alkylation reactor; and b) a control system that enables the alkylation reactor to be operated in an alkylate mode and in a distillate mode; wherein the alkylation reactor can switch back and forth from operating in the alkylate mode to the distillate mode.
摘要翻译：一种处理单元，包括：a）烷基化反应器; 和b）使得烷基化反应器能够以烷基化模式和馏出模式操作的控制系统; 其中烷基化反应器可以来回切换为在烷基化模式下进行至馏出物模式。

8. 发明授权

US09815043B2 Apparatus for reducing organic halide contamination in hydrocarbon products using a metal chloride 有权
公开(公告)号：US09815043B2
公开(公告)日：2017-11-14
申请号：US14690669
申请日：2015-04-20
申请人： Howard Steven Lacheen
发明人： Howard Steven Lacheen
IPC分类号： B01J19/00 , B01J19/24 , C10G29/00 , C10G29/06 , C10G29/12 , C07C2/00 , C07C2/54 , C07C2/56 , C07C2/58 , C07C2/60 , C07C7/12 , C07C7/148 , C07C7/00
CPC分类号： B01J19/245 , B01J2219/24 , C07C2/58 , C07C2/60 , C07C7/12 , C07C7/14858 , C07C2527/125 , C07C2531/26 , C10G29/12 , C10G2300/305 , C07C9/16
摘要： This application provides an apparatus for making a hydrocarbon with a reduced amount of an organic halide, comprising: a. a process unit comprising an effluent port, that produces and discharges the hydrocarbon comprising the organic halide; and b. a halide removal vessel with an inlet that feeds the hydrocarbon from the process unit, wherein the halide removal vessel comprises an anhydrous metal chloride and in which the hydrocarbon comprising the organic halide is contacted with the anhydrous metal chloride under anhydrous conditions to produce a contacted hydrocarbon having from 50-100 wt % of a total halide in the hydrocarbon removed.

9. 发明申请

US20160002542A1 DECOMPOSITION OF ORGANIC CHLORIDE IN ALKYLATE USING METALS AND ALLOYS 审中-公开
标题翻译：使用金属和合金分解有机氯化物在碱金属中的分解
公开(公告)号：US20160002542A1
公开(公告)日：2016-01-07
申请号：US14323302
申请日：2014-07-03
申请人： Howard Steven Lacheen
发明人： Howard Steven Lacheen
IPC分类号： C10G29/04 , C10L1/06 , C10L3/10 , C10G57/00 , C10L3/12
CPC分类号： C10G29/04 , B01D3/009 , C10G29/16 , C10G29/205 , C10G53/02 , C10G57/005 , C10G2300/202 , C10G2300/4087 , C10L1/06 , C10L3/101 , C10L3/12 , C10L2200/0423 , C10L2200/0492 , C10L2270/023 , C10L2290/543
摘要： Processes for decomposing organic chloride in a hydrocarbon stream may comprise contacting a hydrocarbon stream with a dechlorination element in a dechlorination zone under dechlorination conditions to provide a dechlorinated hydrocarbon product, wherein the dechlorination element may comprise a metal or metal alloy having a high surface area configuration. Such a dechlorination element may be disposed within one or more distillation columns and/or within a separate dechlorination vessel.
摘要翻译：用于在烃流中分解有机氯化物的方法可以包括在脱氯条件下在脱氯区将烃流与脱氯元件接触以提供脱氯烃产物，其中脱氯元件可以包含具有高表面积构型的金属或金属合金。这样的脱氯元件可以设置在一个或多个蒸馏塔内和/或在单独的脱氯容器内。

10. 发明授权

US08936768B2 Alkylation process unit for producing high quality gasoline blending components in two modes 有权
标题翻译：用于以两种模式生产高品质汽油调和组分的烷基化方法单元
公开(公告)号：US08936768B2
公开(公告)日：2015-01-20
申请号：US13551904
申请日：2012-07-18
申请人： Hye Kyung Cho Timken , Shawn Shlomo Winter , Howard Steven Lacheen , Sven Ivar Hommeltoft
发明人： Hye Kyung Cho Timken , Shawn Shlomo Winter , Howard Steven Lacheen , Sven Ivar Hommeltoft
IPC分类号： B01J8/08 , C10G29/20 , C07C2/58
CPC分类号： C10G29/205 , C07C2/58 , C07C2527/125 , C07C2531/02 , C10G2300/20 , C10G2300/202 , C10G2300/305 , C10G2400/02 , C07C9/16
摘要： We provide an alkylation process unit, comprising: a control system connected to an alkylation reactor, that enables the alkylation reactor to operate in both an alkylate mode that produces a gasoline blending component having a RON of 90 or higher and in a distillate mode that produces a second gasoline blending component having a RON of 85 or higher.
摘要翻译：我们提供烷基化处理单元，其包括：连接到烷基化反应器的控制系统，其使得烷基化反应器能够以产生具有90或更高RON的RON的汽油调和组分的烷基化模式和在产生 RON为85以上的第二汽油调和组分。

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