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1. 发明申请

US20030059684A1 Nonaqueous electrolyte battery and nonaqueous electrolytic solution 失效
标题翻译：非水电解质电池和非水电解液
公开(公告)号：US20030059684A1
公开(公告)日：2003-03-27
申请号：US10233528
申请日：2002-09-04
申请人： Kabushiki Kaisha Toshiba
发明人： Norio Takami , Haruchika Ishii
IPC分类号： H01M004/46 , H01M004/38 , H01M010/40 , H01M004/58 , H01M004/52 , H01M004/50 , H01M004/48
CPC分类号： H01M10/0569 , H01M4/38 , H01M4/381 , H01M4/46 , H01M4/48 , H01M4/50 , H01M4/505 , H01M4/52 , H01M4/525 , H01M4/58 , H01M4/5825 , H01M6/166 , H01M2300/0025 , H01M2300/0037
摘要： The present invention achieves an increased capacity and prolonged life of nonaqueous electrolyte batteries of the type in which light metals, such as magnesium, calcium or aluminum, are used in the negative electrode. The present invention also provides a thermally stable nonaqueous electrolytic solution for use with such batteries. The nonaqueous electrolyte battery in accordance with the present invention includes a positive electrode; a negative electrode containing at least one element selected from the group consisting of aluminum, calcium and magnesium; and a nonaqueous electrolytic solution composed of a mixed solvent of an organic solvent and an alkyl sulfone having a structure represented by R1R2SO2, where R1 and R2 are each independently an alkyl group, and at least one type of salt selected from the group consisting of aluminum salt, calcium salt and magnesium salt. The organic solvent is capable of dissolving the alkyl sulfone along with at least one type of salt selected from the group consisting of aluminum salt, calcium salt and magnesium salt.
摘要翻译：本发明实现了在负极中使用诸如镁，钙或铝的轻金属的非水电解质电池的增加的容量和延长的使用寿命。本发明还提供了一种与这种电池一起使用的热稳定的非水电解液。根据本发明的非水电解质电池包括正电极; 含有选自铝，钙和镁的至少一种元素的负极; 以及由有机溶剂和具有由R 1 R 2 SO 2表示的结构的烷基砜的混合溶剂组成的非水电解液，其中R 1和R 2各自独立地为烷基，以及至少一种选自铝盐，钙盐和镁盐。有机溶剂能够与烷基砜一起溶解至少一种选自铝盐，钙盐和镁盐的盐。

2. 发明申请

US20030049540A1 Nonaqueous liquid electrolyte and nonaqueous liquid electrolyte secondary battery 失效
公开(公告)号：US20030049540A1
公开(公告)日：2003-03-13
申请号：US10083372
申请日：2002-02-27
申请人： KABUSHIKI KAISHA TOSHIBA
发明人： Tatsuoki Kohno , Norio Takami
IPC分类号： H01M010/40
CPC分类号： H01M10/0566 , H01M2/0207 , H01M2/0287 , H01M6/168 , H01M10/052 , H01M2300/0037 , H01M2300/0085 , Y10T29/49108
摘要： Disclosed is a nonaqueous liquid electrolyte comprising a nonaqueous solvent, an electrolyte dissolved in the nonaqueous solvent and a macromolecular material added to the nonaqueous solvent. The nonaqueous liquid electrolyte is a fluid having a viscosity at 20null C. of 7 cP to 30,000 cP. The nonaqueous liquid electrolyte suppresses leakage, ensures high discharge characteristics, reduces the unevenness of liquid electrolyte, and lessens the change of electrodes and the change in battery resistivity.

3. 发明申请

US20030228521A1 Gel electrolyte precursor and chemical battery 失效
标题翻译：凝胶电解质前体和化学电池
公开(公告)号：US20030228521A1
公开(公告)日：2003-12-11
申请号：US10423922
申请日：2003-04-28
申请人： KABUSHIKI KAISHA TOSHIBA
发明人： Shuzi Hayase , Norio Takami , Hirohisa Miyamoto , Satoshi Mikoshiba
IPC分类号： H01M010/40
CPC分类号： H01M10/052 , H01M6/162 , H01M6/181 , H01M6/22 , H01M10/0565 , H01M2300/0085
摘要： The present invention provides a chemical battery, comprising a positive electrode, a negative electrode, and a gel electrolyte containing a crosslinked body and an electrolyte, the crosslinked body being obtained by crosslinking at least one compound selected from the group consisting of an epoxy compound having an alicyclic structure and at least one epoxy group in a single molecule and an alicyclic epoxy resin.
摘要翻译：本发明提供一种化学电池，其包含正极，负极和含有交联体和电解质的凝胶电解质，所述交联体通过交联至少一种选自以下的化合物获得：单分子中的脂环结构和至少一个环氧基和脂环族环氧树脂。

