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    • 1. 发明申请
    • Production of hydrogen from water using a thermochemical copper-chlorine cycle
    • 使用热化学铜 - 氯循环从水生产氢气
    • US20100129287A1
    • 2010-05-27
    • US12292722
    • 2008-11-25
    • Kamiel Samy GabrielZholin WangGreg Naterer
    • Kamiel Samy GabrielZholin WangGreg Naterer
    • C01B3/08B01J7/02C25B9/00
    • B01J10/005B01J7/00B01J8/002B01J8/003B01J8/0453B01J8/0496B01J2208/00752B01J2219/00006C01B3/068C01B13/0207C25C1/12Y02E60/36
    • A system for producing hydrogen gas from water decomposition using a thermochemical CuCl cycle, the improvement comprising the use of an insulated hydrogen production reactor comprising a reaction chamber and a separation chamber; the reaction chamber having a hydrogen chloride gas inlet and a solid copper inlet; one or more levels provided in the reaction chamber, the number of which is dependant on production scale and pressure drop; each level comprising a perforated plate with associated filter media, the perforations of the plate and media being of decreasing size from top to bottom of the reaction chamber, and being sized to permit downward flow of the hydrogen gas and molten CuCl products, as well as the HCL gas reactant, and to prevent entrainment of solid copper in the molten CuCl; the separation chamber being located below the reaction chamber and being of greater cross section than the reaction chamber and comprising a first hydrogen removal and entrained copper removal zone and a second molten CuCl removal zone; removal of the reaction products being controlled so as to substantially decrease the amount of entrained copper in the molten CuCl; and the first zone having outlets for removal of hydrogen gas and entrained copper particles, with the second zone having an outlet for removal of molten CuCl.
    • 使用热化学CuCl循环从水分解产生氢气的系统,其改进包括使用包含反应室和分离室的绝热氢气生产反应器; 反应室具有氯化氢气体入口和固体铜入口; 在反应室中提供一个或多个水平,其数量取决于生产规模和压降; 每个级别包括具有相关过滤介质的多孔板,板和介质的穿孔从反应室的顶部到底部具有减小的尺寸,并且其尺寸允许氢气和熔融的CuCl产物向下流动,以及 HCL气体反应物,并防止在熔融的CuCl中夹带固体铜; 所述分离室位于所述反应室下方并且具有比所述反应室更大的横截面,并且包括第一除氢和夹带的铜去除区和第二熔融的CuCl去除区; 控制反应产物的去除以显着减少熔融的CuCl中夹带的铜的量; 并且第一区域具有用于除去氢气和夹带的铜颗粒的出口,其中第二区域具有用于除去熔融的CuCl的出口。