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1. 发明申请

US20140197032A1 Anion Exchange Block Copolymers, Their Manufacture And Their Use 有权
标题翻译：阴离子交换嵌段共聚物及其制备及其应用
公开(公告)号：US20140197032A1
公开(公告)日：2014-07-17
申请号：US14154146
申请日：2014-01-13
申请人： Kraton Polymers U.S. LLC
发明人： Carl Lesley Willis , Irwan Hidajat , Mike Heniff
IPC分类号： B01D71/82 , B01D61/44
CPC分类号： B01D71/82 , B01D53/228 , B01D61/44 , B01D65/10 , C08F8/02 , C08F8/24 , C08F8/30 , C08F8/40 , H01M8/1023 , Y02P70/56 , C08F297/00 , C08F297/04
摘要： Selectively amino- or phosphino-functionalized block copolymers, and their preparation, for use as anion exchange membrane materials. The selectively functionalized block copolymers have at least two end blocks A each of which are substantially free of amino- or phosphino-functional groups, and have at least one interior block D which comprises on average at least one amino- or phosphino-functionalized polymer unit of formula (I) wherein Z is nitrogen or phosphorous; R1 is hydrogen or alkyl; R2 is hydrogen or is tertiary alkyl; R each independently, is hydrogen or is alkyl optionally substituted by a moiety -(A1-NRa)xRb; or two R groups, together with the Z to which they are bonded, form an optionally substituted ring; x is 1, 2 or 3; A1 is straight chain alkylene optionally substituted by one or more methyl and/or ethyl groups; and Ra and Rb, each independently, is hydrogen or alkyl; or a corresponding onium salt.
摘要翻译：选择性氨基或膦官能化嵌段共聚物及其制备，用作阴离子交换膜材料。选择性官能化的嵌段共聚物具有至少两个端基A，其各自基本上不含氨基或膦官能团，并且具有至少一个内部嵌段D，其至少包含至少一个氨基或膦官能化聚合物单元式（I）其中Z是氮或磷; R1是氢或烷基; R2是氢或是叔烷基; R各自独立地为氢或任选被部分 - （Al-NR a）x R b取代的烷基; 或两个R基团与它们所键合的Z一起形成任选取代的环; x为1,2或3; A1是任选被一个或多个甲基和/或乙基取代的直链亚烷基; 和R a和R b各自独立地是氢或烷基; 或相应的鎓盐。

2. 发明授权

US10022680B2 Anion exchange block copolymers, their manufacture and their use 有权
公开(公告)号：US10022680B2
公开(公告)日：2018-07-17
申请号：US14154146
申请日：2014-01-13
申请人： Kraton Polymers U.S. LLC
发明人： Carl Lesley Willis , Irwan Hidajat , Mike Heniff
IPC分类号： B01D61/44 , B01D71/82 , B01D65/10 , H01M8/1023 , C08F8/02 , C08F8/24 , C08F8/30 , C08F8/40 , B01D53/22
摘要： Selectively amino- or phosphino-functionalized block copolymers, and their preparation, for use as anion exchange membrane materials. The selectively functionalized block copolymers have at least two end blocks A each of which are substantially free of amino- or phosphino-functional groups, and have at least one interior block D which comprises on average at least one amino- or phosphino-functionalized polymer unit of formula (I) wherein Z is nitrogen or phosphorous; R1 is hydrogen or alkyl; R2 is hydrogen or is tertiary alkyl; R each independently, is hydrogen or is alkyl optionally substituted by a moiety -(A1-NRa)xRb; or two R groups, together with the Z to which they are bonded, form an optionally substituted ring; x is 1, 2 or 3; A1 is straight chain alkylene optionally substituted by one or more methyl and/or ethyl groups; and Ra and Rb, each independently, is hydrogen or alkyl; or a corresponding onium salt.

3. 发明授权

US10066098B2 Styrenic block copolymer compositions 有权
公开(公告)号：US10066098B2
公开(公告)日：2018-09-04
申请号：US15268166
申请日：2016-09-16
申请人： KRATON POLYMERS U.S. LLC
发明人： John E. Flood , Kathryn J. Wright , Xavier D. Muyldermans , Mike Heniff , Carl L. Willis , Yonghua Zhou , Aaron Brothers
IPC分类号： C08L53/02 , C09J153/02 , C08F287/00 , C08L91/00
CPC分类号： C08L53/025 , C08F8/04 , C08F8/46 , C08F287/00 , C08L91/00 , C08L2205/025 , C08L2205/035 , C08L2205/06 , C08L2207/322 , C09J153/025 , C08F222/06 , C08L23/14 , C08F297/044
摘要： This disclosure relates to a block copolymer composition comprising a tetra-branched block copolymer (IV) having a true number average molecular weight of 40,000 to 120,000 represented by the general formula (A-B)4X; a tri-branched block copolymer (III) having a true number average molecular weight of from 30,000 to 90,000 represented by the general formula (A-B)3X; di-branched block copolymer (II) having a true number average molecular weight of from 20,000 to 60,000 represented by the general formula (A-B)2X; and a linear diblock copolymer (I) having a true number average molecular weight of from 10,000 to 30,000 represented by the general formula A-B; where A represents a polymer block of a mono alkenyl arene; B represents a polymer block of a conjugated diene, wherein the B has a true number average molecular weight ranging from 7,000 to 20,000 g/mol; and X represents the residue of an alkoxy silane coupling agent.

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