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1. 发明申请

US20150336862A1 CATALYTIC HYDROGENATION USING COMPLEXES OF BASE METALS WITH TRIDENTATE LIGANDS 有权
标题翻译：使用三元配体的碱金属复合物进行催化氢化
公开(公告)号：US20150336862A1
公开(公告)日：2015-11-26
申请号：US13587717
申请日：2012-08-16
申请人： Kalyan V. Vasudevan , Guoqi Zhang , Susan K. Hanson
发明人： Kalyan V. Vasudevan , Guoqi Zhang , Susan K. Hanson
IPC分类号： C07C29/17 , C07F15/06 , C07F5/04 , C07C67/303 , C07C51/36 , C07D211/46 , C07C41/20 , C07C41/18 , C07C29/145 , C07C41/01 , C07C17/354 , C07C45/62 , C07C209/52 , C07C5/03 , C07C5/05 , B01J31/24 , C07F15/04
CPC分类号： B01J31/2295 , B01J31/189 , B01J31/2476 , B01J2231/643 , B01J2231/645 , B01J2231/646 , B01J2531/0244 , B01J2531/845 , B01J2531/847 , C07C5/03 , C07C5/05 , C07C17/354 , C07C29/141 , C07C29/145 , C07C29/172 , C07C29/175 , C07C41/01 , C07C41/18 , C07C41/20 , C07C41/26 , C07C45/62 , C07C51/36 , C07C67/303 , C07C209/52 , C07C209/70 , C07C2531/14 , C07C2531/22 , C07C2531/28 , C07C2601/14 , C07C2601/16 , C07C2601/18 , C07C2602/08 , C07C2602/42 , C07C2603/12 , C07C2603/18 , C07D211/02 , C07D211/46 , C07F5/04 , C07F15/04 , C07F15/045 , C07F15/06 , C07F15/065 , Y02P20/52 , C07C43/23 , C07C33/20 , C07C33/22 , C07C33/24 , C07C35/38 , C07C69/24 , C07C53/126 , C07C31/125 , C07C33/46 , C07C43/04 , C07C35/32 , C07C43/205 , C07C49/403 , C07C211/27 , C07C211/48 , C07C25/13 , C07C15/073 , C07C15/02 , C07C15/085 , C07C11/02 , C07C13/26 , C07C13/64 , C07C13/20
摘要： Complexes of cobalt and nickel with tridentate ligand PNHPR are effective for hydrogenation of unsaturated compounds. Cobalt complex [(PNHPCy)Co(CH2SiMe3)]BArF4 (PNHPCy=bis[2-(dicyclohexylphosphino)ethyl]amine, BArF4=B(3,5-(CF3)2C6H3)4)) was prepared and used with hydrogen for hydrogenation of alkenes, aldehydes, ketones, and imines under mild conditions (25-60° C., 1-4 atm H2). Nickel complex [(PNHPCy)Ni(H)]BPh4 was used for hydrogenation of styrene and 1-octene under mild conditions. (PNPCy)Ni(H) was used for hydrogenating alkenes.
摘要翻译：钴和镍与三齿配体PNHPR的配合物对于不饱和化合物的氢化是有效的。钴配合物[（PNHPCy）Co（CH2SiMe3）] BArF4（PNHPCy =双[2-（二环己基膦基）乙基]胺，BArF 4 = B（3,5-（CF 3）2 C 6 H 3）4）的烯烃，醛，酮和亚胺在温和条件下（25-60℃，1-4atm H 2）。镍络合物[（PNHPCy）Ni（H）] BPh4用于在温和条件下苯乙烯和1-辛烯的氢化。（PNPCy）Ni（H）用于氢化烯烃。

