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    • 2. 发明授权
    • Silicon polyethers and a method of producing the same
    • 硅聚醚及其制备方法
    • US08198361B2
    • 2012-06-12
    • US12694636
    • 2010-01-27
    • Benjamin FalkKalman KoczoAntonio Palumbo
    • Benjamin FalkKalman KoczoAntonio Palumbo
    • C08L83/00C08L83/04C07F7/02
    • C08G65/336C07F7/081C07F7/0838
    • The present invention provides a non-crosslinked silicon polyether composition comprising at least one compound with the following formula; [(R1O)(C2H4O)a(C3H6O)b(C4H8O)c]dR2(R3)e wherein R1 is a monovalent radical defined as MgMAhMBiMHjMEkDlDHmDEnToTHpTEqQr M=R4R5R6SiO1/2; MA=R7R8R9SiR10; MB=[(R11R12R13Si)sR14]tSi(R15)u(R16)vR17 MH=R18Si(R19)(R20)O1/2; ME=R21R22RESiO1/2; D=R23R24SiO2/2; DH=R25Si(R26)O2/2; DE=R27RESiO2/2; T=R28SiO3/2; TH=R29SiO3/2; TE=RESiO2/2; and Q=SiO4/2; R2 and R14 are polyvalent linear or branched; R3 is —(C2H4O)(C3H6O)b(C4H8O)c—R30 or R1; R30 is a monovalent saturated; R4, R5, R6, R7, R8, R9, R11, R12, R13, R15, R16, R19, R20, R21, R22, R23, R24, R26, R27, and, R28 are monovalent hydrocarbon radicals having from 1 to about 10 carbons; R10, R17, R18, R25 and R29 are divalent hydrocarbon radicals having 1 to about 25 carbons; RE is —R32—(C2H4O)a(C3H6O)b(C4H8O)c—R33; R32 is a divalent hydrocarbon radical having 1 to about 60 carbons; R33 is a monovalent hydrocarbon radical having 1 to about 20 carbons; h is 0 or 1 subject to the limitation if h is 1 then g+i+j+k+l+m+n+o+p+q+r=0; subscript d is 1
    • 本发明提供一种非交联硅聚醚组合物,其包含至少一种具有下式的化合物: [(R1O)(C2H4O)a(C3H6O)b(C4H8O)c] dR2(R3)e其中R1是定义为MgMAhMBiMHjMEkD1DHmDEnToTHpTEqQrM = R4R5R6SiO1 / 2的一价基团; MA = R7R8R9SiR10; MB = [(R11R12R13Si)sR14] tSi(R15)u(R16)vR17 MH = R18Si(R19)(R20)O1 / 2; ME = R21R22RESiO1 / 2; D = R23R24SiO2 / 2; DH = R25Si(R26)O2 / 2; DE = R27RESiO2 / 2; T = R28SiO3 / 2; TH = R29SiO3 / 2; TE = RESiO2 / 2; 和Q = SiO4 / 2; R2和R14是多价直链或支链的; R3是 - (C2H4O)(C3H6O)b(C4H8O)c-R30或R1; R30是一价饱和的; R4,R5,R6,R7,R8,R9,R11,R12,R13,R15,R16,R19,R20,R21,R22,R23,R24,R26,R27和R28均为1〜 10个碳; R 10,R 17,R 18,R 25和R 29是具有1至约25个碳的二价烃基; RE为-R32-(C2H4O)a(C3H6O)b(C4H8O)c-R33; R32是具有1至约60个碳的二价烃基; R33是具有1至约20个碳的一价烃基; h为0或1,如果h为1,则g + i + j + k + l + m + n + o + p + q + r = 0; 下标d是1
    • 6. 发明申请
    • BIODEGRADABLE POLYORGANOSILOXANE DEMULSIFIER COMPOSITION AND METHOD FOR MAKING THE SAME
    • 可生物降解的聚羟基烷氧基化合物组合物及其制备方法
    • US20120329887A1
    • 2012-12-27
    • US13165085
    • 2011-06-21
    • Monjit PHUKANAnubhav SaxenaMayank Kumar DubeyAntonio PalumboKalman Koczo
    • Monjit PHUKANAnubhav SaxenaMayank Kumar DubeyAntonio PalumboKalman Koczo
    • B01D17/00
    • C08L83/12B01D17/047C08G77/46C10G33/04
    • There is provided herein a demulsifying composition comprising at least one polyorganosiloxane compound having the general formula (I): M1aM2bD1cD2dT1eT2fQg  (I) wherein: M1=R1R2R3SiO1/2, M2=R4R5RLSiO1/2, D1=R6R7SiO2/2, D2=R8RLSiO2/2, T1=R9SiO3/2, T2=RLSiO3/2, Q=SiO4/2, where R1, R2, R3, R4, R5, R6, R7, R8 and R9 are each independently chosen from monovalent alkyl, aryl or aralkyl hydrocarbon radicals, or chosen from RP; RP is a monovalent polyether radical independently of the general formula (II): —(CnH2n)—O—(C2H4O)o—(C3H6O)p—(C4H8O)q—R10  (II) RL is a monovalent radical independently chosen from the general formula (III): —X—O—(C2H4O)r—(C3H6O)s—(C4H8O)t—{C(O)CuH2uO}v—R11  (III). There is also provided herein a method for separating emulsions comprising combining the components of the demulsification composition into a mixture; allowing the mixture to separate into at least two phases and separating said at least two phases from each other.