4. 发明申请

US20030124426A1 Nonaqueous electrolyte battery 有权
标题翻译：非水电解液电池
公开(公告)号：US20030124426A1
公开(公告)日：2003-07-03
申请号：US10329418
申请日：2002-12-27
申请人： KABUSHIKI KAISHA TOSHIBA
发明人： Hiroki Inagaki , Norio Takami , Tatsuoki Kohno , Tomokazu Morita
IPC分类号： H01M004/58
CPC分类号： H01M10/0525 , H01M4/13 , H01M4/131 , H01M4/136 , H01M4/485 , H01M4/505 , H01M4/525 , H01M4/58 , H01M2004/021 , H01M2004/027
摘要： It is intended to provide a nonaqueous electrolyte battery that satisfies both of a large discharge capacity and a superior cycle life characteristic by developing a novel negative electrode material. A nonaqueous electrolyte battery uses a negative electrode active material that is a compound expressed by Formula (1): A2MXynullnull(1) where A is at least one element selected from the alkali metals, M is at least one element selected from the group consisting of Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Ru, Rh, Pd, Os, Ir, Pt, and Mg, X is at least one element selected from the group consisting of B, N, Al, Si, P, Ga, Ge, As, In, Sn, Sb, Pb, and Bi, 0nullznull20, and 0.2nullynull6.
摘要翻译：本发明提供一种通过显影新颖的负极材料来满足放电容量大和循环寿命特性优异的非水电解质电池。非水电解质电池使用由式（1）表示的化合物的负极活性物质：A2MXy（1）其中A为选自碱金属中的至少一种元素，M为选自以下的至少一种元素： Ti，V，Cr，Mn，Fe，Co，Ni，Cu，Ru，Rh，Pd，Os，Ir，Pt和Mg，X是选自B，N，Al，Si ，P，Ga，Ge，As，In，Sn，Sb，Pb和Bi，0 <= z <= 20，0.2 <= y <= 6。

5. 发明申请

US20030118913A1 Nonaqueous electrolyte secondary battery 有权
公开(公告)号：US20030118913A1
公开(公告)日：2003-06-26
申请号：US10279077
申请日：2002-10-24
申请人： KABUSHIKI KAISHA TOSHIBA
发明人： Norio Takami , Hiroyuki Hasebe , Takahisa Ohsaki , Motoya Kanda
IPC分类号： H01M010/40 , H01M004/58 , H01M004/62
CPC分类号： H01M10/0587 , H01M2/0275 , H01M2/168 , H01M4/13 , H01M4/131 , H01M4/133 , H01M4/587 , H01M4/80 , H01M6/10 , H01M10/0431 , H01M10/0525 , H01M10/0569 , H01M2002/0297 , H01M2010/4292 , H01M2300/004 , Y02E60/122
摘要： The present invention provides a nonaqueous electrolyte secondary battery, comprising an electrode group including a positive electrode, a negative electrode including a material for absorbing-desorbing lithium ions, and a separator arranged between the positive electrode and the negative electrode, a nonaqueous electrolyte impregnated in the electrode group and including a nonaqueous solvent and a lithium salt dissolved in the nonaqueous solvent, and a jacket for housing the electrode group and having a thickness of 0.3 mm or less, wherein the nonaqueous solvent null-butyrolactone in an amount larger than 50% by volume and not larger than 95% by volume based on the total amount of the nonaqueous solvent.

6. 发明申请

US20020068222A1 Electric cell 失效
标题翻译：电池
公开(公告)号：US20020068222A1
公开(公告)日：2002-06-06
申请号：US09964460
申请日：2001-09-28
申请人： Kabushiki Kaisha Toshiba
发明人： Haruchika Ishii , Norio Takami , Tomokazu Morita , Mitsuo Kasori
IPC分类号： H01M010/26 , H01M004/46
CPC分类号： H01M6/045 , H01M4/463 , H01M4/628 , H01M6/06
摘要： An electric cell using aluminum in a negative electrode has a positive electrode, the negative electrode containing aluminum or aluminum alloy, and an electrolyte arranged between the positive electrode and the negative electrode. The electrolyte includes: at least one ion selected from a group of a sulfate ion (SO42null) and a nitrate ion (NO3null); and an additive. The additive is selected from an organic acid, a salt of the organic acid, an hydrate of the organic acid, an ester of the organic acid, an ion of the organic acid, and derivatives thereof. Thus, the electric cell of the present invention using aluminum in a negative electrode allows the improvements in the voltage and the capacity of the cell as the generation of gas depending on the self-discharge can be prevented.
摘要翻译：在负极中使用铝的电池具有正极，负极含有铝或铝合金，以及配置在正极和负极之间的电解质。电解质包括：选自硫酸根离子（SO42-）和硝酸根离子（NO3-）的至少一种离子; 和添加剂。添加剂选自有机酸，有机酸的盐，有机酸的水合物，有机酸的酯，有机酸的离子及其衍生物。因此，在负极中使用铝的本发明的电池允许可以防止根据自放电产生气体的电池的电压和容量的改善。