2. 发明授权

US09434666B2 Catalytic hydrogenation using complexes of base metals with tridentate ligands 有权
标题翻译：使用贱金属配合物与三齿配体的催化氢化
公开(公告)号：US09434666B2
公开(公告)日：2016-09-06
申请号：US13587717
申请日：2012-08-16
申请人： Kalyan V. Vasudevan , Guoqi Zhang , Susan K. Hanson
发明人： Kalyan V. Vasudevan , Guoqi Zhang , Susan K. Hanson
IPC分类号： C07C29/145 , C07C67/303 , C07C51/36 , C07C41/18 , C07C41/01 , C07C41/20 , C07C45/62 , C07C209/52 , C07C5/03 , C07C5/05 , C07C231/24 , C07F15/04 , C07F15/06 , C07F5/04 , C07D211/46 , C07C29/17 , C07C17/354 , C07C29/141 , C07C41/26 , C07D211/02 , B01J31/18
CPC分类号： B01J31/2295 , B01J31/189 , B01J31/2476 , B01J2231/643 , B01J2231/645 , B01J2231/646 , B01J2531/0244 , B01J2531/845 , B01J2531/847 , C07C5/03 , C07C5/05 , C07C17/354 , C07C29/141 , C07C29/145 , C07C29/172 , C07C29/175 , C07C41/01 , C07C41/18 , C07C41/20 , C07C41/26 , C07C45/62 , C07C51/36 , C07C67/303 , C07C209/52 , C07C209/70 , C07C2531/14 , C07C2531/22 , C07C2531/28 , C07C2601/14 , C07C2601/16 , C07C2601/18 , C07C2602/08 , C07C2602/42 , C07C2603/12 , C07C2603/18 , C07D211/02 , C07D211/46 , C07F5/04 , C07F15/04 , C07F15/045 , C07F15/06 , C07F15/065 , Y02P20/52 , C07C43/23 , C07C33/20 , C07C33/22 , C07C33/24 , C07C35/38 , C07C69/24 , C07C53/126 , C07C31/125 , C07C33/46 , C07C43/04 , C07C35/32 , C07C43/205 , C07C49/403 , C07C211/27 , C07C211/48 , C07C25/13 , C07C15/073 , C07C15/02 , C07C15/085 , C07C11/02 , C07C13/26 , C07C13/64 , C07C13/20
摘要： Complexes of cobalt and nickel with tridentate ligand PNHPR are effective for hydrogenation of unsaturated compounds. Cobalt complex [(PNHPCy)Co(CH2SiMe3)]BArF4 (PNHPCy=bis[2-(dicyclohexylphosphino)ethyl]amine, BArF4=B(3,5-(CF3)2C6H3)4)) was prepared and used with hydrogen for hydrogenation of alkenes, aldehydes, ketones, and imines under mild conditions (25-60° C., 1-4 atm H2). Nickel complex [(PNHPCy)Ni(H)]BPh4 was used for hydrogenation of styrene and 1-octene under mild conditions. (PNPCy)Ni(H) was used for hydrogenating alkenes.
摘要翻译：钴和镍与三齿配体PNHPR的配合物对于不饱和化合物的氢化是有效的。钴配合物[（PNHPCy）Co（CH2SiMe3）] BArF4（PNHPCy =双[2-（二环己基膦基）乙基]胺，BArF 4 = B（3,5-（CF 3）2 C 6 H 3）4）的烯烃，醛，酮和亚胺在温和条件下（25-60℃，1-4atm H 2）。镍络合物[（PNHPCy）Ni（H）] BPh4用于在温和条件下苯乙烯和1-辛烯的氢化。（PNPCy）Ni（H）用于氢化烯烃。

3. 发明申请

US20090128367A1 Sensing ball 审中-公开
标题翻译：感球
公开(公告)号：US20090128367A1
公开(公告)日：2009-05-21
申请号：US12068286
申请日：2008-02-05
申请人： Guoqi Zhang , Xianbin Song , Zheming Li
发明人： Guoqi Zhang , Xianbin Song , Zheming Li
IPC分类号： H03K17/94 , H03M11/00
CPC分类号： A63H33/005
摘要： The present invention provides a sensing ball comprising a ball body on which several sensors are mounted, and in the ball body are mounted motors, an eccentric device driven by the motor and a controller for controlling rotation of the eccentric device, in which the sensors are connected to the controller. When a moving object approaches the sensing ball, the sensors generate sensing signals and input the sensing signals into the controller, and the controller controls rotation of the eccentric device and drives the ball body to roll back and forth in a specified direction or keeps it static based on the sensing signals. The sensing ball according to the present invention can realize a relatively strong interaction with a moving object, for example, when a child approaches the sensing ball, the sensing ball can move toward the direction far from the child, therefore stimulating his/her curiosity and attracting him/her to go ahead or creep so that the child may learn to walk and creep in this way.
摘要翻译：本发明提供了一种感测球，其包括安装有多个传感器的球体，并且在球体中安装有电动机，由电动机驱动的偏心装置和用于控制偏心装置的旋转的控制器，其中传感器是连接到控制器。当移动物体接近感测球时，传感器产生感测信号并将感测信号输入到控制器中，并且控制器控制偏心装置的旋转并驱动球体在指定方向上来回或保持静止基于感测信号。根据本发明的感测球可以实现与移动物体的相对强的相互作用，例如当孩子接近感测球时，感测球可以朝着远离孩子的方向移动，因此刺激他/她的好奇心吸引他/她前进或爬行，以便孩子可以学会以这种方式走路和爬行。

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