    • 本文提供了包含至少一种具有通式(I)的聚有机硅氧烷化合物的破乳组合物:M1aM2bD1cD2dT1eT2fQg(I)其中:M1 = R1R2R3SiO1 / 2,M2 = R4R5RLSiO1 / 2,D1 = R6R7SiO2 / 2,D2 = R8RLSiO2 / 2 ,T1 = R9SiO3 / 2,T2 = RLSiO3 / 2,Q = SiO4 / 2,其中R1,R2,R3,R4,R5,R6,R7,R8和R9各自独立地选自一价烷基,芳基或芳烷基烃基 ,或从RP中选择; RP是独立于通式(II)的单价聚醚基: - (C n H 2n)-O-(C 2 H 4 O)O-(C 3 H 6 O)p - (C 4 H 8 O)q -R 10(II)RL是独立地选自 通式(III):-X-O-(C 2 H 4 O)r - (C 3 H 6 O)s - (C 4 H 8 O)t - {C(O)Cu H 2uO} v -R 11(III)。 本文还提供了用于分离乳液的方法,其包括将破乳组合物的组分混合成混合物; 允许混合物分离成至少两相,并将所述至少两相彼此分离。
    • 7. 发明授权
    • Biodegradable polyorganosiloxane demulsifier composition and method for making the same
    • 可生物降解聚有机硅氧烷破乳剂组合物及其制备方法
    • US08779012B2
    • 2014-07-15
    • US13165085
    • 2011-06-21
    • Monjit PhukanAnubhav SaxenaMayank Kumar DubeyAntonio PalumboKalman Koczo
    • Monjit PhukanAnubhav SaxenaMayank Kumar DubeyAntonio PalumboKalman Koczo
    • B01D17/00
    • C08L83/12B01D17/047C08G77/46C10G33/04
    • There is provided herein a demulsifying composition comprising at least one polyorganosiloxane compound having the general formula (I): M1aM2bD1cD2dT1eT2fQg  (I) wherein: M1=R1R2R3SiO1/2, M2=R4R5RLSiO1/2, D1=R6R7SiO2/2, D2=R8RLSiO2/2, T1=R9SiO3/2, T2=RLSiO3/2, Q=SiO4/2, where R1, R2, R3, R4, R5, R6, R7, R8 and R9 are each independently chosen from monovalent alkyl, aryl or aralkyl hydrocarbon radicals, or chosen from RP; RP is a monovalent polyether radical independently of the general formula (II): —(CnH2n)—O—(C2H4O)o—(C3H6O)p—(C4H8O)q—R10  (II) RL is a monovalent radical independently chosen from the general formula (III): —X—O—(C2H4O)r—(C3H6O)s—(C4H8O)t—{C(O)CuH2uO}v—R11  (III) There is also provided herein a method for separating emulsions comprising combining the components of the demulsification composition into a mixture; allowing the mixture to separate into at least two phases and separating said at least two phases from each other.