7. 发明申请

US20010046629A1 Battery with nonaqueous electrolyte 有权
标题翻译：电池与非水电解质
公开(公告)号：US20010046629A1
公开(公告)日：2001-11-29
申请号：US09797883
申请日：2001-03-05
申请人： Kabushiki Kaisha Toshiba
发明人： Hiroki Inagaki , Norio Takami
IPC分类号： H01M004/40 , H01M004/58 , H01M004/62
CPC分类号： H01M4/134 , H01M4/131 , H01M4/38 , H01M4/46 , H01M10/052
摘要： The development of a novel negative electrode material has led to the provision of a battery with a nonaqueous electrolyte which has a combination of a high discharge capacity with excellent cycling characteristics. The battery with a nonaqueous electrolyte comprises: a positive electrode; a negative electrode having a negative electrode active material capable of occluding and releasing an alkali metal; and a nonaqueous electrolyte. The negative electrode active material contains at least one element selected from the group consisting of group 4B elements and group 5B elements and has at least one crystal structure selected from the group consisting of BiF3 structure, Cu2MnAl structure, and AgAsMg structure. And the negative electrode active material contains at least one element selected from the group consisting of Al, Si, Ge, Sn, P, Sb and Bi and has at least one crystal structure selected from the group consisting of BiF3 structure, Cu2MnAl structure, and AgAsMg structure.
摘要翻译：导致新型负极材料的发展导致提供具有高放电容量和优异的循环特性组合的非水电解质的电池。具有非水电解质的电池包括：正电极; 具有能够吸留和释放碱金属的负极活性物质的负极; 和非水电解质。负极活性物质含有选自4B族元素和5B族元素中的至少一种元素，并且具有选自BiF3结构，Cu2MnAl结构和AgAsMg结构中的至少一种晶体结构。负极活性物质含有选自Al，Si，Ge，Sn，P，Sb，Bi中的至少一种元素，并且具有选自BiF 3结构，Cu 2 Mnn结构和 AgAsMg结构。

8. 发明申请

US20010028979A1 Aluminum battery 有权
标题翻译：铝电池
公开(公告)号：US20010028979A1
公开(公告)日：2001-10-11
申请号：US09793877
申请日：2001-02-28
申请人： KABUSHIKI KAISHA TOSHIBA
发明人： Norio Takami
IPC分类号： H01M004/46 , H01M002/02 , H01M004/66 , H01M006/04
CPC分类号： H01M6/045 , H01M4/38 , H01M4/46 , H01M4/463 , H01M4/66 , H01M4/661 , H01M4/663 , H01M6/06
摘要： There is provided an aluminum battery which comprises a positive electrode, a negative electrode containing at least one kind of active material selected from the group consisting of aluminum metal and aluminum alloys, and an electrolyte containing a halogen ion and at least one kind of ion selected from the group consisting of sulfate ion (SO42null) and nitrate ion (NO3null).
摘要翻译：提供了一种铝电池，其包括正极，含有选自铝金属和铝合金中的至少一种活性物质的负极和选自卤素离子和至少一种离子的电解质由硫酸根离子（SO42-）和硝酸根离子（NO3-）组成。

9. 发明申请

US20030134198A1 Negative electrode material, negative electrode, nonaqueous electrolyte battery and method of manufacturing a negative electrode material 审中-公开
标题翻译：负极材料，负极，非水电解质电池以及负极材料的制造方法
公开(公告)号：US20030134198A1
公开(公告)日：2003-07-17
申请号：US10256046
申请日：2002-09-27
申请人： KABUSHIKI KAISHA TOSHIBA
发明人： Takao Sawa , Toshiya Sakamoto , Tatsuoki Kono , Norio Takami , Shinsuke Matsuno
IPC分类号： H01M004/58 , C01B033/00 , C01B033/08
CPC分类号： H01M4/0485 , H01M4/0471 , H01M4/13 , H01M4/139 , H01M4/364 , H01M4/38 , H01M4/386 , H01M4/405 , H01M4/463 , H01M4/466 , H01M4/58 , H01M4/5805 , H01M10/0525 , H01M10/0565 , H01M2004/021 , H01M2004/027 , H01M2300/0085
摘要： According to the present invention, a negative electrode material is provided. The negative electrode material is capable of storing and releasing lithium, and exhibits at least one peak of heat generation in the range of 200null C. to 450null C. in the differential scanning calorimetry (DSC) at a temperature rise speed of 10null C./min. and a peak derived from a crystalline phase in the X-ray diffraction.
摘要翻译：根据本发明，提供负极材料。负极材料能够储存和释放锂，并且在差示扫描量热法（DSC）中以10°的升温速度在200℃至450℃的范围内显示出至少一个发热峰值 C./min。和衍生自X射线衍射中的结晶相的峰。

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