    • 本文提供了包含至少一种具有通式(I)的聚有机硅氧烷化合物的破乳组合物:M1aM2bD1cD2dT1eT2fQg(I)其中:M1 = R1R2R3SiO1 / 2,M2 = R4R5RLSiO1 / 2,D1 = R6R7SiO2 / 2,D2 = R8RLSiO2 / 2 ,T1 = R9SiO3 / 2,T2 = RLSiO3 / 2,Q = SiO4 / 2,其中R1,R2,R3,R4,R5,R6,R7,R8和R9各自独立地选自一价烷基,芳基或芳烷基烃基 ,或从RP中选择; RP是独立于通式(II)的单价聚醚基: - (C n H 2n)-O-(C 2 H 4 O)O-(C 3 H 6 O)p - (C 4 H 8 O)q -R 10(II)RL是独立地选自 通式(III):-X-O-(C 2 H 4 O)r - (C 3 H 6 O)s - (C 4 H 8 O)t- {C(O)Cu H 2u O} v-R 11(III)本文还提供了分离乳液的方法, 将破乳组合物的组分混合成混合物; 允许混合物分离成至少两相,并将所述至少两相彼此分离。
    • 8. 发明申请
    • Method for demulsifying
    • 破乳方法
    • US20070299143A1
    • 2007-12-27
    • US11472727
    • 2006-06-22
    • Kalman KoczoSabine Isabelle AzouaniBenjamin Falk
    • Kalman KoczoSabine Isabelle AzouaniBenjamin Falk
    • B01D17/05C09K3/00
    • B01D17/047C08G77/46C10G33/04C10L1/285
    • The invention relates to a method for separating emulsions of oil and water, the method comprising incorporating a demulsifying-effective amount of a silicone demulsifier into an emulsion comprising an oil phase and an aqueous phase, the silicone demulsifier having a molecular structure comprising a polysiloxane backbone of at least two siloxane units covalently bound to (i) one or more alkylene oxide groups comprising one or more alkylene oxide units independently having one to five carbon atoms, and (ii) one or more oxirane-containing and/or oxetane-containing groups, wherein said oxirane or oxetane is optionally ring-opened by reaction with a chemical or group capable of ring-opening an oxirane or oxetane ring, respectively, and wherein a solid filler is substantially excluded from the silicone demulsifier and emulsion. The invention also relates to compositions containing the above-described demulsifier and the water and oil phases of an emulsion.
    • 本发明涉及一种用于分离油和水的乳液的方法,所述方法包括将破乳有效量的硅氧烷破乳剂掺入包含油相和水相的乳液中,所述硅氧烷破乳剂具有包含聚硅氧烷主链的分子结构 共价键合至少两个硅氧烷单元(i)一个或多个包含一个或多个独立地具有1-5个碳原子的氧化烯单元的环氧烷基团,和(ii)一种或多种含环氧乙烷和/或含氧杂环丁烷基团 其中所述环氧乙烷或氧杂环丁烷分别通过与能够开环环氧乙烷或氧杂环丁烷环的化学或基团反应而任意开环,并且其中基本上从硅氧烷破乳剂和乳液中排除固体填料。 本发明还涉及含有上述破乳剂和乳液的水相和油相的组合物。
    • 9. 发明授权
    • Method for demulsifying
    • 破乳方法
    • US07745501B2
    • 2010-06-29
    • US11472727
    • 2006-06-22
    • Kalman KoczoSabine Isabelle AzouaniBenjamin Falk
    • Kalman KoczoSabine Isabelle AzouaniBenjamin Falk
    • B01D17/05C10G33/04
    • B01D17/047C08G77/46C10G33/04C10L1/285
    • The invention relates to a method for separating emulsions of oil and water, the method comprising incorporating a demulsifying-effective amount of a silicone demulsifier into an emulsion comprising an oil phase and an aqueous phase, the silicone demulsifier having a molecular structure comprising a polysiloxane backbone of at least two siloxane units covalently bound to (i) one or more alkylene oxide groups comprising one or more alkylene oxide units independently having one to five carbon atoms, and (ii) one or more oxirane-containing and/or oxetane-containing groups, wherein said oxirane or oxetane is optionally ring-opened by reaction with a chemical or group capable of ring-opening an oxirane or oxetane ring, respectively, and wherein a solid filler is substantially excluded from the silicone demulsifier and emulsion. The invention also relates to compositions containing the above-described demulsifier and the water and oil phases of an emulsion.
    • 本发明涉及一种用于分离油和水的乳液的方法,所述方法包括将破乳有效量的硅氧烷破乳剂掺入包含油相和水相的乳液中,所述硅氧烷破乳剂具有包含聚硅氧烷主链的分子结构 共价键合至少两个硅氧烷单元(i)一个或多个包含一个或多个独立地具有1-5个碳原子的氧化烯单元的环氧烷基团,和(ii)一种或多种含环氧乙烷和/或含氧杂环丁烷基团 其中所述环氧乙烷或氧杂环丁烷分别通过与能够开环环氧乙烷或氧杂环丁烷环的化学或基团反应而任意开环,并且其中基本上从硅氧烷破乳剂和乳液中排除固体填料。 本发明还涉及含有上述破乳剂和乳液的水相和油相的组合物。